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| 1 | The oldest basement rock in the Yangtze Craton revealed by zircon U-Pb age and Hf isotope composition显示文摘Here we report an integrated study of zircon U-Pb age and Hf isotope composition for a gneiss sample from the Kongling terrain in the Yangtze Craton. CL imaging reveals that most zircons are magmatic, and a few of them have thin metamorphic rims. The magmatic zircons gave a weighted mean U-Pb age of 3218±13 Ma, indicating the gneiss is the oldest basement rock in the Yangtze Craton found to date. They have εHf(t) value of -2.33±0.51,and two-stage Hf model age of 3679±49 Ma,indicating that the gneiss was derived from partial melting of >3.6 Ga crustal rock. The metamorphic rims yielded an age of 2732±16 Ma, implying that the metamorphic event occurred in the Neoarchean era, which may be also a major tectono-thermal event in the Yangtze Craton. | JIAO WenFang WU YuanBao YANG SaiHong PENG Min WANG Jing | 2009 | Science China Earth Sciences2009，52，9： | 57 |
| 2 | Weighted composition operators between μ-Bloch spaces on the unit ball显示文摘In this paper, necessary and sufficient conditions are given for the weighted composition operator Tψ,ψ to be bounded or compact from the spaceβμ to βv, (or βμ,o to βv,o) on the unit ball of Cn. At the same time, a series of corollaries are also obtained. | ZHANG Xuejun~1 & XIAO Jianbin~2 1. College of Mathematics and Computer Science,Hunan Normal University,Changsha 410006,China(email:xuejunttt@263. net) 2. The School of Science,Hangzhou Dianzi University,Hangzhou 310037,China | 2005 | Science China Mathematics2005，48，10： | 49 |
| 3 | Composition Operators on the Bloch Space of Several Complex Variables | Jihuai Shi Luo Luo Department of Mathematics,University of Science and Technology of China,Heifei 230036,P.R.China Fax:(0551)3631760 | 2000 | Acta Mathematica Sinica,English Series2000，16，1： | 43 |
| 4 | Temperature variations in the past 6000 years inferred from δ^(18)O of peat cellulose from Hongyuan,China显示文摘Trends of the temperature variations recorded in δ18O in Hongyuan peat cellulose are similar to those recorded in δ18O of Jinchuan peat cellulose and in δ18O of Dunde ice core. Climate events have been identified to be globally homogeneous. Two notable climate transition periods have been detected in the past 6000 years, namely 4000 aBP with climate shifting from cold to warm and 1500 aBP with climate shifting from warm to relatively cold. Power spectrum analysis was performed to investigate the periodical signals in the δ18O time series. Typical periodicities of 1200-1087 a, 752 a, 444 a, 325 a, 213 a, 127-123 a, 88 a, 79 a were discovered, indicating an integrated influence on Hongyuan climate from solar, monsoon and ocean activities. Solar forcing has been addressed to be the main driving forcing of Hongyuan climate. | XU Hai, HONG Yetang, LIN Qinghua, HONG Bing, JIANG Hongbo & ZHU YongxuanInstitute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China Graduate School of Chinese Academy of Sciences, Beijing 100039, China | 2002 | Chinese Science Bulletin2002，47，18： | 31 |
| 5 | 内蒙古克什克腾旗小东沟斑岩型钼矿床成岩成矿机制探讨显示文摘本文选取内蒙古克什克腾旗的小东沟斑岩型钼矿区作为研究区,它位于西拉沐伦钼矿带的西南部。对小东沟岩体进行了主微量元素、SHRIMP锆石U-Pb定年等地球化学方面的研究;对岩体中的钾长石和含矿矿物辉钼矿进行了普通铅同位素分析。小东沟岩体具有高硅富钾、REE含量低、Zr含量高、无负铕异常、高ε_(Nd)(t)、低Sr_i等特点,指示岩浆起源于加厚新生下地壳的熔融,同时具有高温、快速熔融、快速析离逃离源区的特点;小东沟岩体的SHRIMP锆石U-Pb定年结果为142±2Ma,对应140Ma左右主应力场由南北向转为东西向的构造体制大转折时期,这个时期大兴安岭处于伸展的构造环境下,底侵作用发育,地幔物质可以添加到下地壳熔融形成的岩浆中;对岩体钾长石和辉钼矿进行的普通铅同位素分析显示前者具有从造山带-地幔过渡的特征,后者则显示有地幔特征,说明成岩、成矿物质来自两个不同的源区,下地壳的岩浆和地幔含矿流体发生了混合。通过以上的分析,结合水-岩浆物理反应的实验结果,本文提出小东沟斑岩型钼矿床的成矿模式:大兴安岭地区在早白垩世伸展的构造背景下,地幔含矿流体加入受底侵作用加热的下地壳中使之熔融形成岩浆,随后更多的地幔含矿流体进入岩浆房,促使其迅速析离逃逸出源区,二者一起上升侵位。在岩浆温度较高时,地幔含矿流体和岩浆大致以较稳定的液态不混溶的状态共存;当岩浆和流体侵位到较浅深度时,压力下降,温度降低,晶体增多,流体-岩浆体系变得不稳定,岩浆被流体分割成许多很小的岩浆团。流体中H^+、K^+和各种成矿元素的存在使之必然会和岩浆或冷却后形成的岩石发生蚀变反应,并晶出成矿矿物,形成现在我们看到的具有浸染状矿化现象的小东沟斑岩型钼矿床。 | 覃锋 刘建明 曾庆栋 罗照华 | 2009 | 岩石学报2009，25，12： | 29 |
| 6 | 固溶温度对激光立体成形GH4169高温合金组织和性能的影响(英文)显示文摘研究激光立体成形GH4169高温合金固溶处理后的组织,分析了固溶过程中合金元素的均匀化,并对材料显微硬度的变化做了讨论。结果表明,随固溶温度的升高,材料的晶界越来越清晰,经1000-1170°C固溶处理1h后材料发生再结晶,当固溶处理温度高于1100°C,有大量孪晶出现,晶粒相比沉积态显著细化,晶粒尺寸约200μm。合金元素的均匀化在1100°C保温1h后基本完成。显微硬度测试结果显示,材料的显微硬度值随固溶温度的升高而降低,在固溶温度低于1100°C时减小趋势较快,高于1100°C时减小趋势减缓。显微硬度的变化与材料中γ′和γ'相及δ相的形态和数量有关。1100°C是激光立体成形GH4169合金比较合适的固溶处理温度下限。 | 刘奋成 林鑫 赵卫卫 赵晓明 陈静 黄卫东 | 2010 | 稀有金属材料与工程2010，39，9： | 29 |
| 7 | 川东北普光气田下三叠统飞仙关组白云岩成因——来自岩石结构与Sr同位素和Sr含量的证据显示文摘研究了川东北普光气田下三叠统飞仙关组白云岩储层的岩石结构Sr的含量和Sr同位素组成,讨论了它的成因,飞仙关组优质储层为成岩期埋藏交代白云化作用的产物,来自岩石结构和Sr同位素和Sr含量的证据包括如下几个方面:(1)与准同生白云岩比较,埋藏白云岩的岩石结构和Sr同位素和Sr含量地球化学特征与前者有显著差别;(2)飞仙关组所有各类碳酸盐岩(或矿物)具有早三叠世海水Sr同位素组成特征,^(87)Sr/^(86)Sr比值变化范围为0.706588~0.708187,覆盖了全球早三叠世海水Sr同位素的变化范围(0.7076~0.7078),平均值0.707656与全球早三叠世平均值(0.707743)基本一致;(3)埋藏白云岩^(87)Sr/^(86)Sr比值变化范围为0.707122~0.707419,平均值0.707421,都略低于全球早三叠世海水Sr同位素变化范围和平均值,但与已报道的川东北早三叠世飞仙关期海水Sr同位素变化范围(0.707330~0.707383)和平均值(0.707350) 都非常接近,说明白云石化流体具有强烈的川东北地区早三叠世飞仙关期海水Sr同位素组成特征;(4)综合岩石结构、Sr同位素和Sr含量地球化学特征,证明飞仙关组白云岩储层为成岩期埋藏交代作用产物,白云石化流体来自地层中高Sr和高盐度的海源地层水。 | 郑荣才 文华国 郑超 罗平 李国军 陈守春 | 2009 | 岩石学报2009，25，10： | 24 |
| 8 | Evolution of strontium isotopic composition of sea-water from Late Permian to Early Triassic based on study of marine carbonates,Zhongliang Mountain,Chongqing,China显示文摘Collected from a Late Permian to Early Triassic sedimentary section in the Zhongliang Mountain of Chongqing, Southwest China, sixty marine carbonate samples were measured for the 87Sr/86Sr ratios, and corresponding evolution curve was constructed. The concentrations of SiO2, CaO, MgO, Mn and Sr are used to evaluate reservation of strontium isotopic composition for original seawater and the credi-bility of the dissolution method for sample preparation. The results show that most of the samples (except seven samples with the Mn/Sr ratios higher than 2) contain the original geochemistry signa-tures of ancient seawater. Compared to the published 87Sr/86Sr ratios from the Late Permian to Early Triassic, our database reported here is the largest and the curve constructed is the most complete. The strontium isotopic curve from Late Permian to Early Triassic is consistent globally and exhibits a gen-eral trend of steady increase during this period. The minimum of 87Sr/86Sr ratios (0.707011) occurs in the Late Permian (30 m in thickness below the Permian-Triassic boundary), and the maximum (0.708281), near the Early-Middle Triassic boundary. The lack of land plants and the rapid continental weathering result in the increase of 87Sr/86Sr ratios during the interval. The Permian-Triassic boundary in Zhongli-ang Mountain Section has been accepted internationally. The 87Sr/86Sr ratios of six samples near the boundary vary from 0.70714 to 0.70715 with an average of 0.70714, which is consistent with the value of 0.70715 (samples are from articulate brachiopod shells) from Korte et al. published in 2006 (within the error range in experiment). Accordingly, the strontium isotope composition in the Permian-Triassic boundary in this paper is of global significance. It can be confirmed that the 87Sr/86Sr ratios of the sea-water in the Permian-Triassic transition are in the range of 0.70714―0.70715. | HUANG SiJing Qing HaiRuo HUANG PeiPei HU ZuoWei WANG QingDong ZOU MingLiang LIU HaoNian | 2008 | Science China Earth Sciences2008，51，4： | 24 |
| 9 | Composition operators between Bloch-type spaces in the polydisc显示文摘We characterize those holomorphic mappings ψ from the polydisc Dn in Cn to itself for which the induced composition operators Cψ are bounded (or compact) from the Bloch-type space Bω to βμ (respectively, from the little Bloch-type space Bω,0 to Bμ,0),where ω is a normal function on [0, 1) andμ is a nonnegative function on [0, 1) withμ(tn) > 0for some sequence {tn}n∞n=1(∪) [0, 1) satisfying limn→∞ tn = 1. | HU Zhangjian | 2005 | Science China Mathematics2005，48，z1： | 23 |
| 10 | 金川Ⅰ号岩体橄榄石Ni-MgO相互关系及其地质意义显示文摘金川超镁铁质岩体赋存着仅次于加拿大Sudbury和俄罗斯Noril'sk-Talnakh的世界第三大在采铜镍硫化物矿床,岩体以一系列的NE向断层为界分成四个小岩体,由西至东依次为:Ⅲ、Ⅰ、Ⅱ、Ⅳ岩体。Ⅰ号岩体主要由二辉橄榄岩、含辉橄榄岩和橄榄二辉岩构成,橄榄石在各岩相中均为保存较好的主要造岩矿物。本文研究得到金川Ⅰ号岩体上部二辉橄榄岩和含辉橄榄岩中橄榄石的镁橄榄石Fo值介于83.9~85.7,而其Ni含量为1396×10^(-6)~2043×10^(-6),大多低于从S不饱和玄武岩浆中结晶出采的橄榄石的Ni含量。模拟计算结果表明橄榄石较低的Ni含量是因为橄榄石结晶的同时,发生了强烈的硫化物熔离;橄榄石的Fo-Ni关系还因与晶间硅酸盐熔浆的物质交换而发生改变。模拟计算还证明大约有30%的晶间硅酸盐岩浆与橄榄石发生Fe-Mg物质交换反应,导致早结晶橄榄石的Fo值减少了1~1.5。同时,橄榄石较小的Fo值变化表明,在橄榄石结晶和硫化物熔离过程中,不断有新的岩浆贯入和补充。 | 陈列锰 宋谢炎 Danyushevsky LV 肖加飞 李士彬 官建祥 | 2009 | 岩石学报2009，25，12： | 22 |
| 11 | Trends in particulate matter and its chemical compositions in China from 2013–2017显示文摘Accurate determination of the atmospheric particulate matter mass concentration and chemical composition is helpful in exploring the causes and sources of atmospheric enthalpy pollution and in evaluating the rationality of environmental air quality control strategies.Based on the sampling and chemical composition data of PM2.5 in different key regions of China in the CARE-China observation network,this research analyzes the environmental air quality data released by the China National Environmental Monitoring Centre during the studied period to determine the changes in the particulate matter mass concentration in key regions and the evolution of the corresponding chemical compositions during the implementation of the Action Plan for Prevention and Control of Air Pollution from 2013-2017.The results show the following.(1)The particulate matter mass concentration in China showed a significant downward trend;however,the PM2.5 annual mass concentration in 64%of cities exceeds the New Chinese Ambient Air Quality Standard(CAAQS)GradeⅡ(GB3095-2012).The region to the east of the Taihang Mountains,the Fenhe and Weihe River Plain and the Urumqi-Changji regions in Xinjiang,all have PM2.5 concentration loading that is still high,and heavy haze pollution occurred frequently in the autumn and winter.(2)During the heavy pollution in the autumn and winter,the concentrations of sulfate and organic components decreased significantly.The mean SO42-concentration in PM2.5 decreased by 76%,12%,81%and 38%in Beijing-Tianjin-Hebei(BTH),the Pearl River Delta(PRD),the Sichuan-Chongqing region(SC)and the Fenhe and Weihe River Plain,respectively.The mean organic matter(OM)concentration decreased by 70%,44%,48%and 31%,respectively,and the mean concentration of NH4+decreased by 68%,1.6%,38%and 25%,respectively.The mean elemental carbon(EC)concentration decreased by 84%and 20%in BTH and SC,respectively,and it increased by 61%and 11%in the PRD and Fenhe and Weihe River Plain,respectively.The mean concentration of mineral and unresolved chemical components(MI)dropped by 70%,24%and 13%in BTH,the PRD and the Fenhe and Weihe River Plain,respectively.The change in the PM2.5 chemical composition is consistent with the decrease of the PM2.5mass concentration.(3)In 2015,the mean OM concentration contributions to fine particles and coarse particles were 13-46%and 46-57%,respectively,and the mean MI concentration contributions to fine particles and coarse and particles were 31-60%and 39-73%,respectively;these values are lower than the 2013 values from the key regions,which is the most important factor behind the decrease of the particulate matter mass concentration.From 2013 to 2015,among the chemical components of different particle size fractions,the peak value of the coarse particle size fraction decreased significantly,and the fine particle size fractions of SO42-,NO3-,and NH4+decreased with the decrease of the particulate matter mass concentration in different particle size fractions.The fine-particle size peaks of SO42-,NO3-and NH4+shifted from 0.65-1.1μm to the finer size range of0.43-0.65μm during the same time frame. | Yuesi WANG Wenjie LI Wenkang GAO Zirui LIU Shili TIAN Rongrong SHEN Dongsheng JI Shuai WANG Lili WANG Guiqian TANG Tao SONG Mengtian CHENG Gehui WANG Zhengyu GONG Jiming HAO Yuanhang ZHANG | 2019 | Science China Earth Sciences2019，62，12： | 23 |
| 12 | 雷琼地区晚新生代玄武岩地球化学:EM2成分来源及大陆岩石圈地幔的贡献显示文摘对雷琼地区21个晚新生代玄武岩样品的主量、微量元素和Sr、Nd、Pb同位素分别用湿化学法、ICP-MS和MC-ICPMS进行了测定。这些玄武岩主要为石英拉斑玄武岩,其次为橄榄拉斑玄武岩和碱性玄武岩。大多数样品的微量元素和同位素成分与洋岛玄武岩(OIBs)相似,而且随着SiO_2不饱和度增加,不相容元素含量也增加。除R4-1可能受到地壳混染外,其他样品相对均一的Nd同位素(ε_(Nd)=2.5~6.0)以及变化明显但范围有限的Sr同位素(0.703106~0.704481),可能继承了地幔源区的特征。^(87)Sr/^(86)Sr与^(206)Pb/^(204)Pb的正相关和^(143)Nd/^(144)Nd与^(206)Pb/^(204)Pb的负相关特征暗示DM(软流圈地幔)与EM2(岩石圈地幔)的混合。地幔捕虏体的同位素特征暗示EM2成分不可能存在于尖晶石橄榄岩地幔,而La/Yb和Sm/Yb系统表明岩浆由石榴石橄榄岩部分熔融产生,这意味着EM2成分可能存在于石榴石橄榄岩地幔。雷琼地区玄武岩的地球化学变化可以用软流圈地幔为主的熔体加入不同比例石榴石橄榄岩地幔不同程度熔融产生的熔体来解释:碱性玄武岩和橄榄拉斑玄武岩是软流圈熔体与石榴石橄榄岩地幔较低程度(7%~9%)熔融体混合,而石英拉斑玄武岩是软流圈熔体与石榴石橄榄岩地幔较高程度(10%~20%)熔融体的混合。 | 韩江伟 熊小林 朱照宇 | 2009 | 岩石学报2009，25，12： | 20 |
| 13 | Petrogenesis and its significance to continental dynamics of the Neogene high-potassium calc-alkaline volcanic rock association from north Qiangtang,Tibetan Plateau显示文摘Detailed studies indicate that the main rock type of the Neogene high-potassium calc-alkaline volcanic rock association from north Qiangtang is andesite, dacite and rhyolite. They belong to typical crust-generation magmatic system and originate from the special thickened crust of the Tibetan Plateau by dehydration melting. This group of rocks exhibits LREE enrichment but no remarkable Eu anomaly that shows their source region should be a thickened deep crust consisting of eclogitic mass group, implying that the crust had been thickened and an eclogitic deep crust had been formed during the Neogene period in Qiangtang area. This understanding is important and significant to making further discussion on the uplift mechanism and continental dynamics of the Tibetan Plateau. | 赖绍聪 刘池阳 S.Y.O’Reilly | 2001 | Science China Earth Sciences2001，44，S1： | 18 |
| 14 | A review of composition evolution in Ni-based single crystal superalloys显示文摘Due to the outstanding creep performance, nickel-based single crystal superalloys(Ni-SXs) are extensively applied in modern aero-engine and industrial gas turbine. Apart from the special single crystal structure which is disadvantageous to extension of creep cracks, Ni-SXs derive the creep strength from intrinsic two-phase microstructure(γ phase and γ’ phase). Main microstructural parameters including volume fraction of γ’ phase and the lattice misfit, and the formation and distribution of precipitated phase are determined by the compositions of alloys. Besides, the creep properties are greatly influenced by these microstructural parameters and precipitated phase. This review has summarized the relationships between different alloying elements and microstructures and indicated their influence on creep properties of Ni-SXs. In addition, with the improvements of experimental methods and characterization technique, some recent discoveries have provided additional evidence to support or challenge the pervious creep theories of superalloys. In view of these new discoveries, this review has provided some perspectives which can be referenced in future compositional design of Ni-SXs. | Wanshun Xia Xinbao Zhao Liang Yue Ze Zhang | 2020 | Journal of Materials Science & Technology2020，44，9： | 16 |
| 15 | 烧结温度对Ti/IrO_2-Ta_2O_5纳米氧化物阳极微观结构和电催化性能的影响(英文)显示文摘采用Pechini法制备Ti/IrO2-Ta2O5纳米氧化物阳极,通过SEM、EDX、XRD、极化曲线、循环伏安、电化学阻抗谱及强化电解寿命试验等测试手段,研究了烧结温度对Ti/IrO2-Ta2O5阳极微观结构和电催化性能的影响。结果表明,阳极涂层成分分布均匀,IrO2晶粒偏析不明显;Ta在铱钽固溶体中的固溶度随烧结温度升高而增大,涂层晶粒逐渐细化。随着烧结温度的升高,阳极析氧电催化活性降低,电化学活性表面积减小;500℃下所得Ti/IrO2-Ta2O5阳极表现出最高的强化电解寿命。 | 辛永磊 许立坤 王均涛 李相波 | 2010 | 稀有金属材料与工程2010，39，11： | 16 |
| 16 | Impact of China’s Air Pollution Prevention and Control Action Plan on PM2.5 chemical composition over eastern China显示文摘China promulgated the Air Pollution Prevention and Control Action Plan(the Action Plan)in 2013 and developed stringent control measures to mitigate fine particulate matter(PM2.5) pollution.Here,we investigated the PM2.5 chemical composition changes over eastern China associated with the Action Plan during 2013-2017 using satellite-based PM2.5 chemical composition data derived using CMAQ simulations and satellite inputs.The PM2.5 concentrations decreased considerably during this time as a result of the reductions in all chemical species in PM2.5.The population-weighted mean concentrations over eastern China decreased from 11.1 to 6.7μgm-3 for SO42-,13.8-13.1μgm-3 for NO3-,7.4-5.8μgm-3 for NH4+,9.9-8.4μgm-3 for OM,4.6-3.8μg m-3 for BC and 12.9-9.6μg m-3 for other species in PM2.5.SO42-had the largest reduction of 40%,while NO3-had the lowest reduction of 5%,resulting in a greater fraction of NO3-and a smaller fraction of SO42-in PM2.5.Among the three key regions,Beijing-Tianjin-Hebei had the largest reduction in PM2.5 and its chemical compositions.The decrease in SO42-concentrations was in line with the reduction of SO2 emissions,and the major driver of the SO2 emission reductions was the industrial sector.The decrease in NO3 concentrations was limited because the decrease in SO2 emissions and the stable NH3 emissions facilitated the formation of NO3-from HNO3,which partially offset the reduction in NOx emissions driven by the power sector.To mitigate PM2.5 pollution more effectively,future efforts are needed to reduce NH3 emissions. | Guannan GENG Qingyang XIAO Yixuan ZHENG Dan TONG Yuxuan ZHANG Xiaoye ZHANG Qiang ZHANG Kebin HE Yang LIU | 2019 | Science China Earth Sciences2019，62，12： | 16 |
| 17 | Noble gas abundances and isotopic compositions in mantle-derived xenoliths,NE China显示文摘Following the researches of helium isotopic compositions in mantle-derived xenoliths in eastern China, this study reported noble gas abundances and isotopic compositions of mantle-derived xenoliths from Kuandian of Liaoning Province, Huinan of Jilin Province and Hannuoba of Hebei Province. Compared with the middle ocean ridge basalt (MORB) and other continental areas, mantle-derived xenoliths in NE China are characterized by slightly low noble gas abundances, 3He/4He equivalent to or lower than that of MORB, 40Ar/36Ar lower than that of MORB, 38Ar/36Ar and Ne-Kr-Xe isotopic ratios equivalent to those of atmosphere. These results indicate the heterogeneity of subcontinental lithospheric mantle beneath northeastern China, that is, a MORB reservoir-like mantle beneath Kuandian and an enriched/metasomatized mantle beneath Huinan. Low 40Ar/ 36Ar ratios in the three studied areas may imply that a subducted atmospheric component has been preserved in the subcontinental lithospheric mantle. | Sheng Xu Congqiang Liu | 2002 | Chinese Science Bulletin2002，47，9： | 12 |
| 18 | Hydrological and water cycle processes of inland river basins in the arid region of Northwest China显示文摘The increasing shortage in water resources is a key factor affecting sustainable socio-economic development in the arid region of Northwest China(ARNC). Water shortages also affect the stability of the region's oasis ecosystem. This paper summarizes the hydrological processes and water cycle of inland river basins in the ARNC, focusing on the following aspects: the spatial-temporal features of water resources(including air water vapor resources, runoff, and glacial meltwater) and their driving forces; the characteristics of streamflow composition in the inland river basins; the characteristics and main controlling factors of baseflow in the inland rivers; and anticipated future changes in hydrological processes and water resources. The results indicate that:(1) although the runoff in most inland rivers in the ARNC showed a significant increasing trend, both the glaciated area and glacial ice reserves have been reduced in the mountains;(2) snow melt and glacier melt are extremely important hydrological processes in the ARNC, especially in the Kunlun and Tianshan mountains;(3) baseflow in the inland rivers of the ARNC is the result of climate change and human activities, with the main driving factors being the reduction in forest area and the over-exploitation and utilization of groundwater in the river basins; and(4) the contradictions among water resources, ecology and economy will further increase in the future. The findings of this study might also help strengthen the ecological, economic and social sustainable development in the study region. | CHEN Yaning LI Baofu FAN Yuting SUN Congjian FANG Gonghuan | 2019 | Journal of Arid Land2019，11，2： | 12 |
| 19 | Elemental and isotopic compositions of the hydrothermal sulfide on the East Pacific Rise near 13°N显示文摘The mineralogical,elemental,and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (12°42.30'N,103°54.48'W,water depth 2655 m) on the East Pacific Rise near 13°N were analyzed.The hydrothermal sulfide was composed mainly of sphalerite,chalcopyrite,and pyrite and was a Zn-rich sulfide;in layer ep-s-1,goethite formed by secondary oxidation was found.The concentrations of rare elements,such as Li (0.15×10-6-0.30×10-6),Be (0.01×10-6-0.05×10-6),Zr (73.8×10-9-1344×10-9),Nb (8.14×10-9-64.7×10-9),Hf (2.54×10-9-28.0×10-9),and Ta (0.203×10-9-1.21×10-9),were far lower in the hydrothermal sulfide than in the ocean crust,whereas the content of Au was higher and the contents of Co,Ni,Sr,Cs,Ba,Bi,and U were low.The correlations between Zn and Cr,Cd and Ga,Cu and P,P and In (R2 > 0.8) were positive,whereas those between Zn and Fe,Cu,and Ba (R2 > 0.8) were distinctly negative.From low-temperature mineral assemblages to high-temperature mineral assemblages,the spatial distributions of dispersive and rare elements (e.g.In,Li,Cs) in the hydrothermal sulfide displayed corresponding variations.The variations observed in some elements (e.g.,Cd,Cs,P) are controlled by Zn,Fe,and Cu sulfides,respectively.Seafloor weathering accounts for the enrichment of V,Mn,and rare earth elements (REE) in the henna sulfide-oxidation layer that bears the secondary oxide mineral,leading to identical REE patterns for this layer (ep-s-1) and seawater.Seafloor weathering also distinctly affects the correlations between the element ratios of the hydrothermal sulfide.From high-temperature mineral assemblages to low-temperature mineral assemblages,Fe content and δ 34S value of the hydrothermal sulfide increase gradually,and Zn content and lead isotopic ratios decrease gradually on the contrary,which indicate the influences of seawater on elements and the sulfur and lead isotopic compositions enhance gradually during the formation of hydrothermal sulfides. | ZENG ZhiGang1,CHEN DaiGeng1,2,YIN XueBo1,WANG XiaoYuan1,ZHANG GuoLiang1,2 & WANG XiaoMei1,2 1 Seafloor Hydrothermal Activity Laboratory of the Key Laboratory of Marine Geology and Environment,Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China 2 Graduate School of Chinese Academy of Sciences,Beijing 100049,China | 2010 | Science China Earth Sciences2010，53，2： | 12 |
| 20 | N_2-Ar-He systematics and source of ore-forming fluid in Changkeng Au-Ag deposit, central Guangdong, China显示文摘Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and 3He/4He and δD-δ18O composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine) but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10%. According to the source of the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping | 孙晓明 孙凯 陈炳辉 陈敬德 David I.Norman | 1999 | Science China Earth Sciences1999，42，5： | 12 |
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