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| 1 | Insight into the interaction between Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode and BF4--introducing electrolyte at 4.5V high voltage显示文摘Owing to the high specific capacity and high voltage,Ni-rich(LiNi0.8Co0.1Mn0.1O2,LNCM811)cathode has been considered as one of the most promising candidate cathode materials for next generation lithium ion batteries,whereas severe capacity fading greatly hinders its practical application.Notably,the compatibility of Ni-rich materials with LiBF4-containing electrolyte has not yet been realized.Herein,1 M LiPF6-based electrolyte with introducing 2 M LiBF4 is proposed to dramatically improve the cyclic stability of high voltage LNCM811/Li half-cell.Addition of high concentrated LiBF4 improves the moisture stability of electrolyte,which hinders the generation of harmful by-product HF,resulting in improved interfacial stability of LNCM811.Lithium plating/stripping reaction of Li/Li symmetric cell confirms that the enhanced cyclic stability is ascribed to the improved interfacial stability of LNCM811 instead of lithium electrode.Morphology and composition characterization results reveal that LiBF4 participates in the CEI film-forming reaction,resulting in suppressed oxidation of electrolyte and interfacial structural destruction of LNCM811. | Guangyuan Lan Hebing Zhou Lidan Xing Jiawei Chen Zifei Li Rude Guo Yanxia Che Weishan Li | 2019 | Journal of Energy Chemistry2019，28，12： | 3 |
| 2 | Protective electrode/electrolyte interphases for high energy lithium-ion batteries with p-toluenesulfonyl fluoride electrolyte additive显示文摘High energy density lithium-ion batteries using Ni-rich cathode(such as LiNi0.6Co0.2Mn0.2O2) suffer from severe capacity decay.P-toluenesulfonyl fluoride(pTSF) has been investigated as a novel film-forming electrolyte additive to enhance the cycling performances of graphite/LiNi0.6Co0.2Mn0.2O2 pouch cell.In comparison with the baseline electrolyte,a small dose of pTSF can significantly improve the cyclic stability of the cell.Theoretical calculations together with experimental results indicate that pTSF would be oxidized and reduced to construct protective interphase film on the surfaces of LiNi0.6Co0.2Mn0.2O2 cathode and graphite anode,respectively.These S-containing surface films derived from pTSF effectively mitigate the decomposition of electrolyte,reduce the interphasial impedance,as well as prevent the dissolution of transition metal ions from Ni-rich cathode upon cycling at high voltage.This finding is beneficial for the practical application of high energy density graphite/LiNi0.6Co0.2Mn0.2O2 cells. | Yanxia Che Xiuyi Lin Lidan Xing Xiongcong Guan Rude Guo Guangyuan Lan Qinfeng Zheng Wenguang Zhang Weishan Li | 2021 | Journal of Energy Chemistry2021，30，1： | 3 |
| 3 | Magnesium deficiency: effect on bone and mineral metabolism in the mouse 显示文摘 | RUDE R K WEI L Y | 2003 | Calcified Tissue Int2003，72，1： | 1 |
| 4 | An examination of self-com-passion in relation to postive psychological functioning and personality traits显示文摘 | Neff KD Rude SS Kirkpatrick K | 2007 | J Res Pers2007，，41： | 1 |
| 5 | Mineralocorticoid receptor inhibition ameliorates the transition to myocardial failure and decreases oxidative stress and inflammation in mice with chronic pressure overload 显示文摘 | Kuster GM Kotlyar E Rude MK | 2005 | Circulation2005，111，4： | 1 |
| 6 | Low serum concentrations of 1,25-dihydroxyvitamin D in human magnesium deficiency显示文摘 | Rude RK Adams JS Ryzen E | | 0，，05： | 1 |
| 7 | Efforts to limit the size of myocardial infarcts显示文摘 | Muller JE Braunwald E | 1981 | Ann Intern Med1981，95，： | 1 |
| 8 | Optimization and profling of the cache performance of parallel lattice Boltzmann codes 显示文摘 | POHL T KOWARSCHIK M WILKE J IGLBERGER K RUDE U | 2003 | Parallel Process Letters2003，13，4： | 1 |
| 9 | Benefits of Expressive Writing in Lowering Rumination and Depressive Symptoms显示文摘 | Gortner E M Rude S S Pennebaker J W | 2006 | Beha Ther2006，37，3： | 1 |
| 10 | Analysis of complica- tions after EUS -FNA in patients with obstructive jaundice and drained with plastic biliary stents or self -expandable metal stent (SEMS): do complications differ between the type of stent? 显示文摘 | BHALALA M RUDE K WANG A | 2013 | J Interv Gastroenterol2013，3，4： | 1 |
| 11 | Effects of melatonin on plasma oxidative stress in rats with streptozotocin induced diabetes 显示文摘 | Klepac N Rudes Z Klepac R | 2006 | Biomed Pharmacother2006，60，1： | 1 |
| 12 | Nonlinear total variation based noise removal algorithms显示文摘 | Ruding L Osher S FatemiI E | 1992 | Phys D1992，60，14： | 1 |
| 13 | Depression-related impairments in prospective memory显示文摘 | Rude SS Hertel PT Jarrold W | | 0，，： | 1 |
| 14 | An examination of self-compassion in relation to positive psychological func- tioning and personality traits 显示文摘 | Neff KD Rude SS Kirkpatrick KL | 2007 | Journal of Research in Personality2007，41，4： | 1 |
| 15 | Implications of arsenic genetoxicity for dose response of carcinogenic effects 显示文摘 | RUDE R SLAYTON T M BECK B D | 1996 | Regulatory Toxicology and pharmacology1996，23，2： | 1 |
| 16 | The effects of varying fluid volume and rate of resuscitation during uncontrolled hemorrhage显示文摘 | Dana M Soucy Malcolm Rude Wen C Hsia | 1999 | J Trauma1999，46，2： | 1 |
| 17 | Origin of the anomalous magnetic behavior in single crystal Fe5O4 films显示文摘 | Margulies D T Parker F T Rudee M L | 1997 | Phys Rev Lett1997，79，： | 1 |
| 18 | Relative benefits of assertion or cognitive self-control treatment for depression as a function of proficiency in each domain 显示文摘 | Rude S S | 1986 | Journal of Consulting and Clinical Psychology1986，54，3： | 1 |
| 19 | Tibial platern fractrues,a comparison of conservative and srugical treatment显示文摘 | Jensen DB Rude C Dnns B | 1990 | J Bone joint surg(Br)1990，7249，： | 1 |
| 20 | Effects of melatonin on plasma oxidative stress in rats with streptozotocin induced diabetes显示文摘 | Klepac N Rudes Z Klepac R | 2006 | Biomed Pharmacother2006，60，： | 1 |
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