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| 1 | Nurturing the marriages of single atoms with atomic clusters and nanoparticles for better heterogeneous electrocatalysis显示文摘Single-atom catalysts,featuring some of the most unique activities,selectivity,and high metal utilization,have been extensively studied over the past decade.Given their high activity,selectivity,especially towards small molecules or key intermediate conversions,they can be synergized together with other active species(typically other single atoms,atomic clusters,or nanoparticles)in either tandem or parallel or both,leading to much better performance in complex catalytic processes.Although there have been reports on effectively combining the multiple components into one single catalytic entity,the combination and synergy between single atoms and other active species have not been reviewed and examined in a systematic manner.Herein,in this overview,the key synergistic interactions,binary complementary effects,and the bifunctional functions of single atoms with other active species are defined and discussed in detail.The integration functions of their marriages are in-vestigated with particular emphasis on the homogeneous and heterogeneous combinations,spatial distribution,synthetic strategies,and the thus-derived outstanding catalytic performance,together with new light shined on the catalytic mechanisms by zooming in several case studies.The dynamic nature of each of the active species and in particular their interactions in such new catalytic entities in the heterogeneous electrocatalytic processes are visited,on the basis of the in situ/operando evidence.Last,we feature the current chal-lenges and future perspectives of these integrated catalytic entities that can offer guidance for advanced catalyst design by the rational combination and synergy of binary or multiple active species. | Lei Zhang Jiawei Zhu Xin Li Shichun Mu Francis Verpoort Junmin Xue Zongkui Kou John Wang | 2022 | Interdisciplinary Materials2022，1，1： | 3 |
| 2 | Low-strain TiP_(2)O_(7) withthree-dimensionalionchannelsas long-life and high-rate anode material for Mg-ion batteries显示文摘Rechargeable magnesium batteries are identified as a promising next-generation energy storage system,but their development is hindered by the anode−electrolyte−cathode incompatibilities and passivation of magnesium metal anode.To avoid or alleviate these problems,the exploitation of alternative anode materials is a promising choice.Herein,we present titanium pyrophosphate(TiP_(2)O_(7))as anode materials for magnesium-ion batteries(MIBs)and investigate the effect of the crystal phase on its magnesium storage performance.Compared with the me-tastable layered TiP_(2)O_(7),the thermodynamically stable cubic TiP_(2)O_(7) displays a better rate capability of 72 mAh g^(−1) at 5000 mA g^(−1).Moreover,cubic TiP_(2)O_(7) exhibits excellent cycling stability with the capacity of 60 mAh g^(−1) after 5000 cycles at 1000 mA g^(−1),which are better than pre-viously reported Ti-based anode materials for MIBs.In situ X-ray diffraction technology confirms the single-phase magnesiumion inter-calation/deintercalation reaction mechanism of cubic TiP_(2)O_(7) with a low volume change of 3.2%.In addition,the density functional theory calcu-lation results demonstrate that three-dimensional magnesiumion diffu-sion can be allowed in cubic TiP_(2)O_(7) with a low migration energy barrier of 0.62 eV.Our work demonstrates the promise of TiP_(2)O_(7) as high-rate and long-life anode materials for MIBs and may pave the way for further development of MIBs. | Fangyu Xiong Yalong Jiang Li Cheng Ruohan Yu Shuangshuang Tan Chen Tang Chunli Zuo Qinyou An Yunlong Zhao Jean-Jacques Gaumet Liqiang Mai | 2022 | Interdisciplinary Materials2022，1，1： | 3 |
| 3 | Materials for evaporation-driven hydrovoltaic technology显示文摘Water constitutes the largest energy carrier on earth,absorbing more than 70%of the solar energy received by the earth's surface,yet its low exploitation has been a constant concern.The hydrovoltaic effect is an emerging technology that generates electricity through the direct interaction between nanomaterials and water of various forms(raindrops,waves,flows,moisture,and natural evaporation).Especially,the evaporation-driven hydrovoltaic effect is a spontaneous and ubiquitous process that can directly convert thermal energy from the surrounding environment into electricity without the demand for additional mechanical work,which shows unique advantages compared with other hydrovoltaic effects.A variety of nanostructured materials have been steadily developed for evaporation-driven hydrovoltaic devices(EHDs)in recent years.However,there has been a lack of a clear specification on the selection and design of materials for improving device performance.Herein,we first analyze the mechanisms of EHDs followed by a summarization of the recent advances in materials,including carbon materials,biomass-based materials,metal oxides,composite materials,and others.We then discuss the strategies for improving the energy conversion efficiency and the output power in terms of structural design,surface modification,and interface treatment.Finally,we provide an outlook on the potential applications of electricity generation,sensors,and desalination technology,as well as the challenges and prospects for the development of this emerging technology in the future. | Chunxiao Zheng Weicun Chu Sunmiao Fang Jin Tan Xiaofan Wang Wanlin Guo | 2022 | Interdisciplinary Materials2022，1，4： | 3 |
| 4 | Acidic oxygen evolution reaction:Mechanism,catalyst classification,and enhancement strategies显示文摘As the most desirable hydrogen production device,the highly efficient acidic proton exchange membrane water electrolyzers(PEMWE)are severely limited by the sluggish kinetics of oxygen evolution reaction(OER)at the anode.Rutile IrO2 is a commercial acid-stable OER catalyst with poor activity and high cost,which has motivated the development of alternatives.However,hitherto most of the designed acidic OER catalysts have disadvantages of low activity or stability,which cannot meet the requirement of industrial applications.Thus,exploring suitable strategies to enhance the activity and stability of cost-effective acidic OER catalysts is crucial for developing the PEMWE technique.In this review,the main OER mechanisms,different types of catalysts,and their activity and stability characteristics are summarized and discussed,and then possible strategies to improve activity and stability are proposed.Finally,the problems and prospects of such catalysts are generalized to shed some light on the future research of advanced catalysts for acidic OER. | Qianli Ma Shichun Mu | 2023 | Interdisciplinary Materials2023，2，1： | 2 |
| 5 | Progress and perspectives of in situ polymerization method for lithium-based batteries显示文摘The application of lithium-based batteries is challenged by the safety issues of leakage and flammability of liquid electrolytes.Polymer electrolytes(PEs)can address issues to promote the practical use of lithium metal batteries.However,the traditional preparation of PEs such as the solution-casting method requires a complicated preparation process,especially resulting in side solvents evaporation issues.The large thickness of traditional PEs reduces the energy density of the battery and increases the transport bottlenecks of lithium-ion.Meanwhile,it is difficult to fill the voids of electrodes to achieve good contact between electrolyte and electrode.In situ polymerization appears as a facile method to prepare PEs possessing excellent interfacial compatibility with electrodes.Thus,thin and uniform electrolytes can be obtained.The interfacial impedance can be reduced,and the lithium-ion transport throughput at the interface can be increased.The typical in situ polymerization process is to implant a precursor solution containing monomers into the cell and then in situ solidify the precursor under specific initiating conditions,and has been widely applied for the preparation of PEs and battery assembly.In this review,we focus on the preparation and application of in situ polymerization method in gel polymer electrolytes,solid polymer electrolytes,and composite polymer electrolytes,in which different kinds of monomers and reactions for in situ polymerization are discussed.In addition,the various compositions and structures of inorganic fillers,and their effects on the electrochemical properties are summarized.Finally,challenges and perspectives for the practical application of in situ polymerization methods in solid-state lithium-based batteries are reviewed. | Guanyou Xiao Hao Xu Chen Bai Ming Liu Yan-Bing He | 2023 | Interdisciplinary Materials2023，2，4： | 2 |
| 6 | Recent progress on the modification of high nickel contentNCM:Coating,doping,and single crystallization显示文摘High nickel content layered cathodes,represented by NCM(LiNi_(x)Co_(y)Mn_(z)O_(2),x+y+z=1),are now widely employed in the market of electric vehicles,owing to their high energy density.With the gradual increase of nickel content and capacity,the issues on cycling life and safety become more serious.In this review,various strategies for improving the performance of high nickel NCM are summarized on the aspects of surface coating,ionic doping,and singlecrystal NCM.The coating strategy was separately described according to the physical property of coating species,including inert material coating,Li^(+)-conductor coating,electronic conductor coating,and mixed conductor coating.These coating species help to suppress the interfacial oxidation of electrolytes by NCM,improving the cycling life and safety.The elemental doping in the crystal lattice of NCM is then presented in the aspects of cation,anion,and mixed-ion doping,which are beneficial to stabilize the layered structure during charge–discharge and so promote the electrochemical performance.In quite recent years,the strategy of single-crystal NCM was demonstrated to be a promising pathway,owing to the dramatically reduced surface area and grain boundary.Finally,the remaining unsolved challenges and future strategies for further development of NCM cathode materials are outlined. | Junqing Yan Hao Huang Junfan Tong Wei Li Xiaohang Liu Haoxuan Zhang Heqin Huang Weidong Zhou | 2022 | Interdisciplinary Materials2022，1，3： | 2 |
| 7 | Iron anode-based aqueous electrochemical energy storage devices: Recent advances and future perspectives显示文摘The ever-growing demands for green and sustainable power sources for ap-plications in grid-scale energy storage and portable/wearable devices have enabled the continual development of advanced aqueous electrochemical energy storage(EES)systems.Aqueous batteries and supercapacitors made of iron-based anodes are one of the most promising options due to the remark-able electrochemical features and natural abundance,pretty low cost and good environmental friendliness of ferruginous species.Though impressive ad-vances in developing the state-of-the-art ferruginous anodes and designing various full-cell aqueous devices have been made,there still remain key issues and challenges on the way to practical applications,which urgently need discussing to put forwards possible solutions.In this review,rather than focusing on the detailed methods to optimize the iron anode,electrolyte,and device performance,we first give a comprehensive review on the charge storage mechanisms for ferruginous anodes in different electrolyte systems,as well as the newly developed iron-based aqueous EES devices.The deep in-sights,involving the inherent failure mechanisms and corresponding modification/optimization strategies toward iron anodes for the development of high-performance aqueous EES devices,will then be discussed.The advances in applying iron-based aqueous EES devices for emerging fields such as flexible/wearable electronics and functionalized building materials will be further outlined.Last,future research trends and perspectives for maximizing the potential of current iron anodes and devices as well as exploiting brand-new iron-based aqueous EES systems are put forward. | Jian Jiang Jinping Liu | 2022 | Interdisciplinary Materials2022，1，1： | 2 |
| 8 | Three‐terminal perovskite/integratedbackcontactsilicon tandem solar cells under low light intensity conditions显示文摘The current climate and energy crisis urgently needs solar cells with efficiencies above the 29% single junction efficiency bottleneck.Silicon/perovskite tandem solar cells are a solution,which is attracting much attention.While silicon/perovskite tandem cells in 2-terminal and 4-terminal configurations are well documented,the three-terminal concept is still in its infancy.It has significant advantages under low light intensities as opposed to concentrated sunlight,which is the critical factor in designing tandem solar cells for low-cost terrestrial applications.This study pre-sents novel studies of the sub-cell performance of the first three-terminal perovskite/silicon selective band offset barrier tandem solar cells fabricated in an ongoing research project.This study focuses on short circuit current and operating voltages of the subcells under light intensities of one sun and below.Lifetime studies show that the perovskite bulk carrier lifetime is insensitive to illumination,while the silicon cell's lifetime decreases with decreasing light intensity.The combination of perovskite and silicon in the 3T perovskite-silicon tandem therefore reduces the sensitivity of V_(OC) to light intensity and maintains a relatively higher V_(OC) down to low light intensities,whereas silicon single-junction cells show a marked decrease.This technological advantage is proposed as a novel advantage of three-terminal perovkite/silicon solar cells for low light intensities of one sun or less. | Hiroyuki Kanda Valentin Dan Mihailetchi Marie-Estelle Gueunier-Farret Jean-Paul Kleider Zakaria Djebbour Jose Alvarez Baranek Philippe Olindo Isabella Malte R.Vogt Rudi Santbergen Philip Schulz Fiala Peter Mohammad K.Nazeeruddin James P.Connolly | 2022 | Interdisciplinary Materials2022，1，1： | 2 |
| 9 | Unraveling the reaction mechanisms of electrode materials for sodiumion and potassium‐ion batteries by in situ transmission electron microscopy显示文摘Sodium ion batteries(SIBs)and potassium ion batteries(PIBs)have caught numerous attention due to the low cost and abundant availability of sodium and potassium.However,their power density,cycling stability and safety need further improvement for practical applications.Investigations on the reaction mechanisms and structural degradation when cycling are of great importance.In situ transmission electron microscopy(TEM)is one of the most significant techniques to understand and monitor electrochemical processes at an atomic scale with real-time imaging.In this review,the current progress in unraveling reaction mechanisms of electrode materials for SIBs and PIBs via in situ TEM is summarized.First,the importance of in situ TEM is highlighted.Then,based on the three types of electrochemical reaction,i.e.,intercalation reac-tion,conversion reaction and alloying reaction,the structural evolution and reaction kinetics at atomic resolution,and their relation to the electrochemical performance of electrode materials are reviewed and described in detail.Fi-nally,future directions of in situ TEM for SIBs and PIBs are proposed.Therefore,the in‐depth understanding revealed by in situ TEM will give an instructive guide in rational design of electrode materials for high performance electrode materials of SIBs and PIBs. | Hong Wang Fang Liu Ruohan Yu Jinsong Wu | 2022 | Interdisciplinary Materials2022，1，2： | 2 |
| 10 | Direct ink writing of programmable functional silicone-based composites for 4D printing applications显示文摘Polydimethylsiloxane(PDMS)has been widely used in flexible electronics,soft robotics,and bioelectronics.However,the fabrication of PDMS-based devices has mostly relied on conventional approaches,such as casting and molding,thereby limiting their potential.Here we fabricate PDMS-based composites with programmable microstructures by direct ink writing and realize their practical functionalities of four-dimensional(4D)printing.The mechanical,thermomechanical and magnetic properties of the three-dimensional-printed composites can be well tailored by using carbon,metal,or ceramic functional fillers.By taking advantage of the printable,flexible,and magnetic PDMS composites,we demonstrate new practical functionalities of 4D printing by designing programmable architectures,including magnetic-field-driven battery cases and patchworks,as well as arbitrary morphing ceramic structures.In particular,4D-printed batteries are constructed by PDMS-based battery cases for the first time,which can be actuated via external magnetic field.This study broadens the paradigm of 4D printing for prospective applications,such as implant batteries,biomimetic engineering,and customized biomedical devices. | Zhiyang Lyu J.ustin Koh Gwendolyn J.H.Lim Danwei Zhang Ting Xiong Lei Zhang Siqi Liu Junfei Duan Jun Ding John Wang Jinlan Wang Yunfei Chen Chaobin He | 2022 | Interdisciplinary Materials2022，1，4： | 2 |
| 11 | A comprehensive review on Bi_(2)Te_(3)-based thin films: Thermoelectrics and beyond显示文摘Bi_(2)Te_(3)-based materials are not only the most important and widely used room temperature thermoelectric(TE)materials but are also canonical examples of topological insulators in which the topological surface states are protected by the time-reversal symmetry.High-performance thin films based on Bi_(2)Te_(3)- have attracted worldwide attention during the past two decades due primarily to their outstanding TE performance as highly efficient TE coolers and as miniature and flexible TE power generators for a variety of electronic devices.Moreover,intriguing topological phenomena,such as the quantum anomalous Hall effect and topological superconductivity discovered in Bi_(2)Te_(3)-based thin films and heterostructures,have shaped research directions in the field of condensed matter physics.In Bi_(2)Te_(3)-based films and heterostructures,delicate control of the carrier transport,film composition,and microstructure are prerequisites for successful device operations as well as for experimental verification of exotic topological phenomena.This review summarizes the recent progress made in atomic defect engineering,carrier tuning,and band engineering down to a nanoscale regime and how it relates to the growth and fabrication of high-quality Bi_(2)Te_(3)-based films.The review also briefly discusses the physical insight into the exciting field of topological phenomena that were so dramatically realized in Bi_(2)Te_(3)-and Bi_(2)Se_(3)‐based structures.It is expected that Bi_(2)Te_(3)-based thin films and heterostructures will play an ever more prominent role as flexible TE devices collecting and converting low-level(body)heat into electricity for numerous electronic applications.It is also likely that such films will continue to be a remarkable platform for the realization of novel topological phenomena. | Xinfeng Tang Ziwei Li Wei Liu ingjie Zhang Ctirad Uher | 2022 | Interdisciplinary Materials2022，1，1： | 1 |
| 12 | Machine learning in energy storage materials显示文摘With its extremely strong capability of data analysis,machine learning has shown versatile potential in the revolution of the materials research paradigm.Here,taking dielectric capacitors and lithium‐ion batteries as two representa-tive examples,we review substantial advances of machine learning in the research and development of energy storage materials.First,a thorough discussion of the machine learning framework in materials science is presented.Then,we summarize the applications of machine learning from three aspects,including discovering and designing novel materials,enriching theoretical simulations,and assisting experimentation and characterization.Finally,a brief outlook is highlighted to spark more insights on the innovative implementation of machine learning in materials science. | Zhong-Hui Shen Han-Xing Liu Yang Shen Jia-Mian Hu Long-Qing Chen Ce-Wen Nan | 2022 | Interdisciplinary Materials2022，1，2： | 1 |
| 13 | Artificial nanomotors: Fabrication, locomotion characterization, motion manipulation, and biomedical applications显示文摘Artificial nanomotors are nanoscale machines capable of converting surrounding other energy into mechanical motion and thus entering the tissues and cells of organisms.They hold great potential to revolutionize the diagnosis and treatment of diseases by actively targeting the lesion location,though there are many new challenges that arise with decreasing the size to nanoscale.This review sum-marizes and comments on the state-of-the-art artificial nanomotors with ad-vantages and limitations.It starts with the fabrication methods,including common physical vapor deposition and colloidal chemistry methods,followed by the locomotion characterization and motion manipulation.Then,the in vitro and in vivo biomedical applications are introduced in detail.The challenges and future prospects are discussed at the end. | Liangmeng Wang Xiaomeng Hao Zhixue Gao Zili Yang Yi Long Ming Luo Jianguo Guan | 2022 | Interdisciplinary Materials2022，1，2： | 1 |
| 14 | Covalent organic frameworks as electrode materials for rechargeable metal-ion batteries显示文摘Covalent organic frameworks(COFs),as a class of crystalline porous polymers,featuring designable structures,tunable frameworks,well-defined channels,and tailorable functionalities,have emerged as promising organic electrode materials for rechargeable metal-ion batteries in recent years.Tremendous efforts have been devoted to improving the electrochemical performance of COFs.However,although significant achievements have been made,the electrochemical behaviors of developed COFs are far away from the desirable performance for practical batteries owing to intrinsic problems,such as poor electronic conductivity,the trade-off relationship between capacity and redox potential,and unfavorable micromorphology.In this review,the recent progress in the development of COFs for rechargeable metal-ion batteries is presented,including Li,Na,K,and Zn ion batteries.Various research strategies for improving the electrochemical performance of COFs are summarized in terms of the molecular-level design and the material-level modification.Finally,the major challenges and perspectives of COFs are also discussed in the aspect of large-scale production and electrochemical performance improvements. | Manman Wu Zhen Zhou | 2023 | Interdisciplinary Materials2023，2，2： | 1 |
| 15 | Artificial intelligence biosensors for continuous glucose monitoring显示文摘Artificial intelligence(AI)algorithms in combination with continuous monitoring technologies have the potential to revolutionize chronic disease management.The recent innovations in both continuous glucose monitoring(CGM)and the closed-loop highlight the far-reaching potential of AI biosensors for individual healthcare.This review summarizes some of the most advanced progress made in CGM biosensing.We will focus on three main applications of AI algorithms in diabetes management:closed-loop control algorithms,glucose predictions,and calibrations.The challenges and opportunities of AI technologies for CGM in individualized and proactive medicine will also be discussed. | Xiaofeng Jin Andrew Cai Tailin Xu Xueji Zhang | 2023 | Interdisciplinary Materials2023，2，2： | 1 |
| 16 | Bioinspired mechanically interlocking holey graphene@SiO_(2)anode显示文摘Mechanically interlocking structures that can enhance adhesion at the interface and regulate the stress distribution have been widely observed in biological systems.Inspired by the biological structures in the wings of beetles,we synthesized a holey graphene@SiO_(2)anode with strong mechanical interlocking,characterized it electrochemically,and explained its performance by finite element analysis and density functional calculations.The mechanically interlocking structure enhances lithium-ion(Li^(+))storage by transmitting the strain from SiO_(2)to the holey graphene and by a mechano-electrochemical coupling effect.The interlocking fit hinders the abscission of SiO_(2)and the distinctive structure reduces the stress and strain of SiO_(2)during(de)lithiation.The positive mechano-electrochemical coupling effect preserves the amount of electrochemically active phase(LixSi)during cycles and facilitates Li+diffusion.Therefore,the capacity shows only a slight attenuation after 8000 cycles(cycling stability),and the specific capacity is~1200 mA h g^(−1)at 5 A/g(rate-performance).This study furnishes a novel way to design high-performance Li^(+)/Na+/K^(+)/Al3^(+)anodes with large volume expansion. | Fei Wang Xiaobin Liao Haoyu Wang Yan Zhao Jian Mao Donald G.Truhlar | 2022 | Interdisciplinary Materials2022，1，4： | 1 |
| 17 | Monolithic bilayered In_(2)O_(3) as an efficient interfacial material for high-performance perovskite solar cells显示文摘Carrier recombination at the buried SnO_(2)/perovskite interface limits the efficiency and stability of n-i-p-structured perovskite solar cells(PSCs).Herein,we report an In_(2)O_(3)interfacial layer with the distinctive structure of the monolithic compact/nanostructured bilayer.The partial hydrolysis nature of the In^(3+)ion enables the formation of nanorods on top of the compact In_(2)O_(3)layer when spin-coating the In(NO_(3))_(3) aqueous solution.This novel interfacial layer reduces the pinholes of the SnO_(2)film and increases the contact area between the perovskite and electron transport material.Therefore,PSCs with the incorporation of the interfacial layer demonstrate enhanced electron extraction and suppressed carrier recombination.Consequently,the champion device achieves a power conversion efficiency of 23.87%with a high fill factor of 82.14%.The optimized device also shows robust operational stability,retaining over 80%of the initial power conversion efficiency after working at the maximum power point for over 500 h under continuous one-sun illumination. | Wanjia Tian Peiquan Song Yaping Zhao Lina Shen Kaikai Liu Lingfang Zheng Yujie Luo Chengbo Tian Liqiang Xie Zhanhua Wei | 2022 | Interdisciplinary Materials2022，1，4： | 1 |
| 18 | The extraction of Nd from waste Nd-Fe-B alloys by the glass slag method 显示文摘 | SAITO T SATO H OZAWA S | 2003 | Journal of Al- loys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics2003，353，1： | 1 |
| 19 | NASICONs-type solid-state electrolytes:The history,physicochemical properties,and challenges显示文摘Solid-state electrolytes are critical for the development of next-generation high-energy and high-safety rechargeable batteries.Among all the candidates,sodium(Na)superionic conductors(NASICONs)are highly promising because of their evident advantages in high ionic conductivity and high chemical/electrochemical stability.The concept of NASICONs was proposed by Hong and Goodenough et al.in 1976 by reporting the synthesis and characterization of Na1+xZr2(SixP3−x)O12(0≤x≤3),which has attracted tremendous attention on the NASICONs-type solid-state electrolytes.In this review,we are committed to describing the development history of NASICONs-type solid-state electrolytes and elucidating the contribution of Goodenough as a tribute to him.We summarize the correlations and differences between lithium-based and sodium-based NASICONs electrolytes,such as their preparation methods,structures,ionic conductivities,and the mechanisms of ion transportation.Critical challenges of NASICONs-structured electrolytes are discussed,and several research directions are proposed to tackle the obstacles toward practical applications. | Lixiao Zhang Yimeng Liu Ya You Ajayan Vinu Liqiang Mai | 2023 | Interdisciplinary Materials2023，2，1： | 1 |
| 20 | A critical review of key materials and issues in solid oxide cells显示文摘Solid oxide cells(SOCs)are all solid ceramic devices with the dual functionality of solid oxide fuel cells(SOFCs)to convert the chemical energy of fuels like H2,natural gas and other hydrocarbons to electricity and of solid oxide electrolysis cells(SOECs)to store renewable electric energy of sun and wind in hydrogen fuel.Among the electrochemical energy conversion and storage devices,SOCs are the most clean and efficient technology with unique dual functionality.Due to the high operation temperature(typically 600–800°C),SOCs exhibit many advantages over other energy conversion devices,such as low material cost,high efficiency and fuel flexibility.There has been rapid development of SOC technologies over the last decade with significant advantages and progress in key materials and a fundamental understanding of key issues such as an electrode,electrolyte,performance degradation,poisoning,and stack design.The reversible polarization also has a critical effect on the surface segregation and stability of the electrode and electrode/electrolyte interface.This critical review starts with a brief introduction,working principles and thermodynamics of SOC technology to readers with interests in this rapidly developing and emerging field.Then the key materials currently used in SOCs are summarized,followed by the discussion of the most advanced electrode modification methods and critical issues of SOCs,including the surface chemistry,segregation,electrode/electrolyte interface and varying material degradation mechanisms under reversible operations.The challenges and prospects of SOC technology for future developments are discussed. | Shuai He Yuanfeng Zou Kongfa Chen San P.Jiang | 2023 | Interdisciplinary Materials2023，2，1： | 1 |
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