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| 1 | Zircon U-Pb geochronological framework of Qitianling granite batholith, middle part of Nanling Range, South China显示文摘The Qitianling granite batholith (QGB) is located in the southern Hunan Province, middle part of the Nanling Range, South China. Its total exposure area is about 520 km2. Based on our 25 single grain zircon U-Pb age data and 7 published data as well as the geological, petrological, and space distribution characteristics, we conclude that QGB is an Early Yanshanian (Jurassic) multi-staged composite pluton. Its formation process can be subdivided into three major stages. The first stage, emplaced at 163―160 Ma with a peak at about 161 Ma, is mainly composed of hornblende-biotite monzonitic granites and locally biotite granites, and distributed in the eastern, northern, and western peripheral parts of the pluton. The second stage, emplaced at 157―153 Ma with a peak at 157―156 Ma, is mainly composed of biotite granites and locally containing hornblende, and distributed in the middle and southeastern parts of the pluton. The third stage, emplaced at 150―146 Ma with a peak at about 149 Ma, is mainly composed of fine-grained (locally porphyritic) biotite granites, and distributed in the middle-southern part of the pluton. Each stage can be further disintegrated into several granite bodies. The first two intrusive stages comprise the major phase of QGB, and the third intrusive stage comprises the additional phase. Many second stage fine-grained granite bosses and dykes intruded into the first stage host granites with clear chilling margin-baking phenomena at their intrusive contacts. They were emplaced in the open fracture space of the earlier stage consolidated rocks. Their isotopic ages are mostly 2―6 Ma younger than their hosts. Conceivably, the time interval from magma emplacement, through cooling, crystallization, solidification, up to fracturing of the earlier stage granites cannot exceed 2―6 Ma. During the Middle-Late Jurassic in the Qitianling area and neighboring Nanling Range, the coeval granitic and basic-intermediate magmatic activities were widely developed. It indicates that the Early Yanshanian period was the culmination time of magmatic activities in this region. The Nanling Range was under a post-orogenic, intracontinental geotectonic environment with an obvious lithospheric extension and thinning. The crust-mantle interaction played an important role in formation of granitic rocks in this region. | ZHU JinChu WANG RuCheng ZHANG PeiHua XIE CaiFu ZHANG WenLan ZHAO KuiDong XIE Lei YANG Ce CHE XuDong YU APeng WANG LuBin | 2009 | Science China Earth Sciences2009，52，9： | 27 |
| 2 | Primary Sn-rich titianite in the Qitianling granite, Hunan Province, southern China: An important type of tin-bearing mineral and its implications for tin exploration显示文摘The Qitianling calc-alkaline granite in Hunan Province (South China) has attracted much attention since the discovery of the Furong super-large tin deposit. The present study provides new mineralogical data to address their implications for exploration of tin deposits. In the Taoxiwo granite in the southeastern part of the Qitianling granite body, Sn-rich titanite was identified as an important type of Sn-bearing mineral. The titanite commonly occurs with biotite as euhedral crystals, exhibiting typical envelope-like shape and sector-zoning texture. These indicate that the titanite most likely crystallized in the mag-matic stage. Electron-microprobe analyses show that the titanite is enriched in tin up to 1.12 wt% SnO2, with an average of 0.43 wt%. With the crystallization of the granite, primary minerals undertook hydro-thermal alteration by magma-derived fluids. Subsequently, in the hydrothermal stage, the primary Sn-bearing titanite was altered (at least partially), but still preserved its typical envelope-shaped outline. Micro-scale cassiterite is a representative product of such alteration; other secondary minerals include fluorite, ilmenite, Sn-bearing rutile and quartz. Therefore, the titanite, commonly present in the calc- alkaline granites, can be treated as an important Sn-carrying mineral in the Qitianling granite, reflecting the primary magmatic environment with tin enrichment. The hydrothermal alteration of the primary titanite and subsequent crystallization of cassiterite recorded a process of leaching and accumulation of tin in magmatic-hydrothermal evolution of the Snbearing granite. Thus, this titanite has important implications for tin exploration. | XIE Lei WANG RuCheng CHEN Jun ZHU JinChu ZHANG WenLan WANG DeZi YU APeng | 2009 | Chinese Science Bulletin2009，54，5： | 10 |
| 3 | Tin-carrier minerals in metaluminous granites of the western Nanling Range (southern China): Constraints on processes of tin mineralization in oxidized granites显示文摘 | Ru Cheng Wang Lei Xie Jun Chen Apeng Yu Lubin Wang Jianjun Lu Jinchu Zhu | 2012 | Journal of Asian Earth Sciences2012，，： | 1 |
| 4 | Design,synthesis and antimycobacterial activity of novel nitrobenzamide derivatives显示文摘We report herein the design and synthesis of a series of novel nitrobenzamide derivatives. Results reveal that many of them display considerable in vitro antitubercular activity. Four N-benzyl or N- (pyridine-2-yl)methyl 3,5-dinitrobenzamides A6, All, Cl and C4 have not only the same excellent MIC values of<0.016 μg/mL against both drug-sensitive MTB strain H37 Rv and two drug-resistant clinical isolates as PBTZ169 and the lead 1, but also acceptable safety indices (SI > 1500), opening a new direction for further development. | Hongjian Wang Kai Lv Xiaoning Li Bo Wang Apeng Wang Zeyu Tao Yunhe Geng Bin Wang Menghao Huang Mingliang Liu Huiyuan Guo Yu Lu | 2019 | Chinese Chemical Letters2019，30，2： | 0 |
| 5 | N-(2-Phenoxy)ethyl imidazo[1,2-a]pyridine-3-carboxamides containing various amine moieties:Design,synthesis and antitubercular activity显示文摘Seven 2,6-disubstituted N-(2-phenoxy)ethyl imidazo[1,2-a]pyridine-3-carboxamide series containing various amine moieties were designed and synthesized as new anti-TB agents.Many of them show excellent in vitro activity against both drug-sensitive MTB strain H37Rv and two MDR-MTB clinical isolates(MIC:<0.002-0.030 μg/mL).Compounds 2f,5e and 5g display acceptable safety and pharmacokinetic profiles,opening a new direction for further development. | Linhu Li Apeng Wang Bin Wang Mingliang Liu Kai Lv Zeyu Tao Chao Ma Xican Ma Bing Han Aoyu Wang Yu Lu | 2020 | Chinese Chemical Letters2020，31，2： | 0 |
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