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| 1 | Synthesis and light-emitting properties of 2-(N-phenyl-α-naphthylamino) and 2-dimesitylboron-7-(N-phenyl-α-naphthylamino)-9,9-diethylfluorene显示文摘A fluorescent organic triarylamine with a symmetric structure, 2,7-bis(N-α-naphthyl-phenylamino)-9,9- diethylfluorene (NPAEF) was synthesized using two methods, modified Ullmann coupling and modified palladium-catalyzed amination. An activated copper and a combination of Pd(OAc)2/P(t-Bu)3 and Pd(dba)2/P(t-Bu)3 were selected as catalysts to improve yields of reactions. These synthetic procedures were also successfully applied to an asymmetric 2-dimesitylboron-7-(N-phenyl-α-naphthylamino)-9,9-diethylfluorene (BNPEF). Photoluminescent emission peaks in solid film and in diluted solution of NPAEF were both observed at 461 nm, while the main emission peaks of BNPEF appeared at 422 nm in hexane, and at 480 nm in methanol. The double emission peaks of BNPEF in hexane reflected fine structure in the vibrational state. With an increasing polarity of solvent, the main PL emission peaks were red-shifted and vibrational fine structure disappeared. Additionally, energy levels of NPAEF were investigated and an electroluminescence (EL) device of ITO/PVK:NPAEF/Al was fabricated, which showed a turn-on voltage of 9 V and peaked at 462 nm. The EL spectrum was in good agreement with PL spectrum, which indicated that they were from the same emitting center in the device. | ZHANG WenGuan HE ZhiQun HUI GuanBao MU LinPing WANG YongSheng ZHAO ShengMin JING XiPing | 2009 | Science China Chemistry2009,52,7: | 3 |
| 2 | Single-cell transcriptomic landscape of human blood cells显示文摘High throughput single-cell RNA-seq has been successfully implemented to dissect the cellular and molecular features underlying hematopoiesis.However,an elaborate and comprehensive transcriptome reference of the whole blood system is lacking.Here,we profiled the transcriptomes of 7551 human blood cells representing 32 immunophenotypic cell types,including hematopoietic stem cells,progenitors and mature blood cells derived from 21 healthy donors.With high sequencing depth and coverage,we constructed a single-cell transcriptional atlas of blood cells(ABC) on the basis of both protein-coding genes and long noncoding RNAs(lncRNAs),and showed a high consistence between them.Notably,putative lncRNAs and transcription factors regulating hematopoietic cell differentiation were identified.While common transcription factor regulatory networks were activated in neutrophils and monocytes,lymphoid cells dramatically changed their regulatory networks during differentiation.Furthermore,we showed a subset of nucleated erythrocytes actively expressing immune signals,suggesting the existence of erythroid precursors with immune functions.Finally,a web portal offering transcriptome browsing and blood cell type prediction has been established.Thus,our work provides a transcriptional map of human blood cells at single-cell resolution,thereby offering a comprehensive reference for the exploration of physiological and pathological hematopoiesis. | Xiaowei Xie Mengyao Liu Yawen Zhang Bingrui Wang Caiying Zhu Chenchen Wang Qing Li Yingying Huo Jiaojiao Guo Changlu Xu Linping Hu Aiming Pang Shihui Ma Una Wang Wenbin Cao Shulian Chen Qiuling Li Sudong Zhang Xueying Zhao Wen Zhou Hongbo Luo Guoguang Zheng Erlie Jiang Sizhou Feng Lixiang Chen Lihong Shi Hui Cheng Sha Hao Ping Zhu Tao Cheng | 2021 | National Science Review2021,8,3: | 3 |
| 3 | Phosphorus Efficacy in Four Chinese Long-Term Experiments with Different Soil Properties and Climate Characteristics显示文摘 | Linping Zhao Yibing Ma Guoqing Liang Shutian Li Lishu Wu | 2009 | Communications in Soil Science and Plant Analysis . 2009 (19-2)2009,,19: | 1 |
| 4 | Isolation and eharacterisation of the isoflavones from sprouted chickpea seeds显示文摘 | Zhao Shuhui Zhang Linping Gao Peng | 2009 | Food Chem2009,114,3: | 1 |
| 5 | Factors associated with dysglycemia and its post-surgical resolution in patients with pheochromocytomas显示文摘Dear Editor,Pheochromocytomas are rare neuroendocrine tumors originating from chromaffin cells in the adrenal medulla(Neumann et al., 2019). A number of case reports and small cohorts have reported the association between dysglycemia and pheochromocytomas(Elenkova et al., 2020;Khatiwada et al., 2020;Krumeich et al., 2021). However, there are few large sample studies reporting the outcomes of dysglycemia in patients with pheochromocytomas after resection. | Lin Zhao Xu Meng Qiongyu Zhang Yi Zhou Ting Zhang Tao Tian Hua Fan Huadong Zhu Yecheng Liu Fang Luo Linping Wang Weixian Yang Xianliang Zhou | 2023 | Science China(Life Sciences)2023,66,2: | 0 |
| 6 | Geological Characteristics and Manifestations of Geological Processes of Sequence Boundaries and Their Vicinities显示文摘This paper discusses the geological characteristics and architectures of sequence boundaries and their vicinities and has proposed a classification scheme for the sequence boundaries, which can thus be grouped into three types and eight categories: type I includes exposed truncated surface, palaeosol surface, palaeokarst surface and exposed surface; type Ⅱ boundaries include structural transitional surface during sea-level fall and transgressive onlap surface; and type Ⅲ includes submarine erosional diagenetic diastem and event surface. A study has been made for the three major boundaries lying between the Permian and pre-Permian, the Permian and Triassic, and the Middle and Lower Triassic respectively in terms of multiple disciplines such as lithostratigraphy, biostratigraphy, magnetostratigraphy and carbon and oxygen isotopic geology. These three boundaries are ascribed to type I , typeⅡ and typeⅢ, respectively. | Xiao Linping Testing Centre of Geotechnical Engineering, Southwest Jiaotong Universityand Zhao YuguangChengdu Institute of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, Sichuan, 610082 Liu Xinzhu | 1997 | Acta Geologica Sinica(English Edition)1997,71,4: | 0 |
| 7 | Role of Agricultural Product Quality and Safety in High Quality Development of China's Agriculture显示文摘The quality and safety of agricultural products are closely related to human health.They also play an important role in enhancing the competitiveness of China’s agricultural products market,shaping the brand value of agricultural products,and promoting the high-quality development of agriculture.At present,there are still a series of problems in the quality and safety of agricultural products.Relevant departments of the state should strengthen guidance and supervision,improve the quality and safety awareness and management level of agricultural product producers,and encourage producers to participate in the product certification and process certification of agricultural products.In addition,it is necessary to take effective control measures in accordance with the certification requirements,to evaluate their effectiveness,so as to improve the quality and safety of agricultural products and promote the high-quality development of China’s agriculture. | Xuan WANG Shengcai JI Linping ZHAO Azhen NIE Xuefeng ZHAO Mengyu LI Songtao JIA | 2021 | Asian Agricultural Research2021,13,11: | 0 |