| 1 | Decomposition of hexachlorobenzene over Al_2O_3 supported metal oxidecatalysts显示文摘Decomposition of hexachlorobenzene(HCB)was investigated over several metal oxides(i.e.,MgO,CaO,BaO,La2O3,CeO2,MnO2, Fe2O3,and Co3O4)supported on Al2O3,which was achieved in closed system at a temperature of 300°C.Catalysts were prepared by incipient wetness impregnation with different metal oxides loading and impregnating solvents.The decomposition effciency of different catalysts for this reaction depends on the nature of the metal oxide used,and Al2O3 supported La2O3 was found to be the most active one.Pentachlorobenzene(PeCB),and all tetrachlorobenzene(TeCB),trichlorobenzene(TrCB),and dichlorobenzene(DCB)isomers were detected after the decomposition reaction,indicating that the decomposition was mainly a dechlorination process.The detection of all lower chlorinated benzenes suggested the complexity of decomposition and the presence of more than one dechlorination pathway. | Lifei ZHANG Minghui ZHENG Bing ZHANG Wenbin LIU Lirong GAO Te BA Zhiyuan REN Guijin SU | 2008 | Journal of Environmental Sciences2008，20，12： | 4 |
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