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| 1 | Segregation-assisted spinodal and transient spinodal phase separation at grain boundaries显示文摘Segregation to grain boundaries affects their cohesion,corrosion,and embrittlement and plays a critical role in heterogeneous nucleation.In order to quantitatively study segregation and low-dimensional phase separation at grain boundaries,here,we apply a density-based phase-field model.The current model describes the grain-boundary thermodynamic properties based on available bulk thermodynamic data,while the grain-boundary-density profile is obtained using atomistic simulations.To benchmark the performance of the model,Mn grain-boundary segregation in the Fe–Mn system is studied.3D simulation results are compared against atom probe tomography measurements conducted for three alloy compositions.We show that a continuous increase in the alloy composition results in a discontinuous jump in the segregation isotherm.The jump corresponds to a spinodal phase separation at grain boundary.For alloy compositions above the jump,we reveal an interfacial transient spinodal phase separation.The transient spinodal phenomenon opens opportunities for knowledge-based microstructure design through the chemical manipulation of grain boundaries.The proposed density-based model provides a powerful tool to study thermodynamics and kinetics of segregation and phase changes at grain boundaries. | Reza Darvishi Kamachali Alisson Kwiatkowski da Silva Eunan McEniry Dirk Ponge Baptiste Gault Jörg Neugebauer Dierk Raabe | 2020 | npj Computational Materials2020，，1： | 2 |
| 2 | Circulating interleukin-1 beta, interleukin-6, tumor necrosis factor-Alpha, and soluble ICAM-I in patient with chronic stable angina and myocardial infarctior显示文摘 | Y Balbay H Tikiz R J Baptiste | 2001 | Angiology2001，32，2： | 1 |
| 3 | Micro-displacement or bending measurement using a long-period fibre grating in a self-referenced fibre optic intensity sensor显示文摘 | BAPTIST J SANTOS S REGO G | 2006 | Optics Communications2006，260，1： | 1 |
| 4 | Tribological behaviour of epoxy based composites for rapid tooling显示文摘 | Vasconcelos P V Lino F J Baptists A M | 2006 | Wear2006，260，12： | 1 |
| 5 | Generalized Petri net reduction method 显示文摘 | LEE-KWANG H FAVREL J BAPTISTE P | 1987 | IEEE Transaction on Systems Man and Cybernetic1987，17，2： | 1 |
| 6 | Effects of temperature copper and chlorine on fish during simulated entrainment in power-plant condenser cooling systems显示文摘 | Hoss D E Costonl C Baptist J P | 1975 | IAEA-SM1975，189，19： | 1 |
| 7 | Abundance and isotopic composition of helium in hydrothermal sulfides from the East Pacific Rise at 13N显示文摘 | Baptiste P J Fouquet Y | 1996 | Geochimica et Cosmochimica Acta1996，60，： | 1 |
| 8 | A phase I study of swainsonine in patients with advanced malignancies 显示文摘 | Goss P E Baptiste J Fernandes B | 1994 | Cancer Research1994，54，： | 1 |
| 9 | The imquence of dietary protein and energy levels on growth and survival of penaeid shrimp 显示文摘 | Andrews J W Sick L V Baptist G J | 1972 | Aquaculture1972，，1： | 1 |
| 10 | The influence ofdietary protein and energy levels on growth and survivalof penaeid shrimp 显示文摘 | Andrews J W Sick L V Baptist G J | 1972 | Aquaculture1972，1，： | 1 |
| 11 | A review of the equine age - related changes in the immune system:comparisons between human and equine aging, with focus on lung - specific immune - aging显示文摘 | Hansen S Baptiste KE Fjeldborg J | 2015 | Ageing Research Reviews2015，20，： | 1 |
| 12 | Identification and localization of the structural proteins of Anguillidherpesvirus 1显示文摘 | VAN BEURDEN S J BAPTISTE L WATTIEZ R | 2011 | Veterinary Research2011，42，： | 1 |
| 13 | Trading volume and transaction costs in futures markets显示文摘 | Wang G H Yau J Baptiste T | 1997 | Journal of Futures Markets1997，17，： | 1 |
| 14 | A comparison of pro- inflammatory cytokine mRNA expression in equine bronchoalveolar lavage (BAL) and peripheral blood显示文摘 | Hansen S Baptiste KE Fjeldborg J | 2014 | Vet Immunol Immuno- pathol2014，158，34： | 1 |
| 15 | Abundance and isotopic composition of helium in hydrothermal sulfides from the East Pacific Rise at 13°N 显示文摘 | Baptiste P J Fouquet Y | 1996 | Geochimica et Cosmochimica Acta1996，60，1： | 1 |
| 16 | Generalized Petri net reduction method 显示文摘 | HYUNG L-K FAVREL J BAPTISTE P | 1987 | IEEE Transactions on Systems Man and Cybernetics1987，17，2： | 1 |
| 17 | A Phase I study of swainsonine in patients with advanced malignancies显示文摘 | Cross P E Baptiste J Fernandes B | 1994 | Cancer Research1994，54，： | 1 |
| 18 | Abundealce and isotopic composition of helium in hydrothermal sulfides from the East Pacific Rise at 13N 显示文摘 | Baptiste P J Fouquet Y | 1996 | Geochimica et Cesmochimica Acta1996，60，： | 1 |
| 19 | Mineral and gas ehemistl'y of hydrothermal fluids on an ultrafast spreading ridge: East Pacific Rise, 17° to 19° (Naudur cruise, 1993)--phase separation processes controlled by volcanic and teetonie activity 显示文摘 | Charlou J L Fouquet Y Donval J P Auzende J M Baptiste P J Stievenard M Miehel S | 1996 | Journal ' Geophysical Research1996，101，15： | 1 |
| 20 | Mechano-transduction mediated secretion and uptake of galectin-3 in breast earcinoma cells: implications in the extracellular functions of the lectin 显示文摘 | Baptiste TA Ashley J Saria M | 2007 | ExpCellRes2007，313，4： | 1 |
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