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| 1 | A review on completing arsenic biogeochemical cycle: Microbial volatilization of arsines in environment显示文摘Arsenic(As) is ubiquitous in the environment in the carcinogenic inorganic forms, posing risks to human health in many parts of the world. Many microorganisms have evolved a series of mechanisms to cope with inorganic arsenic in their growth media such as transforming As compounds into volatile derivatives. Bio-volatilization of As has been suggested to play an important role in global As biogeochemical cycling, and can also be explored as a potential method for arsenic bioremediation. This review aims to provide an overview of the quality and quantity of As volatilization by fungi, bacteria, microalga and protozoans. Arsenic bio-volatilization is influenced by both biotic and abiotic factors that can be manipulated/elucidated for the purpose of As bioremediation. Since As biovolatilization is a resurgent topic for both biogeochemistry and environmental health, our review serves as a concept paper for future research directions. | Peipei Wang Guoxin Sun Yan Jia Andrew A Meharg Yongguan Zhu | 2014 | Journal of Environmental Sciences2014,26,2: | 22 |
| 2 | Silencing RhoA inhibits migration and invasion through Wnt/β-catenin pathway and growth through cell cycle regulation in human tongue cancer显示文摘地岬相当或相同的事物基因家庭成员 A (RhoA ) 作为肿瘤的一个批评管理者被识别了好攻击的行为。在 thisstudy,我们在位于有鳞的细胞 carcinomaof 舌头(TSCC ) 的生长,移植,和侵略下面的机制估计了 RhoA 的角色。TSCC 房间线 SCC-4 和 CAL27 击倒的稳定的 RhoA 用 Lentiviral transfection 被完成。房间移植,侵略,和房间增长上的 RhoA 弄空的 Theeffects 是坚定的。TSCC 房间线上的可能的位于决定 Galectin-3 (Gal-3 ) 的表示下面 mechanismof RhoA 弄空被也评估,在 vivo 的 -catenin, andmatrix metalloproteinase-9 (MMP-9 ) 。同时, TSCC 生长的内在的机制被 cyclin D1/2 的分析学习, p21 CIP1/WAF1 , 和 p27 Kip1 蛋白质层次。Immunohistochemical 评价被执行进一步证明 Gal-3 和 -catenin expression.We 的改变发现了那,在与在舌头的人的 TSCC 房间注射的老鼠, RhoA 层次与在正常纸巾的那些相比在主要肿瘤和 metastasizedlymph 节点是更高的。RhoA 的 Silencing 显著地减少了肿瘤生长, Gal-3 的 decreasedthe 层次, -catenin, MMP-9,和 cyclin D1/2,并且增加了 p21 CIP1/WAF1 和 p27 Kip1 。在 vitro, RhoA 击倒也导致了房间移植,侵略,和增长的抑制。我们的数据建议 RhoA 由通过分别地通过房间周期规定表明小径 andcell 增长的 Wnt/-catenin 调整房间移植和侵略在 TSCC 前进起 asignificant 作用。RhoA 可能是 TSCC 的一个新奇治疗学的目标。 | Guoxin Yan Ronghai Zou Zhenggang Chen Bing Fan Zhaoyan Wang Ying Wang Xiaonan Yin Dong Zhang Lei Tong Fang Yang Weina Jiang Wensheng Fu Jiwei Zheng Martin O. Bergo Martin Dalin Jiawei Zheng Shulan Chen Jianhua Zhou | 2014 | Acta Biochimica et Biophysica Sinica2014,46,8: | 7 |
| 3 | Hierarchical peony-like FeCo-NC with conductive network and highly active sites as efficient electrocatalyst for rechargeable Zn-air battery显示文摘Carbon materials featuring hierarchical pores and atomically dispersed metal sites are promising catalysts for energy storage and conversion applications.Herein,we developed a facile strategy to construct functional carbon materials with a fluffy peony-like structure and dense binary FeCo-Nx active sites(termed as f-FeCo-CNT).By regulating the metal content in precursors,a three-dimensional(3D)interconnected conductive carbon nanotubes network was in-situ formed throughout the atomically dispersed FeCo-NC matrix during pyrolysis.Taking advantage of rich pore hierarchy and co-existence of highly active FeCo-Nx sites and beneficial FeCo alloy nanoparticles,the f-FeCo-CNT material exhibited excellent bifunctional performance towards oxygen reduction reaction/oxygen evolution reactions(ORR/OER)with respect to the atomically dispersed FeCo-NC(SA-f-FeCo-NC)and commercial Pt/C+Ru02 mixture,surpassing the SA-f-FeCo-NC with a 20 mV higher ORR half-wave potential and a 100 mV lower OER overpotential(at 10.0 mA/cm^2).Remarkably,the f-FeCo-CNT-assembled Zn-air battery(ZAB)possessed a maximum specific power of 195.8 mW/cm^2,excellent rate capability,and very good cycling stability at large current density of 20.0 mA/cm^2.This work provides a facile and feasible synthetic strategy of constructing low-cost cathode materials with excellent comprehensive ZAB performance. | Yiyan Wang Anuj Kumar Mang Ma Yin Jia Yu Wang Ying Zhang Guoxin Zhang Xiaoming Sun Zifeng Yan | 2020 | Nano Research2020,13,4: | 5 |
| 4 | Taking advantage of glass:capturing and retaining the helium gas on the moon显示文摘Helium-3(3He)is a noble gas that has critical applications in scientific research and promising application potential as clean fusion energy.It is thought that the lunar regolith contains large amounts of helium,but it is challenging to extract because most helium atoms are reserved in defects of crystals or as solid solutions.Here,we find large amounts of helium bubbles in the glassy surface layer of ilmenite particles that were brought back by the Chang’E-5 mission.The special disordered atomic packing structure of glasses should be the critical factor for capturing the noble helium gas.The reserves in bubbles do not require heating to high temperatures to be extracted.Mechanical methods at ambient temperatures can easily break the bubbles.Our results provide insights into the mechanism of helium gathering on the moon and offer guidance on future in situ extraction. | Ao Li Xiao Chen Lijian Song Guoxin Chen Wei Xu Juntao Huo Meng Gao Ming Li Lei Zhang Bingnan Yao Min Ji Yan Zhang Shaofan Zhao Wei Yao Yanhui Liu Jun-Qiang Wang Haiyang Bai Zhigang Zou Mengfei Yang Weihua Wang | 2022 | Materials Futures2022,1,3: | 2 |
| 5 | In situ real-time study buckling behavior of boron nitride nanotubes with axial compression by TEM显示文摘Boron nitride nanotubes(BNNTs)were treated as brittle materials and could be used to enhance the composite mechanical properties.Many approaches were used to verify the theoretical prediction experimentally,but how to in situ real-time characterize nanomechanical properties of BNNTs was still interested to the researchers.An in situ transmission electron microscopy(TEM)equipped with a force transducer holder had been used to study the structure evolution behavior of BNNTs with axial compression.Real-time video and the force transducer had been used synchronously to record the whole force loading process where the mechanical deformation of BNNT began,buckled and ended with fracture.An in dividual ultrathin BNNT was employed to con duct the loading test.The results showed that the elastic deformation happened on the BNNT.Young's modulus?1.05-1.37 Tpa and elasticity coefficient?198.7-255.9 N/m of BNNT were calculated by Euler formula and Hooker's law,respectively. | Guoxin Chen Huanming Lu Junfeng Cui Haitao Yu Bo Wang Yan Liu He Li Nan Jiang | 2019 | Chinese Chemical Letters2019,30,7: | 2 |
| 6 | Application and Development Prospect of Se-rich & High-Ca Organic Fertilizer显示文摘Se is one of trace elements necessary for the human body,and human body could absorb Se via the food. Se intake is insufficient in 2/3 region of China,which seriously affects health of local residents. Therefore,the research of Se-rich fertilizer and the development of Se-rich product become the research focus in food science,medicine and other fields. There are rich marine resources in Beibu Gulf waters of Guangxi,and much carapace organic waste is generated. These carapace waste not only has high Se content but also is composed of a lot of Ca. The preparation of Se-rich & high-Ca fertilizer by these carapace waste not only reaches the target of recycling and environment friendly but also increases the yield of agricultural products,reduces diseases and pests,improves quality,increases the added value of agricultural product,which brings better economic benefit and meets people's demand for healthy food. | Sha Guoxin Huang Wei Liu Yongxian Pan Liping Song Yan Zhang Yu Wang Daobo | 2018 | Meteorological and Environmental Research2018,9,3: | 2 |
| 7 | Heterojunction interface editing in Co/NiCoP nanospheres by oxygen atoms decoration for synergistic accelerating hydrogen and oxygen evolution electrocatalysis显示文摘Controllable designing of well-defined heterojunction nanostructures provides an insightful strategy for accelerating the kinetics of the hydrogen and oxygen evolution reactions(HER/OER),but such task is still challenging.Herein,we proposed a protocol of heterojunction interface editing(HIE)strategy by oxygen atoms decoration for synergistic boosting electrocatalytic HER and OER performances.A novel Co/NiCoP nanospheres(NSs)heterojunction was synthesized by crystal seed template transformation method with Ni_(5)P_(4) microspheres as seeds.The effective oxygen atoms interface editing increased the oxidation state of Co atoms and prolonged the Co-P bond length of Co/NiCoP NSs heterojunction,thus the electron localization on P sites was enhanced,leading to the dramatically elevated HER and OER performances simultaneously.The as-constructed O-Co/NiCoP NSs show excellent electrocatalytic activity with 361 and 430 mV vs.reversible hydrogen electrode(RHE)to arrive high current density of 300 mA·cm^(-2)for HER and OER in 1 M KOH as well as good stability.The proposed HIE concept could provide a new perspective on the catalyst design for energy conversion systems. | Yan Lin Xiaojiao Cui Yilin Zhao Zhicheng Liu Guoxin Zhang Yuan Pan | 2023 | Nano Research2023,16,7: | 1 |
| 8 | A MDM 2‐dependent positive‐feedback loop is involved in inhibition of mi R ‐375 and mi R ‐106b induced by H elicobacter pylori lipopolysaccharide显示文摘 | Feng Ye Chunli Tang Weijia Shi Juan Qian Shuping Xiao Min Gu Yini Dang Jianping Liu Yan Chen Ruihua Shi Guoxin Zhang | 2015 | Cancer2015,,9: | 1 |
| 9 | Cadmium ( ]I ) biosorption from aqueous solutions using Hydrilla verticiUata 显示文摘 | LI Guoxin YAN Changzhou ZHANG Dandan | 2013 | The Canadian Journal of ChemicaI Engineering2013,91,6: | 1 |
| 10 | Levels of estrogenic compounds in Xiamen Bay sediment, China显示文摘 | Xian Zhang Qingzhao Li Guoxin Li Zaosheng Wang Changzhou Yan | 2009 | Marine Pollution Bulletin2009,,8: | 1 |
| 11 | Twinning,phase boundary structure and development of high coercivity in Fe-rich Sm_(2)Co_(17)-type magnets显示文摘The microstructure of twinning as well as the phase boundary between 1:5 H and 2:17 R phase in Fe-rich Sm_(2)Co_(17)-type magnets was characterized at atomic scale using nanobeam diffraction and highresolution STEM-HAADF imaging,and the reason for the dramatic increase of coercivity during slow cooling was investigated based on the microchemistry analysis.The twinning relationship in the 2:17 R phase originates from ordered substitution of Sm atoms by Co-Co atomic pairs on every three(3033)and(3033)planes,leading to formation of two corresponding equivalent twin variants.The basal plane of the 2:17 R phase,the 1:3 R platelet phase across the 2:17 R cell and the 1:5 H cell boundary phase between two adjacent 2:17 R cells all can act as effective twin boundary.The cell boundary phase is precipitated along the pyramidal habit plane,and a fully coherent phase boundary(PB)is formed between the 1:5 H and 2:17 R phases with the orientation relationship to be PB//(1121)1:5 H//(1011)_(2):17 R.The phase boundary may either be parallel to or intersect with the pyramidal planes occupied by Co-Co atomic pairs.The substantial increase of coercivity during slow cooling is ascribed to the development of large gradient of the elements concentration within the cell boundary phase,resulting in large gradient of domain wall energy,and thus the pinning strength of the cell boundary phase against magnetic domain wall motion is significantly enhanced. | Haichen Wu Zhuang Liu Chaoyue Zhang Qiqi Yang Huanming Lu Guoxin Chen Xinming Wang Yong Li Renjie Chen Aru Yan | 2022 | Journal of Rare Earths2022,40,1: | 1 |
| 12 | Computational models of flatfoot with three-dimensional fascia and bulk soft tissue interaction for orthosis design显示文摘The finite element(FE)method has been widely used to investigate the internal force of plantar fascia,which could reveal the relationship between plantar fascia dysfunction and flatfoot deformity during weight-bearing conditions.However,for most foot FE models,plantar fascia utilized truss elements or three-dimensional geometry that did not consider the interaction between plantar fascia and bulk soft tissue.These configurations could ignore the impact of superoinferior loading induced by arch support and underestimate the plantar fascia loading.This study aims to investigate how the fascia-bulk soft tissue interaction affects the internal foot biomechanics in the flatfoot FE analysis with a three-dimensional plantar fascia model,which included both fascia-bone and fascia-bulk soft tissue interactions(3DBPT).To evaluate the effect of fascia-bulk soft tissue interaction on internal foot mechanics,this study compared the 3DBPT model with the other two plantar fascia models,including linear fascia(BPL)and three-dimensional plantar fascia without fascia-bulk soft tissue interaction(3DBP).The predicted foot contact pressure in the 3DBPT model was compared with the measured value obtained by the F-Scan pressure measurement system in balanced standing.Peak von Mises stresses in the plantar fascia and foot ligaments were reported.The stress of the plantar fascia in the 3DBPT model was higher than that of 3DBP.In the 3DBPT model,the superoinferior loading exerted on the bulk soft tissue could be directly transferred to the plantar fascia.The proposed model,including the plantar fascia and bulk soft tissue interaction,could reveal relatively reliable plantar fascia loading in flatfoot deformity,thereby contributing to the development of orthotic designs for the flatfoot deformity. | Yinghu Peng Duo Wai-Chi Wong Yan Wang Tony Lin-Wei Chen Guoxin Zhang Fei Yan Ming Zhang | 2021 | Medicine in Novel Technology and Devices2021,,1: | 1 |
| 13 | Effect of Amino-,Methyl- and Epoxy-Silane Coupling as a Molecular Bridge for Formatting a Biomimetic Hydroxyapatite Coating on Titanium by Electrochemical Deposition显示文摘The objective of this study was to determine the role of functional groups of silane coupling on bioactive titanium(Ti) surface by electrochemical deposition, and calcium phosphate(CaP) coating, as well as bone cell adhesion and proliferation. Methyl group(—CH_3), amino group(—NH_2), and epoxy group(—glyph name—C(O)C) were introduced onto the bioactive Ti surface using self-assembled monolayers(SAMs)with different silane coupling agents as molecular bridges. The effect of the surface functional groups on the growth features of the CaP crystals was analyzed(including chemical compositions, element content,minerals morphology and crystal structure etc.). CH_3- terminated SAMs showed a hydrophobic surface and others were hydrophilic by contact angle measurement; NH_2-terminated SAMs showed a positive charge and others were negatively charged using zeta-potential measurement. Scanning electron microscopy results confirmed that flower-like structure coatings consisting of various pinpoint-like crystals were formatted by different functional groups of silane coupling, and the CaP coatings were multicrystalline consisting of hydroxyapatite(HA) and precursors. Ca P coating of CH_3- terminated SAMs exhibited more excellent crystallization property as compared to coatings of —NH_2 and —C(O)C groups. In vitro MC3T3-E1 cells adhesion and proliferation were performed. The results showed that CaP coatings on silane coupling functionalized surfaces supported cell adhesion and proliferation. Thus, these functional groups of silane coupling on Ti can form homogeneous and oriented nano-CaP coatings and provide a more biocompatible surface for bone regeneration and biomedical applications. | Guoxin Tan Kongyou Ouyang Hang Wang Lei Zhou Xiaolan Wang Yan Liu Lan Zhang Chengyun Ning | 2016 | Journal of Materials Science & Technology2016,32,9: | 1 |
| 14 | Comparison of real-time reverse transcription loop-mediated isothermal amplification and real-time reverse transcription polymerase chain reaction for duck Tembusu virus显示文摘 | Liping Yan Shan Peng Pixi Yan Jiewen Zhou Qiaoyang Teng Guoxin Li Xuesong Li Zejun Li | 2012 | Journal of Virological Methods (-)2012,,1: | 1 |
| 15 | Expression of an Arabidopsis vacuolar sodium/proton antiporter gene in cotton improves photosynthetic performance under salt conditions and increases fiber yield in the field显示文摘 | Cixin He Juqiang Yan Guoxin Shen | 2005 | Plant Cell Physiol2005,45,11: | 1 |
| 16 | Arsenic accumulation and speciation in the submerged macrophyte Ceratophyllum demersum L.显示文摘 | Peiying Xue Changzhou Yan Guoxin Sun Zhuanxi Luo | 2012 | Environmental Science and Pollution Research2012,,9: | 1 |
| 17 | Boosting the Ni-Zn interplay via O/N dual coordination for high-efficiency CO_(2) electroreduction显示文摘Design of supportive atomic sites with a controllably adjusted coordinating environment is essential to advancing the reduction of CO_(2) to value-added fuels and chemicals and to achieving carbon neutralization.Herein,atomic Ni(Zn)sites that are uniquely coordinated with ternary Zn(Ni)/N/O ligands were successfully decorated on formamide-derived porous carbon nanomaterials,possibly forming an atomic structure of Ni(N_(2)O_(1))-Zn(N_(2)O_(1)),as studied by combining X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.With the mediation of additional O coordination,the Ni-Zn dual site induces significantly decreased desorption of molecular CO.The NiZn-NC decorated with rich Ni(N_(2)O_(1))-Zn(N_(2)O_(1))sites remarkably gained>97%CO Faraday efficiency over a wide potential range of -0.8 to -1.1 V(relative to reversible hydrogen electrode).Density functional theory computations suggest that the N/O dual coordination effectively modulates the electronic structure of the Ni-Zn duplex and optimizes the adsorption and conversion properties of CO_(2) and subsequent intermediates.Different from the conventional pathway of using Ni as the active site in the Ni-Zn duplex,it is found that the Ni-neighboring Zn sites in the Ni(N_(2)O_(1))-Zn(N_(2)O_(1))coordination showed much lower energy barriers of the CO_(2) protonation step and the subsequent dehydroxylation step. | Ying Zhang Hailei Jiang Anuj Kumar Hongchuan Zhang Zongge Li Tongxin Xu Yuan Pan Yaqun Wang Zhiming Liu Guoxin Zhang Zifeng Yan | 2023 | Carbon Energy2023,5,4: | 0 |
| 18 | Sensitively detecting antigen of SARS-CoV-2 by NIR-Ⅱ fluorescent nanoparticles显示文摘Early detection of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)infection is an efficient way to prevent the spread of coronavirus disease 2019(COVID-19).Detecting SARS-CoV-2 antigen can be rapid and convenient,but it is still challenging to develop highly sensitive methods for effective diagnosis.Herein,a lateral flow assay(LFA)based on fluorescent nanoparticles emitting in the second near-infrared(NIR-II)window is developed for sensitive detection of SARS-CoV-2 antigen.Benefiting from the NIR-II fluorescence with high penetration and low autofluorescence,such NIR-II based LFA allows enhanced signal-to-background ratio,and the limit of detection is down to 0.01 ng·mL^(−1)of SARS-CoV-2 antigen.In the clinical swab sample tests,the NIR-II LFA outperforms the colloidal gold LFA with higher overall percent agreement with the polymerase chain reaction test.The clinical samples with low antigen concentrations(~0.015–~0.068 ng·mL^(−1))can be successfully detected by the NIR-II LFA,but fail for the colloidal gold LFA.The NIR-II LFA can provide a promising platform for highly sensitive,rapid,and cost-effective method for early diagnosis and mass screening of SARS-CoV-2 infection. | Ruibin Hu Tao Liao Yan Ren Wenming Liu Rui Ma Xinyuan Wang Qihui Lin Guoxin Wang Yongye Liang | 2022 | Nano Research2022,15,8: | 0 |
| 19 | Status,Existing Problems and Countermeasures of Industrialization of Se-enriched Agriculture in Guangxi显示文摘With the rapid development of China's agricultural production and the improvement of people's living standards and health awareness,people's demands for food quality and nutrition have become increasingly strong. Agricultural products that meet various functional needs such as nutrition,health care and safety are increasingly favored by the general public. Se,one of the trace elements necessary for the human body,has begun to be applied and developed in medicine and other life sciences. Developing Se-enriched agricultural relying on Guangxi's unique Se-enriched soil resources is of great significance to enhance people's quality of life,increase the added value of agricultural products,and promote the transformation and upgrading of modern agriculture in the region. Starting with the development status and advantages of industrial development of Se-enriched agriculture in Guangxi,the main problems existing in the current industrial development of Se-enriched agriculture in Guangxi were summarized,and specific countermeasures were put forward in this paper,so as to provide theoretical support for the development of Se-enriched agriculture in Guangxi. | Guoxin SHA Wei HUANG Yongxian LIU Daobo WANG Liping PAN Yan SONG Yu ZHANG | 2018 | Asian Agricultural Research2018,10,5: | 0 |
| 20 | Single-atom Zn for boosting supercapacitor performance显示文摘Single-atom metal-incorporated carbon nanomaterials(CMs)have shown great potential towards broad catalytic applications.In this work,we show that N-doped porous CMs embedded with redox-able Zn atoms exhibit superior capacitive performance.High Zn(~2.72 at.%)/N(~12.51 at.%)doping were realized by incorporating Zn2+and benzamide into the condensation and carbonization of formamide and subsequent annealing at 900℃.The Zn and N species are mutually benefited during the formation of ZnN4 motif.The as-obtained Zn1NC material affords a very large capacitance of 621 F·g^(−1)(at 0.1 A·g^(−1)),superior rate capability(~65%retention at 100 A·g^(−1)),and excellent cycling stability(0.00044%per cycle at 10 A·g^(−1)).These merits are attributed to the high Zn/N loading,atomic Zn-boosted pseudocapacitive behavior,large specific surface area(~1,085 m^(2)·g^(−1)),and rich pore hierarchy,thus ensuring both large pseudo-capacitance(e.g.,~37.9%at 10 mV·s^(−1))and double-layer capacitance.Besides of establishing a new type of high Zn/N-loading carbon materials,our work uncovers the capacitive roles of atomically dispersed metals in CMs. | Zongge Li Danni Wang Huifang Li Mang Ma Ying Zhang Zifeng Yan Stefano Agnoli Guoxin Zhang Xiaoming Sun | 2022 | Nano Research2022,15,3: | 0 |