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| 1 | Microbiologically influenced corrosion behavior of S32654 super austenitic stainless steel in the presence of marine Pseudomonas aeruginosa biofilm显示文摘S32654 super austenitic stainless steel(SASS) is widely used in highly corrosive environments. However,its microbiologically influenced corrosion(MIC) behavior has not been reported yet. In this study, the corrosion behavior of S32654 SASS caused by a corrosive marine bacterium Pseudomonas aeruginosa was investigated using electrochemical measurements and surface analysis techniques. It was found that P. aeruginosa biofilm accelerated the corrosion rate of S325654 SASS, which was demonstrated by a negative shift of the open circuit potential(EOCP), a decrease of polarization resistance and an increase of corrosion current density in the culture medium. The largest pit depth of the coupons exposed in the P.aeruginosa broth for 14 days was 2.83 m, much deeper than that of the control(1.33 m) in the abiotic culture medium. It was likely that the P. aeruginosa biofilm catalyzed the formation of CrO_3, which was detrimental to the passive film, resulting in MIC pitting corrosion. | Huabing Li Chuntian Yang Enze Zhou Chunguang Yang Hao Feng Zhouhua Jiang Dake Xu Tingyue Gu Ke Yang | 2017 | Journal of Materials Science & Technology2017，33，12： | 10 |
| 2 | Antibacterial Performance of a Cu-bearing Stainless Steel against Microorganisms in Tap Water显示文摘Tap water is one of the most commonly used water resources in our daily life. However, the increasing water contamination and the health risk caused by pathogenic bacteria, such as Staphylococcus aureus and Escherichia coli have attracted more attention. The mutualism of different pathogenic bacteria may diminish antibacterial effect of antibacterial agents. It was found that materials used for making pipe and tap played one of the most important roles in promoting bacterial growth. This paper is to report the performance of an innovative type 304 Cu-bearing stainless steel(304Cu SS) against microbes in tap water. The investigation methodologies involved were means of heterotrophic plate count, contact angle measurements, scanning electron microscopy for observing the cell and subtract surface morphology,atomic absorption spectrometry for copper ions release study, and confocal laser scanning microscopy used for examining live/dead bacteria on normal 304 stainless steel and 304 Cu SS. It was found that the surface free energy varied after being immersed in tap water with polar component and Cu ions release.The results showed 304 Cu SS could effectively kill most of the planktonic bacteria(max 95.9% antibacterial rate), and consequently inhibit bacterial biofilms formation on the surface, contributing to the reduction of pathogenic risk to the surrounding environments. | Mingjun Li Li Nan Dake Xu Guogang Ren Ke Yang | 2015 | Journal of Materials Science & Technology2015，31，3： | 10 |
| 3 | Progress in ENSO prediction and predictability study显示文摘ENSO is the strongest interannual signal in the global climate system with worldwide climatic, ecological and societal impacts. Over the past decades, the research about ENSO prediction and predictability has attracted broad attention. With the development of coupled models, the improvement in initialization schemes and the progress in theoretical studies, ENSO has become the most predictable climate mode at the time scales from months to seasons. This paper reviews in detail the progress in ENSO predictions and predictability studies achieved in recent years. An emphasis is placed on two fundamental issues: the improvement in practical prediction skills and progress in the theoretical study of the intrinsic predictability limit. The former includes progress in the couple models, data assimilations, ensemble predictions and so on, and the latter focuses on efforts in the study of the optimal error growth and in the estimate of the intrinsic predictability limit. | Youmin Tang Rong-Hua Zhang Ting Liu Wansuo Duan Dejian Yang Fei Zheng Hongli Ren Tao Lian Chuan Gao Dake Chen Mu Mu | 2018 | National Science Review2018，5，6： | 8 |
| 4 | Effect of nitrogen on corrosion behaviour of a novel high nitrogen medium-entropy alloy CrCoNiN manufactured by pressurized metallurgy显示文摘A novel high nitrogen medium-entropy alloy CrCoNiN, which had higher strength and slightly lower ductility than CrCoNi alloy, was successfully manufactured by pressurized metallurgy. The microstructure and corrosion behaviour were investigated by microscopic, electrochemical and spectroscopic methods.The results indicated that nitrogen existed in the form of Cr_2N precipitates and uniformly distributed N atoms, and nitrogen alloying significantly refined the grain size. Besides, nitrogen enriched on the outmost surface of passive film and metal/film interface as ammonia(NH-_3 and NH_4^+) and CrN, respectively. The significant improvement of corrosion resistance of CrCoNiN was attributed to the lower metastable pitting susceptibility together with thicker, less defective and more compact passive film. | Hao Feng Huabing Li Xiaolei Wu Zhouhua Jiang Si Zhao Tao Zhang Dake Xu Shucai Zhang Hongchun Zhu Binbin Zhang Muxin Yang | 2018 | Journal of Materials Science & Technology2018，34，10： | 8 |
| 5 | Microbiologically influenced corrosion of titanium caused by aerobic marine bacterium Pseudomonas aeruginosa显示文摘Microbiologically influenced corrosion(MIC) is a big threat to the strength and safety of many metallic materials used in different environments throughout the world. The metabolites and bioactivity of the microorganisms cause severe deterioration on the metals. In this study, MIC of pure titanium(Ti) was studied in the presence of a highly corrosive aerobic marine bacterium Pseudomonas aeruginosa. The results obtained from electrochemical test showed that Ti was corrosion resistant in the abiotic culture medium after 14 d, while the increased corrosion current density(i_(corr)) obtained from polarization curves and the decreased charge transfer resistance(R_(ct)) from electrochemical impedance spectroscopy(EIS)indicated the accelerated corrosion of Ti caused by P. aeruginosa biofilm. For further confirmation of the above results, the surface of Ti was investigated using scanning electron microscopy(SEM), confocal laser scanning microscopy(CLSM) and X-ray photoelectron spectroscopy(XPS). According to the XPS results, TiO_2 was formed in both abiotic and biotic conditions, while unstable oxide Ti_2O_3 was detected in the presence of P. aeruginosa, leading to the defects in the passive film and localized corrosion. Pitting corrosion was investigated with the help of CLSM, and the largest pit depth found on Ti surface immersed in P. aeruginosa was 1.2 μm. Ti was not immune to MIC caused by P. aeruginosa. | M.Saleem Khan Zhong Li Ke Yang Dake Xu Chunguang Yang Dan Liu Yassir Lekbach Enze Zhou Phuri Kalnaowakul | 2019 | Journal of Materials Science & Technology2019，35，1： | 8 |
| 6 | Advances in research of the mid-deep South China Sea circulation显示文摘The South China Sea(SCS)is a large marginal sea connecting the Indian and Pacific oceans.Under the factors of monsoons,strait transport,and varied bathymetry,the SCS presents a three-layer structure and strong diapycnal mixing which is far greater than that in the open ocean.Theoretical analysis and observations reveal that internal tides,internal solitary waves,and strong winds are the sources of the strong mixing in the northern SCS.A major consequence of the strong mixing is an active mid-deep circulation system.This system promotes exchange of water between the SCS and adjacent oceans,and also regulates the upper layer of wind-driven circulation,making the 3 dimensional SCS circulation clearly different from that in other tropical and subtropical marginal seas.The mass transport capacity of the mid-deep circulation has a substantial impact on marine sedimentation,the biogeochemical cycle,and other processes in the SCS.This paper summarizes the recent advances in middeep sea circulation dynamics of the SCS,and discusses the opportunities and challenges in this area. | Dongxiao WANG Qiang WANG Shuqun CAI Xiaodong SHANG Shiqiu PENG Yeqiang SHU Jingen XIAO Xiaohui XIE Zhiwei ZHANG Zhiqiang LIU Jian LAN Dake CHEN Huijie XUE Guihua WANG Jianping GAN Xinong XIE Rui ZHANG Hui CHEN Qingxuan YANG | 2019 | Science China Earth Sciences2019，62，12： | 8 |
| 7 | Microbial corrosion resistance of a novel Cu-bearing pipeline steel显示文摘Microbiologically influenced corrosion(MIC) is becoming a serious problem for buried pipelines. Developing environmentally friendly strategies for MIC control is increasingly urgent in oil/gas pipeline industry.Copper(Cu) in steels can not only provide aging precipitation strengthening, but also kill bacterium,offering a special biofunction to steels. Based on the chemical composition of traditional X80 pipeline steel, two Cu-bearing pipeline steels(1% Cu and 2% Cu) were fabricated in this study. The microstructure,mechanical properties and antibacterial property against sulphate-reducing bacteria(SRB) and Pseudomonas aeruginosa(P. aeruginosa) were studied. It was found that the novel pipeline steel alloyed by 1%Cu exhibited acicular ferrite microstructure with nano-sized Cu-rich precipitates distribution in the matrix, resulting in better mechanical properties than the traditional X80 steel, and showed good MIC resistance as well. The pitting corrosion resistance of 1% Cu steel in as-aged condition was significantly better than that of X80 steel. A possible antibacterial mechanism of the Cu-bearing pipeline steel was proposed. | Xianbo Shi Wei Yan Dake Xu Maocheng Yan Chunguang Yang Yiyin Shan Ke Yang | 2018 | Journal of Materials Science & Technology2018，34，12： | 7 |
| 8 | A novel Cu-bearing high-entropy alloy with significant antibacterial behavior against corrosive marine biofilms显示文摘The design of novel high-entropy alloys(HEAs)provides a unique opportunity for the development of structure-function integrated materials with high mechanical and antimicrobial properties.In this study,by employing the antibacterial effect of copper,a novel Al0.4CoCrCuFeNi HEA with broad-spectrum antibacterial and strong mechanical properties was designed.High concentrations of copper ions released from the HEA prevented growth and biofilm formation by biocorrosive marine bacterial species.These findings serve as a proof-of-concept for further development of unique HEA materials with high antimicrobial efficiency and mechanical properties,compared to conventional antibacterial alloys. | Enze Zhou Dongxu Qiao Yi Yang Dake Xu Yiping Lu Jianjun Wang Jessica A.Smith Huabing Li Hongliang Zhao Peter K.Liaw Fuhui Wang | 2020 | Journal of Materials Science & Technology2020，42，11： | 6 |
| 9 | Methanogenic archaea and sulfate reducing bacteria induce severe corrosion of steel pipelines after hydrostatic testing显示文摘Complex interactions within a microbial consortium can induce severe corrosion in oil pipelines.This study investigated the mechanism of microbiologically influenced corrosion(MIC)that led to failure of X52 steel pipelines after hydrostatic testing.Laboratory hydrostatic testing with untreated lake water and underground water were used to simulate and study the events that led to the actual corrosion.Biofilm analysis,weight loss,and several electrochemical measurements demonstrated rapid corrosion rates after hydrostatic testing.Analysis of microbial community structures revealed that methanogenic archaea and sulfate reducing bacteria(SRB),introduced by the hydrotest water,formed corrosive biofilms on X52 steel coupon surfaces that induced severe pitting. | Enze Zhou Jianjun Wang Masoumeh Moradi Huabing Li Dake Xu Yuntian Lou Jinheng Luo Lifeng Li Yulei Wang Zhenguo Yang Fuhui Wang Jessica A.Smith | 2020 | Journal of Materials Science & Technology2020，47，13： | 5 |
| 10 | Effect of Cu Addition to 2205 Duplex Stainless Steel on the Resistance against Pitting Corrosion by the Pseudomonas aeruginosa Biofilm显示文摘The effect of copper addition to 2205 duplex stainless steel(DSS) on its resistance against pitting corrosion by the Pseudomonas aeruginosa biofilm was investigated using electrochemical and surface analysis techniques. Cu addition decreased the general corrosion resistance, resulting in a higher general corrosion rate in the sterile medium. Because DSS usually has a very small general corrosion rate, its pitting corrosion resistance is far more important. In this work, it was shown that 2205-3%Cu DSS exhibited a much higher pitting corrosion resistance against the P. aeruginosa biofilm compared with the 2205 DSS control, characterized by no significant change in the pitting potential and critical pitting temperature(CPT) values. The strong pitting resistance ability of 2205-3%Cu DSS could be attributed to the copper-rich phases on the surface and the release of copper ions, providing a strong antibacterial ability that inhibited the attachment and growth of the corrosive P. aeruginosa biofilm. | Ping Li Yang Zhao Yuzhi Liu Ying Zhao Dake Xu Chunguang Yang Tao Zhang Tingyue Gu Ke Yang | 2017 | Journal of Materials Science & Technology2017，33，7： | 5 |
| 11 | Enhanced resistance of 2205 Cu-bearing duplex stainless steel towards microbiologically influenced corrosion by marine aerobic Pseudomonas aeruginosa biofilms显示文摘An antibacterial 2205-Cu duplex stainless steel(DSS)was shown to inhibit the formation and growth of corrosive marine biofilms by direct contact with copper-rich phases and the release of Cu^(2+)ions from the2205-Cu DSS surface.In this work,the microbiologically influenced corrosion(MIC)resistance of 2205-Cu DSS in the presence of the corrosive marine bacterium Pseudomonas aeruginosa was investigated.The addition of copper improved the mechanical properties such as the yield strength,the tensile strength and the hardness of 2205 DSS.Electrochemical test results from linear polarization resistance(LPR),electrochemical impedance spectroscopy(EIS)and critical pitting temperature(CPT)measurements showed that 2205-Cu DSS possessed a larger polarization resistance(R_p),charge transfer resistance(R_(ct))and CPT values,indicating the excellent MIC resistance of 2205-Cu DSS against the corrosive P.aeruginosa biofilm.The live/dead staining results and the SEM images of biofilm confirmed the strong antibacterial ability of 2205-Cu DSS.The largest pit depth of 2205-Cu DSS was considerably smaller than that of 2205 DSS after 14 d in the presence of P.aeruginosa(2.2μm vs 12.5μm).2205-Cu DSS possessed a superior MIC resistance to regular 2205 DSS in the presence of aerobic P.aeruginosa. | Dake Xu Enze Zhou Ying Zhao Huabing Li Zhiyong Liu Dawei Zhang Chunguang Yang Hai Lin Xiaogang Li Ke Yang | 2018 | Journal of Materials Science & Technology2018，34，8： | 4 |
| 12 | Applicability of the Welch method for examining self-noise level parameters for broadband seismometers显示文摘Seismometer self-noise levels were determined using Sleeman's three-sensor method in combination with the Welch method for different parameter combinations. The self-noise levels decreased with the increasing segment window length, which is equivalent to the subwindow length, and with the increasing segment overlap rate for different frequency points at a fixed band. After the statistical examination of 9800 different parameter combinations, a zone of reasonable self-noise calculation parameter combinations was identified. Reasons for the unsuitability of certain parameter combinations were explored with respect to their distortion of the seismometer's self-noise levels. | Li Xiaojun Yang Dake Xie Jianbo Ma Jiemei Yuan Songyong Xu Weiwei Zhao Jianhe Li Dongsheng | 2015 | Geodesy and Geodynamics2015，6，3： | 3 |
| 13 | Review on the corrosion-promotion activity of graphene and its inhibition显示文摘Graphene films(GFs) and graphene-reinforced nanocomposite coatings(GNCs) have received unprecedented attention for corrosion protection because graphene possesses a remarkable chemical inertness and is completely impermeable to aggressive chemicals. However, the high electric conductivity and positive potential of graphene make graphene-based metal protectors tend to exhibit an undesirable high corrosion-promotion activity(CPA), which is widely known as the phenomenon that graphene connecting with metal accelerates the corrosion of metal substrate by inducing micro-galvanic corrosion at the defect sites of GFs or GNCs in aggressive environments. Therefore, inhibiting the CPA of graphene is currently a key focus for the application of graphene in the field of corrosion protection. In this review, the mechanisms, influencing factors, and inhibition strategies of the CPA of GFs and GNCs are highlighted from the point of view of corrosion science to address the bottlenecks and challenges for future research and potential applications of graphene for corrosion protection. | Wen Sun Yanjia Yang Zhengqing Yang Lida Wang Jing Wang Dake Xu Guichang Liu | 2021 | Journal of Materials Science & Technology2021，，32： | 2 |
| 14 | Microbial ingress and in vitro degradation enhanced by glucose on bioabsorbable Mg-Li-Ca alloy显示文摘Biodegradable magnesium alloys are challenging to be implanted in patients with hyperglycemia and diabetes.A hypothesis is suggested that glucose accelerates microbial ingress and in vitro degradation of Mg-Li-Ca implants.Corrosion resistance and mechanical properties was demonstrated using electrochemical,hydrogen evolution and tensile tests.The bacteria from Hank's solution were isolated via 16S rRNA gene analysis.The results revealed that Mg-1Li-1Ca alloy exhibited different responses to Hank's solution with and without glucose.The solution acidity was ascribed to Microbacterium hominis and Enterobacter xiangfangensis,indicating that glucose promoted microbial activity and degradation and deterioration in mechanical property of Mg-1Li-1Ca alloy. | Ling-Yu Li Zhuang-Zhuang Han Rong-Chang Zeng Wei-Chen Qi Xiao-Fan Zhai Yi Yang Yun-Tian Lou Tingyue Gu Dake Xu Ji-Zhou Duan | 2020 | Bioactive Materials2020，5，4： | 2 |
| 15 | Corrosion Inhibition of X80 Steel in Simulated Marine Environment with Marinobacter aquaeolei显示文摘In the present study, a novel bacterium( Marinobacter aquaeolei) was examined for its corrosion inhibiting behaviour against X80 pipeline steel. Electrochemical results showed that X80 steel immersed in the solution inoculated with M. aquaeolei possessed very high corrosion resistance compared to that of abiotic control. Besides, scanning electron microscopy, confocal laser scanning microscopy and energy-dispersive X-ray spectroscopy were employed to analyse the corrosion product and the biofi lm formed on the metal surface. Fourier-transform infrared spectroscopy was also applied to determine the composition of extracellular polymeric substances(EPS). Above results indicated that the corrosion inhibition effciency observed in biotic medium was very high(91%), proving that M. aquaeolei was an effective inhibitive agent for the corrosion of carbon steel. The inhibition was credited to the formation of bacterial biofi lm and the compact protective layer of the secreted EPS. Thus, this study will introduce a natural, environmentally friendly and cost-effective system for the corrosion control of the carbon steel. | M.Saleem Khan Dake Xu Dan Liu Yassir Lekbach Ke Yang Chunguang Yang | 2019 | Acta Metallurgica Sinica(English Letters)2019，32，11： | 2 |
| 16 | Electron transfer mediator PCN secreted by aerobic marine Pseudomonas aeruginosa accelerates microbiologically influenced corrosion of TC4 titanium alloy显示文摘Titanium alloys possess excellent corrosion resistance in marine environments,thus the possibility of their corrosion caused by marine microorganisms is neglected.In this work,microbiologically influenced corrosion(MIC)of TC4 titanium alloy caused by marine Pseudomonas aeruginosa was investigated through electrochemical and surface characterizations during a 14-day immersion test.Results revealed that the unstable surface caused by P.aeruginosa resulted in exposure of Ti_(2)O_(3) and severe pitting corrosion with maximum pit depth of 5.7μm after 14 days of incubation.Phenazine-1-carboxylate(PCN),secreted by P.aeruginosa,promoted extracellular electron transfer(EET)and accelerated corrosion.Deletion of the phzH gene,which codes for the enzyme that catalyzes PCN production,from the P.aeruginosa genome,resulted in significantly decreased rates of corrosion.These results demonstrate that TC4 titanium alloy is not immune to marine MIC,and EET contributes to the corrosion of TC4 titanium alloy caused by P.aeruginosa. | Dan Liu Hongying Yang Jianhui Li Jiaqi Li Yizhe Dong Chuntian Yang Yuting Jin Lekbach Yassir Zhong Li David Hernandez Dake Xu Fuhui Wang Jessica A.Smith | 2021 | Journal of Materials Science & Technology2021，，20： | 1 |
| 17 | Cyanostilbene-based near-infrared emissive platinum(Ⅱ) metallacycles for cancer theranostics显示文摘In this work,a near-infrared emissive dipyridyl ligand was synthesized and used to prepare three platinum(II)metallacycles with different shapes via metal-coordination-driven self-assembly with different platinum(II)precursors.These metallacycles were further used for both cell imaging and cancer therapy,offering a new type of theranostic agents towards cancer treatment. | Lingzhi Ma Tianfeng Yang Zeyuan Zhang Siping Yin Zhongxiao Song Wen Shi Dake Chu Yanmin Zhang Mingming Zhang | 2019 | Chinese Chemical Letters2019，30，11： | 1 |
| 18 | mTOR regulate EMT through RhoA and Rac1 pathway in prostate cancer显示文摘 | XianGuo Chen HaiYan Cheng TengFei Pan Yi Liu Yang Su CuiPing Ren DaKe Huang XiaoJun Zha ChaoZhao Liang | 2015 | Mol. Carcinog2015，，10： | 1 |
| 19 | Injectable Self‑Healing Adhesive pH‑Responsive Hydrogels Accelerate Gastric Hemostasis and Wound Healing显示文摘Endoscopic mucosal resection(EMR)and endoscopic submucosal dissection(ESD)are well-established therapeutics for gastrointestinal neoplasias,but complications after EMR/ESD,including bleeding and perforation,result in additional treatment morbidity and even threaten the lives of patients.Thus,designing biomaterials to treat gastric bleeding and wound healing after endoscopic treatment is highly desired and remains a challenge.Herein,a series of injectable pH-responsive selfhealing adhesive hydrogels based on acryloyl-6-aminocaproic acid(AA)and AA-g-N-hydroxysuccinimide(AA-NHS)were developed,and their great potential as endoscopic sprayable bioadhesive materials to efficiently stop hemorrhage and promote the wound healing process was further demonstrated in a swine gastric hemorrhage/wound model.The hydrogels showed a suitable gelation time,an autonomous and efficient self-healing capacity,hemostatic properties,and good biocompatibility.With the introduction of AA-NHS as a micro-cross-linker,the hydrogels exhibited enhanced adhesive strength.A swine gastric hemorrhage in vivo model demonstrated that the hydrogels showed good hemostatic performance by stopping acute arterial bleeding and preventing delayed bleeding.A gastric wound model indicated that the hydrogels showed excellent treatment effects with significantly enhanced wound healing with type I collagen deposition,α-SMA expression,and blood vessel formation.These injectable self-healing adhesive hydrogels exhibited great potential to treat gastric wounds after endoscopic treatment. | Jiahui He Zixi Zhang Yutong Yang Fenggang Ren Jipeng Li Shaojun Zhu Feng Ma Rongqian Wu Yi Lv Gang He Baolin Guo Dake Chu | 2021 | Nano-Micro Letters2021，13，5： | 1 |
| 20 | Improved corrosion resistance and biofilm inhibition ability of copper-bearing 304 stainless steel against oral microaerobic Streptococcus mutans显示文摘304 stainless steel(SS) used as orthodontic wire during orthodontics faces the risk of microbiologically influenced corrosion(MIC) due to diverse flora environment. Hereinto, Streptococcus mutans(S. mutans)is the most important cariogenic bacteria. In this work, MIC behavior of a new 304-Cu SS in presence of S. mutans was studied by the observations using scanning electron microscopy(SEM) and confocal laser scanning microscopy(CLSM) including live/dead staining, extracellular polymeric substance(EPS)staining and pitting corrosion, electrochemical test, and X-ray photoelectron spectroscopy(XPS). Above results showed that 304-Cu SS possessed excellent biofilm inhibition ability and presented lower corrosion current density(icorr), larger polarization resistance(Rp) and charge transfer resistance(Rct) in the presence of S. mutans, indicating that 304-Cu SS had a better MIC resistance against S. mutans. It was further affirmed by XPS results that the presence of Cu-oxide in passive film of 304-Cu SS inhibited the formation of biofilm. | Hanyu Zhao Yupeng Sun Lu Yin Zhao Yuan Yiliang Lan Dake Xu Chunguang Yang Ke Yang | 2021 | Journal of Materials Science & Technology2021，，7： | 1 |
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