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	题名	作者	年代	出处	被引量
1	Estimation of Time to Maximum Rate Under Adiabatic Conditions(TMR_(ad)) Using Kinetic Parameters Derived From DSC-Investigation of Thermal Behavior of 3-Methyl-4-Nitrophenol显示文摘Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kinetic approach for the determination of the thermal behavior also under adiabatic conditions occurring e.g.in batch reactors in case of cooling failure.The kinetics of the decomposition of different samples(different manufacturers and batches) of 3-methyl-4-nitrophenol were investigated by conventional DSC in non-isothermal(few heating rates varying from 0.25 to 8.0K/min) and isothermal(range of 200~260℃) modes.The kinetic parameters obtained with AKTS-Thermokinetics Software were applied for calculating reaction rate and progress under different heating rates and temperatures and verified by comparing simulated and experimental signals.After application of the heat balance to compare the amount of heat generated during reaction and its removal from the system,the knowledge of reaction rate at any temperature profiles allowed the determination of the temperature increase due to the self-heating in adiabatic and pseudo-adiabatic conditions.Applied advanced kinetic approach allowed simulation the course of the Heat-Wait-Search(HWS) mode of operation of adiabatic calorimeters.The thermal safety diagram depicting dependence of Time to Maximum Rate(TMR) on the initial temperature was calculated and compared with the results of HWS experiments carried out in the system with Ф-factor amounting to 3.2.The influence of the Ф-factor and reaction progress reached at the end of the HWS monitoring on the TMR is discussed.Presented calculations clearly indicate that even very minor reaction progress reduces the TMRad of 24h characteristic for a sample with initial reaction progress amounting to zero.Described estimation method can be verified by just one HWS-ARC,or by one correctly chosen ISO-ARC run of reasonable duration by knowing in advance the dependence of the TMR on the initial temperature for any Ф-factor.Proposed procedure results in significant shortening of the measuring time compared to a safety hazard approach based on series of ARC experiments carried out at the beginning of a process safety evaluation.	Bertrand Roduit Patrick Folly Alexandre Sarbach Beat Berger Franz Brogli Francesco Mascarello Mischa Schwaninger Thomas Glarner Eberhard Irle Fritz Tobler Jacques Wiss Markus Luginbühl Craig Williams Pierre Reuse Francis Stoessel	2011	化学推进剂与高分子材料2011，9，1：	3
2	Advanced kinetics based simulation of time to maximum rate under adiabatic eon- ditions显示文摘	Roduit B Dermaut W Lunghi A	2008	Journal of Thermal Analysis and Calorimetry2008，93，1：	1
3	Renewable functionalized pyridines derived from microbial metabolites of the alkaloid (S)-nicotine显示文摘	RODUIT J P WELLIG A KIENERT A	1997	Heterocycles1997，，45：	1
4	A role for hormone- sensitive lipase in glucose-stimulated insulin secretion:q a study in hormone sensitive lipase-deficient mice显示文摘	Roduit R Masiello P Wang S P	2001	Diabetes2001，50，9：	1
5	Inhibition of Glucose-Induced Insulin Secretion by Long-Term Preexposure of Pancreatic Isletsto Leptin显示文摘	RODUIT R THORENS B	1997	FEBS Letters1997，415，：	1
6	Glucose down-regulates the expression of the peroxisome proliferator-activated receptor-alpha gene in the pancreatic beta -cell显示文摘	Roduit R Morin J Masse F	2000	J Biol Chem2000，275，35：	1
7	Glucagon-like peptide-1 promotes DNA synthesis, activates phosphatidylinositol 3-kinase and increases transcription factor pancreatic and duodenal homeobox gene 1 ( PDX- 1 ) DNA binding activity in beta ( INS-1 ) -cells 显示文摘	Buteau J Roduit R Susini S	1999	Diabetologia1999，42，7：	1
8	Hospital undernutrition:how not to ignore it any more 显示文摘	Berthod G Roduit J Roulet M	2007	Rev Med Suisse2007，3，131：	1
9	Asthma at 8 years of age in children born by caesarean section显示文摘	Roduit C ScholtensS deJongsteJC	2009	Thorax2009，64，：	1
10	Elastic Membrane Heterogeneity of Living Cells Revealed by Stiff Nanoscale Membrane Domains显示文摘	Roduit C van der Goot F G De Los Rios P		0，，04：	1
11	A role for the malonyl - CoA/long - chain acyl - CoA pathway of lipid signaling in the regulation of insu: lin secretion in response to both fuel and nonfuel stimuli显示文摘	Roduit R Nolan C Alarcon C	2004	Diabetes2004，53，4：	1
12	Preparation of(S)-piperazine-2-carboxylic acid,(R)-piperazine-2-carboxylic acid,and(S)-piperizine-2-carboxylic acidby kinetic resolution of the corresponding racemiccarboxamides with stereoselective amidases in wholebacterial cells显示文摘	Eichhorn E Roduit J P Shaw N	1997	Tetrahed:As-ymm1997，8，15：	1
13	The loss of GLUT2 expression in the pancreatic beta-cells of diabetic db/db mice is associated with an impaired DNA-binding activity of islet transacting factors显示文摘	Bonny C Roduit R Gremlich S	1997	Mol Cell Endocrinol1997，135，1：	1
14	Dexamethasone induces posttranslational degradation of GLUT2 and inhibition of insulin secretion in isolated pancreatic beta cells显示文摘	GREMLICH S RODUIT R THORENS B	1997	J Biol Chem1997，272，6：	1
15	Global kinetic modelingof reactions occurring during selective catalytic reductionof NO by NH3 over vanadia/titania-based catalysts 显示文摘	Roduit B WokaunA Baiker A	1998	Industrial & Engineering Chemistry Research1998，37，12：	1
16	Up-scaling of DSC data of high energetic materials simulation of cook-off experiments显示文摘	Roduit B Borgeat C Berger B	2006	Journal of Thermal Analysis and Calorimetry2006，85，1：	1
17	A Role for Septins in the Interaction between the Listeria monocytogenes Invasion Protein InlB and the Met Receptor显示文摘	Serge Mostowy Sébastien Janel Claire Forestier Charles Roduit Sandor Kasas Javier Pizarro-Cerdá Pascale Cossart Frank Lafont	2011	Biophysical Journal2011，，8：	1
18	Computational aspects of kinetic analysis: part E: The ICTAC kinetics project--numerical techniques and kinetics of solid state processes 显示文摘	RODUIT B	2000	Thermochimica Acta2000，355，1：	1
19	The simulation of the thermal behavior of energetic materials based on DSC and HFC signals 显示文摘	Roduit B Xia L Folly P	2008	Journal of ThermalAnalysis and Calorimetry2008，93，1：	1
20	The simulation of the thermal behavior of energetic materials based on DSC and HFC signal显示文摘	Roduit B Xia L Folly P	2008	Journal of Thermal Analysis and Calorime- try2008，93，：	1

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