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| 1 | Review on modelling of corrosion under droplet electrolyte for predicting atmospheric corrosion rate显示文摘Atmospheric corrosion of metals is the most common type of corrosion which has a significant impact on the environment and operational safety in various situations of everyday life.Some of the common examples can be observed in land,water and air transportation systems,electronic circuit boards,urban and offshore infrastructures.The dew drops formed on metal surface due to condensation of atmospheric moisture facilitates corrosion as an electrolyte.The corrosion mechanisms under these droplets are different from classically known bulk electrolyte corrosion.Due to thin and non-uniform geometric thickness of the droplet electrolyte,the atmospheric oxygen requires a shorter diffusion path to reach the metal surface.The corrosion under a droplet is driven by the depletion of oxygen in the center of the droplet compared to the edge,known as differential aeration.In case of a larger droplet,differential aeration leads to preferential cathodic activity at the edge and is controlled by the droplet geometry.Whereas,for a smaller droplet,the oxygen concentration remains uniform and hence cathodic activity is not controlled by droplet geometry.The geometry of condensed droplets varies dynamically with changing environmental parameters,influencing corrosion mechanisms as the droplets evolve in size.In this review,various modelling approaches used to simulate the corrosion under droplet electrolytes are presented.In the efforts of developing a comprehensive model to estimate corrosion rates,it has been noted from this review that the influence of geometric evolution of the droplet due to condensation/evaporation processes on corrosion mechanisms are yet to be modelled.Dynamically varying external factors like environmental temperature,relative humidity,presence of hygroscopic salts and pollutants influence the evolution of droplet electrolyte,making it a complex phenomenon to investigate.Therefore,an overview of available dropwise condensation and evaporation models which describes the formation and the evolution of droplet geometry are also presented from an atmo s pheric corrosion viewpoint. | Bangalore Gangadharacharya Koushik Nils Van den Steen Mesfin Haile Mamme Yves Van Ingelgem Herman Terryn | 2021 | Journal of Materials Science & Technology2021，，3： | 3 |
| 2 | Towards Cr(VI)-free anodization of aluminum alloys for aerospace adhesive bonding applications: A review显示文摘 | Shoshan T. Abrahami John M.M. de Kok Herman Terryn Johannes M.C. Mol | 2017 | Frontiers of Chemical Science and Engineering2017，11，3： | 3 |
| 3 | SKPFM and SEM study of the deposition mechanism of Zr/Ti based pre-treatment on AA6016 aluminum alloy显示文摘 | F. Andreatta A. Turco I. de Graeve H. Terryn J.H.W de Wit L. Fedrizzi | 2007 | Surface & Coatings Technology2007，，18： | 2 |
| 4 | New insights into the mechanism of localised corrosion induced by TiN-containing inclusions in high strength low alloy steel显示文摘This work investigated the chemical and electrochemical mechanisms of localised corrosion triggered by CaS·xMgO·y Al_(2)O_(3)·TiN complex inclusions in high strength low alloy steel(HSLAS)under a simulated marine environment.Special focus was given to the role of the TiN portion of the inclusion on the initiation and growth of the corrosion pits.The thermodynamic process of pitting initiation was investigated by Gibbs free energy,Pourbaix diagram and first principle calculation.Localised corrosion is mainly induced by inclusions and triggered by dissolution of adjacent distorted matrix.Chemical dissolution of CaS portion in CaS·xMgO·y Al_(2)O_(3)·TiN complex inclusion creates an acidic aggressive environment that accelerates the further dissolution of inclusion and matrix.Galvanic coupling effect between TiN inclusion and matrix is directly verified.TiN covered with a TiOfilm acts as the cathodic phase in galvanic corrosion,although it has a lower Volta potential than the matrix.This is an unusual correlation with the scanning Kelvin probe force microscopy result,which has been explained for this special system. | Chao Liu Reynier I.Revilla Xuan Li Zaihao Jiang Shufeng Yang Zhongyu Cui Dawei Zhang Herman Terryn Xiaogang Li | 2022 | Journal of Materials Science & Technology2022，，29： | 2 |
| 5 | A transmission electron microscopy study of hard anodic oxide layers on AlSi(Cu) alloys 显示文摘 | FRATILA-APACHINTEI L E TICHELAAR F D THOMPSON G E TERRYN H SKELDON P DUSZCZYK J | 2004 | Electrochimica Acta2004，49，19： | 1 |
| 6 | Phenytoin intoxication in critically ill patients显示文摘 | de Schoenmakere G de Waele J Terryn W | 2005 | Am J Kidney Dis2005，45，1： | 1 |
| 7 | Delayed grit function inrenal transplantation显示文摘 | Peters P Terryn W Vanholder R et a1 | 2004 | Curtan Crit Care2004，10，6： | 1 |
| 8 | GTP - binding proteins in plants 显示文摘 | Terryn N Van M Inze D | 1993 | Plant MoL Biol1993，22，： | 1 |
| 9 | Corrosion behavior of different tempers of AA7075 aluminum alloy显示文摘 | Andreatta F Terryn H de Wit J H W | 2004 | Electrochim Acta2004，49，17： | 1 |
| 10 | Effect of solution heat treatment on galvanic coupling be-tween intermetallics and matrix in AA7075-T6显示文摘 | ANDREATTA F TERRYN H DEWIT J H W | 2003 | Corrosion Science2003，45，： | 1 |
| 11 | Electrochemical characterisation of aluminum AA7075-T6 and solution heat treated AA7075 using a micro-capillary cell显示文摘 | ANDREATTA F LOHRENGEL M M TERRYN H | 2003 | Electrochimica Acta2003，48，2003： | 1 |
| 12 | Effect of solution heat treatment on galvanic coupling between intermetallics and matrix in AA7075-T6显示文摘 | F. Andreatta H. Terryn J.H.W. de Wit | 2003 | Corrosion Science2003，，8： | 1 |
| 13 | Management of Bladder Function after Outpatient Surgery显示文摘 | Janet D. Pavlin Edward G. Pavlin Dermot R. Fitzgibbon Meagan E. Koerschgen Terryn M. Plitt | 1999 | Anesthesiology1999，，1： | 1 |
| 14 | Investiga- tion of the barrier properties of silanes on cold rolled steel 显示文摘 | Schaftinghen T V Pena C L Terryn H | 2004 | Electrochimica Acta2004，49，1718： | 1 |
| 15 | Effect of solution heat treatment on galvanic coupling between intermetallics and matrix in AA7075-T6显示文摘 | Andreatta F Terryn H de Wit J H W | 2003 | Corrosion Science2003，8，45： | 1 |
| 16 | Correlation between hydroxyl fraction and O/AI atomic ratio as determined from XPS spectra of aluminium oxide layers 显示文摘 | VAN DEN BRAND J SLOOF W G TERRYN H | 2004 | Surface and Interface Analysis2004，36，1： | 1 |
| 17 | Silane coating of metal substrates: Complementary use of electrochemical, optical and thermal analysis for the evaluation of film properties显示文摘 | I. De Graeve J. Vereecken A. Franquet T. Van Schaftinghen H. Terryn | 2006 | Progress in Organic Coatings2006，，3： | 1 |
| 18 | Composition and thickness of non- functional organosilane films coated on aluminium stud- ied by means of infra-red spectroscopic ellipsometry显示文摘 | Franquet A Terryn H | 2003 | Thin Solid Films2003，441，1： | 1 |
| 19 | Formation of a cerium-based conversion coating on AA2024 : relationship with the microstructure 显示文摘 | Campestrini P Terryn H Hovestad A | 2004 | Surface and Coatings Technology2004，176，： | 1 |
| 20 | Corrosion behaviour of different tempers of AA7075 aluminium alloy显示文摘 | F Andreatta H Terryn De Wit | 2004 | Electroehimiea Acta2004，49，1718： | 1 |
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