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| 1 | Low-strain TiP_(2)O_(7) withthree-dimensionalionchannelsas long-life and high-rate anode material for Mg-ion batteries显示文摘Rechargeable magnesium batteries are identified as a promising next-generation energy storage system,but their development is hindered by the anode−electrolyte−cathode incompatibilities and passivation of magnesium metal anode.To avoid or alleviate these problems,the exploitation of alternative anode materials is a promising choice.Herein,we present titanium pyrophosphate(TiP_(2)O_(7))as anode materials for magnesium-ion batteries(MIBs)and investigate the effect of the crystal phase on its magnesium storage performance.Compared with the me-tastable layered TiP_(2)O_(7),the thermodynamically stable cubic TiP_(2)O_(7) displays a better rate capability of 72 mAh g^(−1) at 5000 mA g^(−1).Moreover,cubic TiP_(2)O_(7) exhibits excellent cycling stability with the capacity of 60 mAh g^(−1) after 5000 cycles at 1000 mA g^(−1),which are better than pre-viously reported Ti-based anode materials for MIBs.In situ X-ray diffraction technology confirms the single-phase magnesiumion inter-calation/deintercalation reaction mechanism of cubic TiP_(2)O_(7) with a low volume change of 3.2%.In addition,the density functional theory calcu-lation results demonstrate that three-dimensional magnesiumion diffu-sion can be allowed in cubic TiP_(2)O_(7) with a low migration energy barrier of 0.62 eV.Our work demonstrates the promise of TiP_(2)O_(7) as high-rate and long-life anode materials for MIBs and may pave the way for further development of MIBs. | Fangyu Xiong Yalong Jiang Li Cheng Ruohan Yu Shuangshuang Tan Chen Tang Chunli Zuo Qinyou An Yunlong Zhao Jean-Jacques Gaumet Liqiang Mai | 2022 | Interdisciplinary Materials2022，1，1： | 3 |
| 2 | Tunable Ru-Ru2P heterostructures with charge redistribution for efficient pH-universal hydrogen evolution显示文摘Designing synergistic heterogeneous catalytic interfaces is the key to developing highly compatible pH-universal electrocatalysts for complex chemical environments.Our theoretical calculation results demonstrate that the Ru-Ru2P heterointerface can not only promote the redistribution of charges,but also reduce the d-band center,and then enhances the adsorption capacity of the key intermediate.However,in situ and facile synthesis of Ru-Ru2P heterostructures is severely limited by thermodynamic obstacles.Herein,we propose a molten salt-assisted catalytic synthesis scheme,and successfully build a series of homologous metallic Ru-Ru2P heterostructure catalysts with different molar ratios of Ru to P under atmospheric pressure and low-temperature(400C).The resultant Ru-Ru2P with rich heterostructures show the Pt-like HER performance in different pH media.Particularly,it is prominent under alkaline conditions(18 mV@10 mA cm^(2)),which outperforms the Pt catalyst(37 mV@10 mA cm^(2)).Furthermore,Ru-Ru2P heterostructures also show certain potential in the electrolysis of seawater to produce hydrogen.This work represents a significant supplement of high-efficiency pH-universal HER catalysts,and provides a new light on interface engineering in energy technology fields and beyond. | Ding Chen Ruohan Yu Ruihu Lu Zonghua Pu Pengyan Wang Jiawei Zhu Pengxia Ji Dulan Wu Jinsong Wu Yan Zhao Zongkui Kou Jun Yu Shichun Mu | 2022 | InfoMat2022，4，5： | 2 |
| 3 | Structural architecture of Neoproterozoic rifting depression groups in the Tarim Basin and their formation dynamics显示文摘The Tarim Basin is the largest, oil-bearing, superimposed basin in the northwest of China. The evolution and tectonic properties of the initial Tarim Basin have been hotly disputed and remain enigmatic. The Neoproterozoic basin is covered by a vast desert and a huge-thickness of sedimentary strata, has experienced multiple tectonic movements, had a low signal to noise ratios(SNRs) of deep seismic reflection data, all of which have posed critical obstacles to research. We analysed four field outcrops, 18 wells distributed throughout the basin, 27 reprocessed seismic reflection profiles with higher SNRs across the basin and many ancillary local 2D and 3D profiles and aeromagnetic data. We found about 20 normal fault-controlled rifting depressions of the Cryogenian and Ediacaran scattered throughout the basin, which developed on the Precambrian metamorphic and crystalline basement. The structural framework is clearly different from that of the overlying Phanerozoic. The rifting depressions consist of mainly half grabens, symmetrical troughs and horst-grabens. From the northeast to southwest of the basin,they are divided into three rifting depression groups with the WNW, ENE, and NW-trends that are mainly controlled by normal faults. The maximum thicknesses of the strata are up to 4100 m. From the Cryogenian to Ediacaran, most of the main inherited faults to active and eventually ceased at the end of the Ediacaran or Early Cambrian, while subsidence centres appeared and migrated eastward along the faults. They revealed that the different parts of the Tarim continental block were in NNE-SSWoriented and NNW-SSE-oriented extensional paleo-stress fields(relative to the present) during the Neoproterozoic, and were accompanied by clockwise shearing. According to the analysis of the activities of syn-sedimentary faults, filling sediments,magmatic events, and coordination with aeromagnetic anomalies, the tectonic properties of the fault depressions are different and are primarily continental rifts or intra-continental fault-controlled basins. The rifting phases mainly occurred from 0.8–0.61 Ga.The formation of the rifting depression was associated with the initial opening of the South Altun-West Kunlun Ocean and the South Tianshan Ocean, which were located at the northern and southern margins of the Tarim Block, respectively, in response to the break-up of the Supercontinent Rodinia and the initial opening of the Proto-Tethys Ocean. | Bizhu HE Cunli JIAO Taizhu HUANG Xingui ZHOU Zhihui CAI Zicheng CAO Zhongzheng JIANG Junwen CUI Zhuoyin YU Weiwei CHEN Ruohan LIU Xiaorui YUN Guangming HAO | 2019 | Science China Earth Sciences2019，62，3： | 2 |
| 4 | Unraveling the reaction mechanisms of electrode materials for sodiumion and potassium‐ion batteries by in situ transmission electron microscopy显示文摘Sodium ion batteries(SIBs)and potassium ion batteries(PIBs)have caught numerous attention due to the low cost and abundant availability of sodium and potassium.However,their power density,cycling stability and safety need further improvement for practical applications.Investigations on the reaction mechanisms and structural degradation when cycling are of great importance.In situ transmission electron microscopy(TEM)is one of the most significant techniques to understand and monitor electrochemical processes at an atomic scale with real-time imaging.In this review,the current progress in unraveling reaction mechanisms of electrode materials for SIBs and PIBs via in situ TEM is summarized.First,the importance of in situ TEM is highlighted.Then,based on the three types of electrochemical reaction,i.e.,intercalation reac-tion,conversion reaction and alloying reaction,the structural evolution and reaction kinetics at atomic resolution,and their relation to the electrochemical performance of electrode materials are reviewed and described in detail.Fi-nally,future directions of in situ TEM for SIBs and PIBs are proposed.Therefore,the in‐depth understanding revealed by in situ TEM will give an instructive guide in rational design of electrode materials for high performance electrode materials of SIBs and PIBs. | Hong Wang Fang Liu Ruohan Yu Jinsong Wu | 2022 | Interdisciplinary Materials2022，1，2： | 2 |
| 5 | Diagnosis of sewer pipe defects on image recognition of multi-features and support vector machine in a southern Chinese city显示文摘Closed circuit television(CCTV)systems are widely used to inspect sewer pipe conditions.During the diagnosis process,the manual diagnosis of defects is time consuming,labor intensive and error prone.To assist inspectors in diagnosing sewer pipe defects on CCTV inspection images,this paper presents an image recognition algorithm that applies features extraction and machine learning approaches.An algorithm of image recognition techniques,including Hu invariant moment,texture features,lateral Fourier transform and Daubechies(DBn)wavelet transform,was used to describe the features of defects,and support vector machines were used to classify sewer pipe defects.According to the inspection results,seven defects were defined;the diagnostic system was applied to a sewer pipe system in a southern city of China,and 28,760 m of sewer pipes were inspected.The results revealed that the classification accuracies of the different defects ranged from 51.6% to 99.3%.The overall accuracy reached 84.1%.The diagnosing accuracy depended on the number of the training samples,and four fitting curves were applied to fit the data.According to this paper,the logarithmic fitting curve presents the highest coefficient of determination of 0.882,and more than 200 images need to be used for training samples to guarantee the accuracy higher than 85%. | Xiangyang Ye Jian’e Zuo Ruohan Li Yajiao Wang Lili Gan Zhonghan Yu Xiaoqing Hu | 2019 | Frontiers of Environmental Science & Engineering2019，13，2： | 1 |
| 6 | Donor-Acceptor Typed AIE Luminogens with Near-infrared Emission for Super-resolution Imaging显示文摘Aggregation-induced emission(AIE)luminogens(AIEgens)with high brightness in aggregates exhibit great potentials in biological imaging,but these AIEgens are seldom applied in super-resolution biological imaging,especially in the imaging by using the structural illumination microscope(SIM).Based on this consideration,we synthesized the donor-acceptor typed AIEgen of DTPA-BTN,which not only owns high brightness in the near-infrared(NIR)emission region from 600 nm to 1000 nm(photoluminescence quantum yield,PLQYs=11.35%),but also displays excellent photo-stability.In addition,AIE nanoparticles based on 4,7-ditriphenylamine-[1,2,5]-thiadiazolo[3,4-c]pyridine(DTPA-BTN)were also prepared with highly emissive features and excellent biocompatibility.Finally,the developed DTPA-BTN-based AIE nanoparticles were applied in the super-resolution cellular imaging via SIM,where much smaller full width at half-maximum values and high signal to noise ratios were obtained,indicating the superior imaging resolution.The results here imply that highly emissive AIEgens or AIE nanoparticles can be promising imaging agents for super-resolution imaging via SIM. | SHEN Qifei XU Ruohan WANG Zhi ZHAO Tianyu ZHOU Yu XU Yanzi YANG Zhiwei LEI Ming MENG Lingjie DANG Dongfeng | 2021 | Chemical Research in Chinese Universities2021，37，1： | 0 |
| 7 | Chemical cross-linking and mechanically reinforced carbon network constructed by graphene boosts potassium ion storage显示文摘Carbon-based electrodes of potassium-ion batteries are of great research interest ascribed to their low cost and environmentally friendly distinctions.However,traditional carbon materials usually exhibit weak mechanical properties and incomplete crosslinking,resulting in poor stability and electrochemical performance.Herein,we report a new strategy for modifying reduced graphene oxide into a uniform few-layer structure through a sol–gel method combined with acid etching treatment.The obtained chemical cross-linking and mechanically reinforced carbon network constructed by graphene(CNCG)demonstrates excellent electrochemical and mechanical properties.Adopted as a free-standing anode(~7 mg·cm^(−2))for potassium ion battery,the asachieved CNCG delivers a high reversible specific capacity of 317.7 mAh·g^(−1) at a current density of 50 mA·g^(−1) and admirable cycle stability(208.4 mAh·g^(−1) at 50 mA·g^(−1) after 500 cycles).The highly reversible structural stability and fully cross-linked properties during potassiation are revealed by ex-situ characterization.This work provides new ideas for the synthesis of new carbon materials and the development of high-performance electrodes. | Chenxu Wang Ruohan Yu Wen Luo Wencong Feng Yuanhao Shen Nuo Xu Liqiang Mai | 2022 | Nano Research2022，15，10： | 0 |
| 8 | Dynamic Routing of Multiple QoS-Required Flows in Cloud-Edge Autonomous Multi-Domain Data Center Networks显示文摘The 6th generation mobile networks(6G)network is a kind of multi-network interconnection and multi-scenario coexistence network,where multiple network domains break the original fixed boundaries to form connections and convergence.In this paper,with the optimization objective of maximizing network utility while ensuring flows performance-centric weighted fairness,this paper designs a reinforcement learning-based cloud-edge autonomous multi-domain data center network architecture that achieves single-domain autonomy and multi-domain collaboration.Due to the conflict between the utility of different flows,the bandwidth fairness allocation problem for various types of flows is formulated by considering different defined reward functions.Regarding the tradeoff between fairness and utility,this paper deals with the corresponding reward functions for the cases where the flows undergo abrupt changes and smooth changes in the flows.In addition,to accommodate the Quality of Service(QoS)requirements for multiple types of flows,this paper proposes a multi-domain autonomous routing algorithm called LSTM+MADDPG.Introducing a Long Short-Term Memory(LSTM)layer in the actor and critic networks,more information about temporal continuity is added,further enhancing the adaptive ability changes in the dynamic network environment.The LSTM+MADDPG algorithm is compared with the latest reinforcement learning algorithm by conducting experiments on real network topology and traffic traces,and the experimental results show that LSTM+MADDPG improves the delay convergence speed by 14.6%and delays the start moment of packet loss by 18.2%compared with other algorithms. | Shiyan Zhang Ruohan Xu Zhangbo Xu Cenhua Yu Yuyang Jiang Yuting Zhao | 2024 | Computers, Materials & Continua2024，78，2： | 0 |
| 9 | Synthesis of D-A typed AIE luminogens in isomeric architecture and their application in latent fingerprints imaging显示文摘Among the emitters in powder dusting to visualize the latent fingerprints(LFPs),aggregation-induced emission luminogens(AIEgens)are well employed for their high brightness and resistance to photobleaching.However,the serious background interference and low resolution still limit their fast development.Therefore,to further enhance the signal-to-noise ratio in LFPs imaging,especially to improve the analysis for level 3 details,donor-acceptor(D-A)typed AIEgens of DTPA-2,3-P,DTPA-2,5-P and DTPA-2,6-P are designed here.It is observed that strong emission covering from 450nm to 650nm can be obtained for all these molecules,especially that a high PLQY value of 10.06%in solids is achieved in DTPA-2,3-P.This is much higher than that of the other two cases(0.80%and 0.51%).By utilizing the DTPA-2,3-P in powder dusting,fluorescence imaging of LFPs can be clearly captured on both smooth and rough substrates.Moreover,confocal laser scanning microscope(CLSM)enables us to achieve high-resolution LFPs imaging in both 2D and 3D views,providing more detailed information of fingerprints pores in width,distance,distribution,and shapes.The results here demonstrate that highly emissive AIEgen of DTPA-2,3-P could be an excellent candidate for the visualization of fingerprints,thus providing the potential application in criminal investigation in the future. | Peijuan Zhang Qifei Shen Yu Zhou Fengyi He Bo Zhao Zhi Wang Ruohan Xu Yanzi Xu Zhiwei Yang Lingjie Meng Dongfeng Dang | 2023 | Chinese Chemical Letters2023，34，8： | 0 |
| 10 | Transformation of Undesired Li_(2)CO_(3)into Lithiophilic Layer Via Double Replacement Reaction for Garnet Electrolyte Engineering显示文摘Garnet-type solid-state electrolytes(SSEs)are a remarkable Li-ion electrolyte for the realization of next-generation all-solid-state lithium batteries due to their excellent stability against Li metal as well as high ionic conductivities at room temperature.However,garnet electrolytes always contain undesired and hardly removable Li_(2)CO_(3) contaminations that have persistently large resistance and unstable interface contact with Li metal.This is a critical bottleneck for the practical application of garnet electrolytes.Here,we design a novel strategy to completely root out Li_(2)CO_(3) both inside and on the surface of garnet.This is achieved by a so-called double replacement reaction between Li_(2)CO_(3) and SiO_(2) during one-step hot press process for garnet electrolyte densification.It leads to in-situ transformation of LixSiOy(LSO)mostly locating around the grain boundaries of garnet.Due to the higher ion conductivity and better electrochemistry stability of LSO than Li_(2)CO_(3),the modified garnet electrolyte shows much improved electrochemical performance.Moreover,the wettability between modified garnet electrolyte and lithium metals was significantly enhanced in the absence of surface Li_(2)CO_(3).As a proof of concept,an assembled Li symmetric cell with modified garnet electrolyte displays a high critical current density(CCD)of 0.7 mA cm^(-2)and a low interfacial impedance(5Ωcm^(2))at 25℃.These results indicate that the upcycling of Li_(2)CO_(3)is a promising strategy to well-address the degradation and interfacial issue associated with garnet electrolytes. | Jiaxu Zhang Ruohan Yu Jun Li Huiyu Zhai Gangjian Tan Xinfeng Tang | 2022 | Energy & Environmental Materials2022，5，3： | 0 |
| 11 | Tuning Active Metal Atomic Spacing by Filling of Light Atoms and Resulting Reversed Hydrogen Adsorption-Distance Relationship for Efficient Catalysis显示文摘Precisely tuning the spacing of the active centers on the atomic scale is of great significance to improve the catalytic activity and deepen the understanding of the catalytic mechanism,but still remains a challenge.Here,we develop a strategy to dilute catalytically active metal interatomic spacing(d_(M-M))with light atoms and discover the unusual adsorption patterns.For example,by elevating the content of boron as interstitial atoms,the atomic spacing of osmium(d_(Os-Os))gradually increases from 2.73 to 2.96?.More importantly,we find that,with the increase in dOs-Os,the hydrogen adsorption-distance relationship is reversed via downshifting d-band states,which breaks the traditional cognition,thereby optimizing the H adsorption and H_2O dissociation on the electrode surface during the catalytic process;this finally leads to a nearly linear increase in hydrogen evolution reaction activity.Namely,the maximum dOs-Os of 2.96?presents the optimal HER activity(8 mV@10 mA cm^(-2))in alkaline media as well as suppressed O adsorption and thus promoted stability.It is believed that this novel atomic-level distance modulation strategy of catalytic sites and the reversed hydrogen adsorption-distance relationship can shew new insights for optimal design of highly efficient catalysts. | Ding Chen Ruihu Lu Ruohan Yu Hongyu Zhao Dulan Wu Youtao Yao Kesong Yu Jiawei Zhu Pengxia Ji Zonghua Pu Zongkui Kou Jun Yu Jinsong Wu Shichun Mu | 2023 | Nano-Micro Letters2023，15，10： | 0 |
| 12 | IL-21 regulates macrophage activation in human monocytic THP-1-derived macrophages显示文摘Background:Interleukin-21(IL-21)has a regulatory effect on various immune cells.Its effect on macrophage function remains unclear.Aims:This study aimed to investigate the effect of IL-21 on the macrophagesmediated inflammatory response and explore its mechanism.Materials&Methods:Phorbol myristate acetate was used to induce THP-1-derived macrophages.Then,cells were stimulated with IL-21 and/or lipopolysaccharide(LPS).To determine the effect of IL-21 on the production of inflammatory factors in THP-1-derived macrophages,the messenger RNA(mRNA)and protein levels of IL-6,tumor necrosis factor-α(TNF-α),IL-8,and IL-10 were detected by real-time polymerase chain reaction(RT-PCR)and enzyme-linked immunosorbent assay(ELISA),respectively.Meanwhile,to explore the effect of IL-21 on macrophage polarization,macrophage phenotype,gene expression,and cytokine secretion mediated by THP-1-derived macrophage were detected by flow cytometry,RT-PCR,and ELISA.Results:First,we found that the IL-21 receptor was expressed in THP-1-derived macrophages.IL-21 enhanced LPS-mediated TNF-α,IL-6,and IL-10 production in THP-1-derived macrophages.During the polarization of THP-1-derived macrophages to M1-like macrophages,IL-21 induced the expression of macrophage surface markers CD86 and CD80,and related genes,such as TNF-α,IL-6,IL-1β,and DC-SIGN mRNA,inhibited Dectin-1 mRNA expression and promoted the secretion of TNF-α.During the polarization of THP-1-derived macrophages to M2-like macrophages,IL-21 enhanced the expression of macrophage surface markers CD86 and CD163,and related genes,such as TNF-α,IL-1β,IL-10,Dectin-1,and DC-SIGN mRNA,and promoted the secretion of IL-10.Conclusion:IL-21 promotes LPS-mediated production of inflammatory cytokines by THP-1-derived macrophages;IL-21 plays a two-way regulatory role in THP-1-derived macrophage polarization. | Leilei Jian Changhong Li Lin Sun Zhenzhen Ma Xinyu Wang Ruohan Yu Xiangyuan Liu Jinxia Zhao | 2021 | Rheumatology & Autoimmunity2021，1，1： | 0 |
| 13 | Photoexcitation-induced passivation of SnO_(2) thin film for efficient perovskite solar cells显示文摘A high-quality tin oxide electron transport layer(ETL)is a key common factor to achieve high-performance perovskite solar cells(PSCs).However,the conventional annealing technique to prepare high-quality ETLs by continuous heating under near-equilibrium conditions requires high temperatures and a long fabrication time.Alternatively,we present a non-equilibrium,photoexcitation-induced passivation technique that uses multiple ultrashort laser pulses.The ultrafast photoexcitation and following electron–electron and electron–phonon scattering processes induce ultrafast annealing to efficiently passivate surface and bulk defects,and improve the crystallinity of SnO_(2),resulting in suppressing the carrier recombination and facilitating the charge transport between the ETL and perovskite interface.By rapidly scanning the laser beam,the annealing time is reduced to several minutes,which is much more efficient compared with conventional thermal annealing.To demonstrate the university and scalability of this technique,typical antisolvent and antisolvent-free processed hybrid organic–inorganic metal halide PSCs have been fabricated and achieved the power conversion efficiency(PCE)of 24.14%and 22.75%respectively,and a 12-square-centimeter module antisolvent-free processed perovskite solar module achieves a PCE of 20.26%,with significantly enhanced performance both in PCE and stability.This study establishes a new approach towards the commercialization of efficient low-temperature manufacturing of PSCs. | Nianyao Chai Xiangyu Chen Zhongle Zeng Ruohan Yu Yunfan Yue Bo Mai Jinsong Wu Liqiang Mai Yi-Bing Cheng Xuewen Wang | 2023 | National Science Review2023，10，11： | 0 |
| 14 | Ultrathin Metal Silicate Hydroxide Nanosheets with Moderate Metal-Oxygen Covalency Enables Efficient Oxygen Evolution显示文摘Exploring efficient,cost-effective,and durable electrocatalysts for electrochemical oxygen evolution reaction(OER)is pivotal for the large-scale application of water electrolysis.Recent advance has demonstrated that the activity of electrocatalysts exhibits a strong dependence on the surface electronic structure.Herein,a series of ultrathin metal silicate hydroxide nanosheets(UMSHNs)M_(3)Si_(2)O_(5)(OH)_(4)(M=Fe,Co,and Ni)synthesized without surfactant are introduced as highly active OER electrocatalysts.Cobalt silicate hydroxide nanosheets show an optimal OER activity with overpotentials of 287 and 358 m V at 1 and 10 m A cm^(-2),respectively.Combining experimental and theoretical studies,it is found that the OER activity of UMSHNs is dominated by the metal-oxygen covalency(MOC).High OER activity can be achieved by having a moderate MOC as reflected by aσ^(*)-orbital(e_(g))filling near unity and moderate[3d]/[2p]ratio.Moreover,the UMSHNs exhibit favorable chemical stability under oxidation potential.This contribution provides a scientific guidance for further development of active metal silicate hydroxide catalysts. | Jiexin Zhu Shikun Li Zechao Zhuang Shan Gao Xufeng Hong Xuelei Pan Ruohan Yu Liang Zhou Lyudmila V.Moskaleva Liqiang Mai | 2022 | Energy & Environmental Materials2022，5，1： | 0 |
| 15 | ZIF-Mediated Anchoring of Co species on N-doped Carbon Nanorods as an Efficient Cathode Catalyst for Zn-Air Batteries显示文摘Developing efficient oxygen reduction reaction(ORR)catalyst is essential for the practical application of Zn-air batteries(ZABs).In this contribution,we develop a novel zeolitic imidazolate framework(ZIF)-mediated strategy to anchor Co species on N-doped carbon nanorods for efficient ORR.Featuring ultrahigh N-doping(10.29 at.%),monodisperse Co nanocrystal decoration,and well-dispersed Co-N_(x)functionalization,the obtained Co-decorated N-doped carbon nanorods(Co@NCNR)exhibit a decent ORR performance comparable to commercial Pt/C in alkaline media.Aqueous ZABs have been assembled using Co@NCNR as the cathode catalyst.The assembled ZABs manifest high initial open-circuit voltage as well as high energy density.In addition,the Co@NCNR also demonstrates ideal ORR performance in quasi-solid-state ZABs. | Qiang Yu Jianshuai Lv Jiantao Li Ruohan Yu Jinsong Wu Shibo Xi Xinyuan Li Nuo Xu Liang Zhou Liqiang Ma | 2023 | Energy & Environmental Materials2023，6，3： | 0 |
| 16 | Single-Atom Lithiophilic Sites Confined within Ordered Porous Carbon for Ultrastable Lithium Metal Anodes显示文摘Attributing to the high specific capacity and low electrochemical reduction potential,lithium(Li)metal is regarded as the most promising anode for high-energy Li batteries.However,the growth of lithium dendrites and huge volume change seriously limit the development of lithium metal batteries.To overcome these challenges,an ordered mesoporous N-doped carbon with lithiophilic single atoms is proposed to induce uniform nucleation and deposition of Li metal.Benefiting from the synergistic effects of interconnected three-dimensional ordered mesoporous structures and abundant lithiophilic single-atom sites,regulated local current density and rapid mass transfer can be achieved,leading to the uniform Li deposition with inhibition of dendrites and buffered volume expansion.As a result,the as-fabricated anode exhibits a high CE of 99.8%for 200 cycles.A stable voltage hysteresis of 14 mV at 5 mA cm^(−2)could be maintained for more than 1330 h in the symmetric cell.Furthermore,the full cell coupled with commercial LiFePO_(4)exhibits high reversible capacity of 108 mAh g^(−1)and average Coulombic efficiency of 99.8%from 5th to 350th cycles at 1 C.The ordered mesoporous carbon host with abundant lithiophilic single-atom sites delivers new inspirations into rational design of high-performance Li metal anodes. | Wenzhong Huang Shanlin Liu Ruohan Yu Liang Zhou Zhenhui Liu Liqiang Mai | 2023 | Energy & Environmental Materials2023，6，3： | 0 |
| 17 | Activating Inert Sites in Cobalt Silicate Hydroxides for Oxygen Evolution through Atomically Doping显示文摘Metal silicate hydroxides have been recognized as efficient oxygen evolution reaction(OER)electrocatalysts,yet tailoring of their intrinsic activity remains confused.Herein,Fe had been incorporated into cobalt silicate hydroxide nanosheets and the resulted material achieves a competitive OER catalytic activity.It is found that the doping state obviously affects the electrical transport property.Specifically,highly dispersed Fe atoms(low-concentration Fe doping)trigger slight electron transfer to Co atoms while serried Fe(highconcentration Fe doping)attract vast electrons.By introducing 6 at.%Fe doping,partial relatively inert Co sites are activated by atomically dispersed Fe,bearing an optimal metal 3d electronic occupation and adsorption capacity to oxygen intermediate.The introduced Co-O-Fe unit trigger the p-donation effect and decrease the number of electrons in p*-antibonding orbitals,which enhance the Fe-O covalency and the structural stability.As a result,the sample delivers a low overpotential of 293 mV to achieve a current density of 10 mA cm^(-2).This work clarifies the superiority of atomically dispersed doping state,which is of fundamental interest to the design of doped catalyst. | Jiexin Zhu Lixue Xia Wenxuan Yang Ruohan Yu Wei Zhang Wen Luo Yuhang Dai Wei Wei Liang Zhou Yan Zhao Liqiang Mai | 2022 | Energy & Environmental Materials2022，5，2： | 0 |
| 18 | Bi nanoparticles encapsulated in nitrogen-doped carbon as a long-life anode material for magnesium batteries显示文摘Bismuth has garnered significant interest as an anode material for magnesium batteries(MBs) because of its high volumetric specific capacity and low working potential. Nonetheless, the limited cycling performance(≤100 cycles) limits the practical application of Bi as anode for MBs. Therefore, the improvement of Bi cycling performance is of great significance to the development of MBs and is also full of challenges. Here, Bi nanoparticles encapsulated in nitrogen-doped carbon with single-atom Bi embedded(Bi@NC) are prepared and reported as an anode material for MBs. Bi@NC demonstrates impressive performance, with a high discharge capacity of 347.5 mAh g^(-1) and good rate capability(206.4 mAh g^(-1)@500 mA g^(-1)) in a fluoride alkyl magnesium salt electrolyte. In addition, Bi@NC exhibits exceptional long-term stability, enduring 400 cycles at 500 mA g^(-1). To the best of our knowledge, among reported Bi and Bi-based compounds for MBs, Bi@NC exhibits the longest cycle life in this work. The magnesium storage mechanism of Bi@NC is deeply studied through X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. This work provides some guidance for further improving the cycling performance of other alloy anodes in MBs. | Junjun Wang Ruohan Yu Jianxiang Wang Juncai Long Fan Qiao Lei Zhang Guanjie He Qinyou An Liqiang Mai | 2023 | Journal of Magnesium and Alloys2023，11，11： | 0 |
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