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| 1 | Preparation and characterization of vanadium(IV) oxide supported on SBA-15 and its catalytic performance in benzene hydroxylation to phenol using molecular oxygen显示文摘Preparation of dispersed transition metal oxides catalyst with low oxidation state still remains a challenging task in heterogeneous catalysis.In this study,vanadium oxides supported on zeolite SBA-15 have been prepared under hydrothermal condition using V 2 O 5 and oxalic acid as sources of vanadium and reductant,respectively.The structures of samples,especially the oxidation state of vanadium,and the surface distribution of vanadium oxide species,have been thoroughly characterized using various techniques,including N 2-physisorption,X-ray diffraction(XRD),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),UV-visible spectra(UV-Vis) and UV-visible-near infrared spectra(UV-Vis-NIR).It is found that the majority of supported vanadium was in the form of vanadium(IV) oxide species with the low valence of vanadium.By adjusting hydrothermal treatment time,the surface distribution of vanadium(IV) oxide species can be tuned from vanadium(IV) oxide cluster to crystallites.These materials have been tested in the hydroxylation of benzene to phenol in liquid-phase with molecular oxygen in the absence of reductant.The catalyst exhibits high selectivity for phenol(61%) at benzene conversion of 4.6%,which is a relatively good result in comparison with other studies employing molecular oxygen as the oxidant. | Xing Chen Wenguang Zhao Feng Wang Jie Xu | 2012 | Journal of Natural Gas Chemistry2012，21，5： | 5 |
| 2 | Oxygen‑Deficient β‑MnO_(2)@Graphene Oxide Cathode for High‑Rate and Long‑Life Aqueous Zinc Ion Batteries显示文摘Recent years have witnessed a booming interest in grid-scale electrochemical energy storage,where much attention has been paid to the aqueous zinc ion batteries(AZIBs).Among various cathode materials for AZIBs,manganese oxides have risen to prominence due to their high energy density and low cost.However,sluggish reaction kinetics and poor cycling stability dictate against their practical application.Herein,we demonstrate the combined use of defect engineering and interfacial optimization that can simultaneously promote rate capability and cycling stability of MnO_(2) cathodes.β-MnO_(2) with abundant oxygen vacancies(VO)and graphene oxide(GO)wrapping is synthesized,in which VO in the bulk accelerate the charge/discharge kinetics while GO on the surfaces inhibits the Mn dissolution.This electrode shows a sustained reversible capacity of~129.6 mAh g^(−1) even after 2000 cycles at a current rate of 4C,outperforming the state-of-the-art MnO_(2)-based cathodes.The superior performance can be rationalized by the direct interaction between surface VO and the GO coating layer,as well as the regulation of structural evolution ofβ-MnO_(2) during cycling.The combinatorial design scheme in this work offers a practical pathway for obtaining high-rate and long-life cathodes for AZIBs. | Shouxiang Ding Mingzheng Zhang Runzhi Qin Jianjun Fang Hengyu Ren Haocong Yi Lele Liu Wenguang Zhao Yang Li Lu Yao Shunning Li Qinghe Zhao Feng Pan | 2021 | Nano-Micro Letters2021，13，11： | 3 |
| 3 | Efficient base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over copper-doped manganese oxide nanorods with tert-butanol as solvent显示文摘2,5-Furandicarboxylic acid(FDCA)is an important and renewable building block and can serve as an alternative to terephthalic acid in the production of biobased degradable plastic.In this study,Cu-doped MnO_(2) nanorods were prepared by a facile hydrothermal redox method and employed as catalysts for the selective oxidation of 5-hydroxymethylfurfural(HMF)to FDCA using tert-butyl hydroperoxide(TBHP)as an oxidant.The catalysts were characterized using X-ray diffraction analysis,Fourier transform infrared spectroscopy,thermo-gravimetric analysis,and transmission electron microscopy.The effects of oxidants,solvents,and reaction conditions on the oxidation of HMF were investigated,and a reaction mechanism was proposed.Experimental results demonstrated that 99.4% conversion of HMF and 96.3% selectivity of FDCA were obtained under suitable conditions,and tert-butanol was the most suitable solvent when TBHP was used as an oxidant.More importantly,the Cu-doped MnO_(2) catalyst can maintain durable catalytic activity after being recycled for more than ten times. | Feng Cheng Dongwen Guo Jinhua Lai Meihui Long Wenguang Zhao Xianxiang Liu Dulin Yin | 2021 | Frontiers of Chemical Science and Engineering2021，15，4： | 2 |
| 4 | Biomedical polymers: synthesis, properties, and applications显示文摘Biomedical polymers have been extensively developed for promising applications in a lot of biomedical fields, such as therapeutic medicine delivery, disease detection and diagnosis, biosensing, regenerative medicine, and disease treatment. In this review, we summarize the most recent advances in the synthesis and application of biomedical polymers, and discuss the comprehensive understanding of their property-function relationship for corresponding biomedical applications. In particular, a few burgeoning bioactive polymers, such as peptide/biomembrane/microorganism/cell-based biomedical polymers, are also introduced and highlighted as the emerging biomaterials for cancer precision therapy. Furthermore, the foreseeable challenges and outlook of the development of more efficient, healthier and safer biomedical polymers are discussed. We wish this systemic and comprehensive review on highlighting frontier progress of biomedical polymers could inspire and promote new breakthrough in fundamental research and clinical translation. | Wei-Hai Chen Qi-Wen Chen Qian Chen Chunyan Cui Shun Duan Yongyuan Kang Yang Liu Yun Liu Wali Muhammad Shiqun Shao Chengqiang Tang Jinqiang Wang Lei Wang Meng-Hua Xiong Lichen Yin Kuo Zhang Zhanzhan Zhang Xu Zhen Jun Feng Changyou Gao Zhen Gu Chaoliang He Jian Ji Xiqun Jiang Wenguang Liu Zhuang Liu Huisheng Peng Youqing Shen Linqi Shi Xuemei Sun Hao Wang Jun Wang Haihua Xiao Fu-Jian Xu Zhiyuan Zhong Xian-Zheng Zhang Xuesi Chen | 2022 | Science China Chemistry2022，65，6： | 2 |
| 5 | Insights into the phenomenon of an explosive growth and sharp decline in haze:A case study in Beijing显示文摘A severe haze episode occurred in winter in the North China Plain(NCP),and the phenomenon of an explosive growth and sharp decline in PM2.5(particulate matter with an aerodynamic diameter equal to or less than 2.5μm)concentration was observed.To study the systematic causes for this phenomenon,comprehensive observations were conducted in Beijing from November 26 to December 2,2015;during this period,meteorological parameters,LIDAR data,and the chemical compositions of aerosols were determined.The haze episode was characterized by rapidly varying PM2.5 concentration,and the highest PM2.5 concentration reached 667μg/m3.During the haze episode,the NCP was dominated by a weak high-pressure system and continuously low PBL(planetary boundary layer)heights,which are unfavorable conditions for the diffusion of pollutants.The large increases in the concentrations of SNA(SO42-,NO3-and NH4+)during the haze implied that the formation of SNA was the largest contribution.Water vapor also played a vital role in the formation of haze by promoting the chemical transformation of secondary pollutants,which led to higher PM2.5 concentrations.The spatial distributions of PM2.5 in Beijing at different times and the backward trajectories of the air masses also indicated that pollutants from surrounding provinces in particular,contributed to the higher PM2.5concentration. | Wenguang Li Xingang Liu Yuanhang Zhang Qinwen Tan Miao Feng Mengdi Song Lirong Hui Yu Qu Junling An Haokai Gao | 2019 | Journal of Environmental Sciences2019，31，10： | 1 |
| 6 | Film forming kinetics and reaction mechanism of γ-glycidoxypropyltrimethoxysilane on low carbon steel surfaces显示文摘 | Lixia Yang Jun Feng Wenguang Zhang Jun-e Qu | 2010 | Applied Surface Science2010，，22： | 1 |
| 7 | Resource types, formation, distribution and prospects of coal-measure gas显示文摘Coal-measure gas is the natural gas generated by coal, carbonaceous shale, and dark shale in coal-measure strata. It includes resources of continuous-type coalbed methane (CBM), shale gas and tight gas reservoirs, and trap-type coal-bearing gas reservoirs. Huge in resources, it is an important gas source in the natural gas industry. The formation and distribution characteristics of coal-measure gas in San Juan, Surat, West Siberia and Ordos basins are introduced in this paper. By reviewing the progress of exploration and development of coal-measure gas around the world, the coal-measure gas is confirmed as an important strategic option for gas supply. This understanding is mainly manifested in three aspects. First, globally, the Eurasian east-west coal-accumulation belt and North American north-south coal-accumulation belt are two major coal-accumulation areas in the world, and the Late Carboniferous–Permian, Jurassic and end of Late Cretaceous–Neogene are 3 main coal-accumulation periods. Second, continuous-type and trap-type are two main accumulation modes of coal-measure gas;it is proposed that the area with gas generation intensity of greater than 10×10^8 m^3/km^2 is essential for the formation of large coal-measure gas field, and the CBM generated by medium- to high-rank coal is usually enriched in syncline, while CBM generated by low-rank coal is likely to accumulate when the source rock and caprock are in good configuration. Third, it is predicted that coal-measure gas around the world has huge remaining resources, coal-measure gas outside source is concentrated in Central Asia-Russia, the United States, Canada and other countries/regions, while CBM inside source is largely concentrated in 12 countries. The production of coal-measure gas in China is expected to exceed 1000×10^8 m^3 by 2030, including (500–550)×10^8 m^3 conventional coal-measure gas,(400–450)×10^8 m^3 coal-measure tight gas, and (150–200)×10^8 m^3 CBM. | ZOU Caineng YANG Zhi HUANG Shipeng MA Feng SUN Qinping LI Fuheng PAN Songqi TIAN Wenguang | 2019 | Petroleum Exploration and Development2019，46，3： | 1 |
| 8 | Characterizing and optimizing TPC-C workloads on large-scale systems using SSD arrays显示文摘Transaction processing performance council benchmark C(TPC-C) is the de facto standard for evaluating the performance of high-end computers running on-line transaction processing applications. Differing from other standard benchmarks, the transaction processing performance council only defines specifications for the TPC-C benchmark, but does not provide any standard implementation for end-users. Due to the complexity of the TPC-C workload, it is a challenging task to obtain optimal performance for TPC-C evaluation on a large-scale high-end computer. In this paper, we designed and implemented a large-scale TPC-C evaluation system based on the latest TPC-C specification using solid-state drive(SSD) storage devices. By analyzing the characteristics of the TPC-C workload, we propose a series of system-level optimization methods to improve the TPC-C performance. First, we propose an approach based on Small File table space to organize the test data in a round-robin method on all of the disk array partitions; this can make full use of the underlying disk arrays.Second, we propose using a NOOP-based disk scheduling algorithm to reduce the utilization rate of processors and improve the average input/output service time. Third, to improve the system translation lookaside buffer hit rate and reduce the processor overhead, we take advantage of the huge page technique to manage a large amount of memory resources. Lastly, we propose a locality-aware interrupt mapping strategy based on the asymmetry characteristic of non-uniform memory access systems to improve the system performance. Using these optimization methods, we performed the TPC-C test on two large-scale high-end computers using SSD arrays. The experimental results show that our methods can effectively improve the TPC-C performance. For example, the performance of the TPC-C test on an Intel Westmere server reached 1.018 million transactions per minute. | Jidong ZHAI Feng ZHANG Qingwen LI Wenguang CHEN Weimin ZHENG | 2016 | Science China(Information Sciences)2016，59，9： | 1 |
| 9 | The effect of sodium sulphate on the hydrogen reduction process of nickel laterite ore显示文摘 | Jie Lu Shoujun Liu Ju Shangguan Wenguang Du Feng Pan Song Yang | 2013 | Minerals Engineering2013，，： | 1 |
| 10 | Recent advances in the catalytic production of bio-based diol 2,5-bis(hydroxymethyl)furan显示文摘Biomass-derived 2,5-bis(hydroxymethyl)furan(BHMF)has received great attention and interest due to its broad application prospects in polyesters and medicine.Over the past decades,the catalytic systems including thermocatalytic,biocatalytic,electrocatalytic,and photocatalytic hydrogenation of 5-hydroxymethylfurfural(HMF)into BHMF have been developed to a great extent.To understand the present status and challenges of BHMF production,this review systematically evaluates recent findings and developments of HMF hydrogenation through various reaction systems,with an emphasis on catalyst screening,synthesis processes,and reaction mechanism.Furthermore,a few potential research trends are also proposed,in order to provide innovative ideas for further exploration of BHMF synthesis in a simpler,efficient,and economical way. | Wenguang Zhao Feng Wang Kangyu Zhao Xianxiang Liu Xiaoting Zhu Le Yan Yuan Yin Qiong Xu Dulin Yin | 2023 | Carbon Resources Conversion2023，6，2： | 0 |
| 11 | Effects of Different Sterilization Methods on the Product Characteristics of Sichuan Industrialized Huiguorou显示文摘Pasteurization,116 and 121℃sterilization were used in the development of Sichuan Industrial Huiguorou.The sensory,color,texture,lipid oxidation,preservation and flavor substance types and contents of the products were determined,and the effects of different sterilization methods on product characteristics were compared.The results showed that pasteurization was the best way to maintain the edible quality of products,but the storage period of products was very short,so the products could only be quickly distributed and consumed.Sterilization at 116℃and sterilization at 121℃could ensure the shelf life of Huiguorou under non-refrigeration conditions,and effectively solve the problem of long-term storage and transportation of Sichuan meat dishes.However,higher temperature had more or less adverse effect on the flavor of the product,and the product texture was too soft.It suggested that the better way was to sterilize at 116℃,which had less adverse effect on the flavor of the product,and could greatly prolong the non-refrigerated storability of the product,and increase the content of aldehydes and esters,so as to improve the flavor. | Lili JI Yinfeng ZHAO Benting HUANG Wenguang FENG Yuhang ZHOU Wei WANG | 2021 | Agricultural Biotechnology2021，10，5： | 0 |
| 12 | Recent progress in Li and Mn rich layered oxide cathodes for Li-ion batteries显示文摘Li and Mn rich(LMR)layered oxides,written as xLi_(2) MnO_(3)·(1-x)LiMO_(2)(M=Mn,Ni,Co,Fe,etc.),have been widely reported in recent years due to their high capacity and high energy density.The stable structure and superior performance of LMR oxides make them one of the most promising candidates for the next-generation cathode materials.However,the commercialization of these materials is hindered by several drawbacks,such as low initial Coulombic efficiency,the degradation of voltage and capacity during cycling,and poor rate performance.This review summarizes research progress in solving these concerns of LMR cathodes over the past decade by following three classes of strategies:morphology design,bulk design,and surface modification.We elaborate on the processing procedures,electrochemical performance,mechanisms,and limitations of each approach,and finally put forward the concerns left and the possible solutions for the commercialization of LMR cathodes. | Yiwei Li Zhibo Li Cong Chen Kai Yang Bo Cao Shenyang Xu Ni Yang Wenguang Zhao Haibiao Chen Mingjian Zhang Feng Pan | 2021 | Journal of Energy Chemistry2021，30，10： | 0 |
| 13 | Modern Ecological Chicken Raising and Its Research Progress显示文摘Modern ecological breeding has the characteristics of protecting the ecological environment,health,nutrition,delicious,and so on.In the ecological breeding of traditional breeding chicken,using non antibiotic breeding,traditional Chinese medicine and other breeding technologies can not only obtain green,non-harmful and safe food products,but also reduce the cost of farmers and provide breeding efficiency This is a sustainable development path.This paper gave a brief overview of this field. | Qian HUANG Yinfeng ZHAO Wenguang FENG Kaiqiang ZHAO Wenwen YU Xin HE Lili JI | 2021 | Agricultural Biotechnology2021，10，4： | 0 |
| 14 | Design of advanced porous silver powder with high-sintering activity to improve silicon solar cells显示文摘Silver(Ag)paste is widely used in semiconductor metallization,especially in silicon solar cells.Ag powder is the material with the highest proportion in Ag paste.The morphology and structure of Ag powder are crucial which determine its characteristics,especially for the sintering activity.In this work,a simple method was developed to synthesize a type of microcrystalline spherical Ag particles(SP-A)with internal pores and the structural changes and sintering behavior were thoroughly studied by combining ultra-small-angle X-ray scattering(USAXS),small-angle X-ray scattering(SAXS),in-situ heating X-ray diffraction(XRD),focused ion beam(FIB),and thermal analysis measurement.Due to the unique internal pores,the grain size of SP-A is smaller,and the coefficient of thermal expansion(CTE)is higher than that of traditional solid Ag particles.As a result,the sintering activity of SP-A is excellent,which can form a denser sintered body and form silver nanoparticles at the Ag–Si interface to improve silver silicon contact.Polycrystalline silicon solar cell built with SP-A obtained a low series resistance(Rs)and a high photoelectric conversion efficiency(PCE)of 19.26%.These fill a gap in Ag particle structure research,which is significant for the development of high-performance electronic Ag particles and efficient semiconductor devices. | Yongsheng Li Ziwei Chen Rui Zhou Wenguang Zhao Mu Li Jun Chen Zhongyuan Huang Jian Liu Yuhang Li Maolin Yang Minghan Yu Dong Zhou Yuan Lin Feng Pan | 2024 | Nano Research2024，17，4： | 0 |
| 15 | LotusSQL:SQL Engine for High-Performance Big Data Systems显示文摘In recent years,Apache Spark has become the de facto standard for big data processing.SparkSQL is a module offering support for relational analysis on Spark with Structured Query Language(SQL).SparkSQL provides convenient data processing interfaces.Despite its efficient optimizer,SparkSQL still suffers from the inefficiency of Spark resulting from Java virtual machine and the unnecessary data serialization and deserialization.Adopting native languages such as C++could help to avoid such bottlenecks.Benefiting from a bare-metal runtime environment and template usage,systems with C++interfaces usually achieve superior performance.However,the complexity of native languages also increases the required programming and debugging efforts.In this work,we present LotusSQL,an engine to provide SQL support for dataset abstraction on a native backend Lotus.We employ a convenient SQL processing framework to deal with frontend jobs.Advanced query optimization technologies are added to improve the quality of execution plans.Above the storage design and user interface of the compute engine,LotusSQL implements a set of structured dataset operations with high efficiency and integrates them with the frontend.Evaluation results show that LotusSQL achieves a speedup of up to 9 in certain queries and outperforms Spark SQL in a standard query benchmark by more than 2 on average. | Xiaohan Li Bowen Yu Guanyu Feng Haojie Wang Wenguang Chen | 2021 | Big Data Mining and Analytics2021，4，4： | 0 |
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