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| 1 | Germafluorene conjugated copolymer——synthesis and applications in blue-light-emitting diodes and host materials显示文摘A germafluorene-fluorene copolymer was successfully obtained via Suzuki polymerization.The ger-manium containing copolymer has an efficient blue light emission under the ultraviolet irradiation and its single layer EL device showed the highest brightness of 2630 cd/m2 at 7.8 V and the highest effi-ciency of 0.301 lm/W at 6.2 V.The copolymer can also serve as the host material for phosphorescent metal complexes with the maximum brightness of 15600 cd/m2 and the quantum efficiency of 8.5%.The results are quite promising and promise that as its analogs of fluorene and silafluorene,germafluorene is an excellent building block for blue light-emitting polymers and host materials. | CHEN RunFeng ZHU Rui ZHENG Chao LIU ShuJuan FAN QuLi HUANG Wei | 2009 | Science China Chemistry2009，52，2： | 12 |
| 2 | Carbon-nitrogen/graphene composite as metal-free electrocatalyst for the oxygen reduction reaction显示文摘Sheet-like carbon-nitrogen (CNx)/graphene composites with a high content of nitrogen (x≤0.15) was prepared by the carbonization of polypyrrole (PPy)/reduced-graphene-oxide (rGO) composite at 600-800°C. We used rGO instead of graphene oxide (GO) sheets as a template and a substrate to immobilize PPy since the PPy/GO composite agglomerates easily because of the dehydration of excess oxygen-containing groups on the GO sheets during the drying process. The dried PPy/rGO intermediate and its derived CNx/graphene products retain their high dispersion and loose-powder features. The as-prepared CNx/graphene composites have a total nitrogen content of about 10 at% and their nitrogen state is mainly of pyridinic and graphitic type. CNx/graphene composites exhibit excellent performance for the oxygen reduction reaction (ORR) in terms of electrocatalytic activity, stability and immunity towards methanol crossover and CO poisoning, suggesting their potential as metal-free electrocatalysts for the ORR. | MA YanWen ZHANG LingRong LIJuanJuan NI HaiTao LI Meng ZHANG JinLei FENG XiaoMiao FAN QuLi HU Zheng HUANG Wei | 2011 | Chinese Science Bulletin2011，56，33： | 11 |
| 3 | Star-shaped conjugated oligoelectrolyte for bioimaging in living cells显示文摘A new star-shaped oligoelectrolyte (TEFCOONa) with triphenylamine as the core, acetylene as linkage and anionic fluorenes as arms was obtained and used for direct imaging in living PANC-1 cells. Because of the hydrophobic conjugated groups of the oli-goelectrolyte, TEFCOONa can form nanospheres with an average diameter of^75 nm in 10 mmol/L PBS. These nanospheres possess a relatively high absolute quantum yield (16.5% in PBS), low cytotoxicity and can penetrate into the nucleus through the cytoplasm, which is essential for living cellular imaging. Collectively, these results validate our rational design of conjugated oligoelectrolyte and even hyper branched polymers-copolyelectrolyte as effective nanovectors for bioimaging and other clinical applications. | SONG WenLi JIANG RongCui YUAN Yan LU XiaoMei HU WenBo FAN QuLi HUANG Wei | 2013 | Chinese Science Bulletin2013，58，21： | 4 |
| 4 | Nitrogen-doped carbon nanotube/polyaniline composite:Synthesis, characterization, and its application to the detection of dopamine显示文摘Nitrogen-doped carbon nanotubes (N-CNTs)/polyaniline (PANI) composites are developed as an electrode material for biosensors. The morphology, composition, and optical properties of the resulting products were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and ultraviolet-visible absorption spectra (UV-vis). Furthermore, N-CNTs/PANI composite was immobilized on the surface of a glassy carbon electrode (GCE) and applied to construct a sensor. The obtained N-CNTs/PANI-modified GCE showed one pair of redox peaks and high catalytic activity for the oxidation of dopamine (DA) in a neutral environment. Differential pulse voltam-mograms results illustrate that the fabricated DA biosensor has high anti-interference ability towards ascorbic acid (AA). In addition, the fabricated biosensor showed superior performances with two wide linear ranges from 1 to 80 μM and from 1.5 to 3.5 mM and a low detection limit of 0.01 μM. | FENG XiaoMiao LI RuiMei MA YanWen CHEN RunFeng MEI QunBo FAN QuLi HUANG Wei | 2011 | Science China Chemistry2011，54，10： | 3 |
| 5 | Synthesis of new carbon nanomolecule: C_(141)显示文摘A new [70]fullerene dimer consisting of 141 carbon atoms was first synthesized by a new method with neutron irradiation of [70]fullerene. The results of separation and isolation with two-step HPLC (high performance liquid chromatography) show that this odd-numbered fullerene dimer is stable in air. Laser induced dissociation of C141 mainly yields fragmental species C70 and C71. The UV-vis spectrum of C141 shows that its vis feature is diminished as compared to that of C70. Experiments indicate that this new method for synthesis of fullerene dimers with neutron irra-diation has a high selectivity for formation of C2n-X-C2n type carbon nanomolecules. | CHENZhenling ZHAOYuliang QULi GAOXingfa ZHANGJun YUANHui CHAIZhifang XINGGengmei CHENGYue | 2004 | Chinese Science Bulletin2004，49，8： | 3 |
| 6 | Water-soluble light-emitting nanoparticles prepared by non-covalent bond self-assembly of a hydroxyl group functionalized oligo(p-phenyleneethynylene) with different water-soluble polymers显示文摘Water-soluble light-emitting nanoparticles were prepared from hydroxyl group functionalized oligos(p-phenyleneethynylene) (OHOPEL) and water-soluble polymers(PEG,PAA,and PG) by non-covalent bond self-assembly.Their structure and optoelectronic properties were investigated through dynamic light scattering(DLS) ,UV and PL spectroscopy.The optical properties of OHOPEL-based water-soluble nanoparticles exhibited the same properties as that found in OHOPEL films,indicating the existence of interchain-aggregation of OHOPELs in the nanoparticles.OHOPEL-based nanoparticles prepared from conjugated oligomers show smaller size and lower dispersity than nanoparticles from conjugated polymers,which means that the structures of water-soluble nanoparticles are linked to the conjugated length.Furthermore,the OHOPEL/PG and OHOPEL/PAA systems produced smaller particles and lower polydispersity than the OHOPEL/PEG system,indicating that there may exist influence of the strength of non-covalent bonds on the size and degree of dispersity of the nanoparticles. | Lu XiaoMei Fan QuLi Zhang GuangWei Pu KanYi Huang Wei | 2010 | Science China Chemistry2010，53，5： | 3 |
| 7 | Synthesis,characterization and applications of vinylsilafluorene copolymers:New host materials for electroluminescent devices显示文摘Vinylsilafluorene(VSiF) was successfully synthesized and copolymerized with vinylcarbazole and methyl methacrylate via free radical copolymerization for the first time.The synthesis,photophysical properties,computational modeling studies,and organic light-emitting devices of the VSiF copolymers were presented.The good coordinated photoluminescent(PL) spectra with the absorption of blue light-emitting materials and the high energy band-gap of the VSiF copolymers were observed.Higher triplet band gap(3Eg) to host the blue phosphorescent emitters and better HOMO and LUMO than PVK for electron and hole injection and transportation of the VSiF model compounds were revealed by density functional theory(DFT) calculations.The preliminary device results in applications of these copolymers as host materials for green phosphorescent emitters demonstrate the copolymers of VSiF and vinylcarbazole have comparable device performance of polyvinylcarazole(PVK),suggesting a bright future of VSiF as building blocks for host materials. | CHEN RunFeng,ZHU Rui,ZHENG Chao,FAN QuLi & HUANG Wei* Key Laboratory for Organic Electronics & Information Displays(KLOEID) Institute of Advanced Materials(IAM),Nanjing University of Posts and Telecommunications(NUPT),Nanjing 210046,China | 2010 | Science China Chemistry2010，53，11： | 2 |
| 8 | DNA biosensors based on water-soluble conjugated polymers 显示文摘 | Liu Xingfen Fan Quli Huang Wei | 2011 | Bio- sens Bioelectron2011，26，5： | 1 |
| 9 | Synthesis and properties of polyurethane modify with aminoethylaminopropyl poly(dimethyl siloxane)显示文摘 | Fan Quli Fang Jianglin Chen Qingmin | 1999 | Journal of Applied Polymer Science1999，74，25： | 1 |
| 10 | Near-Infrared-Excitable Organic Ultralong Phosphorescence through Multiphoton Absorption显示文摘Organic ultralong room-temperature phosphorescence(OURTP)with a long-lived triplet excited state up to several seconds has triggered widespread research interests,but most OURTP materials are excited by only ultraviolet(UV)or blue light owing to their unique stabilized triplet-and solid-state emission feature.Here,we demonstrate that near-infrared-(NIR-)excitable OURTP molecules can be rationally designed by implanting intra/intermolecular charge transfer(CT)characteristics into Haggregation to stimulate the efficient nonlinear multiphoton absorption(MPA).The resultant upconverted MPA-OURTP show ultralong lifetimes over 0.42 s and a phosphorescence quantum yield of~37%under both UV and NIR light irradiation.Empowered by the extraordinary MPA-OURTP,novel applications including two-photon bioimaging,visual laser power detection and excitation,and lifetime multiplexing encryption devices were successfully realized.These discoveries illustrate not only a delicate design map for the construction of NIR-excitable OURTP materials but also insightful guidance for exploring OURTP-based nonlinear optoelectronic properties and applications. | Ye Tao Lele Tang Qi Wei Jibiao Jin Wenbo Hu Runfeng Chen Qingqing Yang Huanhuan Li Ping Li Guichuan Xing Quli Fan Chao Zheng Wei Huang | 2020 | Research2020，，1： | 1 |
| 11 | Predictive value of coronary artery stenosis and C - reactive protein levels in patients with stable coronary artery disease显示文摘 | Arroyo - Espliguero R Avanzas P Qulies J | 2009 | Atherosclerosis2009，201，1： | 1 |
| 12 | Effects of the substrate on deposition structure and reactivity in the chemical vapor deposition of carbon 显示文摘 | Thrower P A Radovic L R | 1998 | Carbon1998，36，： | 1 |
| 13 | Study on the architecture and associated technologies for Interact of things显示文摘 | Shen Subin Fan Quli Zong Ping | | 0，，06： | 1 |
| 14 | Synthesis and properties of polyurethane modified with an aminoethylaminopropyl - substituted polydimethysiloxane 显示文摘 | CHEN HONG FAN QULI CHEN DONGZHONG | 2001 | Journal of Applied Polymer Science2001，79，： | 1 |
| 15 | ON HOW CULTURAL KNOWLEDGE AFFECTS TOEFL SCORES显示文摘This paper presents a study of the effect of cultur-al background on TOEFL scores.It proceeds from therelation between culture and language,then illus-trates with actual questions from various sections ofTOEFL tests how American cultural background exertsa remarkable influence on TOEFL scores,and con-cludes with revelations with regard to English teachingin this country. | Zhang Congyi Zhong Quli Wang Shuaili Central South University,Jishou University | 2000 | Chinese Journal of Applied Linguistics2000，23，4： | 1 |
| 16 | Synthesis and properties of polyurethane ionomers based on carboxylated polycaprolactoneL显示文摘 | Hong Chen Dongzhong Chen Quli Fan | 2000 | Journal of Applied Polymer Science2000，76，14： | 1 |
| 17 | An Improved Turn-On Aptasensor for Thrombin Detection Using Split Aptamer Fragments and Graphene Oxide显示文摘为凝血酵素察觉使用的改进刺激 aptasensor 切开了 aptamer 碎片和 graphene 氧化物(去) 被报导。凝血酵素绑定 aptamer (Apt15 ) 被分成为目标识别,用荧光黄(FAM-Apt-A ) 标记的一个 8 底序列和 7 底 oligonucleotide 的二部分定序(Apt-B ) 。当目标蛋白质不在时, FAM-Apt-A/Apt-B 的荧光被熄灭由通过 Π-Π 叠在之间去并且搁浅单人赛的 DNA。不管多么当凝血酵素被介绍进系统时,一有二裂口 aptamer 碎片和凝血酵素的导致目标的 G 四倍的形式。荧光由于在之间的弱相互作用恢复了 G 四倍并且去。用未经触动的 aptamer 比作策略,探查集中被降低,并且改进敏感被获得。而且,加热过程避免相反的第二等的结构由于更短的裂口 aptamer 碎片的使用被避免。 | Xingfen Liu Yonghong Yang Xiaoxiao Hua Xiaomiao Feng Shao Su Yanqin Huang Quli Fan Lianhui Wang Wei Huang | 2015 | Chinese Journal of Chemistry2015，33，8： | 1 |
| 18 | The p38 - PGC - 1l alpha- irisin -betatrophin axis: Exploring new pathways in insulin resistance 显示文摘 | Sanchis - Gomar F Perez - Qulis C | 2014 | Adipocyte2014，3，1： | 1 |
| 19 | Synthesis, struc- ture, and optoelectronic properties of Phosphafluorene co- polymers 显示文摘 | Chen Runfeng Zhu Rui Fan Quli | 2008 | Organic Letters2008，10，13： | 1 |
| 20 | Highly selective detection of copper(Ⅱ) by a “ligand-free” conjugated copolymer in nucleophilic solvents显示文摘The synthesis of N-cyclohexyl carbamate-attached fluorene-alt-phenylene copolymer(PFPNCC)and the use of PFPNCC as a“ligand-free”fluorescent chemosensor for Cu(Ⅱ)are described.Addition of Cu(Ⅱ)can efficiently quench the fluorescence of PFPNCC in nucleophilic solvents such as DMF and DMSO,but not in low nucleophilic solvents such as 1,4-dioxane and THF.Ultraviolet-visible spectra of the mixture of the conjugated polymer and Cu(Ⅱ)indicate the presence of a reduced Cu(Ⅰ)ion in the solution.Furthermore,fluorescence recovery of PFPNCC observed at low temperature suggests that the quenching and reducing mechanism is most probably due to a photo-induced electron transfer from excited PFPNCC to Cu(Ⅱ).Our findings provide a novel strategy for highly selective conjugated polymer-based chemosensors for various target analytes,albeit“ligand-free”. | Weixing Deng Pengfei Sun Quli Fan Lei Zhang Tsuyoshi Minami | 2020 | Frontiers of Chemical Science and Engineering2020，14，1： | 1 |
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