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| 1 | In vitro and in vivo studies on the biodegradable behavior and bone response of Mg69Zn27Ca4 metal glass for treatment of bone defect显示文摘In the present work, the biodegradable behavior, cytocompatibility and osteogenesis activity of a Mg69Zn27Ca4 metal glass were investigated. Electrochemical test, immersion test, cytotoxicity test and histopathological evaluation were carried out. The results showed that there was a dense protective layer formed on the surface of Mg69Zn27Ca4 metal glass which could inhibit the degradation process in the Hank’s solution. In vitro cytotoxicity test showed that Mg69Zn27Ca4 metal glass had good biocompatibility. Histopathological evaluation showed that the degradation of Mg69Zn27Ca4 metal glass could promote the new bone formation with no obvious inflammatory reactions. After 2 months implantation, the diameter of the bone defect was reduced from the original φ6 mm to φ3.35 ± 0.40 mm with the degradation of Mg69Zn27Ca4 metal glass. Therefore, it can be concluded that Mg69Zn27Ca4 glass has great potential to be used as bone substitutes. | Junxiu Chen Jiahui Dong Huameng Fu Haifeng Zhang Lili Tan Dewei Zhao Ke Yang | 2019 | Journal of Materials Science & Technology2019，35，10： | 4 |
| 2 | Fe-based metallic glass:An efficient and energy-saving electrode material for electrocatalytic degradation of water contaminants显示文摘Excessive consumption of electrical energy has hampered the widespread application of electrochemical technology for degradation of various contaminants. In this paper, a Fe-based metallic glass(MG) was demonstrated as a new type of electrocatalyst to effectively and economically degrade an azo dye. In comparison to other typical electrodes, Fe-based MG electrodes exhibit a minimized degradation time, and the specific energy is 4-6 orders of magnitude lower than that of dimensionally stable anode(DSA), metal-like boron-doped diamond(BDD) and other electrodes. As sacrificial electrode materials, Fe-based MGs have less specific electrode mass consumption than iron electrodes. The use of Fe-based MGs will promote the practical application of electrochemical technology and the use of MGs as functional materials. | Xindong Qin Zhengkun Li Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2018 | Journal of Materials Science & Technology2018，34，12： | 3 |
| 3 | Correlation Between Dynamic Compressive Strength and Fracture Behaviors of Bulk Metallic Glasses显示文摘The mechanical behaviors of Zr43.5Cu43.5Ni4Al8Nb1,Zr55.4Cu31.6Ni4Al8Nb1,Ti32.8Zr30.2Ni5.3Cu9Be22.7(at.%)metallic glass at different strain rates were studied.For all the present alloys,the dispersion over 700 MPa was observed on the strength in the repeated dynamic compressions,which was much stronger than that of the quasi-static compressive strength.Such the dispersion of the dynamic compressive strength was well correlated with the corresponding fracture behaviors.The area of fracture surface was calculated and also showed a strong dispersion for all the fractured specimens tested at the strain rate of 500 s^-1 and 1000 s^-1.All the specimens showed a linear relationship between the square of dynamic compressive strength and the area of fracture surface in the dynamic compression tests.This phenomenon was mainly thought to be related to the difference of mean initial free volume concentration of different samples,stress concentration caused by the split Hopkinson pressure bar experimental setup and high sensitivity of defects under dynamic deformation.These findings were beneficial to deeply understand the effect of strain rate on the mechanical properties of the metallic glass. | Wenqing Li Zhengwang Zhu Guojie Li Long Zhang Zhengkun Li Huameng Fu Hongwei Zhang Hong Li Aimin Wang Haifeng Zhang | 2020 | Acta Metallurgica Sinica(English Letters)2020，33，10： | 2 |
| 4 | Co_(78)Si_(8)B_(14)metallic glass:A highly efficient and ultra-sustainable Fenton-like catalyst in degrading wastewater under universal pH conditions显示文摘Overcoming the pH limitation and increasing the catalyst reusability remain pressing demands for metal-lic glass(MG)in wastewater remediation.Herein,Co_(78)Si_(8)B_(14)MG ribbons are used to degrade dye wastew-ater by activating hydrogen peroxide(H_(2)O_(2))as Fenton-like catalysts.The Co-based MG catalysts exhibit high degradation efficiency under both acidic and alkaline conditions,and the kinetic reaction rate at pH 10(0.176 min^(−1)) and pH 4(0.089 min^(−1)) is 5.9 and 1.2 times higher than that of the extensively studied Fe-based MG catalysts,respectively.Impressively,the Co-based MG catalysts can be reused up to 20-60 times at universal pH conditions,demonstrating fairly good reusability.The newly discovered Co-based MG catalysts do not follow the classical Fenton reactions with H_(2)O^(2) the way Fe-based MGs do.In an acid environment,hydroxyl radicals play a dominant role in the degradation,while in an alkaline environ-ment,the effect of hydroxyl radicals is weakened,and Co^(3+) ions exert a relatively major function on the degradation.The excellent performance in catalytic activity and reusability at universal pH conditions of the Co-based MGs will inspire the development of MGs in wastewater treatment. | Xindong Qin Jiliang Xu Zhengwang Zhu Zhengkun Li Dawei Fang Huameng Fu Shiming Zhang Haifeng Zhang | 2022 | Journal of Materials Science & Technology2022，，18： | 2 |
| 5 | Mechanism and kinetics of treatment of acid orange II by aged Fe-Si-B metallic glass powders显示文摘The mechanism and kinetics of acid orange II(AOII) treated by aged gas-atomized Fe-Si-B metallic glass(MG) powders were investigated in this study. The decolorization reaction is shown to obey the pseudofirst-order kinetic model, and the treatment processes could be divided into two stages: a slow step followed by a rapid one. This observation is in accordance with the following results, the azo dye is simply adsorbed onto the Fe-based MG powders in the initial stage, because the oxide layer coated on the powder surface depresses the degradation reaction by covering the activity sites, and then the degradation occurs with the desquamation of the powders. The AOII could be degraded with a rapid reaction rate when the Fe-based MG powders are applied to the treatment process again, because of the consumption of the oxide layer and the unchanged core of the Fe-based MGs. These findings will promote the practical application of MGs in degrading azo dyes. | Xindong Qin Zhengkun Li Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2017 | Journal of Materials Science & Technology2017，33，10： | 2 |
| 6 | Thermal Residual Stresses in W Fibers/Zr-based Metallic Glass Composites by High-energy Synchrotron X-ray Diffraction显示文摘Thermal residual stresses in W fibers/Zr-based metallic glass composites were measured by in situ high energy synchrotron X-ray diffraction(HEXRD). The W fibers for the composites were 300,500,and 700 m m in diameter,respectively. Coaxial cylinder model(CCM) and finite element model(FEM) were employed to simulate the distribution of thermal residual stress,respectively. HEXRD results showed that the selected diameters of W fiber had little influence on the value of thermal residual stresses in the present composites. Thermal residual stresses simulated by CCM and FEM were in good agreement with HEXRD measured results. In addition,FEM results exhibited that thermal residual stress concentrated on interface between the two phases and area where the two W fibers were the closest ones to each other. | Xinqiang Zhang Yunfei Xue Haifeng Zhang Huameng Fu Zhengbin Wang Zhihua Nie Lu Wang | 2015 | Journal of Materials Science & Technology2015，31，2： | 1 |
| 7 | Corrosion mechanisms of Zr-based bulk metallic glass in NaF and NaCl solutions显示文摘So far,some investigations related to the corrosion mechanism of Zr-based metallic glasses in solutions containing Cl-have been developed.However,few attentions have been paid to the situation in F--containing solution.This paper describes the corrosion behaviours of Zr52Al10Ni6Cu32 bulk metallic glass(BMG)in Na F and Na Cl aqueous solutions.The corrosion mechanism of Zr-based BMG in F–containing solution was proposed for the first time.It was found that in Na Cl solutions,Zr-based BMG samples underwent typical pitting corrosion.Selective dissolution of Zr,Al and enrichment of Cu were observed in corrosion pits.However,corrosion occurred in the form of general breakdown of passive film in Na F solutions.Such difference is interpreted in terms of the binding ability of anions to surrounding molecules,i.e.,Cl-with loose surrounding water passes through the passive film to cause pitting;F-with a tight surrounding molecules layer absorbs on passive film then coordinates with cations from matrix. | Zhangweijia Qiu Zhengkun Li Huameng Fu Hongwei Zhang Zhengwang Zhu Aimin Wang Hong Li Long Zhang Haifeng Zhang | 2020 | Journal of Materials Science & Technology2020，42，11： | 1 |
| 8 | Designing new work-hardenable ductile Ti-based multilayered bulk metallic glass composites with ex-situ and in-situ hybrid strategy显示文摘To overcome the trade-off between the devisable micro structure and the excellent tensile ductility of bulk metallic glass composites(BMGCs),a novel ex-situ and in-situ hybrid strategy is successfully proposed to design a series of the work-hardenable ductile Ti-based multilayered BMGCs(ML-BMGCs).The asprepared ML-BMGCs,consisting of α-phases,β-phases and amorphous phases,exhibit a controllable multilayered structure of the Ti layers and the amorphous layers with alternative distribution.The size and volume fraction of the crystalline phases are tuned by Nb microalloying.It is found that the ML-BMGCs possess a suitable size and volume fraction of the crystalline phases when Nb microalloying content are5%(at.) or 8%(at.),and they obtain an optimum combination of the specific strength of 243 MPa g kg-1 or 216 MPa g kg-1,and tensile plasticity of 4.33%±0.1 % or 5.10%±0.1%.The deformation mechanism of the as-prepared ML-BMGCs during tension is also revealed.The ex-situ Ti layers and in-situ dendrites together effectively serve as absorbers to suppress the propagation of shear bands and multiply shear bands.And the defo rmation of ex-situ α-Ti phases by dislocation slip and the transformation from in-situ metastable β-Ti phase to orthorhombic α-Ti during tension impart significant work-hardening capability to the ML-B MGCs.The present study provides a guidance of developing novel high-performance BMGCs with a controllable micro structure. | Shifeng Lin Zhengwang Zhu Shaofan Ge Long Zhang Dingming Liu Yanxin Zhuang Huameng Fu Hong Li Aimin Wang Haifeng Zhang | 2020 | Journal of Materials Science & Technology2020，47，15： | 1 |
| 9 | Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in-situ TiC particles显示文摘 | Huameng Fu Haifeng Zhang Hao Wang Qingsheng Zhang Zhuangqi Hu | 2004 | Scripta Materialia2004，，7： | 1 |
| 10 | High-temperature Mechanical Properties and Dynamic Recrystallization Mechanism of in situ Silicide-reinforced MoNbTaTiVSi Refractory High-entropy Alloy Composite显示文摘The hypoeutectic composite material composed of BCC phase and in situ precipitated Ti_(5)Si_(3) was prepared by adding Si into MoNbTaTiV high-entropy alloy.The obvious oriented in situ Ti_(5)Si_(3) phase formed eutectic phase with BCC phase in the inter-dendritic area,which leads to excellent properties of the composite.The alloy exhibits ultra-high yield stress of 718 MPa at 1200℃ and obvious compression plasticity.After reaching the maximum strength,dynamic recovery(DRV)and dynamic recrystallization(DRX)caused soften phenomena.The DRX mechanism of the dual-phase eutectic structure is analyzed by electron backscatter diffraction.The DRX of the BCC phase conforms to the discontinuous DRX and continuous DRX mechanisms,while the Ti_(5)Si_(3) phase has a geometric DRX mechanism in addition to the above two mechanisms.The high performance of this composite has enough potential high-temperature applications such as nuclear and aero engine. | Shaofan Ge Shifeng Lin Huameng Fu Long Zhang Tieqiang Geng Zhengwang Zhu Zhengkun Li Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2022 | Acta Metallurgica Sinica(English Letters)2022，35，10： | 1 |
| 11 | Effects of Al addition and cryogenic cyclic treatment on impact toughness of phase-transformable Ti-based bulk metallic glass composites显示文摘Developing bulk metallic glass composites(BMGCs)with high toughness is vital for their practical application.However,the influence of different microstructures on the impact toughness of BMGCs is still unclear.The effects of Al addition and cryogenic cyclic treatment(CCT)on the Charpy impact toughness,a K,at 298 and 77 K of a series of phase-transformable BMGCs are investigated in this work.It is found that deformation-induced martensitic transformation(DIMT)of theβ-Ti dendrites is the dominant toughening mechanism in the phase-transformable BMGCs at 298 K,but at 77 K,the toughness of BMGCs is primarily determined by the intrinsic toughness of the glass matrix.The addition of Al can moderately tune theβ-Ti phase stability,which then affects the amount of DIMT and impact toughness of the BMGCs at 298 K.However,at 77 K,Al addition causes a monotonic decrease in the toughness of the BMGCs due to the embrittlement of the glass matrix.It is found that CCT can effectively rejuvenate the phase-transformable BMGCs,which results in an enhanced impact toughness at 298 K.However,the toughness at 77 K monotonously decreases with increasing the number of CCT cycles,suggesting that the rejuvenation of the glass matrix affects the toughness at both 298 and 77 K of BMGCs,but in dramatically different ways.These findings reveal the influence of microstructures and CCT on the impact toughness of BMGCs and provide insights that could be useful for designing tougher BMGs and BMGCs. | Tingyi Yan Long Zhang R.Lakshmi Narayan Jingyu Pang Yi Wu Huameng Fu Hong Li Upadrasta Ramamurty Haifeng Zhang | 2023 | Journal of Materials Science & Technology2023，，9： | 1 |
| 12 | Simultaneous enhancement of strength and ductility of body-centered cubic TiZrNb multi-principal element alloys via boron-doping显示文摘Body-centered cubic(BCC)multi-principal element alloys(MPEAs)have intrinsic high strength but poor ductility,which greatly limits their potential applications.Here we present the boron-doping strategy to enhance the strength and ductility of TiZrNb MPEAs simultaneously.The yield strength and ductility of the TiZrNb MPEA with boron addition of 500 ppm are increased by 19.0%and 48.7%compared to the boron-free TiZrNb MPEA,respectively.Boron-doping induced high efficiency in grain refinement from~96.0μm to~16.2μm is the main factor for strengthening.Dislocation dominated deformation mechanism involving cross slip and dislocation pining in the TiZrNb containing 500 ppm boron serves to enhance the strain-hardening capacity,resultant the enhancement of ductility from 7.8%to 11.6%.While the planar slip of dislocations is the dominated deformation mechanism for the boron-free TiZrNb. | Jingyu Pang Hongwei Zhang Long Zhang Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Zhengkun Li Haifeng Zhang | 2021 | Journal of Materials Science & Technology2021，，19： | 0 |
| 13 | Wettability and Interfacial Reactions Between Metallic Glass Melts and Cu/Mo Used as Roller Materials for Twin-Roll Casting显示文摘Twin-roll casting has been recently revealed to be an effi cient technique to produce rejuvenated metallic glass(MG)strips.Due to the high melting point and high hardness,pure Mo is considered as a good roller material as pure Cu.However,the wettability and interfacial reactions between MG melts and Cu or Mo remain largely unknown.In this work,a series of sessile droplet wetting experiments are designed to investigate the wettability and reactions between Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10)Be_(22.5)(Vit.1)or(Zr 0.401 Ti_(0.133)Cu_(0.118)Ni_(0.101)Be_(0.247))_(99)Nb_(1)(Nb1)MG melts and Cu/Mo substrates at temperatures of 1073,1123 and 1173 K.It is found that the wettability and interfacial reactions of the Vit.1 and Nb1 MG melts on the Cu substrates are very similar.The equilibrium contact angles are~30°at 1073 K and~25°-27°at 1123 K.The MG melts completely spread out on the Cu substrates at 1173 K.Cu substrates are slightly dissolved in the MG melts event at 1073 K,and a transitional reaction layer exists between the droplet and the Cu substrate.In comparison,the Vit.1 MG melt exhibits a much improved wettability on the Mo substrate.The equilibrium contact angle of the Vit.1/Mo is only 6°at 1073 K and 5°at 1123 K.No signifi cant diff usion of Mo into the droplet occurs even at 1173 K with a holding time of~30 min.The interfaces of the Vit.1/Mo samples are sharp,and no interfacial reaction layers form.These fi ndings indicate that pure Mo can be a good roller material for twin-roll casting at high temperatures,and the Mo-made rollers are expected of capability to produce MG strips with good quality. | Yi Wu Long Zhang Hongwei Zhang Huameng Fu Zhengwang Zhu Hong Li Aimin Wang Haifeng Zhang | 2022 | Acta Metallurgica Sinica(English Letters)2022，35，7： | 0 |
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