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| 1 | Anomaly Models of Spatial Structures for Copper-Molybdenum Ore Deposits and their Application显示文摘This paper discusses the enrichment and depletion regularities for porphyry copper-molybdenum ore deposits in different regions and varied deposit genetic types in the same area, taking three porphyry copper-molybdenum ore deposits (i.e., the Chengmenshan in Jiangxi, Wunugetushan in Inner Mongolia, Baishantang in Gansu) and two copper deposits in Gansu Province (the Huitongshan skarn deposit and Gongpoquan composite deposit) as case studies. The results show that porphyry Cu-Mo deposits or skarn copper deposits include both enrichment of the ore-forming elements and associated elements, and depletion of some lithophile dispersed elements, rare earth elements (REE) and some major elements. And the depleted elements vary with deposits, having generality and their own features. On a deposit scale, the positive anomalies of enriched elements and negative anomalies of depleted elements follow in a sequence to comprise regular anomaly models of spatial structures. The exploration in the Tongchang deposit in Jiangxi and Huitongshan deposit in Gansu suggests that anomaly models play a key role in the identification of mineral occurrences and deposits compared to one single enriched element anomaly. And the anomaly models exert a critical effect on the optimization of prospecting targets and their potential evaluation. | MA Shengming ZHU Lixin LIU Chongmin XI Mingjie TANG Shixin | 2013 | Acta Geologica Sinica(English Edition)2013，87，3： | 9 |
| 2 | Partitioning properties of rare earth ores in China显示文摘The properties of rare earth partitioning in Chinese industrial rare earth ores were analyzed. Rare earth ores canbe divided into the single-mineral type ore with bastnaesite, the multi-mineral type ore with bastnaesite and monazite, andthe weathering crust type. Both the Bayan Obo rare earth ore and the Zhushan rare earth ore are a kind of mixed ore, con-sisting of bastnaesite and monazite. Their rare earth partitionings are strongly enriched in light rare earths, where CeO2 is50% and the light rare earth partitioning is totally over 95%. The Mianning rare earth ore as well as the Weishan rare earthis a kind of rare earth ore only having bastnaesite. Their rare earth partitionings are also strongly enriched in light rare earths,in which CeO2 is 47% and the light rare earth partitioning is totally over 94%. For the weathering crust type rare earth ore,there are the Longnan rare earth ore, the Xunwu rare earth ore, and the middle yttrium and rich europium ore. In the Long-nan rare earth ore, which is strongly enriched in heavy rare earths, Y2O3 is 64.83%, and the heavy and light rare earthpartitionings are 89.40% and 10.53%, respectively. In the Xunwu rare earth ore, which is strongly enriched in light rareearths, CeO2 is 47.16%, and the light rare earth partitioning is totally 93.25%. Y and Eu are enriched in the middle yttriumand rich europium ore. Its middle rare earth partitioning is totally over 10%, and Eu2O3 and Y2O3 are over 0.5% and 20%,respectively, which are mainly industrial resources of the middle and the heavy rare earths. | CHI Ru 'an LI Zhongjun PENG Cui ZHU Guocai XU Shengming | 2005 | Rare Metals2005，24，3： | 8 |
| 3 | Theoretical study of 2-mercaptobenzimidazole derivatives as chelating collectors in flotation separation of galena and pyrite显示文摘Three 2-mercaptobenzimidazole derivatives,1-ethyl-2-mercapto-benzimidazole(EMBI),1-propyl-2-mercapto-benzimidazole(PMBI)and 1-benze-2-mercapto-benzimidazole(BMBI),were designed and synthesized in the paper,and their collecting behavior in flotation separation process of galena over pyrite was investigated by flotation tests on lab scale.Apart from this,density functional theory(DFT)calculation and molecular dynamics(MD)simulation were also used to elucidate their collecting mechanism.Results of flotation tests indicate that separation of galena over pyrite is feasible at pH 10,and BMBI has the best floatability among three collectors.DFT calculations show that BMBI has the highest occupied molecular orbital(HOMO)energy and strongest collecting effciency.The adsorption mode of three collectors on mineral surface by MD method indicates that the combination processes of collectors with mineral are exothermic,and the higher the binding energy,the frmer the collector adsorbs on the mineral surface and the higher collecting capacity.The calculation results demonstrate that the floatability of three collectors follows the order:BMBI>PMBI>EMBI,which is highly consistent with the flotation tests. | Qin Wei Xu Shengming Xie Qiang | 2013 | International Journal of Mining Science and Technology2013，23，4： | 7 |
| 4 | Preparation of V-doped TiO_2 Photocatalysts by the Solution Combustion Method and Their Visible Light Photocatalysis Activities显示文摘A series of nanocrystalline V-doped(0.0-3.0 at.%) TiO2 catalysts have been successfully prepared by the one-step solution combustion method using urea as a fuel. The obtained powders were characterized by XRD, SEM, Raman, XPS and UV-Vis DRS. The effects of V doping concentration on the phase structure and photocatalytic properties were investigated. XRD, Raman, and XPS show that V doping diffuses into TiO2 crystal lattice mainly in the form of V5+ and causes a phase transition from anatase to rutile. V doping can widen the light absorption range of TiO2, with the absorption threshold wavelength shifting from 425 to 625 nm. The photocatalytic activity of V-doped TiO2 powders were evaluated by the photocatalytic degradation of methyl orange(MO) under visible light irradiation. It is found that V doping enhances the photocatalytic activity under visible light irradiation and the optimal degradation rate of MO is about 95.8% with 1.0 at% V-doped TiO2. | 马晓 薛丽红 YIN Shengming YANG Miao YAN Youwei | 2014 | Journal of Wuhan University of Technology(Materials Science)2014，29，5： | 6 |
| 5 | Regulation of antiviral immune response by African swine fever virus(ASFV)显示文摘African swine fever(ASF)is a highly contagious and acute hemorrhagic viral disease with a high mortality approaching 100%in domestic pigs.ASF is an endemic in countries in sub-Saharan Africa.Now,it has been spreading to many countries,especially in Asia and Europe.Due to the fact that there is no commercial vaccine available for ASF to provide sustainable prevention,the disease has spread rapidly worldwide and caused great economic losses in swine industry.The knowledge gap of ASF virus(ASFV)pathogenesis and immune evasion is the main factor to limit the development of safe and effective ASF vaccines.Here,we will summarize the molecular mechanisms of how ASFV interferes with the host innate and adaptive immune responses.An in-depth understanding of ASFV immune evasion strategies will provide us with rational design of ASF vaccines. | Xiaojie Zheng Shengming Nie Wen-Hai Feng | 2022 | Virologica Sinica2022，37，2： | 6 |
| 6 | Dark matter direct search sensitivity of the PandaX-4T experiment显示文摘The Panda X-4T experiment, a 4-ton scale dark matter direct detection experiment, is being planned at the China Jinping Underground Laboratory. In this paper we present a simulation study of the expected background in this experiment. In a 2.8-ton fiducial mass and the signal region between 1-10 keV electron equivalent energy, the total electron recoil background is found to be 4.9 × 10^(-5) kg^(-1) d^(-1) keV^(-1). The nuclear recoil background in the same region is 2.8 × 10^(-7) kg^(-1) d^(-1) keV^(-1). With an exposure of 5.6 ton-years, the sensitivity of Panda X-4 T could reach a minimum spin-independent dark matter-nucleon cross section of 6 × 10^(-48) cm^2 at a dark matter mass of 40 Ge V/c^2. | HongGuang Zhang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui BinBin Dong DeQing Fang ChangBo Fu Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo ZhiFan Guo Ke Han ChangDa He ShengMing He Di Huang XingTao Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju ShaoLi Li Yao Li Heng Lin HuaXuan Liu JiangLai Liu YuGang Ma YaJun Mao KaiXiang Ni JinHua Ning XiangXiang Ren Fang Shi AnDi Tan AnQing Wang Cheng Wang HongWei Wang Meng Wang QiuHong Wang SiGuang Wang XiuLi Wang XuMing Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu JuMin Yuan JianFeng Yue Dan Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou | 2019 | Science China(Physics,Mechanics & Astronomy)2019，62，3： | 6 |
| 7 | Effect of contact- and sliding-mode electrification on nanoscale charge transfer for energy harvesting显示文摘费用转移的过程最近作为收获技术的一个新、有希望的精力的基础基于 triboelectrification (TE ) 和接触充电(CE ) 被利用了,即,摩擦电 nanogenerators,以及 selfpowered 传感器和系统。在二表面之间的静电的费用转移能发生在 TE 和取决于相对滑动磨擦的参与的 CE 模式。在 TE 的滑动行为从 CE 在费用转移导致任何基本差别吗?因为挑战,很少研究在这比较上是可得到的。这份报纸基于扫描探查在 nanoscale 在 CE 和 TE 在基本差别上提供第一研究显微镜的方法。在相等的接触时间和力量的二进程的量的比较被提供,并且结果建议从 TE 的费用转移从 CE,而是转移费用密度的浸透值是比那快得多的是一样。11 eV 的测量摩擦精力驱散尖端什么时候在 1 的距离上扫描?使潜在的机制清楚些:磨擦可以经由电子刺激便于费用转移过程。这些结果提供基本指导让材料和设备结构的选择在不同应用启用 TE 或 CE;CE 模式为象收获的颤动精力那样的经常的中等接触是有利的, TE 模式为象从人的走精力收获那样的立刻的运动是有利的。 | Yu Sheng Zhou Shengming Li Simiao Niu Zhong Lin Wang | 2016 | Nano Research2016，9，12： | 5 |
| 8 | Convolution without multiplication:A general speed up strategy for CNNs显示文摘Convolutional Neural Networks(CNN)have achieved great success in many computer vision tasks.However,it is difficult to deploy CNN models on low-cost devices with limited power budgets,because most existing CNN models are computationally expensive.Therefore,CNN model compression and acceleration have become a hot research topic in the deep learning area.Typical schemes for speeding up the feed-forward process with a slight accuracy loss include parameter pruning and sharing,low-rank factorization,compact convolutional filters and knowledge distillation.In this study,we propose a general acceleration scheme that replaces the floating-point multiplication with integer addition.To this end,we propose a general accelerate scheme,where the floating point multiplication is replaced by integer addition.The motivation is based on the fact that every floating point can be replaced by the summation of an exponential series.Therefore,the multiplication between two floating points can be converted to the addition among exponentials.In the experiment section,we directly apply the proposed scheme to AlexNet,VGG,ResNet for image classification,and Faster-RCNN for object detection.The results acquired from ImageNet and PASCAL VOC show that the proposed quantized scheme has a promising performance,even with only one item of exponential.Moreover,we analyzed the eciency of our method on mainstream FPGAs.The experimental results show that the proposed quantized scheme can achieve acceleration on FPGA with a slight accuracy loss. | CAI GuoRong YANG ShengMing DU Jing WANG ZongYue HUANG Bin GUAN Yin SU SongJian SU JinHe SU SongZhi | 2021 | Science China(Technological Sciences)2021，64，12： | 5 |
| 9 | Effect of cigarette smoke extraction on the expression of found in inflammatory zone 1 in rat lung epithelial L2 cells显示文摘 | Lin Chunyan Chen Li Huang Zhihong Wu Yi Liu Shengming | 2014 | Chinese Medical Journal2014，，12： | 5 |
| 10 | Extractant(2,3-dimethylbutyl)(2,4,40-trimethylpentyl) phosphinic acid(INET-3) impregnated onto XAD-16 and its extraction and separation performance for heavy rare earths from chloride media显示文摘(2,3-Dimethylbutyl)(2,4,40-trimethylpentyl)phosphinic acid(INET-3) was impregnated onto dry macroporous resins XAD-16 and pretreated XAD-16 with ethyl alcohol and HCl(Pre-XAD-16) to prepare the solvent impregnated resins SIRs-INET-3/XAD-16 and SIRs-INET-3/Pre-XAD-16. The molecular weight distribution of the low molecular weight(LMW) polymers washed off by ethyl alcohol during XAD-16 pretreatment was determined by gel permeation chromatography(GPC). The macroporous resins(XAD-16 & Pre-XAD-16), the corresponding solvent impregnated resins(SIRs-INET-3/XAD-16 &SIRs-INET-3/Pre-XAD-16) and the PVA coated SIRs-INET-3/Pre-XAD-16 with boric acid as cross-linking agent were characterized by FT-IR, SEM-EDS and TGA. The effects of XAD-16 pretreatment and PVA coating technology on RE(III) adsorption equilibrium time, INET-3 losses during extraction and adsorption capacity were investigated. The adsorption kinetics, selectivity and stripping behaviors of SIRs-INET-3/XAD-16 were further studied. The washed off LMW polymers had the Mn of 36,656, Mw of 40,310 and polydispersity coefficient of 1.10. The SIRs-INET-3/XAD-16 had shorter equilibrium time,less INET-3 loss and more Tm(III) adsorption capacity than the SIRs-INET-3/Pre-XAD-16. The PVA coated SIRs-INET-3/Pre-XAD-16 had less INET-3 loss and more Tm(III) adsorption capacity but longer equilibrium time than the uncoated SIRs-INET-3/Pre-XAD-16. The adsorption of RE(III) on the SIRsINET-3/XAD-16 followed the pseudo-second-order kinetic model. The Tm(III) accumulative adsorption amounts onto SIRs-INET-3/XAD-16 after eight extraction stages was 23.6 mg/g. The separation factors of adjacent heavy RE(III) β_(Er/Ho), β_(Tm/Er), β_(Yb/Tm) and β_(Lu/Yb) values were 1.76, 2.59, 2.56 and 1.19,respectively. The adsorbed Lu(III) onto the SIRs-INET-3/XAD-16 can be stripped completely by 1.0 mol/L H_2SO_4. | Junlian Wang Meiying Xie Juanjuan Ma Huajun Wang Shengming Xu | 2017 | Journal of Rare Earths2017，35，12： | 5 |
| 11 | sTLR4/MD-2 complex inhibits colorectal cancer migration and invasiveness in vitro and in vivo by IncRNA H19 down-regulation显示文摘 | Weijun Liang Yan Zou Fengxian Qin Jifei Chen Junyi Xu Shifeng Huang Jingfan Chen Shengming Dai | 2017 | Acta Biochimica et Biophysica Sinica2017，49，11： | 5 |
| 12 | Catalytic Enantioselective Simultaneous Control of Axial Chirality and Central Chirality in Allenes显示文摘 | Jianxin Dai Xinyu Duan Jing Zhou Chunling Fu Shengming Ma | 2018 | Chinese Journal of Chemistry2018，36，5： | 5 |
| 13 | Bevacizumab biosimilar LY01008 compared with bevacizumab(Avastin)as first-line treatment for Chinese patients with unresectable,metastatic,or recurrent non-squamous non-small-cell lung cancer:A multicenter,randomized,double-blinded,phase Ⅲ trial显示文摘Background:Previous studies have demonstrated the preclinical pharmacological and toxicological consistency,and clinical pharmacokinetic equivalence of bevacizumab biosimilar LY01008 with reference bevacizumab(Avastin).This randomized controlled trial aimed to compare the efficacy and safety of LY01008 with Avastin in first-line treatment of Chinese patients with advanced or recurrent non-squamous non-small cell lung cancer(NSCLC).Methods:StageⅢB-ⅣNSCLC patients with evaluable lesions,good physical status,and adequate organ functions from 67 centers across China were randomized in a ratio of 1:1 to receive LY01008 or Avastin 15 mg/kg intravenously in combination with paclitaxel/carboplatin(combined treatment)for 4-6 cycles,followed by maintenance monotherapy with LY01008 until disease progression,intolerable toxicity,or death.The primary endpoint was objective response rate(ORR)in accordance with Response Evaluation Criteria in Solid Tumors(RECIST)version 1.1 confirmed by independent radiological review committees(IRRC).Secondary endpoints included disease control rate(DCR),duration of response(DoR),progression-free survival(PFS),overall survival(OS),and safety.This study was registered in Clinical Trials.gov(NCT03533127).Results:Between December 15^(th),2017,and May 15^(th),2019,a total of 649 patients were randomized to the LY01008(n=324)or Avastin(n=325)group.As of September 25th,2019 for primary endpoint analysis,589 patients received ORR evaluation,with a median number of combined treatment cycles of 5(range 1-6)andmedian duration of treatment of 3.0(range 0.0-5.1)months.ORRof responseevaluable patients in the LY01008 and Avastin groups were 48.5% and 53.0%,respectively.The stratified ORR ratio was 0.91(90%CI 0.80-1.04,within the prespecified equivalence margin of 0.75-1.33).Up to May 15^(th),2020,with a median follow-up of 13.6(range 0.8-28.4)months,no notable differences in DCR,median DoR,median PFS,median OS,and 1-year OS rate were observed between the LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,or recurrent non-squamous NSCLC patients in the first-line setting. | Yuankai Shi Kaijian Lei Yuming Jia Bingqiang Ni Zhiyong He Minghong Bi Xicheng Wang Jianhua Shi Ming Zhou Qian Sun Guolei Wang Dongji Chen Yongqian Shu Lianke Liu Zhongliang Guo Yong Liu Junquan Yang Ke Wang Ke Xiao LinWu Tienan Yi Debin Sun Mafei Kang Tianjiang Ma Yimin Mao Jinsheng Shi Tiegang Tang Yan Wang Puyuan Xing Dongqing Lv Wangjun Liao Zhiguo Luo Bin Wang Xiaohong Wu Xiaoli Zhu Shuhua Han Qisen Guo Rongyu Liu Zhiwei Lu Jianyong Zhang Jian Fang Changlu Hu Yinghua Ji Guolong Liu Hong Lu Dedong Wu Junhong Zhang Shuyang Zhu Zheng Liu Wensheng Qiu Feng Ye Yan Yu Yanqiu Zhao Qinhong Zheng Jun Chen Zhanyu Pan Yiping Zhang Wenjuan Lian Bo Jiang Bo Qiu Guojun Zhang Hua Zhang Yanju Chen Yuan Chen Hongbing Duan Manxiang Li Shengming Liu Lijun Ma Hongming Pan Xia Yuan Xueli Yuan Yulong Zheng Emei Gao Li Zhao Shumin Wang Can Wu | 2021 | Cancer Communications2021，41，9： | 5 |
| 14 | Negishi Coupling for Highly Selective Syntheses of Allenes via Ligand Effect and Mechanistic Study via SAESI-MS/MS显示文摘β-H elimination is an intrinsic problem in transition metal-catalyzed reactions.We describe herein an interesting ligand effect for Et2Zn acting as either ethyl provider or H provider,respectively:by applying SPhos or Gorlos-Phos as the ligand,β-H elimination has been successfully controlled in the corresponding Negishi coupling reaction affording different poly-substituted allenes in good yields and excellent selectivities.SAESI-MS (Solvent Assisted Electrospray Ionization Mass Spectrometry) has been applied to successfully capture the highly reactive organometallic intermediates,which show the different coordination behaviors of Pd with SPhos or Gorlos-Phos as the ligand in the catalytic cycle.In addition,the different reactivities of Int 1 and Int 2 towards the formation of the final allene products have been demonstrated via SAESI-MS/MS experiments.These MS studies visualized the whole catalytic cycle for the Negishi coupling reaction while nicely explain the observed reactivity and selectivity. | Yangguangyan Zheng Bukeyan Miao Anni Qin Junzhe Xiao Qi Liu Gen Li Li Zhang Fang Zhang Yinlong Guo Shengming Ma | 2019 | Chinese Journal of Chemistry2019，37，10： | 5 |
| 15 | Study of low bit rate speech codec algorithm in underwater acoustic communication显示文摘At medium or long distance(> 10 km) underwater acoustic speech communication,information transfer rate is constrained by the complicated,time varying channel and limited bandwidth.The bit rate of speech coding is required to be as low as possible.The time delay of underwater acoustic wave propagation can be used for low bit rate speech coding.After investigating the Mixed Excitation Linear Prediction(MELP) standard and taking account of the auditory perceptual features,a variable and adjustable bit rate speech codec algorithm has been proposed,whose average bit rate is about 600 bps.The average Perceptual Evaluation of Speech Quality Mean Opinion Score(PESQ MOS) of synthesized speeches is about 2.8.It has been proved by the computer simulation and sea trial that the performance of the proposed algorithm is well and robust when bit error rate is no more than 10^(-3).The synthesized speech is vivid and intelligible,and keeps main individual characteristics of speaker. | XIAO Dong MO Fuyuan CHEN Geng GUO Shengming MA Li | 2013 | Chinese Journal of Acoustics2013，32，4： | 4 |
| 16 | Scorpion venom heat-resistant protein decreases immunoreactivity of OX-42-positive microglia cells in MPTP-treated mice显示文摘BACKGROUND:Microglia function as the immune surveyors of the brain under normal physiological conditions.However,microglia become activated in response to brain injuries and immunological stimula-tion.OBJECTIVE:To explore the influence of scorpion venom(SV) heat-resistant protein on frontal cortex and hippocampal microglia cells in a mice model of Parkinson's disease.DESIGN,TIME AND SETTING:Randomized,controlled,cellular immunity study.The experiment was performed at the Physiology Department Laboratory in Dalian Medical University between June 2005 and July 2008.MATERIALS:Ninety-six healthy,C57Bl/6 mice;1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine(MPTP) from Sigma,USA;SV heat-resistant protein(Experimental Base Institute in Dalian Medical University).The mice were randomly divided into four groups(n = 24):normal control,negative control,model,and SV heat-resistant protein.METHODS:Mice in the model and SV heat-resistant protein groups were subcutaneously injected with MPTP(20 mg/kg) to model Parkinson's disease,while the normal control and negative control groups were injected with physiological saline in the neck for 8 successive days.In addition,mice in the model and nor-mal control groups were intraperitoneally injected with physiological saline 2 hours following administration,while SV heat-resistant protein and negative control groups were injected SV heat-resistant protein(0.01 mg/kg).MAIN OUTCOME MEASURES:Immunoreactivity of microglia cells in MPTP-treated mice.RESULTS:Compared with normal control mice,MPTP-treated mice displayed increased OX-42 expression in the brain.However,in the SV heat-resistant protein-treated mice,OX-42 expression was decreased,com-pared to the model group.In the model mouse group,the number of OX-42-positive microglia was increased in the frontal cortex,caudatum,and hippocampal hilus,compared to the normal control mice(P < 0.01).However,in the SV heat-resistant protein-treated mice,the number of OX-42-positive microglia significantly decreased in the frontal cortex,caudatum,and hippocampal hilus,compared to the model group(P < 0.01).CONCLUSION:SV heat-resistant protein inhibited MPTP-induced microglial activation in the mouse fron-tal cortex and hippocampus,resulting in reduced microglial activation in the brain. | Shengming Yin Deqin YU Xi Gao Yan Peng Yanhui Feng Jie Zhao Yiyuan Tang Wanqin Zhang | 2008 | Neural Regeneration Research2008，3，9： | 4 |
| 17 | Highly Selective Nucleophilic 4-Aryl-2,3-allenylation of Malonates显示文摘of main observation and conclusion Allenes are a class of very important compounds and the development of straightforward,efficient,and highly enantioselective synthetic strategies for allenes have attracted extensive interests.Along this line,it is well known that aryl-substituted allenes may be readily racemized,thus,difficult to prepare in high ee.Herein,an efficient palladium-catalyzed nucleophilic allenylation of malonates w ith racemic 4-aryl-2,3-butadienyl carbonates has been developed.The selectivity issue of mono-vs.bis-allenylation with 2-non-substituted malonates has been addressed.By utilizing(R)-(-)-DTBM-SEGPHOS(5,5'-bisldi(3,5,-di-t-butyl-A-methoxyphenyOphosphino)-4,4'-bi-l,3-benzodioxole)as a chiral ligand,various aryl-substituted allenes and bisallenes have been prepared with good to excellent yields with high chemoselectivity and enantioselectivity under mild reaction conditions.Au-catalyzed cycloisomerization and APK(allenic Pauson-Khand)reactions affording optically active mono-and bicyclic products have been demonstrated. | Shihua Song Shengming Ma | 2020 | Chinese Journal of Chemistry2020，38，11： | 4 |
| 18 | One Stone for Three Birds-Rhodium-Catalyzed Highly Diastereoselective Intramolecular [4+2] Cycloaddition of Optically Active Allene-1,3-dienes显示文摘Summary of main observation and conclusion RhCI(PPh3)3-catalyzed [4+2] intramolecular cycloaddition of optically active axially chiral allene-dienes afforded c/s-fused [3.4.0]-bicyclic products with three chiral centers in good yields with an excellent chemo-and diastereoselectivity. A pair of enantiomers of such products was gen erated highly selectively from both ena ntiomers of starting allene-die nes, indicati ng that the axial chirality dictated the absolute configurations of the three in situ generated chiral centers with a very high efficiency of chirality transfer. | Yulin Han Anni Qin Shengming Ma | 2019 | Chinese Journal of Chemistry2019，37，5： | 4 |
| 19 | Oligolayered Ti3C2Tx MXene towards high performance lithium/sodium storage显示文摘Nano Research volume 13,pages1659–1667(2020)Cite this article 232 Accesses 3 Citations Metrics details Abstract 2D MXenes are highly attractive for achieving ultrafast and stable lithium/sodium storage due to their good electric conductivity and abundant redox active sites.While,effective strategies for scalable preparation of oligolayered MXenes are still under exploration.Herein,oligolayered Ti3C2Tx MXene is successfully obtained after conventional synthesis of multilayered Ti3C2 and subsequent delamination process via an organic solvent of tetramethyl-ammonium hydroxide(TMAOH).Comprehensive electrochemical study reveals that surface-controlled redox reaction dominated the charge storage behavior of oligolayered Ti3C2Tx with fast reaction kinetics.Impressively,the obtained oligolayered Ti3C2Tx exhibits excellent lithium/sodium storage performance,featured for a high specific capacity of 330 mAhg^−1 at 1.0 Ag^−1 after 800 cycles for lithium storage and 280 mAhg^−1 at 0.5 Ag^−1 after 500 cycles for sodium storage.Such impressive performance will advance the development of oligolayered Ti3C2Tx based materials for lithium/sodium storage and even broaden their application into energy storage. | Xiaolan Song Hui Wang Shengming Jin Miao Lv Ying Zhang Xiaodong Kong Hongmei Xu Ting Ma Xinyuan Luo Hengfeng Tan Dong Hu Chaoyong Deng Xinghua Chang Jianlong Xu | 2020 | Nano Research2020，13，6： | 4 |
| 20 | First experimental constraints on WIMP couplings in the effective field theory framework from CDEX显示文摘We present weakly interacting massive particles(WIMPs) search results performed using two approaches of effective field theory from the China Dark Matter Experiment(CDEX), based on the data from both CDEX-1B and CDEX-10 stages. In the nonrelativistic effective field theory approach, both time-integrated and annual modulation analyses were used to set new limits for the coupling of WIMP-nucleon effective operators at 90% confidence level(C.L.) and improve over the current bounds in the low mχregion. In the chiral effective field theory approach, data from CDEX-10 were used to set an upper limit on WIMP-pion coupling at 90% C.L. We for the first time extended the limit to the m_(χ)<6 GeV/c^(2) region. | Yi Wang Zhi Zeng Qian Yue LiTao Yang KeJun Kang YuanJing Li Mehment Agartioglu HaiPeng An JianPing Chang JingHan Chen YunHua Chen JianPing Cheng Cheng Yi Chiang WenHan Dai Zhi Deng ChangHao Fang XinPing Geng Hui Gong QiuJu Guo XuYuan Guo HongJian He Li He ShengMing He JinWei Hu TuChen Huang HanXiong Huang HaiTao Jia LiPing Jia Xi Jiang HauBin Li JianMin Li Jin Li MingXuan Li RenMingJie Li Xia Li YuLan Li Bin Liao FongKay Lin ShinTed Lin ShuKui Liu YanDong Liu Yu Liu YuanYuan Liu ZhongZhi Liu Hao Ma YuCai Mao QiYuan Nie JinHua Ning Hui Pan NingChun Qi Jie Ren XiChao Ruan ChangSong Shang Vivek Sharma Ze She Lakhwinder Singh Monoj Kumar Singh TianXi Sun ChangJian Tang WeiYou Tang Yang Tian GuangFu Wang Li Wang Qing Wang Yu Chen Wang YunXiang Wang Zhen Wang Henry Tsz-King Wong ShiYong Wu YuCheng Wu HaoYang Xing Yin Xu Tao Xue YuLu Yan Nan Yi ChunXu Yu HaiJun Yu JianFeng Yue Ming Zeng BingTao Zhang Lei Zhang FengShou Zhang ZhenYu Zhang KangKang Zhao MingGang Zhao JiFang Zhou ZuYing Zhou JingJun Zhu | 2021 | Science China(Physics,Mechanics & Astronomy)2021，64，8： | 3 |
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