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    题名 作者 年代 出处 被引量
1METTL3-mediated N^6-methyladenosine mRNA modification enhances long-term memory consolidation显示文摘Zeyu Zhang Meng Wang Dongfang Xie Zenghui Huang Lisha Zhang Ying Yang Dongxue Ma Wenguang Li Qi Zhou Yun-Gui Yang Xiu-Jie Wang 2018Cell Research2018,28,11:29
2An economic and low-carbon day-ahead Pareto-optimal scheduling for wind farm integrated power systems with demand response显示文摘Demand response(DR)and wind power are beneficial to low-carbon electricity to deal with energy and environmental problems.However,the uncertain wind power generation(WG)which has anti-peaking characteristic would be hard to exert its ability in carbon reduction.This paper introduces DR into traditional unit commitment(UC)strategy and proposes a multi-objective day-ahead optimal scheduling model for wind farm integrated power systems,since incentive-based DR can accommodate excess wind power and can be used as a source of system spinning reserve to alleviate generation side reserve pressure during both peak and valley load periods.Firstly,net load curve is obtained by forecasting load and wind power output.Then,considering the behavior of DR,a day-ahead optimal dispatching scheme is proposed with objectives of minimum generating cost and carbon emission.Non-dominated sorting genetic algorithm-II(NSGA-II)and satisfaction-maximizing method are adopted to solve the multi-objective model with Pareto fronts and eclectic decision obtained.Finally,a case study is carried out to demonstrate that the approach can achieve economic and environmental aims and DR can help to accommodate the wind power.Rui MA Kai LI Xuan LI Zeyu QIN 2015Journal of Modern Power Systems and Clean Energy2015,3,3:20
3Involvement of carbon monoxide produced by heme oxygenase in ABA-induced stomatal closure in Vicia faba and its proposed signal transduction pathway显示文摘Carbon monoxide (CO) has recently proven to be an important bioactive or signaling molecule in mammalian cells. Its effects are mainly mediated by nitric oxide (NO) and cyclic GMP (cGMP). In Vicia faba leaves, CO production and heme oxygenase (HO) activity, an important CO synthetic enzyme, are first reported to increase in response to ABA treatment, which could result in stomatal closure. Inter- estingly, ABA-induced stomatal closure in V. faba guard cells is partially blocked when the synthetic CO inhibitor ZnPP, or the CO/NO scavenger Hb is added. Furthermore, we show that, exogenously applied CO donor, hematin, and CO aqueous solution not only result in the enhancement of CO release, but also time-dependently induce stomatal closure, and the latter is mimicked by the application of an NO donor SNP. The above-mentioned stomatal closure effects are differentially reversed by the addition of tungstate, a potent inhibitor of NO synthetic enzyme nitrate reductase (NR), the specific NO scavenger cPTIO, ZnPP, or Hb. During treatment for 4 h, SNP, 0.01% CO aqueous solution or hematin significantly triggers NO synthesis, whereas cPTIO, or tungstate approximately fully inhibits NO fluorescence. Ad- ditionally, application of the GC inhibitor ODQ blocks CO-induced stomatal closure. This inhibition could be reversed when 8-Br-cGMP is added. Thus, the above results suggest that CO produced by HO is involved in ABA-induced stomatal closure, and NO and cGMP may function as downstream interme- diates in the CO signaling responsible for stomatal closure.CAO ZeYu HUANG BenKai WANG QingYa XUAN Wei LING TengFang ZHANG Bo CHEN Xi NIE Li SHEN WenBiaot 2007Chinese Science Bulletin2007,52,17:16
4Spatiotemporal spectrum and momentum flux of the stratospheric gravity waves generated by a typhoon显示文摘The simulation results of Typhoon Matsa (2005) by using the Weather Research and Forecasting (WRF) model show that pronounced stratospheric gravity waves (GWs) are generated in the vicinity of the typhoon. Using the model output, we investigate the spatial structures and the temporal variations of the GWs through a three dimensional (3-d) spectral analysis, i.e. the spectrum with respect to two horizontal wavenumbers and frequency. We further derive the momentum flux carried by the GWs. Spectral investigation results show that the power spectral density (PSD) of the GWs exhibits a single-peaked spectrum, which consists primarily of a distinct spectrum at horizontal wavelength of ~1000km, time period of 12-18h, and vertical wavelength of 7-9km. This spectrum is different from the spectra of GWs generated by deep convections disclosed by the previous researches. Both the PSD and momentum flux spectrum are prominent in positive k h portion, which is consistent with the fact that the GWs propagate in the upstream of mean flow. Large momentum flux is found to be associated with the GWs, and the net zonal momentum flux is 0.7845×10 3 Pa at 20km height, which can account for ~26% of the momentum flux that is required in driving the QBO phenomenon.CHEN Dan CHEN ZeYu Lü DaRen 2013Science China Earth Sciences2013,56,1:15
5Visualizing the emerging trends of biochar research and applications in 2019:a scientometric analysis and review显示文摘Biochar,derived from thermal pyrolysis of biomass,has been regarded as a low-cost,sustainable and beneficial material and widely applied in agriculture,environment and energy during the last two decades.To elucidate the research status timely and future trends in biochar field,CiteSpace is used to systematically analyze the related literature retrieved from the Web of Science core collection in 2019.Based on the keywords clustering analysis,it was found that“biochar production”,“organic pollutants removal”,“heavy metals immobilization”,“bioremediation”were the main hotspots in research covering biochar.“Bioremediation”is an emerging topic and deserves extensive attention due to its highly effective and environmentally friendly treatment of pollutants.Improving the phytoremediation effect,immobilizing functional microorganisms on biochar,and using microorganisms as raw materials to produce biochar were the common methods of biochar-assisted bioremediation.While studies focused on“soil quality and plant growth”and“biochar and global climate change”decreased,investigations concentrated in the toxicity of biochar to soil biota and ruminants are sustainably growing.Research on direct and catalytic thermal pyrolysis of green waste(mainly microalgae)for biofuels(bio-oil,biodiesel,syngas,etc.)and biochar production is increasing.Converting municipal wastes(e.g.,sewage sludge,fallen leaves)into biochar through pyrolysis was a suitable treatment for municipal waste and became a popular topic in recent time.Moreover,the biochar produced from these municipal wastes exhibited excellent performance in the removal of pollutants from wastewater and soil.This review may help to identify future directions in biochar research and applications.Ping Wu Zeyu Wang Hailong Wang Nanthi S.Bolan Yujun Wang Wenfu Chen 2020Biochar2020,2,2:14
6Simulation of the stratospheric gravity waves generated by the Typhoon Matsa in 2005显示文摘The generation of stratospheric gravity waves(GWs) due to typhoon is simulated by using a meso-scale model(WRF) with a typhoon case,the Matsa in 2005.An 8-day model run that covers the major stages of the Matsa's development reproduces the key features of the typhoon.For example,good agreements in the typhoon's track,the intensity,and the spiral clouds,as well as mean state of stratosphere,are seen between the simulation results and the observation.Simulation results clearly show that with typhoon propagates northwestward,pronounced stratospheric GWs are generated continuously in the vicinity of Matsa.The GWs exhibit the typical curve-like wave fronts away from the Typhoon Matsa,and propagate preferentially in the upstream of the background winds.These characteristics reflect that the stratospheric GWs are closely associated with the typhoon,and thus the GWs are referred to as Tropical Cyclone related Gravity Waves(TC-GWs).The results also show that these waves should have a rather large horizontal scale so that the outmost wave fronts can be seen at the distance of ~1000 km to the typhoon center in the horizontal plane of 20 km.This is consistent with the phenomenon of stratospheric TC-GWs with ~1000 km horizontal scale disclosed by the previous observational analysis results.CHEN Dan CHEN ZeYu Lü DaRen 2012Science China Earth Sciences2012,55,4:12
7From surface to bulk modification: Plasma polymerization of amine-bearing coating by synergic strategy of biomolecule grafting and nitric oxide loading显示文摘Integration of two or more biomolecules with synergetic and complementary effects on a material surface can help to obtain multi-functions for various biomedical applications.However,the amounts of biomolecules integrated and their physiological functions are compromised due to the limited surface anchoring sites.Herein,we propose a novel concept of film engineering strategy“from surface to bulk synergetic modification”.This new concept is realized by employing the surface amine groups of plasma polymerized allylamine(PPAm)film for grafting a molecule e.g.,thrombin inhibitor,bivalirudin(BVLD),meanwhile its bulk amine groups is used as a universal depot for storing and releasing therapeutic nitric oxide(NO)gas as supplement to the functions of BVLD.It is demonstrated that such a“from surface to bulk synergetic modification”film engineering can impart the modified-substrates with anti-platelet and anti-coagulant dual functions,giving rise to a highly endotheliummimetic thromboresistant property.We believe that our research provides a very promising strategy to deliver multifunctional surface versatilely that require NO release in combination with other properties,which will find broad biomedical applications in blood-contacting devices,and et al.Moreover,it also provides a brand-new film engineering strategy for tailoring surface multi-functionalities of a wide range of materials.Tong Yang Zeyu Du Hua Qiu Peng Gao Xin Zhao Huaiyu Wang Qiufen Tu Kaiqin Xiong Nan Huang Zhilu Yang 2020Bioactive Materials2020,5,1:10
8Changes of plasma C-reactive protein in patients with craniocerebral injury before and after hyperbaric oxygenation: A randomly controlled study显示文摘BACKGROUND: Plasma inflammatory factor, such as C-reactive protein, whose content is regarded as a sensitively pathological marked protein and quantitative indexes of central nervous system injury, has been paid more and more attention in clinic. OBJECTIVE: To observe the effects and clinical significance of C-reactive protein in patients with craniocerebral injury after hyperbaric oxygenation. DESIGN: Randomized controlled study. SETTING: Departments of Neurosurgery, Laboratory and Hyperbaric Oxygen, the Second Affiliated Hospital, Medical College of Shantou University. PARTICIPANTS: A total of 60 patients with craniocerebral injury were selected from Department of Neurosurgery, the Second Affiliated Hospital, Medical College of Shantou University from October 2006 to April 2007. There were 37 males and 23 females and the mean age was 26 years. All subjects were certainly diagnosed as history of craniocerebral injury. Patients hospitalized at 24 hours after injury, Glasgow Coma Score ranged from 3 to 12 points, and all patients were certainly diagnosed with CT or MR scanning. Patients and their relatives provided confirmed consent. All the subjects were randomly divided into hyperbaric oxygenation group and control group with 30 in each group. METHODS: Patients in the control group were treated with routinely neurosurgical therapy after hospitalization; however, based the same basic treatment in the control group, patients in the hyperbaric oxygenation group received hyperbaric oxygenation by using iced-wheel four-door 2-cabin air-compression chamber (made in Yantai) from 24 hours to 10 days after operation or injury. After entering the cabin, patients who had a clear consciousness breathed the oxygen by using face mask; contrarily, patients directly breathed the oxygen. Therapeutic project: Expression was increased for about 15–20 minutes, maintained for about 70–80 minutes, and decreased for 20 minutes. Otherwise, pressure was maintained from 0.2 to 0.25 MPa. Hyperbaric oxygenation took an hour for once a day and 10 times were regarded as a course. Venous blood was collected before treatment and on the next day of the first course end. Content of C-reactive protein in plasma was measured with immune turbidimetry in hyperbaric oxygenation group; in addition, content of C-reactive protein in plasma was directly measured with the same method at the corresponding time in the control group. If the content was less or equal to 8 mg/L, it was regarded as normal value. Effects of the two groups were evaluated based on Glasgow Coma Score before and after treatment. MAIN OUTCOME MEASURES: Content of plasma C-reactive protein and Glasgow Coma Score in the two groups before and after treatment. RESULTS: All 60 patients were involved in the final analysis. ① Content of plasma C-reactive protein: The two contents were obviously higher than normal value after craniocerebral injury. There was no significant difference in the two groups before treatment (P > 0.05), but both contents were decreased after treatment, and there was significant difference between HBOT group and control group after treatment (t =4.756, P < 0.01). In addition, there was significant difference in hyperbaric oxygen therapy group before and after treatment (t =5.236, P < 0.01). ② Glasgow Coma Score: There was no significant difference in the two groups before treatment (P > 0.05), but scores were increased in both groups after treatment (t =9.92, 2.51, P < 0.01, 0.05); on the other hand, therefore, there was significant difference between the two groupsafter treatment (t =9.21, P < 0.01). CONCLUSION: Hyperbaric oxygenation can remarkably decrease content of plasma C-reactive protein in patients with craniocerebral injury at the phase of stress.Zeyu Xie Minghua Zhuang Lan Lin Hongwu Xu Linxing Chen Lina Hu 2007Neural Regeneration Research2007,2,5:9
9CO2 and SO2 emission characteristics of the whole process industry chain of coal processing and utilization in China显示文摘The total coal consumption in China is on the rise.The characteristics of CO2 and SO2 emissions in the whole process of coal processing and utilization in China are worthy of study.Based on the five links of the whole process of coal production and utilization,including coal production,raw coal processing,logistics and transportation,conversion and utilization and resource utilization,this paper summarized and analyzed the energy consumption and pollutant emission sources of these five links,combined with the US Environmental Protection Agency’s AP-42 method and IPCC method,to calculate total pollutant discharge and emission factors,where the emission factors were corrected by conversion efficiency.At the same time,uncertainty analysis is performed about CO2 and SO2 emissions.The results showed that CO2 emissions were 3.657 billion tons,and emission reductions were 61 million tons,and SO2 emissions were 4,844,500 tons,and emission reductions were 10.3595 million tons in 2015.Tao Zhu Ruonan Wang Nengjing Yi Wenfeng Niu Lifeng Wang Zeyu Xue 2020International Journal of Coal Science & Technology2020,7,1:8
10小麦TILLING突变体检测中基因组DNA提取方法的优化显示文摘为了优化小麦高通量TILLING突变体扫描所需基因组DNA提取的方法,对利用SDS法、改良SDS法、CTAB法、改良CTAB法、AxyPrep DNA提取试剂盒、Qiagen DNeasy Plant Mini Kit试剂盒以及再生Qiagen硅胶柱方法提取的小麦基因组DNA进行了系统比较。结果表明,尽管7种方法所提取DNA的纯度及琼脂糖凝胶电泳检测结果均良好,但再生Qiagen硅胶柱方法、CTAB法和改良SDS法的DNA浓度显著高于其他方法。根据小麦细胞分裂素氧化酶基因1(TaCKX1)的DNA序列设计引物,以新鲜DNA样品用于PCR扩增大于1 000bp的片段时,后4种方法扩增效果优于前3种方法;DNA在-20℃下保存100d后重新进行PCR扩增时,则只有Qiagen试剂盒和再生Qiagen硅胶柱2种方法提取的DNA能扩增出大于1 000bp的片段。采用本实验室与新西兰坎特伯雷大学合作建立的再生硅胶柱与自配提取液提取小麦基因组DNA,既保证了DNA的高质量,又降低了使用试剂盒的成本,为小麦TILLING库的构建及其他相关试验提供了一种经济有效的DNA提取方法。徐艳 徐继法 陈磊 赵吉强 FU Zeyu JAMESON Paula E 宋建成 2017麦类作物学报2017,37,2:8
11Chinese Marine Economy Development: Dynamic Evolution and Spatial Difference显示文摘This study focuses on China's coastal area and its marine economic development. Applying the information diffusion method, the study establishes a kernel density function and its decomposition using a marine economic per capita as the index of the model to depict the dynamic evolution law and the internal influential factors of the Chinese marine economy during 1996–2013. The relative development rate was introduced to analyze the spatial differences in the marine economy's development. In this way, space and time dimensions fully characterized the evolution of the Chinese marine economy. Additionally, the influence of growth and inequality in the process of its development can be analyzed. The study shows that the Chinese marine economy as a whole has been growing, and regional marine economic development is relatively coordinated. In addition, the marine economy began to develop even more rapidly after 2004. There are three factors affecting the dynamic evolution of China's marine economy: first, the most influential mean effect, followed by, second, the variance effect, and third, the least influential residual effect. The biggest influence on the dynamic evolution of the marine economy is the improvement of the development level of the marine economy in the coastal area. Meanwhile, due to the existence of inequality, provinces at higher development levels are more dispersed. Furthermore, the existence of the residual effect weakens the influence of the mean effect, and the influence on the dynamic evolution of the marine economy continuously increases. In the analysis of the influencing factors of the evolution and spatial difference of marine economic development, the level of opening to the outside world, the level of investment in fixed assets and the industrial structure have a positive role in promoting economic development. However, capital investment in scientific human research has a negative correlation with economic development, and does not pass the significant test. The difference in regional development levels and development speed is also very apparent; namely, the provinces with higher development levels generally displayed faster development speeds while those with lower development levels showed slower development speeds across the four periods analyzed.SUN Caizhi LI Xin ZOU Wei WANG Song WANG Zeyu 2018Chinese Geographical Science2018,28,1:8
12Simulation of the stratosphere-troposphere exchange process in a typical cold vortex over Northeast China显示文摘A mesoscale weather research and forecasting(WRF)model was used to simulate a cold vortex that developed over Northeast China during June 19–23,2010.The simulation used high vertical resolution to reproduce the key features of the cold vortex development.Characteristics of the associated stratosphere-troposphere exchange(STE),specifically the spatiotemporal distribution of the cross-tropopause mass flux(CTF),were investigated using the Wei formula.The simulation results showed that the net mass exchange induced by the cold vortex was controlled by stratosphere-to-troposphere transport(STT)processes.In the pre-formation stage of the cold vortex(i.e.,the development of the trough and ridge),active exchange was evident.Over the lifecycle of the cold vortex,STT processes prevailed at the rear of the trough and moving vortex,whereas troposphere-to-stratosphere transport(TST)processes prevailed at the front end.This spatial pattern was caused by temporal fluctuations of the tropopause.However,because of the cancellation of the upward flux by the downward flux,the contribution of the tropopause fluctuation term to the net mass exchange was only minor.In this case,horizontal motion dominated the net mass exchange.The time evolution of the CTF exhibited three characteristics:(1)the predominance of the STT during the pre-formation stage;(2)the formation and development of the cold vortex,in which the CTF varied in a fluctuating pattern from TST to STT to TST;and(3)the prevalence of the STT during the decay stage.CHEN Dan Lü DaRen CHEN ZeYu 2014Science China Earth Sciences2014,57,7:7
13Advances in the Researches in Middle and Upper Atmosphere in 2006—2008显示文摘This paper summarizes the research results obtained by Chinese scientists and/or through international collaborations in 2006—2008.Specifically,this paper focus on the research fields in the middle and upper atmosphere,including developments in facilities and instruments,and the advancements in scientific issues.CHEN Zeyu CHEN Hongbin CHEN Wen LU Daren 2008空间科学学报2008,28,5:6
14Female directors and real activities manipulation:Evidence from China显示文摘Unlike previous studies that focus on accrual-based earnings management, this study analyzes real activities manipulation and investigates whether female directors on boards of directors(Bo Ds) affect managers' real activities manipulation. Using a large sample of 11,831 firm-year observations from Chinese listed companies from the 2000 to 2011 period, we find that higher female participation on Bo Ds is associated with lower levels of real activities manipulation, and that this negative relationship is stronger when female directors have higher ownership. These results hold for a battery of robustness checks.Overall, our findings indicate that board gender diversity may serve as a substitute mechanism for corporate governance to curb real activities manipulation and thus provide interested stakeholders with higher quality earnings reports.Jin-hui Luo Yuangao Xiang Zeyue Huang 2017China Journal of Accounting Research2017,,2:6
15Mycorrhizal fungal community composition in seven orchid species inhabiting Song Mountain, Beijing, China显示文摘Mycorrhizal fungi play an important role in the germination and growth of orchids essentially influencing their survival,abundance, and spatial distribution. In this study, we investigated the composition of the mycorrhizal fungal community in seven terrestrial orchid species inhabiting Song Mountain, Beijing, China, using Illumina MiSeq high-throughput sequencing. The mycorrhizal communities in the seven orchids were mainly composed of members of the Ceratobasidiaceae, Sebacinales, and Tulasnellaceae, while a number of ectomycorrhizal fungi belonging to the Russulaceae, Tricholomataceae, Thelephoraceae, and Cortinariaceae were occasionally observed. However, the dominant fungal associates and mycorrhizal community differed significantly among the orchid species as well as subhabitats. These findings confirm the previous observation that sympatric orchid species show different preferences for mycorrhizal fungi, which may drive niche partitioning and contribute to their cooccurrence.Yanhong Chen Yue Gao Linli Song Zeyu Zhao Shunxing Guo Xiaoke Xing 2019Science China(Life Sciences)2019,62,6:6
16Advances in the Studies of the Middle and Upper Atmosphere in 2004 - 2006显示文摘This paper summarizes the research results obtained by Chinese scientists and/or through international collaborations during 2004 to 2006. Within the context of COSPAR, the progresses in the studies of the middle and upper atmosphere in China in the past two years are introduced with focusing the developments in facilities and instruments, and the advancements in scientific issues, e.g., dynamics related processes, atmospheric constituents, and the coupling with the lower atmosphere.CHEN Zeyu LIU Renqiang CHEN Hongbin CHEN Wen LU Daren XU Jiyao HU Xiong 2006空间科学学报2006,26,z1:6
17Graphene TiO_2 nanocomposites with high photocatalytic activity for the degradation of sodium pentachlorophenol显示文摘A series of graphene–TiO2photocatalysts was synthesized by doping TiO2 with graphene oxide via hydrothermal treatment. The photocatalytic capability of the catalysts under ultraviolet irradiation was evaluated in terms of sodium pentachlorophenol(PCP-Na) decomposition and mineralization. The structural and physicochemical properties of these nanocomposites were characterized by X-ray diffraction, N2adsorption–desorption, transmission electron microscopy, scanning electron microscopy, Ultraviolet–visible diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectra, and Fourier-transform infrared spectroscopy. The graphene–TiO2nanocomposites exhibited higher photocatalytic efficiency than commercial P25 for the degradation of PCP-Na, and 63.4% to 82.9% of the total organic carbon was fully mineralized. The improved photocatalytic activity may be attributed to the accelerated interfacial electron-transfer process and the significantly prolonged lifetime of electron-hole pairs imparted by graphene sheets in the nanocomposites. However,excessive graphene and the inhomogeneous aggregation of TiO2 nanoparticles may decrease photodegradation efficiency.Yaxin Zhang Zeyu Zhou Tan Chen Hongtao Wang Wenjing Lu 2014Journal of Environmental Sciences2014,26,10:6
18Sensitive and selective molecularly imprinted electrochemical sensor based on multi-walled carbon nanotubes for doxycycline hyclate determination显示文摘An electrochemical sensor for doxycycline hyclate(DC)detection with high sensitivity and good selectivity is reported.The sensor was fabricated by electro-polymerization of molecularly imprinted polymers(MIPs)in the presence of DC onto multi-walled carbon nanotubes modified glassy carbon electrode(MWCNTs/GCE).The MWCNTs can significantly increase the current response of the sensor,leading to enhanced sensitivity.The MIPs provide selective recognition sites for DC detection.The experimental parameters,such as the polymer monomer concentration,supporting electrolyte pH,the time for electro-polymerization and the incubation time of the sensor with DC were optimized.Under optimized experimental conditions,the sensor displayed a linear range of 0.05μmol/L-0.5μmol/L towards DC detection,with the detection limit of 1.3×10^-2μmol/L.The sensor was successfully applied for recovery test of DC in human serum samples.Zeyu Xu Xingxing Jiang Shuping Liu Minghui Yang 2020Chinese Chemical Letters2020,31,1:6
19Simulation of the equatorial quasi-biennial oscillation based on the parameterization of continuously spectral gravity waves显示文摘On the basis of previous parameterization schemes, considering both the wave breaking and absorbed at critical level, a parameterization with a continuous spectrum of gravity waves is realized by introducing a momentum flux density function for the wave spectrum, and then the parameterization scheme of the gravity waves is improved. Choosing parameter values of the background atmosphere and waves based on the observations, a more realistic equatorial quasi-biennial oscillation (QBO) driven by the incorporated drag from the planetary and gravity waves can be simulated. The numerical results indicate that the forcing magnitude of the planetary and gravity waves varies with the wind field, and in some phases of the QBO, the contribution of the gravity waves is comparable with that of the planetary waves. After the QBO is steadily formed, its amplitude and period and wind configuration are relevant to the effect of vertical diffusion and the momentum flux distribution with spectrum, however, independent of the initial background wind field. Moreover, for any given nonzero initial background wind, a steady QBO can be finally generated due to the incorporated drag from the planetary and gravity waves.HUANG KaiMing ZHANG ShaoDong ,YI Fan CHEN ZeYu 2009Chinese Science Bulletin2009,54,2:6
20Strongly Coupled 2D Transition Metal Chalcogenide-MXene-Carbonaceous Nanoribbon Heterostructures with Ultrafast Ion Transport for Boosting Sodium/Potassium Ions Storage显示文摘Combining with the advantages of two-dimensional(2D)nanomaterials,MXenes have shown great potential in next generation rechargeable batteries.Similar with other 2D materials,MXenes generally suffer severe self-agglomeration,low capacity,and unsatisfied durability,particularly for larger sodium/potassium ions,compromising their practical values.In this work,a novel ternary heterostructure self-assembled from transition metal selenides(MSe,M=Cu,Ni,and Co),MXene nanosheets and N-rich carbonaceous nanoribbons(CNRibs)with ultrafast ion transport properties is designed for sluggish sodium-ion(SIB)and potassium-ion(PIB)batteries.Benefiting from the diverse chemical characteristics,the positively charged MSe anchored onto the electronegative hydroxy(-OH)functionalized MXene surfaces through electrostatic adsorption,while the fungal-derived CNRibs bonded with the other side of MXene through amino bridging and hydrogen bonds.This unique MXene-based heterostructure prevents the restacking of 2D materials,increases the intrinsic conductivity,and most importantly,provides ultrafast interfacial ion transport pathways and extra surficial and interfacial storage sites,and thus,boosts the high-rate storage performances in SIB and PIB applications.Both the quantitatively kinetic analysis and the density functional theory(DFT)calculations revealed that the interfacial ion transport is several orders higher than that of the pristine MXenes,which delivered much enhanced Na+(536.3 mAh g^(−1)@0.1 A g^(−1))and K^(+)(305.6 mAh g^(−1)@1.0 A g^(−1))storage capabilities and excel-lent long-term cycling stability.Therefore,this work provides new insights into 2D materials engineering and low-cost,but kinetically sluggish post-Li batteries.Junming Cao Junzhi Li Dongdong Li Zeyu Yuan Yuming Zhang Valerii Shulga Ziqi Sun Wei Han 2021Nano-Micro Letters2021,13,7:5
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