|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Nickel cobalt phosphide with three-dimensional nanostructure as al highly efficient electrocatalyst for hydrogen evolution reaction in both I acidic and alkaline electrolytes显示文摘Transition metal phosphides (TMPs) are promising candidates for noble metal free electrocatalysts in water splitting applicati ons. In this work, we prese nt the facile syn thesis of nickel cobalt phosphide electrocatalyst with three-dime nsional nano structure (3D-NiCoP) on the nickel foam, via hydrothermal reaction and phosphorization. The as-prepared electrocatalyst exhibits an excellent activity for hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes, with small overpotentials to drive 10 mA/cm^2 (80 mV for 0.5 M H2SO4, 105 mV for 1 M KOH), small Tafel slopes (37 mV/dec for 0.5 M H2SO4, 79 mV/dec for 1 M KOH), and satisfying durability in long-term electrolysis. 3D-NiCoP also shows a superior HER activity compared to single metal phosphide, such as cobalt phosphide and nickel phosphide. The outstanding performa nee for HER suggests the great pote ntial of 3D-NiCoP as a highly efficient electrocatalyst for water splitting technology. | Bo Ma Zhengchun Yang Yantao Chen Zhihao Yuan | 2019 | Nano Research2019，12，2： | 14 |
| 2 | 磷化铁的制备及其电催化析氢和析氧性能研究显示文摘磷化铁是一种高效析氢和析氧催化剂,为了提高其催化性能,制备了具有多孔结构和均一形貌的FeP,并对其进行了电催化性能分析。分别在酸性和碱性溶液中考察了该催化剂的析氢催化性能,结果表明,该催化剂在碱性测试环境中的催化活性优于酸性条件下的催化活性。另外,在碱性测试环境中,FeP催化剂也表现出很好的析氧催化性能,当电流密度达到10 m A/cm^2时,需要的过电位为380 m V,并且具有较小塔菲尔值,约为73 m V/dec。此外,该催化剂还表现出很好的催化稳定性。 | 高文君 王梦娇 徐冬 孙振新 杨阳 郭桦 | 2019 | 现代化工2019，39，11： | 5 |
| 3 | Cobalt phosphide nanoarrays with crystalline-amorphous hybrid phase for hydrogen production in universal-pH显示文摘To accomplish mass hydrogen production by electrochemical water-splitting,it is a necessary to develop robust,highly active,stable,and cost-effective hydrogen evolution reaction(HER)electrocatalysts that perform comparably to Pt in the universal pH range.In this work,cobalt phosphide hybrid nanosheets supported on carbon felt(CoP HNS/CF)are presented,which exhibit the superior electrocatalytic hydrogen production under a universal-pH.In these nanosheets,a single CoP HNS is composed of polycrystalline CoP and oxygen-enriched amorphous Co-O-P phase.Benefiting from its unique nanoarchitecture,as-fabricated CoP HNS/CF exhibits a tremendous electrocatalytic HER activity and outperforms Pt/C as well as state-of-the-art CoP electrocatalysts in universal-pH.In acidic and neutral media,the CoP HNS/CF shows superior electrocatalytic activity while maintaining its original hybrid crystalline-amorphous phase and morphology.In alkaline medium,the unexpected phase and morphological reorganization of CoP HNS/CF results in outstanding electrocatalytic operation.CoP HNS/CF not only achieves high electrocatalytic activity and kinetics,but also a stable and long operating lifetime even under a high current density of 500 mA cm'2.Furthermore,the fabrication of CoP HNS/CF can be scaled up easily,and the large CoP HNS/CF electrode also exhibits similar electrocatalytic activity and stability. | Hyunseok Yoon Hee Jo Song Bobae Ju Dong-Wan Kim | 2020 | Nano Research2020，13，9： | 4 |
| 4 | Defect engineering of molybdenum disulfide through ion irradiation to boost hydrogen evolution reaction performance显示文摘The inert basal plane of molybdenum disulfide (MoS2) restrains its further hydrogen evolution reaction (HER) performance.This work attempts ion irradiation to activate inert basal plane of MoS2 nanosheet to improve its electrocatalytic performance.Experimental results demonstrate the sulphur vacancies generated by ion irradiation on the basal plane of MoS2 mainly boost the efficiency of HER performance.The moderate fluence of carbon ion irradiation gains the optimum HER performance with an onset potential of 77 mV and Tafel slope of 66 mV/dec. | Cheng Sun Peipei Wang Hao Wang Chuan Xu Juntong Zhu Yanxia Liang Ying Su Yining Jiang Wenqi Wu Engang Fu Guifu Zou | 2019 | Nano Research2019，12，7： | 3 |
| 5 | 肉制品中亚硝残留问题浅探显示文摘通过测定几种熟肉制品在不同存放时间的亚硝残留量 ,探讨了二者的相关关系。并指出了亚硝在当前肉制品生产中 。 | 周旭东 | 2000 | 肉类研究2000，14，2： | 2 |
| 6 | Boosting pH-Universal Hydrogen Evolution of Molybdenum Disulfide Particles by Interfacial Engineering显示文摘The design of high-efficiency non-noble and earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is highly paramount for water splitting and renewable energy systems.Molybdenum disulfide(MoS_(2))with abundant edge sites can be utilized as a promising alternative,but its catalytic activity is greatly related to the pH values,especially in an alkaline environment due to the extremely high energy barriers for water adsorption and dissociation steps.Here we report an exceptionally efficient and stable electrocatalyst to improve the sluggish HER process of layered MoS_(2)particles in different pH electrolytes,especially in base.The electrocatalyst is constructed by in situ growing selenium-doped MoS_(2)(Se-MoS_(2))nanoparticles on three-dimensional cobalt nickel diselenide(mCo_(0.2)Ni_(0.8)Se_(2))nanostructured arrays.Due to the large number of active edge sites of Se-MoS_(2)particles exposed at the surface,robust electrical conductivity and large surface area of mCo_(0.2)Ni_(0.8)Se_(2)support,and strong interfacial interactions between Se-MoS_(2)and mCo_(0.2)Ni_(0.8)Se_(2),this hybrid catalyst shows very outstanding catalytic HER properties featured by low overpotentials of 30 and 122 mV at 10 and 100 mA/cm^(2)with good operational stability in base,respectively,which outperforms most of inexpensive catalysts consisting of layered MoS_(2),transition metal selenides and sulfides,and it performs as well as noble Pt catalysts.Meanwhile,this electrocatalyst is also very active in neutral and acidic electrolytes,requiring low overpotentials of 93 and 94 mV at 10 mA/cm^(2),respectively,demonstrating its superb pH universality as a HER electrocatalyst with excellent catalytic durability.This study provides a straightforward strategy to construct an efficient non-noble electrocatalyst for driving the HER kinetics in different electrolytes. | Liling Liao Lun Yang Gang Zhao Haiqing Zhou Fengming Cai Yi Li Xiuzhang Wang Fang Yu | 2021 | Chinese Journal of Chemistry2021，39，2： | 2 |
| 7 | 电解水制氢中钌基电催化剂的研究进展显示文摘能源枯竭引发了寻找替代能源的热潮,氢气作为一种清洁能源引起了人们的广泛关注,尤其关注于电解水制取氢气,因此开发高效、稳定、廉价的电解水析氢的催化剂就成为研究热点。本文综述了铂(Pt)族元素中最便宜的钌和钌基材料作为高效电催化剂在电解水析氢反应中的研究进展,展望了钌和钌基材料在电解水析氢反应中的产业化应用前景。 | 姚俊杰 唐佳易 杨志娟 陈建 孙迎辉(指导) | 2019 | 电池工业2019，23，3： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员