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| 1 | Orbit determination and time synchronization for BDS-3 satellites with raw inter-satellite link ranging observations显示文摘To provide competitive global positioning and timing services under the condition that monitoring stations are confined to Chinese territory,inter-satellite link(ISL)technology is used by the third-generation BeiDou Navigation Satellite System(BDS-3).The ISL,together with the dual one-way links between satellites and anchor stations,may enable autonomous navigation for BDS-3.In this paper,we propose a general observation model for orbit determination(OD)and time synchronization(TS)directly using non-simultaneous observations,such as raw ISL pseudoranges.With the proposed model,satellite orbits,clocks,and hardware delay biases of ISL equipment can be determined simultaneously by jointly processing inter-satellite one-way pseudorange data and observation data from ground monitoring stations.Moreover,autonomous OD and TS are also achievable with one-way pseudorange data from anchor stations and satellites.Data from eight BDS-3 satellites,two anchor stations,and seven monitoring stations located in China were collected to validate the proposed method.It is shown that by jointly processing data from the ISL and seven monitoring stations,the RMS of overlap orbit differences in radial direction is 0.019 m,the overlap clock difference(95%)is 0.185 ns,and the stability of the estimated hardware delay biases for each satellite is greater than 0.5 ns.Compared with the results obtained with the seven stations,the improvements of orbits in radial direction and clocks are 95.7%and 90.5%,respectively.When the hardware delay biases are fixed to predetermined values,the accuracies of orbits and clocks are further improved.By jointly processing pseudoranges from the satellites and the two anchor stations,the RMS of overlap orbit differences is 0.017 m in the radial direction,and the overlap clock difference(95%)is 0.037 ns.It has also been demonstrated that under the condition of one-way ranging links,the accuracies of orbits and clocks obtained by the above two modes are still significantly better than those obtained by using the data from the monitoring stations alone. | Rengui Ruan Xiaolin Jia Laiping Feng Jun Zhu Zongbo Huyan Jie Li Ziqing Wei | 2020 | Satellite Navigation2020,1,1: | 5 |
| 2 | EXISTENCE OF MULTIPLE POSITIVE SOLUTIONS TO SINGULAR SECOND ORDER NEUMANN BOUNDARY VALUE PROBLEMS显示文摘Using the fixed point index in cones, we study the existence of one and two positive solutions to singular second order Neumann boundary value problems under some conditions, which concerns the first eigenvalue of the relevant linear problem. Our results improve and extend some known ones in the previous literature. | Xiangping Chen, Rengui Li (Dept. of Math., Jining University, Qufu 273155, Shandong) | 2010 | Annals of Differential Equations2010,26,2: | 3 |
| 3 | Preparation and characterization of ramsdellite Li2Ti3O7 as an anode material for asymmetric supercapacitors显示文摘 | Fang Chen Rengui Li | 2005 | Electrochimica Acta2005,51,: | 1 |
| 4 | Effects of Ca-based additives on desulfurization during coal pyrolysis显示文摘 | Rengui Guan Wen Li Baoqing Li | 2003 | Fuel2003,,15: | 1 |
| 5 | 显示文摘 | Guan Rengui Li Wen Li Baoqing | 2003 | Fuel2003,82,1517: | 1 |
| 6 | The release of nitrogen species during of model char loaded with differ-ent additives显示文摘 | Guan Rengui Li Wen Chen Haokan | 2004 | Fuel Processing Technology2004,85,8910: | 1 |
| 7 | Facet effect on the reconstructed Cu-catalyzed electrochemical hydrogenation of 5-hydroxymethylfurfural(HMF) towards 2,5-bis(hydroxymethy)furan (BHMF)显示文摘The electrochemical hydrogenation of HMF to BHMF is an elegant alternative to the conventio nal thermocatalytic route for the production of high-value-added chemicals from biomass resources.In virtue of the wide potential window with promising Faradic efficiency(FE) towards BHMF,Cu-based electrode has been in the center of investigation.However,its structure-activity relationship remains ambiguous and its intrinsic catalytic activity is still unsatisfactory.In this work,we develop a two-step oxidation-reduction strategy to reconstruct the surface atom arrangement of the Cu foam(CF).By combination of multiple quasi-situ/in-situ techniques and density functional theory(DFT) calculation,the critical factor that governs the reaction is demonstrated to be facet effect of the metallic Cu crystal:Cu(110) facet accounts for the most favorable surface with enhanced chemisorption with reactants and selective production of BHMF,while Cu(100) facet might trigger the accumulation of the by-product 5,5'-bis(hydroxy methy)hydrofurion(BHH).With the optimized composition of the facets on the reconstructed Cu(OH)_(2)-ER/CF,the performance could be noticeably enhanced with a BHMF FE of 92.3% and HMF conversion of 98.5% at a potential of -0.15 V versus reversible hydrogen electrode(vs.RHE) in 0.1 M KOH solution.This work sheds light on the incomplete mechanistic puzzle for Cu-catalyzed electrochemical hydrogenation of HMF to BHMF,and provides a theoretical foundation for further precise design of highly efficient catalytic electrodes. | Mengxia Li Tianxi Zheng Dongfei Lu Shiwei Dai Xin Chen Xinchen Pan Dibo Dong Rengui Weng Gang Xu Fanan Wang | 2023 | Journal of Energy Chemistry2023,,9: | 1 |
| 8 | 羟基喜树碱联合FOLFOX4方案二线治疗晚期胃癌的临床分析(英文)显示文摘Objective: To evaluate the therapeutic as well as side effects of hydroxycamptothecin (HCPT) plus FOLFOX4 regimen as salvage therapy for patients with advanced gastric cancer. Methods: A total of 19 patients with advanced gastric cancer received HCPT plus FOLFOX4 as salvage therapy, in detail, Oxaliplatin 85 mg/m2 was given intravenously on day 1, CF 200 mg/m2, 5-Fu 400 mg/m2 given in bolus immediately after CF, days 1-2; 5-Fu 600 mg/m2 given continuously after bolus for 22 h on day 1, day 2, HCPT given intravenously at dosage of 10 mg/m2 on days 1-2. Therapeutic effects were evaluated at least after two cycles of treatment. Results: 17 cases among the 19 patients were valid for response evaluation, with CR 1 , PR 6, SD 4, PD 6. The response rate was 41.2%. For the 12 patients with liver metastasis, response rate of the liver foci was 50%. The main toxicities were bone marrow suppression, nausea and vomiting, and peripheral neuropathy; there were no chemotherapy-related deaths. Conclusion: The combination regimen with HCPT plus FOFLOX4 regimen was effective as salvage therapy for patients with advanced gastric cancer, with particularly high response rate for liver metastasis, and the side effects were tolerable and manageable. | Xiaoqiang Fan Xijian Zhou Xiangyong Li Xinyu Tang Rengui Zhou Dejian Pan | 2008 | The Chinese-German Journal of Clinical Oncology2008,7,12: | 0 |
| 9 | Modulating the Selectivity of Photocatalytic CO_(2)Reduction in Barium Titanate by Introducing Oxygen Vacancies显示文摘Artifi cial photosynthetic reduction of CO_(2) into valuable chemicals is one of the most promising approaches to solve the energy crisis and decreasing atmospheric CO_(2) emissions.However,the poor selectivity accompanied by the low activity of photocatalysts limits the development of photocatalytic CO_(2) reduction.Herein,inspired by the use of oxygen vacancy engi-neering to promote the adsorption and activation of CO_(2) molecules,we introduced oxygen vacancies in the representative barium titanate(BaTiO 3)photocatalyst for photocatalytic CO_(2) reduction.We found that oxygen vacancies brought signifi cant diff erences in the CO_(2) photoreduction activity and selectivity of BaTiO 3.The intrinsic BaTiO 3 showed a low photocatalytic activity with the dominant product of CO,whereas BaTiO 3 with oxygen vacancies exhibited a tenfold improvement in photocatalytic activity,with a high selectivity of~90%to CH 4.We propose that the presence of oxygen vacancies promotes CO_(2) and H 2 O adsorption onto the BaTiO 3 surface and also improves the separation and transfer of photogenerated carriers,thereby boosting the photocatalytic CO_(2) reduction to CH 4.This work highlights the essential role of oxygen vacancies in tuning the selectivity of photocatalytic reduction of CO_(2) into valuable chemicals. | Yi Wang Chengbo Zhang Rengui Li | 2022 | Transactions of Tianjin University2022,28,4: | 0 |
| 10 | Potential industrial applications of photo/electrocatalysis: Recent progress and future challenges显示文摘Nowadays,the rapid development of the social economy inevitably leads to global energy and environmental crisis.For this reason,more and more scholars focus on the development of photocatalysis and/or electrocatalysis technology for the advantage in the sustainable production of high-value-added products,and the high efficiency in pollutants remediation.Although there is plenty of outstanding research has been put forward continuously,most of them focuses on catalysis performance and reaction mechanisms in laboratory conditions.Realizing industrial application of photo/electrocatalytic processes is still a challenge that needs to be overcome by social demand.In this regard,this review comprehensively summarized several explorations in thefield of photo/electrocatalytic reduction towards potential industrial applications in recent years.Special attention is paid to the successful attempts and the current status of photo/electrocatalytic water splitting,carbon dioxide conversion,resource utilization from waste,etc.,by using advanced reactors.The key problems and challenges of photo/electrocatalysis in future industrial practice are also discussed,and the possible development directions are also pointed out from the industry view. | Jinhao Li Jing Ren Shaoquan Li Guangchao Li Molly Meng-Jung Li Rengui Li Young Soo Kang Xiaoxin Zou Yong Luo Bin Liu Yufei Zhao | 2024 | Green Energy & Environment2024,9,5: | 0 |
| 11 | Tailoring morphology symmetry of bismuth vanadate photocatalysts for efficient charge separation显示文摘Although spatial charge separation between different facets of semiconductor crystals has been recognized as a general strategy in photocatalysis, the vital role of crystal morphology symmetry in charge separation properties still remains elusive. Herein,taking monoclinic bismuth vanadate(BiVO_(4)) as a platform, we found distinct charge separation difference via rationally tailoring the morphology symmetry from octahedral to truncated octahedral crystals. For octahedral BiVO_(4), photogenerated electrons and holes can be separated between edges and quasi-equivalent facets. However, as for truncated octahedral crystals,photogenerated electrons tend to transfer to {010} facets while photogenerated holes prefer to accumulate on {120} facets, thus realizing the spatial separation of photogenerated charge between different facets. Morphology tailoring of BiVO_(4) crystals leads to a significantly improved photogenerated charge separation efficiency and photocatalytic water oxidation activity. The built-in electric field for driving the separation of photogenerated electrons and holes is considered to be modulated by tuning the morphology symmetry of BiVO_(4) crystals. This work discloses the significant roles of morphology symmetry in photogenerated charge separation and facilitates the rational design of artificial photocatalysts. | Yuting Deng Hongpeng Zhou Chenwei Ni Fengke Sun Wenchao Jiang Ruotian Chen Wenming Tian Can Li Rengui Li | 2023 | Science China Chemistry2023,66,12: | 0 |
| 12 | Spatiotemporal characteristics and driving mechanisms of land use/land cover(LULC)changes in the Jinghe River Basin,China显示文摘Understanding the trajectories and driving mechanisms behind land use/land cover(LULC)changes is essential for effective watershed planning and management.This study quantified the net change,exchange,total change,and transfer rate of LULC in the Jinghe River Basin(JRB),China using LULC data from 2000 to 2020.Through trajectory analysis,knowledge maps,chord diagrams,and standard deviation ellipse method,we examined the spatiotemporal characteristics of LULC changes.We further established an index system encompassing natural factors(digital elevation model(DEM),slope,aspect,and curvature),socio-economic factors(gross domestic product(GDP)and population),and accessibility factors(distance from railways,distance from highways,distance from water,and distance from residents)to investigate the driving mechanisms of LULC changes using factor detector and interaction detector in the geographical detector(Geodetector).The key findings indicate that from 2000 to 2020,the JRB experienced significant LULC changes,particularly for farmland,forest,and grassland.During the study period,LULC change trajectories were categorized into stable,early-stage,late-stage,repeated,and continuous change types.Besides the stable change type,the late-stage change type predominated the LULC change trajectories,comprising 83.31% of the total change area.The period 2010-2020 witnessed more active LULC changes compared to the period 2000-2010.The LULC changes exhibited a discrete spatial expansion trend during 2000-2020,predominantly extending from southeast to northwest of the JRB.Influential driving factors on LULC changes included slope,GDP,and distance from highways.The interaction detection results imply either bilinear or nonlinear enhancement for any two driving factors impacting the LULC changes from 2000 to 2020.This comprehensive understanding of the spatiotemporal characteristics and driving mechanisms of LULC changes offers valuable insights for the planning and sustainable management of LULC in the JRB. | WANG Yinping JIANG Rengui YANG Mingxiang XIE Jiancang ZHAO Yong LI Fawen LU Xixi | 2024 | Journal of Arid Land2024,16,1: | 0 |
| 13 | Photo-induced carbon dioxide reduction on hexagonal tungsten oxide via an oxygen vacancies-involved process显示文摘Although converting the greenhouse gasses carbon dioxide(CO_(2))into solar fuels is regarded as a convenient means of solar energy storage,the intrinsic mechanism on how the high chemical inertness linear CO_(2)molecules is activated and converted on a semiconductor oxide is still elusive.Herein,by creating the oxygen vacancies on the typical hexagonal tungsten oxide(WO3),we realize the continuous photoinduced CO_(2)reduction to selectively produce CO under light irradiation,which was verified by isotope labeling experiment.Detailed oxygen vacancies evolution investigation indicates that light irradiation can simultaneously induce the in-situ formation of oxygen vacancies on hexagonal WO3,and the oxygen vacancies promote the adsorption and activation of CO_(2)molecules,leading to the CO_(2)reduction to CO on the hexagonal WO3via an oxygen vacancies-involved process.Besides,the existence of water further promotes the formation of CO_(2)reduction intermediate,further promote the CO_(2)photoreduction.Our work provides insight on the mechanism for converting CO_(2)into CO under light irradiation. | Yi Wang Runze Liu Ming Shi Panwang Zhou Keli Han Can Li Rengui Li | 2023 | Chinese Chemical Letters2023,34,1: | 0 |
| 14 | Crystal Facet-Dependent Intrinsic Charge Separation on Well-Defined Bi_(4)TaO_(8)Cl Nanoplate for Efficient Photocatalytic Water Oxidation显示文摘The development of photocatalysts with wide spectral absorption and high charge separation efficiency has always been a pursued objective for photocatalytic solar energy conversion.Herein,we reported a wide-range visible-light-active Bi_(4)TaO_(8)Cl(BTOC)single crystal nanoplate with dominating{110}and{001}facets for enhancing the intrinsic charge separation efficiency.Insitu selective photodeposition of metals and metal oxides provides evidences of photogenerated electrons and holes spatially separated on{110}and{001}coexposed facets of BTOC,respectively.The intrinsic charge separation efficiency was demonstrated to be closely dependent on the crystal facets,which can be modulated by tuning the coexposed crystal facet ratio.Further surface modification of BTOC with suitable dual cocatalyst Ag and RuOx enables remarkable improvement of charge separation efficiency and photocatalytic water oxidation performance.Investigation by comparison between well-defined BTOC nanoplate and BTOC nanoparticles confirmed the significance of coexposed crystal facets for efficient spatial charge separation and the blocking of reverse reaction from Fe^(2+)to Fe^(3+)ions during water oxidation reaction,indicating that rational modulation of exposed crystal facets is significant for controlling the intrinsic charge separation efficiency on Bi_(4)TaO_(8)Cl photocatalyst for efficient photocatalytic water splitting. | Abraham Adenle Ming Shi Xiaoping Tao Yue Zhao Bin Zeng Na Ta Rengui Li | 2022 | Energy Material Advances2022,,1: | 0 |
| 15 | Tuning Exciton Recombination Pathways in Inorganic Bismuth-Based Perovskite for Broadband Emission显示文摘Single-component emitters with broadband emission are attractive but challenging for illumination and display applications.The two-dimensional organic-inorganic hybrid perovskites have exhibited outstanding broad emission property due to low electronic dimensionality and strong exciton-phonon coupling.However,few layered all-inorganic lead-free perovskites with broadband emission have been explored,and the explicit mechanism of exciton recombination in them also needs in-depth understanding.Herein,the inorganic bismuth-based perovskite Cs3Bi2Br9 achieves the stable broadband emission under ambient temperature and pressure by tuning the exciton recombination pathways via antimony(Sb)doping,and the photoluminescence quantum yield(PLQY)realizes an enhancement from 2.9%to 15.9%.The photoluminescence excitation(PLE)spectra indicate that the doped Sb introduces newly extrinsic self-trapped states.The incorporation of Sb promotes the transfer of free excitons(FEs)to extrinsic self-trapped excitons(STEs)observed from Sb content-dependent steady-state PL spectra and,meanwhile,reduces the nonradiative recombination of the generated extrinsic STEs,which are primarily responsible for the remarkably enhanced broad emission.Furthermore,femtosecond transient absorption results elucidate a clear exciton dynamics,in which the transition from FEs to STEs might arise through the gradient energy levels,and finally extrinsic STEs at various energy states contribute to the broadband emission. | Ming Shi Bin Yang Siping Liu Ruiling Zhang Keli Han Can Li Rengui Li | 2022 | Energy Material Advances2022,,1: | 0 |
| 16 | Construction of charge transfer chain in Bi_(12)TiO_(20)-Bi_(4)Ti_(3)O_(12)/α-Bi_(2)O_(3)composites to accelerate photogenerated charge separation显示文摘Photogenerated charge separation and transfer is one of the bottleneck steps in photocatalysis,and efficient charge separation strategies are strongly desired.Here,mimicking the electron transport chain in natural photosynthesis,we report the design and fabrication of a charge transfer chain using bismuth-based semiconductor as a proof-of-concept.In view of the thermodynamic energy band positions and structural similarity based on the density functional theory(DFT)analysis,heterostructured combination ofα-Bi_(2)O_(3),perovskite-like Bi_(4)Ti_(3)O_(12),and sillenite Bi12TiO20 was designed for fabrication of charge transfer chain.By tuning the molar ratio of Bi and Ti precursors,the Bi_(4)Ti_(3)O_(12)and Bi12TiO20 particles were formed on the surface ofα-Bi_(2)O_(3)by an insitu transformation process,giving rise to Bi_(12)TiO_(20)-Bi_(4)Ti_(3)O_(12)/α-Bi_(2)O_(3)composites with charge transfer chain.We propose that the effective charge transfer is accomplished amongα-Bi_(2)O_(3),Bi12TiO20,and Bi_(4)Ti_(3)O_(12),which significantly improves the photogenerated charge separation and transfer,as indicated by photoluminescene,time-resolved photoluminescene,and electrochemical impedance spectra results.As expected,the Bi_(12)TiO_(20)-Bi_(4)Ti_(3)O_(12)/α-Bi_(2)O_(3)shows the superior photocatalytic activity for the degradation of environmental pollutants with high concentration.Even for the refractory pollutants like 4-chlorophenol,the optimal Bi_(12)TiO_(20)-Bi_(4)Ti_(3)O_(12)/α-Bi_(2)O_(3)composite shows 28 times higher than that ofα-Bi_(2)O_(3)for photocatalytic degradation,verifying the superiority of photogenerated charge transfer chain in photocatalysis.This work demonstrates the feasibility of the charge transfer chain strategy to boost the photogenerated charge separation,which is of great significance for designing energy and environmental-related materials in heterogonous photocatalysis. | Jincheng Yin Xuebing Chen Guanna Li Dongxu Liu Chun Li Rengui Li Bingxing Xie Johannes H.Bitter Jing Zhang | 2023 | Nano Research2023,16,3: | 0 |