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| 1 | Rational adjustment to interfacial interaction with carbonized polymer dots enabling efficient large-area perovskite light-emitting diodes显示文摘Film uniformity of solution-processed layers is the cornerstone of large-area perovskite light-emitting diodes,which is often determined by the‘coffee-ring effect’.Here we demonstrate a second factor that cannot be ignored is the solid-liquid interface interaction between substrate and precursor and can be optimized to eliminate rings.A perovskite film with rings can be formed when cations dominate the solid-liquid interface interaction;whereas smooth and homogeneous perovskite emitting layers are generated when anions and anion groups dominate the interaction.This is due to the fact that the type of ions anchored to the substrate can determine how the subsequent film grows.This interfacial interaction is adjusted using carbonized polymer dots,who also orient the perovskite crystals and passivate their buried traps,enabling a 225 mm^(2) large-area perovskite light-emitting diode with a high efficiency of 20.2%. | Fan Yang Qingsen Zeng Wei Dong Chunyuan Kang Zexing Qu Yue Zhao Haotong Wei Weitao Zheng Xiaoyu Zhang Bai Yang | 2023 | Light(Science & Applications)2023，12，6： | 1 |
| 2 | Co-Ru alloy nanoparticles decorated onto two-dimensional nitrogen doped carbon nanosheets towards hydrogen/oxygen evolution reaction and oxygen reduction reaction显示文摘Constructing highly-efficient electrocatalysts toward hydrogen evolution reaction(HER)/oxygen evolution reaction(OER)/oxygen reduction reaction(ORR)with excellent stability is quite important for the development of renewable energy-related applications.Herein,Co-Ru based compounds supported on nitrogen doped two-dimensional(2D)carbon nanosheets(NCN)are developed via one step pyrolysis procedure(Co-Ru/NCN)for HER/ORR and following low-temperature oxidation process(Co-Ru@RuO_(x)/NCN)for OER.The specific 2D morphology guarantees abundant active sites exposure.Furthermore,the synergistic effects arising from the interaction between Co and Ru are crucial in enhancing the catalytic performance.Thus,the resulting Co-Ru/NCN shows remarkable electrocatalytic performance for HER(70 mV at 10 mA cm^(-2))in 1 M KOH and ORR(half-wave potential E_(1/2)=0.81 V)in 0.1 M KOH.Especially,the Co-Ru@RuO_(x)/NCN obtained by oxidation exhibits splendid OER performance in both acid(230 mV at 10 mA cm^(-2))and alkaline media(270 mV at 10 mA cm^(-2))coupled with excellent stability.Consequently,the fabricated two-electrode water-splitting device exhibits excellent performance in both acidic and alkaline environments.This research provides a promising avenue for the advancement of multifunctional nanomaterials. | Huizhen Wang Pengfei Yang Xiaoyuan Sun Weiping Xiao Xinping Wang Minge Tian Guangrui Xu Zhenjiang Li Yubing Zhang Fusheng Liu Lei Wang Zexing Wu | 2023 | Journal of Energy Chemistry2023，，12： | 0 |
| 3 | Skincare plants of the Naxi of NW Yunnan, China显示文摘The Naxi of Northwest Yunnan,China use medicinal plants to treat skin conditions related to traditional lifestyles in extreme environments.However,modernization endangers both the medicinal plants used to treat skin conditions and traditional knowledge.Therefore,investigation and documentation of the medicinal plants used and associated traditional knowledge is necessary.In this study,we conducted an ethnobotanical survey in 12 Naxi communities in Northwest Yunnan.For this purpose,we used semistructured surveys to interview 840 informants from Naxi communities.We used informant consensus factor and use frequency as quantitative indices to evaluate the importance of medicinal plant species.A total of 161 medicinal plant species belonging to 69 families were documented.The highest informant consensus factor(ICF)values were recorded for skin nourishing(ICF?0.849),frostbite and chapped skin(ICF?0.833).These skin treatments are highly related to the environment and lifestyle of Naxi communities.The main active compounds of plants used to treat skin conditions in Naxi communities are known to have skin-treating properties.This study reveals that the skin conditions treated by the Naxi are associated with traditional medicine culture and social economic development.In addition,this study uses ethnobotanical indices to explain how skin condition treatments are linked to the natural environment of Naxi communities. | Yanqiang Zhao Zexing Yang Bayi Lang Manfred Shao Wu Meng Dayuan Xue Lu Gao Lixin Yang | 2020 | Plant Diversity2020，42，6： | 0 |
| 4 | Surface/Interface Engineering of Hierarchical MoO_(2)/MoNi_(4)@Ru/RuO_(2)Heterogeneous Nanosheet Arrays for Alkaline Water Electrolysis with Fast Kinetics显示文摘Realizing the hydrogen economy by water electrolysis is an attractive approach for hydrogen production,while the efficient and stable bifunctional catalysts under high current densities are the bottleneck that limits the half-cell reactions of water splitting.Here,we propose an approach of hydrothermal and thermal annealing methods for robust MoO_(2)/MoNi_(4)@Ru/RuO_(2) heterogeneous cuboid array electrocatalyst with multiplying surface-active sites by depositing a monolayer amount of Ru.Benefiting from abundant MoO_(2)/MoNi_(4)@Ru/RuO_(2)heterointerfaces,MoO_(2)/MoNi_(4)@Ru/RuO_(2) heterogeneous cuboid array electrocatalysts effectively drive the alkaline water splitting with superior hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)performances.The synthesized MoO_(2)/MoNi_(4)@Ru/RuO_(2) has high HER activity,which realizes the working overpotentials of 48 mV at 50 mA·cm^(-2),further achieving overpotentials of 230 mv for industry-level 1000 mA·cm^(-2) in alkaline water electrolysis.Moreover,it also showed an enhanced OER activity than commercial RuO_(2) with a small overpotential of 280 mV at 200 mA·cm^(-2) in alkaline media.When building an electrolyzer with electrodes of(-)MoO_(2)/MoNi_(4)@Ru/RuO_(2)IIMo02/MoNig@Ru/RuO_(2)(+),a cell voltage of 1.63 V and 1.75 V is just required to support the current density of 200 mA·cm^(-2) and 500 mA-cm^(-2) in alkaline water electrolysis,much lower than that of the electrolyzer of(-)Pt/CIIRuO_(2)(+).This work demonstrates that MoO_(2)/MoNig@Ru/RuO_(2) heterogeneous nanosheet arrays are promising candidates for industrial water electrolysis applications,providing a possibility for the exploration of water electrolysis with a large currentdensity. | Qiong Zhang Ruixue Zhang Yingxiu Zhao Tiantian Sun Jianyang Gao Guang-Rui Xu Zexing Wu Yu Yang Lei Wang | 2024 | Chinese Journal of Chemistry2024，42，2： | 0 |
| 5 | Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan显示文摘2,5-bis(hydroxymethyl)furan(BHMF)is an important monomer of polyester.Its oxygen-containing rigid ring structure and symmetrical diol functional group establish it as an alternative to petroleum-based monomer with unique advantages for the prodution of the degradable bio-based polyester materials.Herein,we prepared a boehmite-supported copper-oxide catalyst for the selective hydrogenation of 5-hydroxymethylfurfural into BHMF via catalytic transfer hydrogenation(CTH).Further,ethanol successfully replaced conventional high-pressure hydrogen as the hydrogen donor,with up to 96.9% BHMF selectivity achieved under suitable conditions.Through characterization and factor investigations,it was noted that CuO is crucial for high BHMF selectivity.Furthermore,kinetic studies revealed a higher by-product activation energy compared to that of BHMF,which explained the influence of reaction temperature on product distribution.To establish the catalyst structure-activity correlation,a possible mechanism was proposed.The copper-oxide catalyst deactivated following CTH because ethanol reduced the CuO,which consequently decreased the active sites.Finally,calcination of the catalyst in air recovered its activity.These results will have a positive impact on hydrogenation processes in the biomass industry. | Zexing Huang Zhijuan Zeng Xiaoting Zhu Wenguang Zhao Jing Lei Qiong Xu Yongjun Yang Xianxiang Liu | 2023 | Frontiers of Chemical Science and Engineering2023，17，4： | 0 |
| 6 | Heterogeneous integrated phase modulator based on two-dimensional layered materials显示文摘Silicon nitride,with ultralow propagation loss and a wide transparency window,offers an exciting platform to explore integrated photonic devices for various emerging applications.It is appealing to combine the intrinsic optical properties of two-dimensional layered materials with high-quality optical waveguides and resonators to achieve functional devices in a single chip.Here we demonstrate a micro-ring resonator-based phase modulator integrated with few-layer MoS_(2).The ionic liquid is employed directly on the surface of MoS_(2) to form a capacitor configuration.The effective index of the composite MoS_(2)–SiN waveguide can be modulated via adjusting bias voltages to achieve different charged doping induced electro-refractive responses in MoS_(2) film.The maximum effective index modulation of the composite MoS_(2)–SiN waveguide can be achieved to 0.45×10^(−3).The phase tuning efficiency is measured to be 29.42 pm/V,corresponding to a V_(π)L of 0.69 V·cm.Since the micro-ring resonator is designed near the critical coupling regime,the coupling condition between the bus waveguide and micro-ring resonator can also be engineered from under-coupling to over-coupling regime during the charged doping process.That can be involved as a degree of freedom for the coupling tailoring.The ability to modulate the effective index with two-dimensional materials and the robust nature of the heterostructure integrated phase modulator could be useful for engineering reliable ultra-compact and low-power-consumption integrated photonic devices. | HAO CHEN ZEXING ZHAO ZIMING ZHANG GUOQING WANG JIATONG LI ZHENYUAN SHANG MENGYU ZHANG KAI GUO JUNBO YANG PEIGUANG YAN | 2022 | Photonics Research2022，10，6： | 0 |
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