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| 1 | An examination by GC×GC-TOFMS of organic molecules present inhighly degraded oils emerging from Caribbean terrestrial seeps of Cretaceous age显示文摘For our ancestors, oil seeps were both a fascination and a resource but as the planet's reserves of high quality low density oil becomes increasingly depleted, so there is now a renewed interest in heavier,biodegraded oils such as those encountered in terrestrial seeps. One such seep is Pitch Lake in the Caribbean island of Trinidad, which is the largest natural deposit of asphalt in the world. At the northern end of the Caribbean, oil emerges along a tectonic contact on the island on Cuba. The sources of the oils from these seeps are relatively recent and both are subject to intense weathering due to the tropical conditions. When analysed by gas chromatography(GC) both oils appear as unresolved complex mixtures(UCM) and show a very high degree of biodegradation thus presenting an analytical challenge. In this case study, these two Caribbean seep oils were analysed by comprehensive two dimensional GC with time of flight mass spectrometry(GC×GC-TOFMS) to expose many thousands of the individual compounds that comprise the UCM. The high chromatographic resolution of the GC×GC-TOFMS produced good quality mass spectra allowing many compounds including molecular fossil ‘biomarkers' to be identified. Compound classes included diamondoid hydrocarbons, demethylated hopanes and secohopanes, mono-and tri-aromatic steroids. D-ring aromatised structures of the 8,14-seco-hopanes,including demethylated forms were present in both oils but further demethylation, probably at position C-25 during biodegradation, was only observed in the Pitch Lake oil. Many polycyclic aromatic hydrocarbons(PAHs) were absent although the fungal-derived pentacyclic PAH perylene was present in both oils. The presence of the angiosperm biomarker lupane in the Pitch Lake oil constrained the age to the Late Cretaceous. The higher degree of biodegradation observed in the Cuban oil was likely due to relatively slow anaerobic processes whereas oil within Pitch Lake was probably subject to additional more rapid aerobic metabolism within the lake. | Alan G.Scarlett Ana Ibis Despaigne-Diaz Simon A.Wilde Kliti Grice | 2019 | Geoscience Frontiers2019，10，1： | 5 |
| 2 | The role of 18F-FDG PET/CT in detecting colorectal cancer recurrence in patients with elevated CEA levels显示文摘 | Elgin Ozkan Cigdem Soydal Mine Araz Kemal Metin Kir Erkan Ibis | 2012 | Nuclear Medicine Communications2012，，4： | 2 |
| 3 | A laboratory modification to testicular sperm preparation technique improves spermatogenic cell yield显示文摘阴囊的精子抽取是过去常与 nonobstructive 精子缺乏在人发现 spermatogenic 房间的一个普通过程。biopsied 处理阴囊的纸巾的实验室需要细致地被表现获得房间的高收益。在这研究,在阴囊的活体检视以后切碎纸巾的有效性用组织学的评估被估计,作为在密度坡度 centrifugation 期间是 spermatogenic 房间的迁居上的剩余织物的可能的不利效果。当与精子一起在密度坡度媒介上放了时,我们的结果显示那阴囊的剩余纸巾洗,妨碍 spermatogenic cells’在 centrifugation 期间形成一个小团,并且因此损害 intracytoplasmic 精子注射过程。而从精子的恢复房间的吝啬的数字与剩余织物洗媒介(SWM ) 是 39.435 ±24.849,它尤其是更高(60.189 ±28.214 个房间) 在没有切碎的纸巾的 SWM。留下的织物没在组织学的节包含功能的生精的小管或 spermatogenic 房间。在结论,在切碎阴囊的织物不增加的 biopsied 以后的留下的剩余织物对 spermatogenic 房间检索的任何功能或细胞的贡献;事实上,它可以阻止通过坡度层移居在 centrifugation 和 spermatogenic 房间的原因损失期间形成一个小团在伴随的房间暂停接近细胞的元素。 | Sinan Ozkavukcu Ebru Ibis Sule Kizil Suheyla Isbacar Kaan Aydos | 2014 | Asian Journal of Andrology2014，16，6： | 2 |
| 4 | Successful prenancy in a patient with 'Landesman's Group antosomal dominant polycystic kidney disease nature clinical practice 显示文摘 | Mobin Mohteshamzadeh Andrew Coutinho Ibi Erekosima | 2008 | Nephr Ology2008，4，4： | 1 |
| 5 | Protective effects of 1α,25-(OH)2D3 against the neurotoxicity of glutamate and reactive oxygen species in mesencephalic culture显示文摘 | Ibi M Sawada H Nakanishi M | 2001 | Neuropharmacology2001，40，6： | 1 |
| 6 | Serum paraoxonese activity and phenotype distribution in Turkish subjects with coronary heart disease and its relationship to serum lipids and lipoproteins显示文摘 | Karakaya A Ibis S Kural T | 1999 | Chem Biol Interact1999，118，： | 1 |
| 7 | Estradiol protects dopaminergic neurons in a MPP^+ Parkinson's disease model显示文摘 | Sawada H Ibi M Kihara T | 2002 | Neuropharmacology2002，42，8： | 1 |
| 8 | Development of High Ic Long REBCO Tapes with High Production Rate by PLD Method显示文摘 | Ibi A Miyata S Taneda T | 2013 | Physics Procedia2013，45，： | 1 |
| 9 | Serum paraoxonase activity and phenotype distribution in Turkish subjects with coronary heart disease and its relationship to serum lipids and lipoproteins 显示文摘 | Kara Kary A Ibis S Kural T | 1999 | Chem Biol Interact1999，118，3： | 1 |
| 10 | Fabrication of Eu 1 Ba 2 Cu 3 O 7?δ +BaHfO 3 coated conductors with 141A/cm-w under 3T at 77K using the IBAD/PLD process显示文摘 | T. Yoshida A. Ibi T. Takahashi M. Yoshizumi T. Izumi Y. Shiohara | 2014 | Physica C: Superconductivity and its applications2014，，： | 1 |
| 11 | Mechanism for enhancing dispersion of Co3O4nanoparticles in Co/Si O2Fischer-Tropsch synthesis catalyst by adding glycol to impregnating solution:a quick-XAFS study显示文摘 | Koizumi N Suzuki S Ibi Y | 2012 | J Synchrotron Radiat2012，19，1： | 1 |
| 12 | High-rate deposition of YBa2Cu3O7?δ high-temperature superconducting films by IR-laser-assisted chemical vapor deposition显示文摘 | S Miyata K Matsuse A Ibi T Izumi Y Shiohara T Goto | 2013 | Superconductor Science and Technology2013，，4： | 1 |
| 13 | Syntheses and biological activities of tetramic acid and tetronic acid derivatives显示文摘 | Ibi A Taniguchi E Maekawa K | 1979 | Agric Biol Chem1979，43，8： | 1 |
| 14 | Dopamine D2-type agonists protect mesencephalic neurons from glutamate neurotoxicity: Mechanisms of neuroprotective treatment against oxidative stress显示文摘 | Sawada H Ibi M Kihara T | 1998 | Ann Neurol1998，44，1： | 1 |
| 15 | Report of 24 Left-Sided Portal Hypertension Cases: A Single-Center Prospective Cohort Study显示文摘 | Seyfettin K?klü MD Osman Yüksel MD Mehmet Arhan MD ?ahin ?oban MD ?mer Ba?ar MD ?mer Faruk Yolcu MD Engin U?ar MD Mehmet Ibi? MD ?brahim Ertu?rul MD Burhan ?ahin MD | 2005 | Digestive Diseases and Sciences2005，，5： | 1 |
| 16 | Extraosseous uptake of Tc phos-phate in an extremity显示文摘 | Ozalp E Yagcioglu H Ibis E | | 0，，： | 1 |
| 17 | Mechanisms of antiapoptotic effects of estrogens in nigral dopaminergic neurons显示文摘 | Sawada H Ibi M Kihara T | 2000 | FASEB J2000，14，9： | 1 |
| 18 | Video-assisted thoracoscopic thymectomy(VAT-T) with lateral thoracotomy for stage Ⅱ and Ⅲ thymoma显示文摘 | Hirai K Ibi T Bessho R | 2013 | Ann Thorac Cardiovasc Surg2013，2019，1： | 1 |
| 19 | Mechanism of antiapoptotic effects of estrogens in dopaminergic neurons 显示文摘 | Swada H Ibi M Kihara T | 2000 | FASEB J2000，14，9： | 1 |
| 20 | Open label trial and randomized,doubleblind,placebo controlled,crossover trial of hydrogen enrichedwater for mitochondrial and mflammatory Myopathies 显示文摘 | Ito M Ibi T Ketal S | 2011 | MedGas Res2011，1，1： | 1 |
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