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| 1 | Single-atom site catalysts for environmental catalysis显示文摘In recent decades,the environmental protection and long-term sustainability have become the focus of attention due to the increasing pollution generated by the intense industrialization.To overcome these issues,environmental catalysis has increasingly been used to solve the negative impact of pollutants emission on the global environment and human health.Supported platinum-metal-group(PGM)materials are commonly utilized as the state-of-the-art catalysts to eliminate gaseous pollutants but large quantities of PGMs are required.By comparison,single-atom site catalysts(SACs)have attracted much attention in catalysis owing to their 100%atom efficiency and unique catalytic performances towards various reactions.Over the past decade,we have witnessed burgeoning interests of SACs in heterogeneous catalysis.However,to the best of our knowledge,the systematic summary and analysis of SACs in catalytic elimination of environmental pollutants has not yet been reported.In this paper,we summarize and discuss the environmental catalysis applications of SACs.Particular focus was paid to automotive and stationary emission control,including model reaction(CO oxidation,NO reduction and hydrocarbon oxidation),overall reaction(three-way catalytic and diesel oxidation reaction),elimination of volatile organic compounds(formaldehyde,benzene,and toluene),and removal/decomposition of other pollutants(Hg0 and SO3).Perspectives related to further challenges,directions and design strategies of single-atom site catalysts in environmental catalysis were also provided. | Ningqiang Zhang Chenliang Ye Han Yan Lingcong Li Hong He Dingsheng Wang Yadong Li | 2020 | Nano Research2020，13，12： | 38 |
| 2 | Use of rare earth elements in single-atom site catalysis:A critical review——Commemorating the 100th anniversary of the birth of Academician Guangxian Xu显示文摘Rare earth metals are strategic resources with potential applications in optics,metallurgy and catalysis.In recent years,single-atom site catalysts(SASCs) have attracted increasing attention owing to their 100%atom efficiency and unique catalytic performances.Over the past decade,rare earth elements,including rare earth metals and their oxides,have shown great potential in SASCs.However,systematic analyses of data are still handful.In this mini-review,the use of rare earth metals and their oxides in SASCs was summarized and the results are discussed.A particular focus was paid to the synthetic strategies,characterization of rare earth-containing SASCs,and applications as catalysis supports,promoters and active sites.Current issues faced by rare-earth metals and their oxides in SASCs,as well as future prospects were also provided. | Ningqiang Zhang Han Yan Lingcong Li Rui Wu Liyun Song Guizhen Zhang Wenjun Liang Hong He | 2021 | Journal of Rare Earths2021，39，3： | 4 |
| 3 | Lower temperature synthesis of cerium-doped polycrystalline lutetium pyrosilicate powders by a novel sol-gel processing显示文摘A novel sol-gel processing was developed to synthesize polycrystalline cerium-doped lutetium pyrosilicate(Lu2Si2O7:Ce,LPS:Ce)powders under low temperature.It was found that the addition of propylene oxide(PPO)could promote the formation of Lu-O-Si bonds in precursor,which was beneficial to the formation of LPS phase.X-ray diffraction(XRD)patterns indicated that the single-phased LPS powder was well crystallized at 1050°C.Microstructure observation demonstrated that the synthetic LPS powder was composed of ellipsoidal grains with the mean size of 40 nm.The luminescent properties were characterized by photoluminescence(PL),X-ray excited luminescence(XEL)and vacuum ultraviolet(VUV)spectroscopy at room temperature.The synthetic LPS:Ce powder emitted a broad emission spectrum centered at about 380 nm,which should be ascribed to the 5d→4f transition of Ce3+.Decay time of the synthetic LPS:Ce powder was measured to be only 32 ns. | FAN LingCong XU Jian SHI Ying XIE JianJun LEI Fang | 2014 | Science China(Technological Sciences)2014，57，8： | 3 |
| 4 | Efficacy of Sanqi(Radix Notoginseng)in treating cerebral hemorrhage in rats with traumatic brain injury显示文摘OBJECTIVE:To evaluate the protective efficacy of Sanqi(Radix Notoginseng)on cerebral hemorrhage in a rat model of traumatic brain injury(TBI)by investigating plasminogen activator inhibitor-1(PAI-1),tissue-type plasminogen activator(t-PA),nuclear factor-κB(NF-κB,p-p65),nitric oxide(NO),endothelin(ET),cluster differentiation(CD61CD62),and coagulation.METHODS:The free-fall method was used to create a rat model of TBI.Forty-eight rats were randomly divided into six groups:the blank group,sham group,model group,low-dose Sanqi(Radix Notoginseng)group,middle-dose Sanqi(Radix Notoginseng)group,and high-dose Sanqi(Radix Notoginseng)group.At 24 h after the model was created,we investigated brain MRI,brain tissue morphology using HE staining,flow cytometry,and immunohistochemical changes.RESULTS:Cerebral hemorrhage was aggravated in TBI rats(observed in brain specimens,brain MRI,and brain tissue HE).Cerebral immunohistochemistry results demonstrated that the expression of t-PA,PAI-1 and p-p65 increased significantly in TBI rats,while t-PA/PAI-1 had a significant decrease.In addition,CD61CD62,D2D,and ET were significantly increased in TBI rats,and PT and APTT were significantly prolonged;in contrast,NO was significantly decreased.Sanqi(Radix Notoginseng)decreased cerebral hemorrhage in TBI rats(observed in brain MRI and brain tissue HE),and increased t-PA/PAI-1,CD61CD62 significantly.It also significantly decreased the expression of t-PA,PAI-1,and p-p65 in brain immunohistochemistry and significantly decreased PT,APTT,D2D,and ET.However,there were no differences in NO between the model group and the Sanqi(Radix Notoginseng)group.CONCLUSION:Sanqi(Radix Notoginseng)can decrease the expression of p-p65,increase t-PA/PAI-1,and stem traumatic intracranial hemorrhage in a TBI rat model. | JIANG Tao ZHOU Xiaqing JIANG Huifang YING Rongbiao ZHANG Zhirong CAI Danli WU Yu FANG Haijun WANG Lingcong | 2021 | Journal of Traditional Chinese Medicine2021，41，2： | 2 |
| 5 | Nonlinear state-observer design and applications: part Ⅰ显示文摘 | Chen Lingcong Yuan Pu | 2001 | Control and Instruments in Chemical Industry2001，28，： | 1 |
| 6 | Blood circulation activating effect of Sanqi(Radix Notoginseng) on venous thromboembolism rats显示文摘OBJECTIVE:To explore the blood circulation activating effect and mechanism of Sanqi(Radix Notoginseng)in vivo,using a venous thromboembolism(VTE)rat model.METHODS:We established the VTE rat model,and then intervened with low molecular weight hepa-rin(LMWH),as well as low,medium and high doses of Sanqi(Radix Notoginseng),to observe the blood circulation activating effect of Sanqi(Radix Notoginseng)on VTE rats.RESULTS:After the treatment with high concentrations of Sanqi(Radix Notoginseng),the pulmonary thromboembolism was alleviated,and the lower limb thrombosis was markedly improved.Moreover,the expression quantities of plasma activated partial thromboplastin time,prothrombin time and D-dimer,as well as endothelin,von Willebrand factor,and plasminogen activator inhibitor-1 in thrombosis segment tissues were markedly down-regulated;while those of nitric oxide and tissue-type plasminogen activator were up-regulated.After low and medium concentration Sanqi(Radix Notoginseng)treatment,no obvious improvement was observed in each index.Moreover,the high concentration Sanqi(Radix Notoginseng)showed comparable efficacy to the positive drug LMWH.CONCLUSION:This data suggests that high concentration of Sanqi(Radix Notoginseng)is effective in preventing and treating VTE. | ZHU Chen JIANG Huifang ZHOU Xiaqing ZHANG Zhirong WU Yu FANG Haijun WANG Lingcong | 2021 | Journal of Traditional Chinese Medicine2021，41，5： | 1 |
| 7 | Consolidation of translucent Ce3+-doped Lu2SiO5 scintillation ceramics by pressureless sintering显示文摘 | Lingcong Fan Ying Shi Jian Xu Jianjun Xie Fang Lei | 2014 | Journal of Materials Research2014，，19： | 1 |
| 8 | Nonlinear state-observer design and applications: part Ⅰ显示文摘 | Chen Lingcong Yuan Pu | 2001 | Control and Instruments in Chemical Industry2001，28，： | 1 |
| 9 | Effects of Ce 3+ doping concentrations on microstructure and luminescent properties of Ce 3+ :Lu 3 Al 5 O 12 (Ce:LuAG) transparent ceramics显示文摘 | Jian Xu Lingcong Fan Ying Shi Junlang Li Jianjun Xie Fang Lei | 2014 | Optical Materials2014，，： | 1 |
| 10 | Oxidation of Dibenzothiophene in Model Diesel Using Hydroperoxide Generated via In-Situ Reaction of Octane with Oxygen显示文摘The potential of carrying out oxidative desulfurization(ODS) using oxygen as an oxidant was explored in this work. n-Octane firstly reacted with oxygen to produce hydroperoxides in-situ, which were then used as oxidants to oxidize the dibenzothiophene(DBT) in the absence of catalysts. The hydroperoxides generated in-situ were effective in oxidizing DBT to its corresponding dibenzothiophene sulfone(DBTO_2) which was characterized by FT-IR and ~1H-NMR. The removal rate of DBT could reached 98.4% under conditions covering a temperaure of 140℃, a rection duration of 4 h, and an oxygen partial pressure of 0.4 MPa. The influences of different hydrocarbon components in diesel on DBT removal were investigated. The results showed that cyclohexane and n-dodecane had no effect on the removal of DBT, but xylene had a slight negative effect on DBT removal. A possible oxidation mechanism was proposed and the concentration of hydroperoxides in both O_2-oxidized octane and model diesel were detected. | Guo Erliang Li Jianxin Huang Xiaoqiao Duan Yongshen Zhang Lingcong Yan Lijun Lu Shuxiang | 2018 | China Petroleum Processing & Petrochemical Technology2018，20，1： | 1 |
| 11 | A switching-based backstepping sliding mode control for space manipulator in presence of gravity variation显示文摘A novel switching-based backstepping sliding mode control(SBSMC) scheme is devised for the space manipulator exposed to different gravity.With a view to distinct differences in dynamics properties when the operating conclition of space manipulator changer,the space manipulator can be thought of as a system composed of two subsystems,the ground subsystem and the space subsystem.Two different types of backstepping sliding mode(BSM) controllers are designed,one is suited for the ground subsystem and the other is for the space one.The switching between two subsystems can be implemented automatically when the switching mechanism is triggered,and the controllers for their subsystems experience synchronous switching.In this way,the space manipulator always has good behaviors in trajectory tracking.Moreover,multi-Lyapunov functions are introduced to prove the stability of this switching approach.According to simulation results,the method constructed in this research has better performance in control precision and adaptability compared with proportional-derivative(PD) control. | 刘福才 Zhao Wenna Meng Lingcong Liu Shuo | 2021 | High Technology Letters2021，27，4： | 0 |
| 12 | Two-Step Preparation of Hierarchical Porous Carbon Materials Derived from Tannin for Use as an Electrode Material for Supercapacitors显示文摘The development and utilization of biomass and agroforestry processing byproducts for high-value applications have been an important topic in the field of renewable materials research.Based on this,a two-step microwave hydrothermal pre-carbonization and KOH activation method was proposed to synthesize tannin-based activated carbons with a high specific surface area,hierarchical pore structure,and good electrochemical performance.The microstructure,texture properties,and physicochemical characteristics were investigated.The results show that the prepared tannin-based activated carbons presented a hierarchical pore structure(micro-and mesopores)with a specific surface area as high as 997.46 m^(3) g^(−1).The electrochemical analysis shows that the tannin-based activated carbons have good wettability and charge transfer rates.Under the three-electrode system with 6 M KOH as the electrolyte,the active material TAC_(600-4) had a maximum specific capacitance of 171 F g^(−1)at 0.5 A g^(−1).As the current density increases to 10 A g^(−1),the specific capacitance can still be maintained at 149 F g^(−1),indicating a good rate capability.Therefore,the specific surface area and pore size of tannin-based activated carbons can be effectively adjusted by the alkali/carbon ratio,making it a promising supercapacitor electrode material and providing a new method for the high-value development of tannins in the field of electrochemical energy storage. | Jianping Deng Qianqian Zhang Yuling Lan Lingcong Luo Zimin Dai Zhonghang Lin Zhixin Lu Jiancheng Yuan Yiqi Fu Lu Luo Weigang Zhao | 2023 | Journal of Renewable Materials2023，11，6： | 0 |
| 13 | A novel Eu^(3+)-doped phosphor-in-glass for WLEDs and the effect of borophosphate matrix显示文摘Phosphor-in-glass(PiG)is a potential color convertor for high power WLEDs.A novel glass matrix with advanced performance is still a challenge.Recently,Eu^(3+)doped glass matrix has attracted much consideration mainly due to its red compensation.A new borophosphate matrix to realize Eu^(3+)red light was designed in the Na_(2)O-ZnO-P_(2)O_(5)-B_(2)O_(3)-Eu_(2)O_(3)system.Meanwhile,a series of PiGs composed of different concentrations of Y3Al5O12:Ce phosphor and the matrix were also fabricated by re-sintering.The crystallization of Eu^(3+)based phosphate offers a novel red emission quenching apart from normal concentration quenching in the glass system.No direct energy transfer but only little reabso rption occurs between Eu^(3+)and Ce^(3+)ions.The Ce^(3+)concentration effect is obvious on the electroluminescent color.The optimized color rendering index of 79.7,the CIE coordinates near natural white and the range of CCT from 3943 to 6097 K were obtained for the packaged white light emitting diodes(WLEDs)together with the excellent CCT stability higher than about 97.5%and the quadruple thermal conductivity than that of silicon resin.The work implies borophosphate glass based PiGs with fine transparence and energy conversion efficiency are promising for excellent WLEDs,while the LED by using the PiG sample without any yellow phosphor doped is of high color purity and has a potential use as the 465 nm blue source. | Teng Ma Haohong Chen Luqiao Yin Fang Lei Ying Shi Jianjun Xie Lei Zhang Lingcong Fan | 2023 | Journal of Rare Earths2023，41，2： | 0 |
| 14 | In-situ DRIFT assessment on strengthening effect of cerium over FeO_(x)/TiO_(2)catalyst for selective catalytic reduction of NO_(x) with NH_(3)显示文摘Fe-based catalysts have a great potential to be used for selective catalytic reduction(SCR)of NO_(x)with NH3 reaction due to their low cost,nontoxicity and excellent catalytic activity.The aim of this paper is to investigate Ce doping effect on activity of NH_(3)-SCR over the FeO_(x)/TiO_(2)catalyst.In-situ diffuse reflectance infrared fourier transform(DRIFT)technology was utilized to verity the adsorbed species on the surface of FeO_(x)/TiO_(2)and FeO_(x)-CeO_(2)/TiO_(2)catalysts.With respect to the obtained results,among the four catalysts studied,the FeO_(x)-CeO_(2)/TiO_(2)with the FeO_(x)/CeO_(2)ratio of 3/8 shows the best NO conversion more than 98%in the temperature range of 230—350℃,The active centers for NH_(3)adsorption and activation are assigned to Lewis acid sites over the FeO_(x)-CeO_(2)/TiO_(2)and monodentate nitrates can act as the key intermediate in the NH3-SCR.Moreover,both of Langmuir-Hinshelwood and Eley-Rideal mechanisms are observed over the FeO_(x)-CeO_(2)/TiO_(2)catalysts in the SCR. | Hossein Chitsazi Ningqiang Zhang Lingcong Li Xiaojun Liu Rui Wu Junda He Liyun Song Hong He | 2021 | Journal of Rare Earths2021，39，5： | 0 |
| 15 | Polycrystalline Lutetium-based Scintillation Ceramics: Fabrication, Microstructure and Scintillation Properties显示文摘Scintillation material is a kind of crucial material for radiation detection in the fields of nuclear medicine diagnosis,high energy physics,security inspection and oil well logging.An excellent scintillation material should possess the merits of high density,high light yield and | ying shi lingcong fan jianjun xie | 2016 | 功能材料信息2016，13，1： | 0 |
| 16 | Fabrication and luminescence of highly transparent C12A7:Tb^(3+)glass-ceramics via in-situ crystallization from aerodynamic levitation processed glasses显示文摘Rare earth doped 12CaO·7Al_(2)O_(3)(C12A7)glass-ceramics are one of attractive photonic materials due to their high transparency,high luminescent efficiency and eco-friendly nature.A series of C12A7 glasses with different Tb^(3+)doping concentrations was prepared by aerodynamic levitation method.The C12A7:Tb glass-ceramics were obtained via in-situ growth from the glasses with the identical chemical composition at 800℃.The microstructure observation demonstrates that the elemental distributions of Ca and Al are homogeneous in the glass-ceramics and the grain size of C12A7 is 4-70 nm.The in-line transmittance of glass-ceramics reaches as high as 82%at 1500 nm.The emission spectra of the C12A7:Tb glass-ceramics present characteristic Tb^(3+)emission peaks at 486 nm(^(5)D_(4)→^(7)F_6),541 nm(^(5)D_(4)→^(7)F_(5)),585 nm(^(5)D_(4)→^(7)F_(4))and 621 nm(^(5)D_(4)→^(7)F_(3)).The photolumine scence lifetime of C12A7:0.3%Tb glass-ceramic is 1.9 ms.Compared with the emission intensity of the glasses,that of the glass-ceramics increases due to the reducing in concentration of oxygen vacancy associated with network forming(NWF)cations.The highly transparent C12A7:Tb glass-ceramics may be a promising candidate for green light source in solid state lighting. | Yaling Zhang Lingcong Fan Xuefeng Wang Jiansheng Xie Ying Shi | 2023 | Journal of Rare Earths2023，41，11： | 0 |
| 17 | Atomic dispersion of bulk/nano metals to atomic-sites catalysts and their application in thermal catalysis显示文摘Supported metal-group materials are commonly utilized as state-of-the-art catalysts in industry.Atomic-sites catalysts(ASCs)have attracted increasing attention in catalysis owing to their 100%atom efficiency and unique catalytic performances toward various reactions.In particular,atomic dispersion of bulk and nano metals has become the focus of research and development in the synthesis of ASCs.Over the past decade,burgeoning interests have been paid to atomic dispersion in ASCs and their applications in catalysis.However,to the best of our knowledge,the systematic summary and analysis of atomic dispersion were rarely reported.In this review,recently developed ASCs by atomic dispersion were discussed in terms of synthetic atmosphere,driving force,applications in thermal catalytic reactions.Perspectives related to challenges and directions as well as design strategies of ASCs in atomic dispersion were also provided. | Lingcong Li Ningqiang Zhang | 2023 | Nano Research2023，16，5： | 0 |
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