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    题名 作者 年代 出处 被引量
1Walnut-inspired microsized porous silicon/graphene core-shell composites for high-performance lithium-ion battery anodes显示文摘Wei Zhai Qing Ai Lina Chen Shiyuan Wei Deping Li Lin Zhang Pengchao Si Jinkui Feng Lijie Ci 2017Nano Research2017,10,12:12
2Electroplastic Tensile Behavior of 5A90 Al–Li Alloys显示文摘The electroplastic(EP) tensile properties of 5A90 Al–Li alloys compared with thermal tension were investigated.The microstructural variation at different conditions was observed by SEM and TEM.The current density significantly influences the elongation and the flow stress.With increasing current density,wider and deeper dimples on the fracture surfaces and less dislocation density and pile-ups in the EP tension samples were observed compared with roomtemperature and thermal tension,which indicates the plasticity improvement and flow stress reduction.The EP effect(EPE) mainly results from a comprehensive function of Joule heating and pure EPE.Among them,Joule heating effect is perhaps a dominant factor.Pengchao Song Xifeng Li Wei Ding Jun Chen 2014Acta Metallurgica Sinica(English Letters)2014,27,4:7
3Sepiolite/Cu_2O/Cu photocatalyst: Preparation and high performance for degradation of organic dye显示文摘A novel ternary sepiolite/Cu_2O/Cu(SCC) nanocomposite was successfully synthesized by a facile one-pot method. The Cu_2O/Cu nanoparticles in the SCC nanocomposite are well dispersed on the sepiolite surface. It exhibited enhanced photocatalytic performance in the degradation of congo red(CR), remarkably superior to that of Cu_2O or Cu_2O/Cu nanoparticles. Elemental copper in the SCC serves as a good electron acceptor to promote the transfer of photo-generated electrons in Cu_2O and suppress the recombination of the photo-generated electrons and holes of the composite. The enhanced photocatalytic efficiency is attributed to the synergistic effect of sepiolite and Cu_2O/Cu. This type of SCC nanocomposites is a promising candidate as photocatalytic material for environmental protection.Peisan Wang Chunxia Qi Luyuan Hao Pengchao Wen Xin Xu 2019Journal of Materials Science & Technology2019,35,3:7
4Community structures and population dynamics of “Candidatus Accumulibacter” in activated sludges of wastewater treatment plants using ppk1 as phylogenetic marker显示文摘Candidatus Accumulibacter has been identified as dominant polyphosphate-accumulating organisms(PAOs) in enhanced biological phosphorus(P) removal(EBPR) from wastewater.This study revealed the relevance of community structure, abundance and seasonal population dynamics of Candidatus Accumulibacter to process operation of wastewater treatment plants(WWTPs) in China using ppk1 gene as phylogenetic marker. All sludge samples had properties of denitrifying P removal using nitrate as an electron acceptor.Accumulibacter abundance in the anaerobic-anoxic-oxic(A^2O) process was the highest(26%of total bacteria), and higher in winter than in summer with a better EBPR performance.Type-II was the dominant Accumulibacter in all processes, and type-I accounted for a small proportion of total Accumulibacter. The abundance of Clade-IIC as the most dominant clade reached 2.59 × 10~9 cells/g MLSS and accounted for 87.3% of total Accumulibacter. Clade IIC mainly contributed to denitrifying P removal. Clades IIA, IIC and IID were found in all processes, while clade-IIF was only found in oxidation ditch process through phylogenetic analysis. High proportion of clade IID to total Accumulibacter led to poor performance of aerobic P-uptake in inverted A^2O process. Therefore, Accumulibacter clades in WWTPs were diverse, and EBPR performance was closely related to the clade-level community structures and abundances of Accumulibacter.Wei Zeng Limin Zhang Pengchao Fan Jingjing Guo Yongzhen Peng 2018Journal of Environmental Sciences2018,30,5:6
5Metal-Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries显示文摘Aqueous zinc-ion batteries(AZIBs)are one of the promising energy storage systems,which consist of electrode materials,electrolyte,and separator.The first two have been significantly received ample development,while the prominent role of the separators in manipulating the stability of the electrode has not attracted sufficient attention.In this work,a separator(UiO-66-GF)modified by Zr-based metal organic framework for robust AZIBs is proposed.UiO-66-GF effectively enhances the transport ability of charge carriers and demonstrates preferential orientation of(002)crystal plane,which is favorable for corrosion resistance and dendrite-free zinc deposition.Consequently,Zn|UiO-66-GF-2.2|Zn cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h at 2.0 mA cm^(−2),and Zn|UiO-66-GF-2.2|MnO_(2) cells show excellent long-term stability with capacity retention of 85%after 1000 cycles.The reasonable design and application of multifunctional metal organic frameworks modified separators provide useful guidance for constructing durable AZIBs.Yang Song Pengchao Ruan Caiwang Mao Yuxin Chang Ling Wang Lei Dai Peng Zhou Bingan Lu Jiang Zhou Zhangxing He 2022Nano-Micro Letters2022,14,12:5
6Effect of boehmite sol on the crystallization behavior and densification of mullite formed from a sol-gel precursor显示文摘Hybrid mullite sol was synthesized from an aqueous solution of aluminum nitrate (AN), aluminum isopropoxide (AIP) and tetraethylorthosilicate (TEOS), doped with boehmite sol with different ratios. Pressureless sintering of the xerogel was carried out at different temperatures in the presence of boehmite doping. The xerogel and sintered powder were characterized by FTIR, TG-DSC, XRD, SEM and bulk density. The addition of boehmite caused the formation of metaphase spinel (6Al2O3·SiO2) crystal before the appearance of mullite phase, which could lead to the formation of amorphous phase and suppress the premature formation of mullite. Both of these effects improve the densification of mullite. A maximum density about 98% of the theoretical density (TD, 3.01 g/cm3 ) of mullite could be obtained for 5 wt% boehmite addition at 1200 1C pressureless sintering.Pengchao Liu Yizheng Zhu Jinghong Ma Shuguang Yang Jinghua Gong Jian Xu 2013Progress in Natural Science:Materials International2013,23,2:5
7Co3O4 modified Ag/g-C3N4 composite as a bifunctional cathode for lithium-oxygen battery显示文摘Rechargeable lithium-oxygen(Li-O2)batteries have appeal to enormous attention because they demonstrate higher energy density than the state-of-the-art Li-ion batteries.Whereas,their practical application is impeded by several challenging problems,such as the low energy round trip efficiencies and the insufficient cycle life,due to the cathode passivation caused by the accumulation of discharge products.Developing efficient catalyst for oxygen reduction and evolution reactions is effective to reduce the overpotentials in Li-O2cells.In our work,we report a Co3O4modified Ag/g-C3N4nanocomposite as a bifunctional cathode catalyst for Li-O2cells.The g-C3N4substrate prevents the accumulation of Ag and Co3O4nanoparticles and the presence of Ag NPs improves the surface area of g-C3N4and electronic conductivity,significantly improving the oxygen reduction/evolution capabilities of Co3O4.Due to a synergetic effect,the Ag/g-C3N4/Co3O4nanocomposite demonstrates a higher catalytic activity than each individual constituent of Co3O4or Ag/g-C3N4for the ORR/OER on as catalysts in Li-O2cells.As a result,the Ag/gC3N4/Co3O4composite shows impressive electrochemical performance in a Li-O2battery,including high discharge capacity,small gap between charge and discharge potential,and high cycling stability.Qi Guo Chenwei Zhang Chaofeng Zhang Sen Xin Pengchao Zhang Qiufan Shi Dawei Zhang Ya You 2020Journal of Energy Chemistry2020,29,2:4
8Rejecting Character Recognition Errors Using CNN Based Confidence Estimation显示文摘Although Optical character recognition(OCR) technology has achieved huge progress in recent years, character misrecognition is inevitable. In order to realize high fidelity content of document digitalization,we propose a new Convolutional neural networks(CNN)based confidence estimation method. We detect the misrecognized characters through comparing the confidence value with a preset threshold, so as to leave the recognition errors as embedded images in the output digital documents. We adopted sofmax as the estimation of posteriori probability,overlap pooling and maxout with dropout technologies in CNN architecture design. Experimental results show that our method has achieved an explicit improvement compared to baseline system.LI Pengchao PENG Liangrui WEN Juan 2016Chinese Journal of Electronics2016,25,3:4
9Synthesis, characteristics of hierarchical EU-1 zeolite for xylene isomerization probe reaction显示文摘Introduced a method of synthesizing hierarchical EU-1 zeolite with organosilanes as additive, and studied the influences of following different kinds of organosilanes on the synthesis of hierarchical EU-1 zeolite: γ-glycidoxy propyl trimethoxy silane(GPTMS), N-β-(aminoethyl)-γ-aminopropyl methyl dimethoxyl silane(APAEDMS),and N-(β-aminoethyl)-γ-aminopropyl dimethoxyl(ethyoxyl) silane(TMPED). The hierarchical EU-1 samples were characterized by XRD, SEM, N_2 adsorption, FT-IR and NH_3-TPD to analyze the crystallinity, morphology, surface area, pore size distribution and acidity. The results showed that hierarchical EU-1 zeolites were successfully synthesized; organosilanes have great influence on crystal morphology of EU-1 zeolites; the exterior surface area of hierarchical EU-1 zeolite, which synthesized with organosilanes(APAEDMS) adding into synthesis system, increased by 62.1% and mesopore volume increased by 129.1% compared with conventional EU-1 zeolites, thus can reduce the diffusional restriction markedly in catalytic reaction. The catalytic performance of hierarchical EU-1zeolites were evaluated in m-xylene isomerization on fixed bed reactor. The catalytic data showed that the isomerization activity PX/X of the hierarchical EU-1 zeolites reached around 24.09% in theoretical thermodynamic equilibrium from 23.83%, and the selectivity of C_8 aromatic hydrocarbon increased from 75.16% to 84.87%. The conversion of p-xylene increased from 16.30% to 18.41%.Xiaofeng Li Pengchao Ren Yanting Zhang Xiaozhen Liu Xiaotao Sun Meng Gao Miaojuan Jia Zhiping Lü Tao Dou 2016Chinese Journal of Chemical Engineering2016,24,11:4
10Methodology of drug screening and target identification for new necroptosis inhibitors显示文摘Apoptosis has been considered as the only form of regulated cell death for a long time. However, a novel form of programmed cell death called necroptosis was recently reported. The process of necroptosis is regulated and plays a critical role in the occurrence and development of multiple human diseases. Thus,the study on the molecular mechanism of necroptosis and its effective inhibitors has been an attractive field for researchers. Herein, we introduce the molecular mechanism of necroptosis and focus on the literature about necroptosis drug screening in recent years. In addition, the identification of the critical drug targets of the necroptosis is also discussed.Pengchao Pan Zhenyu Cai Chunlin Zhuang Xiaofei Chen Yifeng Chai 2019Journal of Pharmaceutical Analysis2019,9,2:3
11The 5400 a BP extreme weakening event of the Asian summer monsoon and cultural evolution显示文摘We explored a time series of the Asian summer monsoon(ASM) variability during the transition period from the middle to the late Holocene in the marginal Asian monsoon region. We used an absolutely dated ^(230)Th record with only a ~20-year dating error, and oxygen isotope data with an 8-year average temporal resolution from the top 22-mm segment of stalagmite WXB07-4 from Wanxiang Cave, western Loess Plateau. The ASM intensity weakened gradually from 6420 to 4920 a BP, which was mainly characterized by three phases:(1) a strengthening phase with a higher precipitation amount between 6420 and 6170 a BP;(2) a smooth fluctuating interval during 6170–5700 a BP; and(3) a sudden extreme weakening period from 5700 to 4920 a BP. Interestingly, the extreme weakening interval of the ASM occurred during the period between 5700 and 4920 a BP, an abrupt change dated at 5430 a BP, which is known as the 5400 a BP, or 5.4 ka BP, event. The period included 290 years of gradual weakening, and 350 years of slow strengthening. This was synchronous with some cave records from the Asian monsoon region within dating errors. Comparing with Chinese archaeological archives over the past 7000 years, the early decline of the Yangshao Culture in the Yellow River Basin and the Hongshan Culture in the West Liao River Basin occurred during the period of gradual decrease of ASM precipitation. The dramatic decline in precipitation, caused by the extreme weakening of the ASM at 5400 a BP,may have been partly related to the decline of the Miaodigou Culture at the Yangguanzhai site in the Weihe River valley; the middle Yangshao Culture in western Henan in the Yellow River Basin; the early Dawenkou Culture on the lower reaches of the Yellow River; and the middle Hongshan Culture in the west of the Liaohe River valley. During the later period of the 5400 a BP event(5430–4920 a BP), a small amplitude increase and a subsequent sharp decrease of ASM precipitation may have also been linked to the contemporaneous prosperity and disappearance of the late Yangshao and Hongshan cultures; the disappearance of the late Yangshao Culture represented by the Yangguanzhai site in the Guanzhong basin on the Weihe River; the fourth phase of the late Yangshao Culture on the upstream Dadiwan site; the beginning of the middle Dawenkou Culture, the formation of its late stage,and the rise of the Longshan culture; and the rise of the Qujialing and Liangzhu cultures on the lower Yangtze River. Compared with the stalagmite precipitation records on the Qinghai-Tibetan Plateau, the rise and expansion of the Majiayao Culture in the upper Yellow River valley at 5300 a BP may have also been connected to the more dramatic increase of the summer monsoon precipitation at higher, rather than lower, altitudes during the late 5400 a BP event.BAI YiJun ZHANG PingZhong GAO Tao YU RenZhe ZHOU PengChao CHENG Hai 2017Science China Earth Sciences2017,60,6:3
12Scalable and fast fabrication of graphene integrated micro-supercapacitors with remarkable volumetric capacitance and flexibility through continuous centrifugal coating显示文摘Microscale electrochemical energy storage devices,e.g., micro-supercapacitors(MSCs),possessing tailored performance and diversified form factors of lightweight,miniaturization,flexibility and exceptional integration are highly necessary for the smart power sources-unitized electronics.Despite the great progress,the fabrication of MSCs combining high integration with high volumetric performance remains largely unsolved.Herein,we develop a simple,fast and scalable strategy to fabricate graphene based highly integrated MSCs by a new effective continuous centrifugal coating technique.Notably,the resulting highly conductive graphene films can act as not only patterned microelectrodes but also metal-free current collectors and interconnects,endowing modular MSCs with high integrity,remarkable flexibility,tailored voltage and capacitance output,and outstanding performance uniformity.More importantly,the strong centrifugal force and shear force generated in continuous centrifugal coating process lead to graphene films with high alignment,compactness and packing density,contributing to excellent volumetric capacitance of ~31.8 F cm^(-3) and volumetric energy density of ~2.8 mWh cm^(-3),exceeding most reported integrated MSCs.Therefore,our work paves a novel way for simple and scalable fabrication of integrated MSCs and offers promising opportunities as standalone microscale power sources for new-generation electronics.Xiaoyu Shi Lijun Tian Sen Wang Pengchao Wen Ming Su Han Xiao Pratteek Das Feng Zhou Zhaoping Liu Chenglin Sun Zhong-Shuai Wu Xinhe Bao 2021Journal of Energy Chemistry2021,30,1:3
13Three-Dimensional Self-assembled Hairball-Like VS4 as High-Capacity Anodes for Sodium-Ion Batteries显示文摘Sodium-ion batteries(SIBs)are considered to be attractive candidates for large-scale energy storage systems because of their rich earth abundance and consistent performance.However,there are still challenges in developing desirable anode materials that can accommodate rapid and stable insertion/extraction of Na+and can exhibit excellent electrochemical performance.Herein,the self-assembled hairball-like VS4 as anodes of SIBs exhibits high discharge capacity(660 and 589 mAh g−1 at 1 and 3 A g−1,respectively)and excellent rate property(about 100%retention at 10 and 20 A g−1 after 1000 cycles)at room temperature.Moreover,the VS4 can also exhibit 591 mAh g−1 at 1 A g−1 after 600 cycles at 0°C.An unlike traditional mechanism of VS4 for Na+storage was proposed according to the dates of ex situ characterization,cyclic voltammetry,and electrochemical kinetic analysis.The capacities of the final stabilization stage are provided by the reactions of reversible transformation between Na2S and S,which were considered the reaction mechanisms of Na–S batteries.This work can provide a basis for the synthesis and application of sulfur-rich compounds in fields of batteries,semiconductor devices,and catalysts.Shuangshuang Ding Bingxin Zhou Changmiao Chen Zhao Huang Pengchao Li Shuangyin Wang Guozhong Cao Ming Zhang 2020Nano-Micro Letters2020,12,3:3
14Nonswellable hydrogels with robust micro/nano-structures and durable superoleophobic surfaces under seawater显示文摘Hydrogels, composed mainly of water trapped in three dimensional cross-linked polymer networks, have been widely utilized to construct underwater superoleophobic surfaces. However, the swelling nature and instability of hydrogels under complex marine environment will weaken their underwater superoleophobicity. Herein, we synthesize structured poly(2-hydroxyethylmethacrylate)(PHEMA) hydrogels by using sandpaper as templates. The robust non-swelling of PHEMA hydrogel ensures that micro/nano-structures on the surface of PHEMA hydrogels can be well maintained. Moreover, when roughness Ra of about 3~4 μm, the surface has superior oil-repellency. Additionally, even after immersing in seawater for one-month, their breaking strength and toughness can be well kept. The non-swellable hydrogels with long-term stable under seawater superoleophobicity will promote the development of robust superoleophobic materials in marine antifouling coatings,biomedical devices and oil/water separation.Ling Lin Hui Yi Xinglin Guo Pengchao Zhang Lie Chen Dezhao Hao Shutao Wang Mingjie Liu Lei Jiang 2018Science China Chemistry2018,61,1:3
15High-pressure phases of Weyl semimetals NbP, NbAs, TaP,and TaAs显示文摘In this study, we used the crystal structure search method and first-principles calculations to systematically explore the highpressure phase diagrams of the TaAs family(NbP, NbAs, TaP, and TaAs). Our calculation results show that NbAs and TaAs have similar phase diagrams, the same structural phase transition sequence I4_1 md→P6 m2→P2_1/c→Pm3 m, and slightly different transition pressures. The phase transition sequence of NbP and TaP differs somewhat from that of NbAs and TaAs, in which new structures emerge, such as the Cmcm structure in NbP and the Pmmn structure in TaP. Interestingly, we found that in the electronic structure of the high-pressure phase P6 m2-NbAs, there are coexistingWeyl points and triple degenerate points, similar to those found in high-pressure P6 m2-TaAs.ZhaoPeng Guo PengChao Lu Tong Chen JueFei Wu Jian Sun DingYu Xing 2018Science China(Physics,Mechanics & Astronomy)2018,61,3:2
16Multi-functional vesicles improve Helicobacter pylori eradication by a comprehensive strategy based on complex pathological microenvironment显示文摘Helicobacter pylori(H.pylori),creating a global infection rate over 50%,presents great challenges in clinical therapies due to its complex pathological microenvironment in vivo.To improve the eradication efficacy,herein we fabricated a pharmaceutical vesicle RHL/Cl-Ch-cal where cholesterol-PEG,calcitriol and first-line antibiotic clarithromycin were co-loaded in the rhamnolipid-composed outer lipid layer.RHL/Cl-Ch-cal could quickly penetrate through gastric mucus layer to reach H.pylori infection sites,and then effectively destroyed the architecture of H.pylori biofilms,killed dispersed H.pylori and inhibited the re-adhesion of residual bacteria(called biofilms eradication tetralogy).Moreover,RHL/Cl-Ch-cal activated the host immune response to H.pylori by replenishing cholesterol to repair lipid raft on the cell membrane of host epithelial cells.Finally,RHL/Cl-Ch-cal killed the intracellular H.pylori through recovering the lysosomal acidification and assisting degradation.In experiments,RHL/Cl-Ch-cal demonstrated prominent anti-H.pylori efficacy in the classical H.pylori-infected mice model.Therefore,the study provides a“comprehensive attack”strategy for anti-H.pylori therapies including biofilms eradication tetralogy,immune activation and intracellular bacteria killing.Xiaonan Chen Yiqing Zou Shuqi Zhang Pengchao Fang Shuxuan Li Pengyu Li Yingying Sun Gang Yuan Haiyan Hu 2022Acta Pharmaceutica Sinica B2022,12,9:2
17Development of Bioimplants with 2D, 3D, and 4D Additive Manufacturing Materials显示文摘Over the past 30 years,additive manufacturing(AM)has developed rapidly and has demonstrated great potential in biomedical applications.AM is a materials-oriented manufacturing technology,since the solidification mechanism,architecture resolution,post-treatment process,and functional application are based on the materials to be printed.However,3D printable materials are still quite limited for the fabrication of bioimplants.In this work.2D/3D AM materials for bioimplants are reviewed.Furthermore,inspired by Tai Chi,a simple yet novel soft/rigid hybrid 4D AM concept is advanced to develop complex and dynamic biological structures in the human body based on 4D printing hybrid ceramic precursor/ceramic materials that were previously developed by our group.With the development of multi-material printing technology,the development of bioimplants and soft/rigid hybrid biological structures with 2D/3D/4D AM materials can be anticipated.Guo Liu Yunhu He Pengchao Liu Zhou Chen Xuliang Chen Lei Wan Ying Li Jian Lu 2020Engineering2020,6,11:1
18Bacillus amyloliquefaciens Q‐426 as a potential biocontrol agent against Fusarium oxysporum f. sp. spinaciae显示文摘Pengchao Zhao Chunshan Quan Yingguo Wang Jianhua Wang Shengdi Fan 2014J. Basic Microbiol2014,,5:1
19A creatinine-based model for predicting recurrent bleeding after modified percutaneous transhepatic variceal embolization in patients with cirrhosis显示文摘Background:Patients who survive initial esophagogastric variceal bleeding(EVB)are at an increased risk of recurrent bleeding and death;however,a reliable predictive model is lacking.We aimed to develop a model for rebleeding prediction in patients with EVB after modified percutaneous transhepatic variceal embolization(PTVE)with cyanoacrylate.Methods:A total of 122 patients with EVB who underwent PTVE from January 2015 to November 2020 were enrolled.Multivariate logistic analyses were conducted to determine independent risk factors for nomogram construction.The discrimination,calibration,and clinical utility of the nomogram were compared with the Model for End-stage Liver Disease score(MELD)and the Child–Pugh model.Risk stratification was performed according to the nomogram.Results:Rebleeding within 3 months of PTVE occurred in 32 patients(26.2%).Independent rebleeding indicators included prior history of endoscopic therapy,Child–Pugh score,partial splenic embolization,and creatinine level.The nomogram incorporating these four predictors achieved excellent calibration and discriminatory abilities,with a concordance index of 0.85,which was confirmed to be 0.83 through bootstrapping validation.The nomogram demonstrated superior discrimination and clinical applicability than the MELD and Child–Pugh models.As shown in the Kaplan–Meier curves,high-risk patients had a high probability of rebleeding(P<0.001).Conclusions:The creatinine-based nomogram had a superior ability to predict rebleeding after PTVE in patients with EVB.Risk stratification may help identify high-risk patients and lead to the earlier implementation of aggressive treatments and formulation of intensive follow-up plans.Kun Ji Xin Li Hanlong Zhu Si Zhao Pengchao Zhan Yang Shi Shuwen Ye Bingcan Xie Yuyuan Zhang Peng Yu Zhigang Ren Juan Ding Xinwei Han Zhen Li 2022Journal of Interventional Medicine2022,5,2:1
20Spectrum Sharing in Cognitive Radio Networks--An Auctionbased Approach显示文摘Wang Xinbing Li Zheng Xu Pengchao 2010IEEE Transactions on Systems Man and Cybernetics Part B:Cybernetics2010,40,3:1
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