|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Oxygen‑Deficient β‑MnO_(2)@Graphene Oxide Cathode for High‑Rate and Long‑Life Aqueous Zinc Ion Batteries显示文摘Recent years have witnessed a booming interest in grid-scale electrochemical energy storage,where much attention has been paid to the aqueous zinc ion batteries(AZIBs).Among various cathode materials for AZIBs,manganese oxides have risen to prominence due to their high energy density and low cost.However,sluggish reaction kinetics and poor cycling stability dictate against their practical application.Herein,we demonstrate the combined use of defect engineering and interfacial optimization that can simultaneously promote rate capability and cycling stability of MnO_(2) cathodes.β-MnO_(2) with abundant oxygen vacancies(VO)and graphene oxide(GO)wrapping is synthesized,in which VO in the bulk accelerate the charge/discharge kinetics while GO on the surfaces inhibits the Mn dissolution.This electrode shows a sustained reversible capacity of~129.6 mAh g^(−1) even after 2000 cycles at a current rate of 4C,outperforming the state-of-the-art MnO_(2)-based cathodes.The superior performance can be rationalized by the direct interaction between surface VO and the GO coating layer,as well as the regulation of structural evolution ofβ-MnO_(2) during cycling.The combinatorial design scheme in this work offers a practical pathway for obtaining high-rate and long-life cathodes for AZIBs. | Shouxiang Ding Mingzheng Zhang Runzhi Qin Jianjun Fang Hengyu Ren Haocong Yi Lele Liu Wenguang Zhao Yang Li Lu Yao Shunning Li Qinghe Zhao Feng Pan | 2021 | Nano-Micro Letters2021，13，11： | 3 |
| 2 | Simultaneously Regulating Uniform Zn^(2+) Flux and Electron Conduction by MOF/rGO Interlayers for High‑Performance Zn Anodes显示文摘Owing to the merits of low cost,high safety and environmental benignity,rechargeable aqueous Zn-based batteries(ZBs)have gained tremendous attention in recent years.Nevertheless,the poor reversibility of Zn anodes that originates from dendrite growth,surface passivation and corrosion,severely hinders the further development of ZBs.To tackle these issues,here we report a Janus separator based on a Zn-ion conductive metal-organic framework(MOF)and reduced graphene oxide(rGO),which is able to regulate uniform Zn2+flux and electron conduction simultaneously during battery operation.Facilitated by the MOF/rGO bifunctional interlayers,the Zn anodes demonstrate stable plating/stripping behavior(over 500 h at 1 mA cm^(−2)),high Coulombic efficiency(99.2%at 2 mA cm^(−2) after 100 cycles)and reduced redox barrier.Moreover,it is also found that the Zn corrosion can be effectively retarded through diminishing the potential discrepancy on Zn surface.Such a separator engineering also saliently promotes the overall performance of Zn|MnO2 full cells,which deliver nearly 100%capacity retention after 2000 cycles at 4 A g^(−1) and high power density over 10 kW kg^(−1).This work provides a feasible route to the high-performance Zn anodes for ZBs. | Ziqi Wang Liubing Dong Weiyuan Huang Hao Jia Qinghe Zhao Yidi Wang Bin Fei Feng Pan | 2021 | Nano-Micro Letters2021，13，5： | 3 |
| 3 | Differences in CYP3A4 ? 1G genotype distribution and haplotypes of CYP3A4 , CYP3A5 and CYP3A7 in 3 Chinese populations显示文摘 | Jing Du Lan Yu Lei Wang Aiping Zhang Anli Shu Lingyun Xu Mingsheng Xu Yongyong Shi Xingwang Li Guoyin Feng Qinghe Xing Lin He | 2007 | Clinica Chimica Acta2007，，1： | 1 |
| 4 | Systematic screening for polymorphisms in the CYP3A4 gene in the Chinese population显示文摘 | Jing Du Qinghe Xing Lingyun Xu Mingsheng Xu Anli Shu Yongyong Shi Lan Yu Aiping Zhang Lei Wang Hongsheng Wang Xingwang Li Guoyin Feng Lin He | 2006 | Pharmacogenomics2006，，6： | 1 |
| 5 | 显示文摘 | YUAN Lijuan ZHANG Qinghe FENG Yukui | 2006 | J Chromatogr: A2006，1121，1： | 1 |
| 6 | Epipelagic mesozooplankton communities in the northeastern Indian Ocean off Myanmar during the winter monsoon显示文摘The northern Andaman Sea off Myanmar is one of the relatively high productive regions in the Indian Ocean.The abundance,biomass and species composition of mesozooplankton and their relationships with environmental variables in the epipelagic zone(~200 m)were studied for the first time during the Sino-Myanmar joint cruise(February 2020).The mean abundance and biomass of mesozooplankton were(1916.7±1192.9)ind./m3and(17.8±7.9)mg/m3,respectively.A total of 213 species(taxa)were identified from all samples.The omnivorous Cyclopoida Oncaea venusta and Oithona spp.were the top two dominant taxa.Three mesozooplankton communities were determined via cluster analysis:the open ocean in the Andaman Sea and the Bay of Bengal(Group A),the transition zone across the Preparis Channel(Group B),and nearshore water off the Ayeyarwady Delta and along the Tanintharyi Coast(Group C).Variation partitioning analysis revealed that the interaction of physical and biological factors explained 98.8%of mesozooplankton community spatial variation,and redundancy analysis revealed that column mean chlorophyll a concentration(CMCHLA)was the most important explanatory variable(43.1%).The abundance and biomass were significantly higher in Group C,the same as CMCHLA and column mean temperature(CMT)and in contrast to salinity,and CMT was the dominant factor.Significant taxon spatial variations were controlled by CMCHLA,salinity and temperature.This study suggested that mesozooplankton spatial variation was mainly regulated by physical processes through their effects on CMCHLA.The physical processes were simultaneously affected by heat loss differences,freshwater influx,eddies and depth. | Ping Du Dingyong Zeng Feilong Lin Sanda Naing Zhibing Jiang Jingjing Zhang Di Tian Qinghe Liu Yuanli Zhu Soe Moe Lwin Wenqi Ye Chenggang Liu Lu Shou Feng Zhou | 2023 | Acta Oceanologica Sinica2023，42，6： | 0 |
| 7 | Ladder-Type Thienoacenaphthopyrazine-Based Molecules:Synthesis,Properties,and Application to Construct High-Performance Polymer for Organic Solar Cells显示文摘We present a new design strategy to synthesize ladder-type thienoacenaphthopyrazine(TAP)-based monomers through two different coupling reactions from starting material 5,6-dibromoacenaphthylene-1,2-dione.By bringing varous electron-deficient groups together(such as five-membered aromatic rings,pyrazine,fluorine,and thiadiazols),this new family of molecules exhibits good stability in ambient conditions and easily tunes the electronic,photophysical and film-forming properties of polymers.The unique molecular shape with its extendedπ-conjugated backbone perpendicular to the polymer chain,offers a remarkable platform for the development of a semiconducting polymer with rare geometry.The planar and enlarged conjugated backbone enables TAP-based copolymers PTAP1 and PTAP2 to exhibit distinguishing solubility properties that are different from small-molecule-based polymers,indicating the advantages of novel ladder-type monomers.Their insolubility in chloroform supports orthogonal solvent processing to fabricate layer-by-layer organic solar cells(LBL-OSCs).Owing to its shorterπ–πstacking distance,higher hole mobility,and more favorable phase separation caused bymultifluorine substitution,polymer PTAP1-based LBL-OSC exhibits the highest efficiency of 17.14%by using Y6-BO as the electron acceptor while the efficiency for the PTAP2-based device is 14.20%.This high efficiency indicates the tremendous potential of these novel building units. | Pengwei Han Man Lin Qiuju Jiang Haijun Ning Mingbin Su Li Dang Feng He Qinghe Wu | 2023 | CCS Chemistry2023，5，6： | 0 |
| 8 | Constructing low-valent Ni nanoparticles for highly selective CO_(2) reduction显示文摘The electroreduction of CO_(2)(CO_(2)RR)into value-added chemicals is a sustainable strategy for mitigating global warming and managing the global carbon balance.However,developing an efficient and selective catalyst is still the central challenge.Here,we developed a simple two-step pyrolysis method to confine low-valent Ni-based nanoparticles within nitrogen-doped carbon(Ni-NC).As a result,such Ni-based nanoparticles can effectively reduce CO_(2)to CO,with a maximum CO Faradaic efficiency(FE)of 98%at an overpotential of 0.8 V,as long as good stability.Experimental and the density functional theory(DFT)calculation results reveal that low-valent Ni plays a key role in activity and selectivity enhancement.This study presents a new understanding of Ni-based CO_(2)RR,and provides a simple,scalable approach to the synthesis of low-valent catalysts towards efficient CO_(2)RR. | Kuanda Xu Shisheng Zheng Yang Li Honghao Chu Qi Xiong Zongwei Mei Qinghe Zhao Luyi Yang Shunning Li Feng Pan | 2022 | Chinese Chemical Letters2022，33，1： | 0 |
| 9 | Towards growth of pure AB-stacked bilayer graphene single crystals显示文摘Given its intriguing band structure and unique tunable bandgap,AB-stacked bilayer graphene has great potentials in the applications of high-end electronics,optoelectronics and semiconductors.The epitaxial growth of AB-stacked single-crystal bilayer graphene films requires a strict AB-stacked lattice,identical orientations and seamless stitching of bilayer graphene islands.However,the particles inevitably present on the metal surface that produced during high temperature growth would induce random orientations,twisted stacking islands,and uncontrollable multilayers,which is a great challenge to overcome.Here,we propose a heat-resisting-box assisted strategy to produce nearly pure AB-stacked bilayer graphene single-crystal films on Cu/Ni(111)foils.With our technique,the particles on the Cu/Ni(111)surface are effectively eliminated,which greatly minimizes the occurrence of randomly twisted islands and uncontrollable multilayers.The as-grown AB-stacked bilayer graphene films show>99%alignment and>99%AB stacking order.Our work provides a promising method towards the growth of pure AB-stacked bilayer graphene single crystals and would accelerate its device applications. | Xiaowen Zhang Tao Zhou Yunlong Ren Zuo Feng Ruixi Qiao Qinghe Wang Bin Wang Jinxia Bai Muhong Wu Zhilie Tang Xu Zhou Kaihui Liu Xiaozhi Xu | 2024 | Nano Research2024，17，5： | 0 |
| 10 | Derivatization based on tetrazine scaffolds:synthesis of tetrazine derivatives and their biomedical applications显示文摘Bioorthogonal chemistry is widely used in biological systems and has been trialed in patients,attracting a lot of attention in this century.Tetrazine-based bioorthogonal reactions are essential in chemical biology applications,including cellular labeling,live-cell imaging,diagnosis,drug release,and oncotherapy,due to their tunable rapid reaction kinetics and unique fluorogenic characteristics.However,the scope of de novo tetrazine synthesis is restricted due to the limited supply of commercial starting materials.Therefore,derivatization based on tetrazine scaffolds has been used to synthesize various tetrazine derivatives to enhance the applications of tetrazine bioorthogonal reactions.Herein,the recent advances in tetrazine scaffold-based derivatizations,including tetrazine skeletons,aromatic substituents and alkyl substituents of tetrazines,have been summarized.The advantages and limitations of the derivatization methods and applications of the developed tetrazine derivatives in bioorthogonal chemistry have also been highlighted. | Hongbao Sun Qinghe Xue Chang Zhang Haoxing Wu Ping Feng | 2022 | Organic Chemistry Frontiers2022，9，2： | 0 |
| 11 | Deep Learning Models Based on Weakly Supervised Learning and Clustering Visualization for Disease Diagnosis显示文摘The coronavirus disease 2019(COVID-19)has severely disrupted both human life and the health care system.Timely diagnosis and treatment have become increasingly important;however,the distribution and size of lesions vary widely among individuals,making it challenging to accurately diagnose the disease.This study proposed a deep-learning disease diagnosismodel based onweakly supervised learning and clustering visualization(W_CVNet)that fused classification with segmentation.First,the data were preprocessed.An optimizable weakly supervised segmentation preprocessing method(O-WSSPM)was used to remove redundant data and solve the category imbalance problem.Second,a deep-learning fusion method was used for feature extraction and classification recognition.A dual asymmetric complementary bilinear feature extraction method(D-CBM)was used to fully extract complementary features,which solved the problem of insufficient feature extraction by a single deep learning network.Third,an unsupervised learning method based on Fuzzy C-Means(FCM)clustering was used to segment and visualize COVID-19 lesions enabling physicians to accurately assess lesion distribution and disease severity.In this study,5-fold cross-validation methods were used,and the results showed that the network had an average classification accuracy of 85.8%,outperforming six recent advanced classification models.W_CVNet can effectively help physicians with automated aid in diagnosis to determine if the disease is present and,in the case of COVID-19 patients,to further predict the area of the lesion. | Jingyao Liu Qinghe Feng Jiashi Zhao Yu Miao Wei He Weili Shi Zhengang Jiang | 2023 | Computers, Materials & Continua2023，76，9： | 0 |
| 12 | One-pot synthesis of FeNxC as efficient catalyst for high-performance zinc-air battery显示文摘Rechargeable zinc-air batteries(ZAB)with a high theoretical energy density of 1086 Wh kg^(-1),have received tremendous research attention.However,the practical application of ZABs is still limited by high polarization and poor energy efficiency(low power density)due to the sluggish 4 electrons(e^(-))/oxygen(O_(2))kinetics over the air electrode.Here,a noble-metal-free Fe Nx C electrocatalyst is developed via a onepot approach,which provides a high density of the oxygen reduction reaction(ORR)active site and facilitates the ORR kinetics.Accordingly,the as-assembled Zn-air battery displayed a low charge–discharge voltage gap of 0.71 V at 10 m A cm^(-2),a remarkable peak power density as high as 181.2 m W cm^(-2),as well as the long-term durability for hundreds of hours,among the top level of those reported previously.Our work provides a major boost for the practical application of Zn-air battery in the future. | Yang Li Kuanda Xu Qi Zhang Zhi Zheng Shunning Li Qinghe Zhao Can Li Cheng Dong Zongwei Mei Feng Pan Shixue Dou | 2022 | Journal of Energy Chemistry2022，31，3： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员