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| 1 | Experimental and Numerical Study on Co-combustion Behaviors and NO_(x) Emission Characteristics of Semi-coke and Coal in a Tangentially Fired Utility Boiler显示文摘The utilization of powdery semi-coke as a power fuel in pulverized coal-fired power plants has become a new and potential technique to consume the excess powdery semi-coke.The characteristic of low volatile results in poor combustion performance and high NO_(x) emission,and to co-fire with bituminous coal is a practical strategy to address this problem.However,the co-combustion characteristics and the inherent interaction between semi-coke and coal remain insufficiently understood.In addition,the influences of secondary air arrangement,the boiler operation load,and the fuel type on co-combustion process are still unclear,which is urgent to be further explored.In the present study,experiments and numerical simulations were jointly utilized to inquire into the co-combustion behaviors and NO_(x) emission features of semi-coke and coal.The results demonstrated that the'out-furnace method'was a suitable choice for small-capacity boiler when the proportion of semi-coke was 33%,due to the limited combinations of the semi-coke injection position.It was recommended that semi-coke was preferred to be injected from the middle layers of the furnace under the'in-furnace method'to improve the overall co-combustion performance.The critical value of the separated over fire air ratio in this study was 27.5%,over which a slight drop of carbon content in fly ash could come about.Moreover,the elevation in the proportion of separated over fire air gave rise to the significant decline of NO_(x) concentration.The constricted secondary air arrangement was preferred to be employed due to the high boiler efficiency.The separated over fire air and the surrounding air needed to maintain a wide-open degree to prevent the increase of NO_(x) emissions and the coking of nozzles.For the load reduction regulation method adopted in this study,the NO_(x) concentration first rose and then dropped,while the burnout ratio decreased obviously as the operation load was reduced.Different combinations of coal and semi-coke generated significant influences on co-combustion behaviors within the furnace.The NO_(x )generated by high-volatile fuel (bituminous coal) combustion was mainly affected by volatile-N,while the NO_(x )generated by low-volatile fuel (semi-coke) was mainly impacted by char-N.This study is of guiding significance for the efficient and clean utilization and beneficial to the large-scale application of powder semi-coke in power plants. | WANG Chang’an FENG Qinqin JIN Liyan WANG Zhichao YAO Wei WANGPengqian DU Yongbo ZHANG Xilai YANG Zhongcan CHE Defu | 2021 | Journal of Thermal Science2021，30，4： | 2 |
| 2 | Effective diffusivity of oxygen in the ash layer of Huadian oil shale semicoke显示文摘Diffusion of oxygen in the ash layer usually dominated the combustion of oil shale semicoke particles due to the high ash content.Thus,effective diffusivity of oxygen in the ash layer was a crucial parameter worthy of careful investigation.In this paper,the effective diffusivity of oxygen in the ash layer of Huadian oil shale semicoke was measured directly using an improved Wicke-Kallenbach diffusion apparatus.The experimental results showed that higher temperature would lead to a higher effective diffusivity and a thicker ash layer had the negative effect.Especially,the effective diffusivity along the direction perpendicular to bedding planes was much lower than that along the direction parallel to bedding planes.In addition,an effective diffusivity model was developed,which could be used to describe the mass transfer of oxygen in the ash layer of oil shale semicoke. | Yiqun HUANG Yiran LI Man ZHANG Boyu DENG Hao KONG Junfeng WANG Junfu LYU Hairui YANG Lingmei WANG | 2021 | Frontiers in Energy2021，15，2： | 0 |
| 3 | A deep insight into the structural characteristics of Yilan oil shale kerogen through selective oxidation显示文摘The structural characteristics of oil shale are important to its application.In this work,a deep insight into the structural characteristics of Yilan oil shale kerogen(YLK)was studied using alkali-oxygen oxidation at different times and ruthenium ion catalyzed oxidation(RICO).The results indicate that YLK is gradually converted to humic acids(HAs),water-soluble acids(WSAs),carboxylic acids(CAs),CO_(2)and H_(2)O.^(13)C NMR analyses of YLK,residues and HAs indicate that C-O bonds,especially C_(ar)-O bonds of YLK,are easily cleaved.The condensed aromatic rings and long alkyl chains are difficult to be oxidized during the oxidation process.With increasing oxidation time,the molar fraction of aromatic bridgehead carbon(Xb)of YLK and the residues increases from 0.174 to 0.201,and that of HAs increases from 0.225 to 0.267.The result indicates that the aromatic structures of YLK are composed of 1-ring aromatic clusters(26.5%),2-ring aromatic clusters(67.1%)and 3 or more-ring aromatic clusters(6.4%).Also,the average methylene chain(Cn)of YLK and the residues increases from 2.0 to 5.1,and that of HAs increases from 1.3 to 2.7,indicating that the alkyl chain length is not average but has a distribution.2.5%methylene carbons exist as long n-alkyl chains in the alkyl side chains groups(SCGs)on the aromatic rings in YLK.The carbon number of SCGs ranges from 5 to 22,and C_(15)and C_(17)are predominant.3.8%methylene carbons exist as alkyl bridges linkages(BLs)connecting aromatic rings in YLK.The carbon number of BLs connecting aromatic rings ranges from 6 to 19,and C_(8)is predominant.Because of the existence of above long n-alkyl chains,93.7%methylene carbons in YLK exist as alkyl chains with an average length of 1.84. | Qian Wang Yucui Hou Weize Wu Yupeng Wang Qing Liu Shuhang Ren | 2019 | Carbon Resources Conversion2019，2，3： | 0 |
| 4 | A review on co-pyrolysis of coal and oil shale to produce coke显示文摘It has become the top priority for coking industry to rationally use and enlarge coking coal resources because of the shortage of the resources.This review focuses on the potential utilization of oil shale(OS)as a feedstock for coal-blending coking,in which the initial and basic step is pyrolysis.However,OS has a high ash content.If such OS is directly used for coal-blending coking,the coke product will not meet market demand.Therefore,this review firstly summarizes separation and beneficiation techniques for organic matter in OS,and provides an overview on coal and OS pyrolysis through several viewpoints(e.g.,pyrolysis process,phenomena,and products).Then the exploratory studies on co-pyrolysis of coal with OS,including co-pyrolysis phenom-ena and process mechanism,are discussed.Finally,co-pyrolysis of different ranks of coals with OS in terms of coal-blending coking,where further research deserves to be performed,is suggested. | Xiangchun Liu Ping Cui Qiang Ling Zhigang Zhao Ruilun Xie | 2020 | Frontiers of Chemical Science and Engineering2020，14，4： | 0 |
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