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| 1 | Surface functionalized N-C-TiO_(2)/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H generation显示文摘Surface-functionalized nitrogen/carbon co-doped polymorphic TiO_(2) phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal-organic framework(MOF),NH_(2)-MIL^(-1)25(Ti) at 700℃ under water vapour atmosphere.Introducing water vapour during the pyrolysis of NH_(2)-MIL^(-1)25(Ti) not only functionalizes the derived porous carbon matrix with carboxyl groups but also forms additional oxygen-rich N like interstitial/intraband states lying above the valence band of TiO2 along with the self-doped carbo n,which further narrows the energy band gaps of polymorphic TiO2 nanoparticles that enhance photocatalytic charge transfer efficiency.Without co-catalyst,sample N-C-TiO2/CArW demonstrates H_(2) evolution activity of 426 μmol gcat-1h^(-1),which remarkably outperforms commercial TiO_(2)(P-25) and N-C-TiO_(2)/CAr with a 5-fold and 3-fold H_(2) generation,respectively.This study clearly shows that water vapour atmosphere during the pyrolysis increases the hydrophilicity of the Ti-MOF derived composites by functionalizing porous carbon matrix with carboxylic groups,as well as enhancing the electrical conductivity and charge transfer efficiency due to the formation of additional localized oxygen-rich N like interstitial/intraband states.This work also demonstrates that by optimizing the anatase-rutile phase composition of the TiO2 polymorphs,tuning the energy band gaps by N/C co-doping and functionalizing the porous carbon matrix in the N-C-TiO2/C nanocomposites,the photocatalytic H_(2) generation activity can be further enhanced. | Mian Zahid Hussain Zhuxian Yang Bart van der Linden Zheng Huang Quanli Jia Erik Cerrato Roland A.Fischer Freek Kapteijn Yanqiu Zhu Yongde Xia | 2021 | Journal of Energy Chemistry2021，30，6： | 3 |
| 2 | 显示文摘 | Kapteijn Freek Heiszwolf Johan J Nijhuis T A (Xander) | 1999 | CATTECH1999，3，： | 2 |
| 3 | 显示文摘 | Kapteijn F Nijhuis T A Heiszwolf J J | 2001 | Catalysis Today2001，66，： | 2 |
| 4 | Preoperative radiotherapy combined with total mesorectal excision for respectable rectal cancer显示文摘 | Kapteijn E Marijnen CA Nagtegaal ID | 2001 | N Engl J Med2001，345，9： | 1 |
| 5 | Catalytic oxidation of model soot by metal chlorides 显示文摘 | Mul G Kapteijn F Moulijn J A | 1997 | Applied Catalysis B: Environmental1997，12，： | 1 |
| 6 | The role of the active phase of Raney-type Ni catalysts in the selective hydrogenation of d -glucose to d -sorbitol显示文摘 | B.W Hoffer E Crezee F Devred P.R.M Mooijman W.G Sloof P.J Kooyman A.D van Langeveld F Kapteijn J.A Moulijn | 2003 | Applied Catalysis A General2003，，2： | 1 |
| 7 | Practical approachto zeolite membranes and coatings state of the art,oppor-tunities ,barriers,and future perspectives 显示文摘 | Gascon J Kapteijn F Zomoza B | 2012 | Chem Ma-ter2012，24，： | 1 |
| 8 | Carbon-based monolithic supports for palladium catalysts: The role of the porosity in the gas-phase total combustion of m-xylene显示文摘 | Perez-Cadenas A F Morales-Torres S Kapteijn F | 2008 | Applied Catalysis B: Environmental2008，77，34： | 1 |
| 9 | Catalyst deactivation: Is it predictable? What to do? 显示文摘 | Moulijn J A Diepen A E Kapteijn F | 2001 | Appl Catal A=Gen2001，212，： | 1 |
| 10 | Zeolite based films,membranes and membrane reactors:progress and prospects显示文摘 | McLeary E E Jansen J C Kapteijn F | | 0，，1： | 1 |
| 11 | Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia显示文摘 | KAPTEIJN F SINGOREDJO L ANDREINI A MOULIJN J A | 1994 | Appl Cata B: Environ1994，3，23： | 1 |
| 12 | Manufacture of dense coatings of Cu3 (BTC)2 (HKUST- 1) on a-alumina 显示文摘 | Gascon J Aguado S Kapteijn F | 2008 | Microporous and Mesoporous Materials2008，113，123： | 1 |
| 13 | Kinetics of the hydrodenitrogenation of orthopropylaniline over NiMo(P)/Al2O3 catalysts显示文摘 | Jian M Kapteijn F Prins R | 1997 | J Catal1997，168，2： | 1 |
| 14 | Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis 显示文摘 | PELS J R KAPTEIJN F MOULIJN J A | 1995 | Carbon1995，33，11： | 1 |
| 15 | Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric-oxide with amonia显示文摘 | Singoredjo L Andreini A | 1994 | Applied Catalysis B: Environmental1994，3，： | 1 |
| 16 | Transition metal oxide catalyzed carbon black oxidation : A study with 1802 显示文摘 | MUL G KAPTEIJN F DOORNKAMP C MOUL1JN J A | 1998 | J Catal1998，179，1： | 1 |
| 17 | Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis显示文摘 | J.R. Pels F. Kapteijn J.A. Moulijn Q. Zhu K.M. Thomas | 1995 | Carbon1995，，11： | 1 |
| 18 | Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia 显示文摘 | Kapteijn F Singoredjo L Andreini A | 1994 | Applied Catalysis B:Environmental1994，3，1： | 1 |
| 19 | Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis显示文摘 | Pels J R Kapteijn F Moulijn J A | 1995 | Carbon1995，33，： | 1 |
| 20 | Catalyst deactivation:Is it predictable? What to do?显示文摘 | MOULIJN J A van DIEPEN A E KAPTEIJN F | 2001 | Appl Catal A2001，212，12： | 1 |
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