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| 1 | 化学镀法制备CoP量子点修饰g-C3N4用于光催化产氢(英文)显示文摘光催化分解水制氢被认为是解决当前能源危机和环境污染问题的重要途径之一.在众多光催化剂中,石墨相氮化碳(g-C3N4)因其具有高的热稳定性、高的化学稳定性、合适的能带位置以及成本低廉等优点,受到光催化领域研究者的广泛关注,成为研究热点.然而,由于g-C3N4的禁带宽度较大(Eg=2.7 eV),导致其对可见光的响应较差,而且光生电子-空穴对在其中易于复合,从而导致其光催化产氢活性较低.已有研究表明,助催化剂可以有效地促进催化剂中光生载流子的分离和传输,从而提高光催化剂的光催化活性和氢气的产生速率.目前使用最广泛的助催化剂多为贵金属(Au,Ag,Pt和Pd等),然而贵金属储量低、成本高,极大地限制了其实际应用.因而,开发适用于光催化水分解制氢的非贵金属助催化剂成为该领域的研究热点.其中,用非贵金属助催化剂修饰g-C3N4制备高效光催化剂分解水制氢技术引起了人们极大的兴趣.过渡金属磷化物(FeP,CoP,CuP,NiP等)是一种有效的光催化辅助催化剂.然而,这些金属磷化物的合成通常使用有毒的有机磷化合物和白磷或涉高温煅烧.特别是在传统水热法制备金属磷化物过程中会释放大量氢气,导致容器内压力过高,造成较大的安全问题.据报道,在这些磷化物中,磷化钴由于其合适的能带结构和较高的导电性,作为光催化分解水助催化剂受到了广泛关注.然而,截至目前,关于磷化钴作为助催化剂用于光催化的实用技术报道很少,特别是在温和条件下制备磷化钴修饰的g-C3N4复合光催化剂的研究还有待进行.本文研究了以CoP作为助催化剂来改进g-C3N4(制备g-C3N4/CoP),并用于光催化水裂解制氢气.复合光催化剂g-C3N4/CoP经由两步反应合成.第一步采用尿素热分解法制备g-C3N4,第二步通过化学镀法将CoP修饰在g-C3N4表面.采用XRD,TEM,UV-DRS和XPS等手段表征了g-C3N4/CoP光催剂的性质.结果表明,CoP以量子点(QDs)形式均匀分布在g-C3N4表面,显著提高了g-C3N4的光催化活性.不同CoP负载量的样品中,g-C3N4/CoP-4%表现出优异的光催化活性,H2生成速率为936μmol g^-1 h^-1,甚至高于4%Pt负载的g-C3N4(H2的生成速率仅为665μmol g^-1 h^-1).从紫外可见光谱上看,g-C3N4在451 nm达到吸收波长上限,但与CoP复合后,g-C3N4/CoP-4%的吸收波长上限延展到497 nm.此外,光致发光和光电流测试结果证实,将CoP量子点负载到g-C3N4上不仅可以降低光生电荷-空穴对的复合,而且可以改善光生e--h+对的转移,从而提高光催化剂的产氢性能.这项工作为开发高效的非贵金属助催化剂修饰g-C3N4的技术提供了一个可行策略,所制材料在光催化制氢领域显示出潜在的应用前景. | 戚克振 吕文秀 Iltaf Khan 刘书源 | 2020 | Chinese Journal of Catalysis2020，41，1： | 9 |
| 2 | Mutagenic and cytotoxic potential of Endosulfan and Lambda-cyhalothrin—In vitro study describing individual and combined effects of pesticides显示文摘Excessive use of pesticides poses increased risks to non target species including humans. In the developing countries, lack of proper awareness about the toxic potential of pesticides makes the farmer more vulnerable to pesticide linked toxicities, which could lead to diverse pathological conditions. The toxic potential of a pesticide could be determined by their ability to induce genetic mutations and cytotoxicity. Hence, determination of genetic mutation and cytotoxicity of each pesticide is unavoidable to legislate health and safety appraisal about pesticides. The objective of current investigation was to determine the genotoxic and cytotoxic potential of Endosulfan(EN) and Lambda-cyhalothrin(LC); individually and in combination. 3-(4,5-Dimethylthiazol-2-yl)-2,5-Diphenyltetrazolium Bromide(MTT) assay was utilized to determine cytotoxicity, while two mutant histidine dependent Salmonella strains(TA98, TA100) were used to determine the mutagenicity of EN and LC.Moreover, mutagenicity assay was conducted with and without S9 to evaluate the effects of metabolic activation on mutagenicity. Even though a dose dependent increase in the number of revertant colonies was detected with EN against both bacterial strains, a highly significant(p < 0.05) increase in the mutagenicity was detected in TA98 with S9. In comparison, data obtained from LC revealed less mutagenic potential than EN. Surprisingly,the non-mutagenic individual-concentrations of EN and LC showed dose dependent mutagenicity when combined. Combination of EN and LC synergistically induced mutagenicity both in TA98 and TA100. MTT assay spotlighted comparable dose dependent cytotoxicity effects of both pesticides. Interestingly, the combination of EN and LC produced increased reversion and cytotoxicity at lower doses as compared to each pesticide, concluding that pesticide exposure even at sub-lethal doses can produce cytotoxicity and genetic mutations, which could lead to carcinogenicity. | Umber Saleem Sohail Ejaz Muhammad Ashraf Muhammad Ovais Omer Imran Iltaf Zainab Batool Riffat Fatima Msbah Afzal | 2014 | Journal of Environmental Sciences2014，26，7： | 3 |
| 3 | TLR4 polymorphisms and disease susceptibility显示文摘 | Mamoona Noreen Muhammad Ali A. Shah Sheeba Murad Mall Shazia Choudhary Tahir Hussain Iltaf Ahmed Syed Fazal Jalil Muhammad Imran Raza | 2012 | Inflammation Research2012，，3： | 2 |
| 4 | Bio-capped and green synthesis of ZnO/g-C_(3)N_(4) nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation显示文摘In this research study, we have synthesized the bio-capped ZnO/g-C_(3)N_(4) nanocomposites by employing lemon juice(Citrus limon) as a stabilizer and mediator. Fruitfully, lemon juice which contains various acidic functional groups and citric acid has the capability to block the surface of g-C_(3)N_(4) from chemical reactivity and activated the surface of g-C_(3)N_(4) for various reactions. Consequently, the agglomeration behavior and controlled shape of g-C_(3)N_(4) has also been achieved. Our experimental results i.e. XRD,TEM, HRTEM, PL, FS, XPS, and PEC have confirmed that the lemon juice mediated and green g-C_(3)N_(4)(L-CN) have good performances and remarkable visible light photocatalytic activities as compared to the chemically synthesized g-C_(3)N_(4)(CN). Furthermore, the small surface area and low charge separation of g-C_(3)N_(4) is upgraded by coupling with Zn O nanoparticles. It is proved that the coupling of Zn O worked as a facilitator and photoelectron modulator to enhance the charge separation of g-C_(3)N_(4). Compared to pristine lemon-mediated green g-C_(3)N_(4)(L-CN), the most active sample 5Zn O/L-CN showed ~ 5-fold improvement in activities for ciprofloxacin(CIP) and methylene blue(MB) degradation. More specifically,the mineralization process and degradation pathways, and the mineralization process of ciprofloxacin(CIP) and methylene blue(MB) are suggested. Finally, our present novel research work will provide new access to synthesize the eco-friendly and bio-caped green g-C_(3)N_(4)nanomaterials and their employment for pollutants degradation and environmental purification. | Iltaf Khan Chunjuan Wang Shoaib Khan Jinyin Chen Aftab Khan Sayyar Ali Shah Aihua Yuan Sohail Khan Mehwish KButt Humaira Asghar | 2023 | Chinese Journal of Chemical Engineering2023，56，4： | 1 |
| 5 | TLR4 polymorphisms and disease susceptibility显示文摘 | Mamoona Noreen Muhammad Ali A. Shah Sheeba Murad Mall Shazia Choudhary Tahir Hussain Iltaf Ahmed Syed Fazal Jalil Muhammad Imran Raza | 2012 | Inflammation Research2012，，3： | 1 |
| 6 | A mechanism for detecting dishonest recommendation in indirect trust computation显示文摘 | Iltaf N Ghafoor A and Zia U | 2013 | EURASIP Journal on Wireless Communications and Networking2013，，1： | 1 |
| 7 | Modeling interaction using trust and recommendation in ubiquitous computing environment显示文摘 | ILTAF N GHAFOOR A HUSSAIN M | 2012 | EURASIP Journal on Wireless Communications and Networking2012，，1： | 1 |
| 8 | A Differential Quadrature Based Approach for Volterra Partial Integro-Differential Equation with a Weakly Singular Kernel显示文摘Differential quadrature method is employed by numerous researchers due to its numerical accuracy and computational efficiency,and is mentioned as potential alternative of conventional numerical methods.In this paper,a differential quadrature based numerical scheme is developed for solving volterra partial integro-differential equation of second order having a weakly singular kernel.The scheme uses cubic trigonometric B-spline functions to determine the weighting coefficients in the differential quadrature approximation of the second order spatial derivative.The advantage of this approximation is that it reduces the problem to a first order time dependent integro-differential equation(IDE).The proposed scheme is obtained in the form of an algebraic system by reducing the time dependent IDE through unconditionally stable Euler backward method as time integrator.The scheme is validated using a homogeneous and two nonhomogeneous test problems.Conditioning of the system matrix and numerical convergence of the method are analyzed for spatial and temporal domain discretization parameters.Comparison of results of the present approach with Sinc collocation method and quasi-wavelet method are also made. | Siraj-ul-Islam Arshed Ali Aqib Zafar Iltaf Hussain | 2020 | Computer Modeling in Engineering & Sciences2020，，9： | 1 |
| 9 | 2D seismic interpretation of Sawan gas field integrated with petrophysical analysis:A case study from Lower Indus Basin,Pakistan显示文摘The Lower Indus Basin is the leading hydrocarbon-bearing sedimentary basin in Pakistan.This study has been conducted on the Sawan gas field located in the Lower Indus Basin,adjacent to a few other wellknown gas fields of Pakistan like Kadanwari,Qadirpur,and Miano gas fields.This research aims to present the spatial distribution and reservoir potential of the productive zones of the Lower Goru Formation.The present study utilized various two-dimensional(2D)seismic lines and well-log data(Sawan-01 and Sawan-02)to investigate the structural and stratigraphic features of the area.The stratigraphic layers are mildly deepening in the southeast direction.The 2D seismic interpretation of the research area identifies the existence of extensional remanents,i.e.,normal faults.These extensional structures are associated with horst and graben geometry that acts as a trapping mechanism for hydrocarbons.Wireline logs are used to identify the reservoir's diverse lithology and petrophysical properties.Petrophysical results indicate fair to good effective porosities,low shale volume,and high hydrocarbon saturation(>55%),signifying good reservoir potential in C interval of the Lower Goru Formation. | Abd Ur Rehman Khan Muhammad Amar Gul Rizwan Sarwar Awan Ashar Khan Khawaja Hasnain Iltaf Sibt.E Hassan Butt | 2023 | Energy Geoscience2023，4，2： | 0 |
| 10 | A Comparative Numerical Study of Parabolic Partial Integro-Differential Equation Arising from Convection-Diffusion显示文摘This article studies the development of two numerical techniques for solving convection-diffusion type partial integro-differential equation(PIDE)with a weakly singular kernel.Cubic trigonometric B-spline(CTBS)functions are used for interpolation in both methods.The first method is CTBS based collocation method which reduces the PIDE to an algebraic tridiagonal system of linear equations.The other method is CTBS based differential quadrature method which converts the PIDE to a system of ODEs by computing spatial derivatives as weighted sum of function values.An efficient tridiagonal solver is used for the solution of the linear system obtained in the first method as well as for determination of weighting coefficients in the second method.An explicit scheme is employed as time integrator to solve the system of ODEs obtained in the second method.The methods are tested with three nonhomogeneous problems for their validation.Stability,computational efficiency and numerical convergence of the methods are analyzed.Comparison of errors in approximations produced by the present methods versus different values of discretization parameters and convection-diffusion coefficients are made.Convection and diffusion dominant cases are discussed in terms of Peclet number.The results are also compared with cubic B-spline collocation method. | Kamil Khan Arshed Ali Fazal-i-Haq Iltaf Hussain Nudrat Amir | 2021 | Computer Modeling in Engineering & Sciences2021，，2： | 0 |
| 11 | Geochemical Characterization of Organic Rich Black Rocks of the Niutitang Formation to Reconstruct the Paleoenvironmental Settings during Early Cambrian Period from Xiangxi Area,Western Hunan,China显示文摘The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic matter.Black rock of the Early Cambrian Niutitang Formation is widely distributed in the Yangtze region,but detailed geochemical understanding of it is still emerging.This research discusses the detailed geochemical characteristics of the Niutitang Formation to reconstruct the paleoenvironmental conditions,employing total organic carbon(TOC)content,major,trace,and rare earth element data.For this purpose,black rock specimens of the Niutitang Formation from two outcrop sections were utilized for geochemical characterization,and the results compared with another eight sections from the South China Block.The average total organic carbon in these sediments is significantly higher(5.80 wt.%).In the platform region,lower quantities of TOC indicate a poor potential to produce hydrocarbons.At the same time,significantly higher TOC is observed in the deep shelf and slope sediments,indicating a significant potential to produce hydrocarbons.The average Ce,Eu and Y anomalies from both Longbizui and Sancha sections studied are 0.74,0.86,1.77,1.07,and 1.19,1.30,respectively.The chemical index of alteration(CAI)throughout the Yangtze block is higher(averaging 71.32)than that of Post Archean Australian Shale(PAAS 69),indicating a moderately weathered source of the Niutitang Formation relative to PAAS.As the sediments are moderately weathered,this suggests these rocks might have been derived from felsic rocks,mainly granite-granodiorite.The normalization of REEs in the black rocks reveals a reduction of light REEs with increase in heavy REEs enrichment.Similarly,a positive Eu anomaly,negative Ce anomaly,and a moderate Y/Ho(34.61)are clues to a hybrid depositional mechanism associated with hydrothermal action and terrigenous input.These anomalies are also evidence of upwelling in the paleo-ocean and mixing of organic matter,which created anoxic bottom water during the deposition of the Niutitang Formation in the basin and upper oxic water conditions before deposition.The main controlling factors for the distribution of rare earth elements in these black rocks of the Niutitang Formation are pH,terrigenous input,source rock composition,tectonism,an upwelling mechanism,and hydrothermal activity. | Rizwan Sarwar Awan Chenglin Liu Ashar Khan Khawaja Hasnain Iltaf Qibiao Zang Yuping Wu Sajjad Ali Muhammad Amar Gul | 2023 | Journal of Earth Science2023，34，6： | 0 |
| 12 | 优化水泥厂能源管理和生产运作显示文摘Lehigh水泥公司在对其位于马里兰州Union Bridge的工厂进行现代化管理的过程中,集成运用了过程控制和能源管理以达到改善整个工厂的生产效率的目的。 | Iltaf Khan Moin Shaikh | 2010 | 软件2010，31，1： | 0 |
| 13 | Efficacy of vasopressin, steroid, and epinephrine protocol for in-hospital cardiac arrest resuscitation: a systematic review and meta-analysis of randomized controlled trials with trial sequential analysis显示文摘OBJECTIVES To assess the effect of vasopressin,steroid and epinephrine(VSE)combination therapy on return of spontan-eous circulation(ROSC)after in-hospital cardiac arrest(IHCA),and test the conclusiveness of evidence using trial sequential ana-lysis(TSA).METHODS The systematic search included PubMed,EMBASE,Scopus,and Cochrane Central Register of Controlled Trials.Randomized controlled trials(RCTs)that included adult patients with IHCA,with at least one group receiving combined VSE therapy were selected.Data was extracted independently by two reviewers.The main outcome of interest was ROSC.Other out-comes included survival to hospital discharge or survival to 30 and 90 days,with good neurological outcomes.RESULTS We included a total of three RCTs(n=869).Results showed that VSE combination therapy increased ROSC(risk ra-tio=1.41;95%CI:1.25-1.59)as compared to placebo.TSA demonstrated that the existing evidence is conclusive.This was also validated by the alpha-spending adjusted relative risk(1.32[1.16,1.49],P<0.0001).Other outcomes could not be meta-analysed due to differences in timeframe in the included studies.CONCLUSIONS VSE combination therapy administered in cardiopulmonary resuscitation led to improved rates of ROSC.Fu-ture trials of VSE therapy should evaluate survival to hospital discharge,neurological function and long-term survival. | Danish Iltaf Satti Yan Hiu Athena Lee Keith Sai Kit Leung Jeremy Man Ho Hui Thompson Ka Ming Kot Arslan Babar Gauranga Mahalwar Abraham KC Wai Tong Liu Leonardo Roever Gary Tse Jeffrey Shi Kai Chan International Health Informatics Study(IHIS)Network | 2022 | Journal of Geriatric Cardiology2022，19，9： | 0 |
| 14 | Subsurface geological model of sedimentary and metasedimentary wedge from Mansehra to Battal based on gravity data,Hazara area,Pakistan显示文摘This study is aimed to delineate the subsurface structural elements using geophysical techniques in the Haraza area of Pakistan.We investigated the Oghi and Battal thrust faults,sedimentary and metasedimentary wedge,and the absolute crustal thickness based on terrestrial gravity data.Unlike seismic survey relying on wave propagation,magnetic survey is based on both attraction and repulsion,and electrical and electromagnetics on induction.The attractive gravity field produces relatively simpler patterns of anomalies,like a series of highs and lows over regions with undulating basements and buried structures.A qualitative interpretation of gravity data reveals a good deal of information.During the collision of Indian and Eurasian Plates,compressional structures were developed in the Lesser Himalayas or northwest of the Hazara Kashmir Syntaxis.The study mainly focuses on the western limb of the Hazara Kashmir Syntaxis.The regional and local Bouguer anomalies were incorporated to delineate the regional structural units.The gravity model is computed through geophysical technique along with profile A-A'from Mansehra to the Battal area that demarcates the blind Oghi Thrust and emergent Battal Thrust.Tanol Formation of Precambrian age demarcates the Oghi Thrust near Kotli Pine while the Battal Thrust is demarcated within the Mansehra Granite of Cambrian to Ordovician age near Battal.Along with the Battal Thrust,fault gouge and breccias have been observed during the field studies.The total thickness of the sedimentary/metasedimentary wedge in the Mansehra and Battal areas was estimated to be 13.6 km and 14.2 km.In comparison,the total thickness of crust in the Mansehra and Battal areas was 51.6 km and 52.2 km,respectively. | Rizwan Sarwar Awan Ashar Khan Chenglin Liu Shangfeng Yang Qibiao Zang Yuping Wu Guoxiong Li Khawaja Hasnain Iltaf Muhammad Tahir Sajjad Ali | 2021 | Energy Geoscience2021，2，4： | 0 |
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