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| 1 | Thermodynamic modeling and phase diagram prediction of salt lake brine systems.Ⅰ. Aqueous Mg^2+–Ca^2+–Cl^- binary and ternary systems显示文摘Salt lake brine is a complex salt-water system under natural environment.Although many models can express the thermodynamic properties and phase equilibrium of electrolyte aqueous solution,the multi-temperature characteristics and predictability are still the goals of model development.In this study,a comprehensive thermodynamic model system is re-established based on the eNRTL model and some improvements:(1) new expression of long-range electrostatic term with symmetrical reference state is proposed to handle the electrolyte solution covering entire concentration range;(2) the temperature dependence of the binary interaction parameters is formulated with a Gibbs Helmholtz expression containing three temperature coefficients,the liquid parameters,which associated with Gibbs energy,enthalpy,and heat capacity contribution;and(3) liquid parameters and solid species data are regressed from properties and solubility data at full temperature range.Together the activity coefficient model,property models and parameters of liquid and solid offer a comprehensive thermodynamic model system for the typical bittern of MgCl2-CaCl2-H2 O binary and ternary systems,and it shows excellent agreement with the literature data for the ternary and binary systems.The successful prediction of complete phase diagram of ternary system shows that the model has the ability to deal with high concentration and high non-idealitv system,and the ability to extrapolate the temperature. | Huan Zhou Xiaolong Gu Yaping Dai Jingjing Tang Jian Guo Guangbi Li Xiaoqin Bai | 2020 | Chinese Journal of Chemical Engineering2020，28，9： | 9 |
| 2 | Effect of the graphitic degree of carbon supports on the catalytic performance of ammonia synthesis over Ba-Ru-K/HSGC catalyst显示文摘A series of high surface area graphitic carbon materials(HSGCs) were prepared by ball-milling method. Effect of the graphitic degree of HSGCs on the catalytic performance of Ba-Ru-K/HSGC-x(x is the ball-milling time in hour) catalysts was studied using ammonia synthesis as a probe reaction. The graphitic degree and pore structure of HSGC-x supports could be successfully tuned via the variation of ball-milling time. Ru nanoparticles of different Ba-Ru-K/HSGC-x catalysts are homogeneously distributed on the supports with the particle sizes ranging from 1.6 to 2.0 nm. The graphitic degree of the support is closely related to its facile electron transfer capability and so plays an important role in improving the intrinsic catalytic performance of Ba-Ru-K/HSGC-x catalyst. | Wei Jiang Ying Li Wenfeng Han Yaping Zhou Haodong Tang Huazhang Liu | 2014 | Journal of Energy Chemistry2014，23，4： | 8 |
| 3 | CFD–DEM–CVD multi-physical field coupling model for simulating particle coating process in spout bed显示文摘Particle coating is a very important step in many industrial production processes as the particle coating layers may fix surfaces with unique advantages. Given the limitation and disadvantages of the existing simulation methods, a coupled CFD–DEM–CVD multi-physical field model for particle-coating simulations has been established taking into account the velocity field, temperature field, concentration field, and deposition model. In this model, gas behavior and chemical reactions are simulated in the CFD frame based on the conservation laws of mass, momentum, and energy. The particle behavior is simulated in the DEM frame based on the gas–solid interphase force model and contact force model. The deposition behavior is simulated in the CVD frame based on the particle movement–adhesion–deposition model. The coupled model can be implemented in Fluent-EDEM software with their user definition function and application programming interface. The particle coating process involving the pyrolysis of acetylene was investigated, and the effect of bed temperature and inlet gas velocity on deposition rate and coating efficiency were investigated based on the proposed model with adjustable deposition coefficients. Both the average deposition layer mass and the average deposition layer thickness were found to be proportional to the elapsed time and increased at the rate of about 1.05 × 10^-2 mg/s and 3.45 × 10^-4 mm/s, respectively, setting the inlet gas velocity to 11 m/s and bed temperature to 1680 K. A higher temperature and larger inlet gas velocity lead to a larger deposition rate, but the coating efficiency decreases because of limits imposed by the chemical reaction. At a bed temperature of 1280 K, the average deposition rate is 7.40 × 10?3 mg/s when the inlet gas velocity is set to 11 m/s, which is about double the deposition rate when the inlet gas velocity is set as 5 m/s. The proposed model can provide some guidance for the operating conditions and parameters design of the spouted bed in actual coating settings and can also be further developed as a basic model of mechanisms to integrate detailed information across multiple scales. | Malin Liu Meng Chen Tianjin Li Yaping Tang Rongzheng Liu Youlin Shao Bing Liu Jiaxing Chang | 2019 | Particuology2019，17，1： | 6 |
| 4 | Dolomitization by Penesaline Sea Water in Early Cambrian Longwangmiao Formation, Central Sichuan Basin, China显示文摘The Lower Cambrian Longwangmiao Formation shoal dolostone reservoir in Sichuan Basin is currently an exploration and research highlight in China. Reservoir rocks mainly consist of crystalline dolomite with residual grain texture, and dolarenite of which the arene is mainly composed of muddy to micritic dolomite with some crystalline grain directionally aligned. The trace element indicates that the dolomites of Longwangmiao Formation may be related to the high salinity of sea water. The oxygen isotope values of crystalline dolomite and dolarenite are both similar to that of the Early Cambrian marine dolomites, and the carbon isotope values of every kind of dolomites are completely overlapped with that of the seawater in Early Cambrian, indicating the dolomitization fluid is originated from the Early Cambrian sea water. The restricted marine biological communities and a small amount of gypsum pseudonodule seen in muddy to micritic dolomite indicate that the sea water in Early Cambrian was restricted and evaporated. However, the general lack of massive evaporite mineral and gypsum karst breccia indicates that the salinity of sea water during dolomitization was lower than the value of gypsum's precipitation. The Longwangmiao Formation consists of several high-frequency sedimentary cycles, indicating frequent sea level changes. This study indicates that massive dolomitization may also occur in underwater palaeohigh in carbonate platform through the reflux of penesaline sea water driven by a combination of high-and low-frequency sea-level changes. This kind of dolomitization can explain the generation of massive dolomites in the absence of evaporite precipitation, and further indicates that replacement dolomites can be produced by sea water with a wide range of salinity(normal, penesaline to hypersaline). | Xuefei Yang Hao Tang Xingzhi Wang Yaping Wang Yueming Yang | 2017 | Journal of Earth Science2017，28，2： | 6 |
| 5 | A β-glucosidase-producing M-2 strain: Isolation from cow dung and fermentation parameter optimization for flaxseed cake显示文摘Flaxseed cake contains cyanogenic glucosides, which can be metabolized into hydrocyanic acid in an animal's body, leading to asphyxia poisoning in cells. Beta-glucosidase is highly efficient in degrading cyanogenic glucosides. The Cattle may have b-glucosidase-producing strains in the intestinal tract after eating small amounts of flaxseed cake for a long time. This study aimed to isolate of a strain from cow dung that produces b-glucosidase with high activity and can significantly reduce the amount of cyanogenic glucosides. We used cow dung as the microflora source and an esculin agar as the selective medium. After screening with 0.05% esculin and 0.01% ferric citrate, we isolated 5 strains producing high amounts of b-glucosidase. In vitro flaxseed cake fermentation was fermented by these 5 strains, in which the strain M-2 exerted the best effect(P < 0.05). The strain M-2 was identified as Lichtheimia ramosa and used as the fermentation strain to optimize the fermentation parameters by a single factor analysis and orthogonal experimental design. The optimum condition was as follows: inoculum size3%, water content 60%, time 144 h, and temperature 32℃. Under this condition, the removal rate of cyanogenic glucosides reached 89%, and crude protein increment reached 44%. These results provided a theoretical basis for the removal of cyanogenic glucosides in flaxseed and the comprehensive utilization of flaxseed cake. | Chenhui Li Junshu Wei Yaping Jing Baoxia Teng Pingrong Yang Xinjun Chen Haiying Huang Tang Zhao Tuanjie Che Chunjiang Zhang | 2019 | Animal Nutrition2019，，1： | 5 |
| 6 | Maternal exposure to triclosan constitutes a yet unrecognized risk factor for autism spectrum disorders显示文摘Dear Editor,Autism spectrum disorders(ASD)are complex neurodevelopmental disorders characteristic of core behavioral traits like restricted,repetitive behaviors and deficiency in social interactions.1 The prevalence of ASD has rapidly increased worldwide,rising from 1/149 in 2000,1/68 in 2012,and to?1/40 in 2016 of children at the age of 3-17 in the United States.2 ASD prevalence was found to be associated with socioeconomic status(SES)as overpresented in high-income households,3 and to be significantly enriched in certain regions,e.g.,reaching up to 4.88%in Florida.2 In the last decades,advances in genetic studies have led to unprecedented understanding of the genetic factors that were associated with<50%of human ASD. | Zijian Hao Qionghui Wu Zhengwei Li Yali Li Qiu Li Xi Lai Huan Liu Menghuan Zhang Ting Yang Jie Chen Yaping Tang Jingkun Miao Huatai Xu Tingyu Li Ronggui Hu | 2019 | Cell Research2019，29，10： | 5 |
| 7 | A novel graphene oxide-carbon nanotubes anchored α-FeOOH hybrid activated persulfate system for enhanced degradation of Orange Ⅱ显示文摘Persulfate activation has been applied as one of the efficient advanced oxidation processes(AOPs) to remediate polluted environments. In this study, a novel α-FeOOH anchored by graphene oxide(GO)-carbon nanotubes(CNTs) aerogel(α-FeOOH@GCA) nanocomposite activated persulfate system(α-FeOOH@GCA + K2S2O8) was applied for decolorization of Orange Ⅱ(OⅡ). The decolorization of OⅡ was remarkably enhanced to a level of ~ 99% in this system compared with that of pristine α-FeOOH(~ 44%) or GO-CNTs(~18%). The enhanced catalytic activity of α-FeOOH@GCA was due to the formation of a heterojunction byα-FeOOH and GO-CNTs as confirmed by the presence of Fe–O–C chemical bonds. The degradation intermediates of OⅡ were comprehensively identified. The proposed degradation pathway of OⅡ begins with the destruction of the conjugated structures of OⅡ by the dominant reactive oxygen species, surface-bound SO4·-. The decolorization efficiency of OⅡ by the α-FeOOH@GCA activated persulfate system decreased from the first to third cycle of recycling. Ultraviolet(UV) irradiation or introduction of a small amount of Fe2+ could restore the activation of this system. The results show that the α-FeOOH@GCA persulfate activation system promises to be a highly efficient environmental remediation method for organic pollutants. | Shanshan Su Yuyang Liu Wei He Xianchun Tang Wei Jin Yaping Zhao | 2019 | Journal of Environmental Sciences2019，31，9： | 4 |
| 8 | Porphyromonas gingivalis bacteremia increases the permeability of the blood-brain barrier via the Mfsd2a/Caveolin-1 mediated transcytosis pathway显示文摘Bacteremia induced by periodontal infection is an important factor for periodontitis to threaten general health. P. gingivalis DNA/virulence factors have been found in the brain tissues from patients with Alzheimer’s disease(AD). The blood-brain barrier(BBB) is essential for keeping toxic substances from entering brain tissues. However, the effect of P. gingivalis bacteremia on BBB permeability and its underlying mechanism remains unclear. In the present study, rats were injected by tail vein with P. gingivalis three times a week for eight weeks to induce bacteremia. An in vitro BBB model infected with P. gingivalis was also established. We found that the infiltration of Evans blue dye and Albumin protein deposition in the rat brain tissues were increased in the rat brain tissues with P. gingivalis bacteremia and P. gingivalis could pass through the in vitro BBB model. Caveolae were detected after P. gingivalis infection in BMECs both in vivo and in vitro. Caveolin-1(Cav-1) expression was enhanced after P. gingivalis infection.Downregulation of Cav-1 rescued P. gingivalis-enhanced BMECs permeability. We further found P. gingivalis-gingipain could be colocalized with Cav-1 and the strong hydrogen bonding between Cav-1 and arg-specific-gingipain(RgpA) were detected.Moreover, P. gingivalis significantly inhibited the major facilitator superfamily domain containing 2a(Mfsd2a) expression. Mfsd2a overexpression reversed P. gingivalis-increased BMECs permeability and Cav-1 expression. These results revealed that Mfsd2a/Cav-1 mediated transcytosis is a key pathway governing BBB BMECs permeability induced by P. gingivalis, which may contribute to P. gingivalis/virulence factors entrance and the subsequent neurological impairments. | Shuang Lei Jian Li Jingjun Yu Fulong Li Yaping Pan Xu Chen Chunliang Ma Weidong Zhao Xiaolin Tang | 2023 | International Journal of Oral Science2023，15，1： | 3 |
| 9 | Genetic, hormonal, and environmental control of tillering in wheat显示文摘Tillering contributes greatly to grain yield in wheat.Investigating the mechanisms of tillering provides a theoretical foundation and genetic resources for the molecular breeding of wheat.The regulation of tillering is a complex molecular process that involves a multitude of factors.Little is known about the molecular mechanisms in the wheat genome,although progress has been made in rice.Here we review the developmental characteristics of tillers and summarize current knowledge of the roles of endogenous and environmental factors in wheat tillering.We propose directions for future studies and advanced technologies to be used for gene identification and functional studies. | Qiushuang Shang Yaping Wang Heng Tang Na Sui Xiansheng Zhang Fang Wang | 2021 | The Crop Journal2021，9，5： | 3 |
| 10 | Anomalous Pore-Density Dependence in Nanofluidic Osmotic Power Generation显示文摘 | Jianjian Su Danyan Ji Jialiang Tang Hao Li Yaping Feng Liuxuan Cao Lei Jiang Wei Guo | 2018 | Chinese Journal of Chemistry2018，36，5： | 3 |
| 11 | Three-dimensional silk fibroin scaffolds enhance the bone formation and angiogenic differentiation of human amniotic mesenchymal stem cells:a biocompatibility analysis显示文摘Silk fibroin(SF)is a fibrous protein with unique mechanical properties,adjustable biodegradation,and the potential to drive differentiation of mesenchymal stem cells(MSCs)along the osteogenic lineage,making SF a promising scaffold material for bone tissue engineering.In this study,hAMSCs were isolated by enzyme digestion and identified by multiple-lineage differentiation.SF scaffold was fabricated by freeze-drying,and the adhesion and proliferation abilities of hAMSCs on scaffolds were determined.Osteoblast differentiation and angiogenesis of hAMSCs on scaffolds were further evaluated,and histological staining of calvarial defects was performed to examine the cocultured scaffolds.We found that hAMSCs expressed the basic surface markers of MSCs.Collagen type I(COLI)expression was observed on scaffolds cocultured with hAMSCs.The scaffolds potentiated the proliferation of hAMSCs and increased the expression of COL-I in hAMSCs.The scaffolds also enhanced the alkaline phosphatase activity and bone mineralization,and upregulated the expressions of osteogeniorelated factors in vitro.The scaffolds also enhanced the an gioge nic differe ntiati on of hAMSCs.The cocultured scaffolds in creased bone formati on in treating critical calvarial defects in mice.This study first demonstrated that the application of 3D SF scaffolds co-cultured with hAMSCs greatly enhaneed osteogenic differentiation and angiogenesis of hAMSCs in vitro and in vivo.Thus,3D SF scaffolds cocultured with hAMSCs may be a better alter native for bone tissue engin eering. | Yuwan Li Ziming Liu Yaping Tang Qinghong Fan Wei Feng Changqi Luo Guangming Dai Zhen Ge Jun Zhang Gang Zou Yi Liu Ning Hu Wei Huang | 2020 | Acta Biochimica et Biophysica Sinica2020，52，6： | 2 |
| 12 | Integrated system of comprehensive utilizing the concentrated brine of Yuncheng salt-lake basing on salt-forming diagram显示文摘The comprehensive utilization and environment-friendliness of processes for recovering fresh water or valuable salt from seawater, salt-lakes, or mineral deposits are of utmost importance for sustainable development.One primitive sustainable process for recovering salt from sodium-sulfate-type brine in Yuncheng salt lake had been considered one of the greatest inventions of ancient China, however, the replaced process of mass extraction of single Na_2SO_4 in recent years, has reduced a large amount of residual brine.In this research, relying on the salt-forming diagram in the non-equilibrium state, the technical secrets of ancient salt processes were uncovered, and a new comprehensive utilization system was proposed and tested experimentally.The new system includes a vacuum salt-making process and a normal pressure kieserite process, which can gradually eliminate the existed waste liquid and aid in the sustainable development of the Yuncheng salt-lake.The continuous experiment of salt-making process running stably in the double salt region without double salt formation, which proves the feasibility of salt-forming diagram applied in industrial process.Thus salt-forming diagram would be extremely valuable to industry process design and control, especially, the treatment of concentrated brine. | Huan Zhou Jingjing Tang Jian Guo Yaping Dai Guangbi Li Bo Yan | 2019 | Chinese Journal of Chemical Engineering2019，27，1： | 2 |
| 13 | Photocatalytic degradating methyl orange in water phase by UV-irradiated CdS carried by carbon nanotubes显示文摘A new candidate for photocatalytic degradating organic dyes,CdS carried by car-bon nanotubes(CdS/CNTs) ,is reported. The degradation ratio curves of methyl orange in water phase show that the capability for degradating organic molecules of CdS/CNTs is obviously higher than that of separated CdS. The degradation ca-pability enhances as the increase of the amount of net CdS catalyst,the ratio of carbon nanotubes to CdS,and the area of the template,and is influenced by the pH value and the temperature of aqueous solution. These results suggest that the photocatalyst of CdS/CNTs is very suitable for potential applications in organic waste removal from water. | LI ChenSha TANG YaPing KANG BoNan WANG BinSong ZHOU Feng MA Qiang XIAO Ji WANG DaZhi LIANG Ji | 2007 | Science China(Technological Sciences)2007，50，3： | 2 |
| 14 | Impact of Lithium-Ion Coordination on Lithium Electrodeposition显示文摘The lithium dendrite and parasitic reactions are two major challenges for lithium(Li)metal anode—the most promising anode materials for high-energy-density batteries.In this work,both the dendrite and parasitic reactions that occurred between the liquid electrolyte and Li-metal anode could be largely inhibited by regulating the Li+-solvation structure.The saturated Li+-solvation species exist in commonly used LiPF 6 liquid electrolyte that needs extra energy to desolvation during Li-electrodeposition.Partial solvation induced high-energy state Li-ions would be more energy favorable during the electron-reduction process,dominating the competition with solvent reduction reactions.The Li-symmetric cells that are cycling at higher temperatures show better performance;the cycled lithium metal anode with metallic lustre and the dendrite-free surface is observed.Theoretical calculation and experimental measurements reveal the existence of high-energy state Li+-solvates species,and their concentration increases with temperature.This study provides insight into the Li+-solvation structure and its electrodeposition characteristics. | Li Sheng Yanzhou Wu Jiekang Tian Li Wang Jianlong Wang Yaping Tang Hong Xu Xiangming He | 2023 | Energy & Environmental Materials2023，6，1： | 2 |
| 15 | Preparation of ammonium diuranate particles by external gelation process of uranium in INET显示文摘 | Zhou Xiangwen Ma Jingtao Hao Shaochang Zhao Xingyu Wang Yang Deng Changsheng Liang Tongxiang Guo Wenli Tang Yaping Tang Chunhe | 2012 | Nuclear Engineering and Design2012，，： | 1 |
| 16 | Numerical simulation of uranium tetrafluoride fluorination in a multistage spouted bed using the improved CFD-DEM chemical reaction model显示文摘A CFD-DEM reaction coupling model was established to simulate UF_(4) fluorination process,in which heat and mass transfer,heterogeneous chemical reaction,and particle shrinkage model were considered.The gas behavior was described by the conservation laws of mass,momentum,and energy.The solid phase is modeled with the discrete element method,considering the gas-solid interphase force,contact force,heat transfer,and chemical reaction models based on the discretized surface.Each particle can be individually tracked and associated with specific physical properties.The proposed CFD-DEM reaction coupling model based on particle shrinking reaction model with discretized surface was validated by the experimental and literature results at first.Then a multistage conical spouted bed was proposed and the process of UF_(4) fluoridation reaction in it was investigated.The fluidization characteristics and the con-centration distribution of gaseous products in the spouted bed with an extended gas velocity range were obtained and analyzed.In addition,the effects of different parameters,such as superficial gas velocity,temperature,fluorine concentration,on fluoridation rate and the fluorine conversion rate were inves-tigated based on the proposed CFD-DEM reaction coupling model.The results obtained in this work are beneficial for method development of the chemical reaction simulation research in particle scale using the CFD-DEM model,and useful for operation and equipment parameters design of the uranium tetra-fluoride fluorinate industrial process in the future. | Mofan Qiu Zhao Chen Lin Jiang Rongzhen Liu Yaping Tang Malin Liu | 2023 | Particuology2023，，4： | 1 |
| 17 | Ni-Mn Bi-metal Oxide Catalysts for the Low Temperature SCR Removal of NO with NH3显示文摘 | Wan Yaping Zhao Wenru Tang Yu | 2014 | Applied Catalysis B:Environmental2014，，： | 1 |
| 18 | Synergistie effect of nickel formate on the thermal and flame-retardant properties of polypropylene显示文摘 | Xuecheng Chen Yaping Ding Tao Tang | 2005 | Polymer international2005，54，： | 1 |
| 19 | Research and Development of Fuel Element for Chinese 10 MW High Temperature Gas-cooled Reactor显示文摘 | Tang Chunhe Tang Yaping Zhu Junguo | 2000 | J Nucl Sci Technol2000，37，9： | 1 |
| 20 | Design and Manufacture of the Fuel Element for the 10 MW High Temperature Gas-cooled Reactor显示文摘 | Tang Chunhe Tang Yaping Zhu Junguo | 2002 | Nuclear Engineering and Design2002，218，： | 1 |
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