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| 1 | Preparation of Unsupported Molybdenum Phosphide Hydrofining Catalysts显示文摘 | LI Fengyan, ZHAO Tianbo, SUN Guida, LI Cuiqing (Department of Applied Chemistry, Beijing Institute of Petrochemical Technology, Beijing 102617, China) | 2003 | 催化学报2003，24，2： | 10 |
| 2 | Physicochemical Properties and Catalytic Performance of a Novel Aluminosilicate Composite Zeolite for Hydrocarbon Cracking Reaction显示文摘A novel micro-micro/mesoporous aluminosilicate ZSM-5-Y/MCM-41 composite molecular sieve with a MCM-41 type structure was synthesized through a novel process of the self-assembly of CTAB surfactant micellae with silica-alumina source originated from alkaline treatment of ZSM-5 zeolite.The physical properties of the ZSM-5- Y/MCM-41 composite molecular sieve were characterized by XRD,Py-FTIR and N_2 adsorption-desorption techniques. Different kinds of molecular sieves including ZSM-5,Y zeolite,Al-MCM-41,ZSM-5/MCM-41 and ZSM-5-Y/MCM- 41 as cracking catalysts were investigated,using 1,3,5-triisopropylbenzene(1,3,5-TIPB) as the probe molecule.Catalytic tests showed that the ZSM-5-Y/MCM-41 composite molecular sieve exhibited higher catalytic activity compared with the microporous ZSM-5 zeolite,Y zeolite,mesoporous Al-MCM-41 molecular sieve and ZSM-5/MCM-41 composite molecular sieve under the same conditions.The remarkable catalytic activity was mainly attributed to the presence of the hierarchical pore structure and proper acidity in the ZSM-5-Y/MCM-41 composite catalyst.Meanwhile, a carbenium ion mechanism was put forward for the cracking of 1,3,5-TIPB. | Qi Jian Zhao Tianbo Xu Xin Li Fengyan Sun Guida | 2010 | China Petroleum Processing & Petrochemical Technology2010，12，1： | 4 |
| 3 | Serum IGF-1 is insufficient to restore skeletal size in the total absence of the growth hormone receptor显示文摘 | Wu Y Sun H Basta-Pljakic J Cardoso L Kennedy OD Jasper H Domene H Karabatas L Guida C Schaffler MB Rosen CJ Yakar S | | 0，，： | 1 |
| 4 | Hydrothermal Synthesis and Mechanism for Formation of Novel Micro-Micro-Mesoporous Aluminosilicate Composite Zeolite显示文摘新奇 micro-micro-mesoporous 铝矽酸盐 LS-BFMZ (有 MCM-41 类型结构的 low-silica-BEA (贝它) -faujasite(Y)-mesoporous)composite 沸石通过包含的一个新奇过程被综合 selfassembly ,有硅石氧化铝的 CTAB 表面活化剂 micellae ,来源从贝它 zeolite.The 的碱的处理发源 LS-BFMZ 合成沸石的物理性质用各种各样的技术被描绘,包括 XRD ,红外和 SEM techniques.Meanwhile 。 | QiJian Zhao Tianbo Xu Xin Li Fengyan Sun Guida | 2010 | China Petroleum Processing & Petrochemical Technology2010，12，3： | 1 |
| 5 | Study on physico- chemical properties and catalytic activity of BSiZrAPO- 5 catalysts in linear alkylbenzene synthesis显示文摘 | Peiyong Lian Wenyi Gao Fushan Yan Weqiao Liu Gong Li Haoping Wang Guida Sun | 2002 | Catalysis today2002，74，： | 1 |
| 6 | Effect of Reduction Temperature on Hydrofining Performance of Supported Molybdenum Phosphide Catalyst显示文摘A series of supported molybdenum phosphide catalysts were prepared by impregnation method. XRD, TG-DTG, XPS and BET were used to study the phase, compositions and surface areas of the prepared catalysts. A model reactant containing thiophene, pyridine and cyclohexene was used for the measurements of catalytic activities. The effect of reduction temperature on catalytic activities was in- vestigated. The analysis results by XRD and BET are very different when the reduction temperature is changed from 400 to 900 °C. MOP/γ-Al2 O3 catalysts and CoMoP/γ-Al2O3 catalysts prepared at the reduction temperature of 500 °C are the most active ones. | Fengyan Li Zhifang Zhao Qingjie Li Tianbo Zhao Cuiqing Li Guida Sun | 2005 | Journal of Natural Gas Chemistry2005，14，4： | 0 |
| 7 | Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts显示文摘Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors(supported phospho-tungstate catalysts)in H2 and characterized by X-ray diffraction(XRD),BET,temperature-programmed desorption of ammonia(NH3-TPD)and X-ray photoelectron spectroscopy(XPS).The reduction-phosphiding processes of the precursors were investigated by thermogravimetry and differential thermal analysis(TG-DTA)and the suitable phosphiding temperatures were defined.The hydrodesulfurization(HDS)and hydrodenitrogenation(HDN)activities of the catalysts were tested by using thiophene,pyridine,dibenzothiophene,carbazole and diesel oil as the feedstock.The TiO2,c-Al_(2)O_(3) supports and the Ni,Co promoters could remarkably increase and stabilize active W species on the catalyst surface.A suitable amount of Ni(3%–5%),Co(5%–7%)and V(1%–3%)could increase dispersivity of the W species and the BET surface area of the WP/c-Al_(2)O_(3) catalyst.The WP/c-Al_(2)O_(3) catalyst possesses much higher thiophene HDS and carbazole HDN activities and the WP/TiO2 catalyst has much higher dibenzothiophene(DBT)HDS and pyridine HDN activities.The Ni,Co and V can obviously promote the HDS activity and inhibit the HDN activity of the WP/c-Al_(2)O_(3) catalyst.The G-Ni5 catalyst possesses a much higher diesel oil HDS activity than the sulphided industrial NiW/c-Al_(2)O_(3) catalyst.In general,a support or promoter in the WP/c-Al_(2)O_(3) catalyst which can increase the amount and dispersivity of the active W species can promote its HDS and HDN activities. | Guida SUN Cuiqing LI Zhijun ZHOU Fengyan LI | 2008 | Frontiers of Chemical Science and Engineering2008，2，2： | 0 |
| 8 | Study on Synthesis and Catalytic Performance of Hierarchical Zeolite显示文摘一种层次沸石催化剂被热水的方法综合。X 光检查衍射(XRD ) 和氮吸附解吸附作用方法被用来学习阶段和准备催化剂的孔结构。在样品上吸附的 pyridine 的 Infrared (红外) 系列证明层次沸石确实有更多 Bronsted 和路易斯酸的地点比 HZSM-5 沸石。大烃分子的催化裂开证明层次沸石比 HZSM-5 沸石举办了一项更高催化的活动。 | Zhang Lingling Li Fengyan ZhaoTianbo Sun Guida | 2007 | China Petroleum Processing & Petrochemical Technology2007，9，3： | 0 |
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