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| 1 | Genesis of the Zhaokalong Fe-Cu Polymetallic Deposit at Yushu, China: Evidence from Ore Geochemistry and Fluid Inclusions显示文摘The ore types of the Zhaokalong Fe-Cu deposit are divided into two categories: sulfide-type and oxide-type. The sulfide-type ore include siderite ore, galena-sphalerite ore and chalcopyrite ore, whereas the oxide-type ore include magnetite ore and hematite ore. The ore textures and structures indicate that the Zhaokalong deposit is of the sedimentary-exhalative mineralization type. Geochemical analyses show that the two ore types have a high As, Sb, Mn, Co and Ni content. The REE patterns reveal an enrichment of the LREE compared to the HREE. Isotopic analysis of siderite ore reveal that the δ13CPDB ranges from 2.01 to 3.34 (‰) whereas the δ18O SMOW ranges from 6.96 to 18.95 (‰). The fluid inclusion microthermometry results indicate that homogenization temperatures of fluid inclusions in quartz range from 131 to 181℃, with salinity values of 1.06 to 8.04 wt% NaCl eq. The mineralizing fluid therefore belongs to the low temperature - low salinity system, with a mineralizing solution of a CO2-Ca2+(Na+, K+)-SO42-(F-, Cl-)-H2O system. The geochemical results and fluid inclusion data provide additional evidence that the Zhaokalong deposit is a sedex-type deposit that experienced two stages of mineralization. The sulfide mineralization probably occurred first, during the sedimentary exhalative process, as exhibited by the abundance of marine materials associated with the sulfide ores, indicating a higher temperature and relatively deoxidized oceanic depositional environment. After the main exhalative stage, hydrothermal activity was superimposed to the sulfide mineralization. The later stage oxide mineralization occurred in a low temperature and relatively oxidized environment, in which magmatic fluid circulation was dominant. | LI Huan XI Xiaoshuang WU Chengming Koichiro WATANABE | 2013 | Acta Geologica Sinica(English Edition)2013，87，2： | 15 |
| 2 | Enhancing the catalytic efficiency of the Heck coupling reaction by forming 5 nm Pd octahedrons using kinetic control显示文摘异构的催化作用通过界面的反应的一个过程发生;因此,表面方面和尺寸控制能增加催化效率。八面的 Pd nanocrystals,围住由 { 111 } 方面,应该是理想的几何形状为哎呀联合反应;然而,综合是挑战性的有用存在帽子代理人技术的相对一致的尺寸分布的 5 nm Pd 八面体。这里,我们把钯用作一个模型系统调查原子增加的动力学怎么能精确用注射泵被控制。作为结果,我们的方法生产了象 5 nm 一样小的 Pd 八面体,它增加了催化效率哎呀当减少使用的催化剂的重量时,联合反应。 | Ran Long Di Wu Yaping Li Yu Bai Chengming Wang Li Song Yujie Xiong | 2015 | Nano Research2015，8，6： | 4 |
| 3 | Geochemistry of the Batang Group in the Zhaokalong Area, Yushu, Qinghai: Implications for the Late Triassic Tectonism in the Northern Sanjiang Region, China显示文摘The Batang Group in the Zhaokalong area not only hosts an important Fe-Cu polymetallic deposit but also reveal important insights for the Late Triassic tectonism in the northern Sanjiang region. In order to delineate the tectonic setting and evolutionary process of the paleo arc-basin system, geochemical studies on the Batang Group strata have been carried out. The results suggest that andesite in the Zhaokalong area mainly belongs to the tholeiite series and is characterized by obvious fractionation of LREE and HREE, enrichment in LILE and depletion in HFSE, and a distinctly elevated δ^(34)SCDT average of 10.5‰. The sandstone is classified as lithic sandstone, which is also characterized by obvious fractionation of LREE and HREE, as well as weak negative Ce and Eu anomalies. The limestone displays positive Eu anomalies, with δ^(13)CPDB ranging from-1.3‰ to 4.4‰ and δ^(18) OSMOW ranging from 14.6‰ to 22.5‰. These results indicate that the andesite has a dual signature of both arc andesite and rift volcanic rocks, whereas the sandstone may be formed in an active continental margin, and the limestone could be deposited in a weak oxidizing shallow sea. The sandstone in the Zhaokalong area represents sedimentation in a platform slope facies, corresponding to the main stage of the Jinshajing oceanic basin subduction during the middle period of Late Triassic. The continental arc volcanic activity resulted from subsequent strengthened subduction, forming the andesite in the North Qiangtang backarc basin. Afterwards, the limestone was formed after the cessation of magmatic activity. The information gleaned from the Batang Group strata helped constrain the evolution of the paleo-Jomda island arc and Jinshajiang oceanic subduction in the Late Triassic. | LI Huan XI Xiaoshuang SUN Huashan KONG Hua WU Qianhong WU Chengming Jillian Aira S.GABO-RATIO | 2016 | Acta Geologica Sinica(English Edition)2016，90，2： | 3 |
| 4 | Effects of free-air CO_2 enrichment on adventitious root development of rice under low and normal soil nitrogen levels显示文摘Free air CO2 enrichment(FACE) and nitrogen(N) have marked effects on rice root growth,and numerical simulation can explain these effects. To further define the effects of FACE on root growth of rice, an experiment was performed, using the hybrid indica cultivar Xianyou63. The effects of increasing atmospheric CO2 concentration [CO2], 200 μmol mol-1higher than ambient, on the growth of rice adventitious roots were evaluated, with two levels of N: low(LN, 125 kg ha-1) and normal(NN, 250 kg ha-1). The results showed a significant increase in both adventitious root number(ARN) and adventitious root length(ARL) under FACE treatment. The application of nitrogen also increased ARN and ARL, but these increases were smaller than that under FACE treatment. On the basis of the FACE experiment, numerical models for rice adventitious root number and length were constructed with time as the driving factor. The models illustrated the dynamic development of rice adventitious root number and length after transplanting, regulated either by atmospheric [CO2] or by N application.The simulation result was supported by statistical tests comparing experimental data from different years, and the model yields realistic predictions of root growth. These results suggest that the models have strong predictive potential under conditions of atmospheric [CO2] rises in the future. | Chengming Sun Lijian Wang Tao Liu Doudou Guo Yingying Chen Wei Wu Yulong Wang Jianguo Zhu | 2014 | The Crop Journal2014，2，4： | 2 |
| 5 | Phosphate-induced interfacial electronic engineering in VPO_(4)-Ni_(2)P heterostructure for improved electrochemical water oxidation显示文摘Anodic oxygen evolution reaction(OER)is the key bottleneck for water electrolysis technique owing to its sluggish reaction kinetics.Interfacial engineering on the rationally designed heterostructure can regulate the electronic states efficiently for intrinsic activity improvement.Here,we report a co-phosphorization approach to construct a VPO_(4)-Ni_(2)P heterostructure on nickel foam with strongly chemical binding,wherein phosphate acts as electronic modifier for Ni_(2)P electrocatalyst.Profiting from the interfacial interaction,it is uncovered that electron shifts from Ni_(2)P to VPO_(4)to render valence increment in Ni species.Such an electronic manipulation rationalizes the chemical affinities of various oxygen intermediates in OER pathway,giving a substantially reduced energy barrier.As a result,the advanced VPO_(4)-Ni_(2)P heterostructure only requires an overpotential of 289 mV to deliver a high current density of 350 mA/cm^(2)for OER in alkaline electrolyte,together with a Tafel slope as low as 28 mV/dec.This work brings fresh insights into interfacial engineering for advanced electrocatalyst design. | Kun Chen Keke Mao Yu Bai Delong Duan Shuangming Chen Chengming Wang Ning Zhang Ran Long Xiaojun Wu Li Song Yujie Xiong | 2022 | Chinese Chemical Letters2022，33，1： | 1 |
| 6 | A benign preparation of sec-butanol via transesterification from sec-butyl acetate using the acidic imidazolium ionic liquids as catalysts 显示文摘 | WANG Hongxing WU Chengming BU Xiangwei | 2014 | Chemical Engineering Journal2014，，246： | 1 |
| 7 | Efficacy of Qingre Huayu Fang (清热化瘀方) on atherosclerotic vulnerable plaque in apolipoprotein E knockout mice:proteasome pathway involvement显示文摘OBJECTIVE: To investigate the efficacy and mechanism of the Qingre Huayu Fang(清热化瘀方) on atherosclerotic vulnerable plaque in apolipoprotein E(Apo E) knockout mice through the ubiquitin proteasome pathway.METHODS: Sixty 8-week-old C57BL/6J Apo E knockout mice were fed a high-fat for 12 weeks and randomly divided into four treatment groups(n = 15 each): high-fat control, bortezomib(a proteasome inhibitor), bortezomib combined with Qingre Huayu Fang, and Qingre Huayu Fang alone. Aortic sections were examined for plaque development, inflammatory cell infiltration, type Ⅰ/Ⅲ collagen expression and immunohistochemical staining of CD40L, nuclear factor-kappa B(NF-κB)/P65 and ubiquitin.RESULTS: Mice in the high-fat control group had obvious atherosclerosis, with increased aortic plaque area. The degree of atherosclerosis of the atherosclerotic plaque was reduced in all of the treatment groups that received bortezomib and/or Duzhong(Cortex Eucommiae) Qingre Huayu. The expression of NF-?B, CD40L and ubiquitin were all reduced in the group that received combination bortezomib + Qingre Huayu Fang.CONCLUSION: The Qingre Huayu Fang inhibited aortic atherosclerosis in mice through a mechanism that may involve inhibition of the ubiquitin proteasome pathway. | PANG Jun CHENG Wenli PENG Jingbing LI Hong WU Qiang LI Ling LIU Chengming LIU Wei HUANG Jing | 2021 | Journal of Traditional Chinese Medicine2021，41，3： | 1 |
| 8 | Enhanced O2 reduction on atomically thin Pt-based nanoshells by integrating surface facet, interfacial electronic, and substrate stabilization effects显示文摘 | Wei Ye Zhongti Sun Chengming Wang Mengshan Ye Chenhao Ren Ran Long Xusheng Zheng Junfa Zhu Xiaojun Wu Yujie Xiong | 2018 | Nano Research2018，11，6： | 1 |
| 9 | Robustness of general decay stability of nonlinear neutral stochastic functional differential equations with infinite delay显示文摘 | WU Fuke HU Shigeng HUANG Chengming | 2010 | Systems & Control Letters2010，59，34： | 1 |
| 10 | Multi-Site Spectrographic and Heliographic Observations of Radio Fine Structure on April 10, 2001显示文摘 | G. P. Chernov R. A. Sych Yihua Yan Qijun Fu Chengming Tan Guangli Huang De-Yu Wang Hongao Wu | 2006 | Solar Physics2006，，2： | 1 |
| 11 | Integrating bimetallic AuPd nanocatalysts with a 2D aza-fused π-conjugated microporous polymer for light-driven benzyl alcohol oxidation显示文摘Efficient catalytic system with low energy consumption exhibits increasing importance due to the upcoming energy crisis.Given this situation,it should be an admirable strategy for reducing energy input by effectively utilizing incident solar energy as a heat source during catalytic reactions.Herein,aza-fused7 r-conjugated microporous polymer(aza-CMP)with broad light absorption and high photothermal conversion efficiency was synthesized and utilized as a support for bimetallic AuPd nanocatalysts in light-driven benzyl alcohol oxidation.The AuPd nanoparticles anchored on aza-CMP(aza-CM P/Au_xPdy)exhibited excellent catalytic performance for benzyl alcohol oxidation under 50 mW/cm^2 light irradiation.The improved catalytic performance by the aza-CMP/Au_xPdy is attributed to the unique photothermal effect induced by aza-CMP,which can promote the catalytic benzyl alcohol oxidation occurring at Au Pd.This work presents a novel approach to effectively utilize solar energy for conventional catalytic reactions through photothermal effect. | Yunong Li Lei Wang Jingxiang Low Di Wu Canyu Hu Wenbin Jiang Jun Ma Chengming Wang Ran Long Li Song Hangxun Xu Yujie Xiong | 2020 | Chinese Chemical Letters2020，31，1： | 1 |
| 12 | 13CO mapping study for massive molecular cloud cores显示文摘 | Yuefang Wu Junzhi Wang Jingwen Wu Huirong Yan Chengming Lei Jinjiang Sun Liming Wang | 2001 | Science in China Series A: Mathematics2001，，4： | 1 |
| 13 | High-velocity molecular outflows hear massive young stellar objects显示文摘 | Yuefang Wu Chuanyi Yang Yuexing Li Chengming Lei Jinjiang Sun Jing Lü Fu Han | 1999 | Science in China Series A: Mathematics1999，，7： | 1 |
| 14 | High-velocity molecular outflows hear massive young stellar objects显示文摘 | Yuefang Wu Chuanyi Yang Yuexing Li Chengming Lei Jinjiang Sun Jing Lü Fu Han | 1999 | Science in China Series A: Mathematics1999，，7： | 1 |
| 15 | Evaluation of SmCo and SmCoN magnetron sputtering coatings for SOFC interconnect applications 显示文摘 | Wu Junwei Li Chengming Christopher Johnson | 2008 | Journal of Power Sources2008，175，： | 1 |
| 16 | Struc- ture and Catalytic Properties of K-Doped Manganese Oxide Supported on Alumina 显示文摘 | Tang Qinghu Huang Xiaonan Wu Chengming | 2009 | J Mol Catal A : Chem2009，306，12： | 1 |
| 17 | In- sights into the Nature of Alumina-Supported MnOOH and Its Catalytic Performance in the Aerobic Oxidation of Benzyl Al- cohol显示文摘 | Tang Qinghu Gong Xiaonan Wu Chengming | 2009 | Catal Commum2009，10，7： | 1 |
| 18 | Robustness of general decay stability of nonlinear neutral stochastic functional differential equations with infinite delay 显示文摘 | Wu Fuke Hu Shigeng Huang Chengming | 2010 | Systems and Control Letters2010，59，3： | 1 |
| 19 | Stochastic sta- bility of a class of unbounded delay neutral stochastic differential equations with general decay rate 显示文摘 | Hu Yangzi Wu Fuke Huang Chengming | 2012 | Inter- national Journal of Systems Science2012，43，2： | 1 |
| 20 | Role of the Cu-ZrO_(2) interface in the hydrogenation of levulinic acid to γ-valerolactone显示文摘Here we exquisitely fabricated Cu/ZrO_(2)-dp catalysts with plentiful Cu-ZrO_(2)interfaces by depositing amorphous ZrO_(2)onto Cu nanoparticles for the hydrogenation of levulinic acid(LA)to y-valerolactone(GVL).With the created plentiful CU-ZrO_(2)interfaces,the optimal catalyst 3 Cu/ZrO_(2)-dp exhibited exceptional catalytic performance under mild reaction conditions,and achieved the highest GVL mass productivity of 266.0 mmol GVL·h^(-1)·g^(-1)Cu,which was 12.5 and 2.3 times of CU/ZrO_(2)catalysts with equivalent Cu loadings prepared by traditional impregnation(3 Cu/ZrO_(2)-im)or co-precipitation(3 Cu/ZrO_(2)-cp).As far as we know,this GVL mass productivity stood at the highest level compared with those obtained using non-noble metal catalysts under similar reaction conditions.By systematic investigation with multiple characterizations,density functional theory(DFT)calculations,and kinetic studies,it was found that interfacial active centers were created at Cu-ZrO_(2)interfaces,which contained oxygen vacancies(O_(v)),negatively charged Cu^(δ)-and partially reduced Zr^(3+)The O_(v) favored the adsorption and activation of LA via its ketone group,while negatively charged Cu^(δ)-was able to enhance heterolysis of H2,which resulted in the formation of H^(+)-Cu^(δ)-and Zr^(3+)-H^(-)active species via hydrogen spillover.Also,plentiful acid sites,which derived from coordinatively unsaturated and defective Zr species,generated at Cu-ZrO_(2)interfaces.With the cooperation of interfacial active centers(Cu^(δ-)-O_(v)-Zr^(3+))and acid sites,the fabricated 3 Cu/ZrO_(2)-dp with plentiful Cu-ZrO_(2)interfaces achieved excellent catalytic performance for the hydrogenation of LA to GVL.Hence,the synergistic catalysis of Cu-ZrO_(2)interfaces provided an effective strategy for designing catalysts with a satisfactory performance for the hydrogenation of LA,which also can be expanded to other hydrodeoxygenation reactions. | Ziyi Li Haigang Hao Jingjing Lu Chengming Wu Rui Gao Jifan Li Chun-Ling Liu Wen-Sheng Dong | 2021 | Journal of Energy Chemistry2021，30，10： | 1 |
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