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1Comparing the Diagnostic Criteria for Gestational Diabetes Mellitus of World Health Organization 2013 with 1999 in Chinese Population显示文摘INTRODUCTION Gestational diabetes mellitus (GDM) was earlier defined as 'hyperglycemia first recognized during pregnancy' and has more recently been described by American Diabetes Association (ADA) (2012) as diabetes diagnosed during pregnancy that is not clearly overt diabetes.[1] The hyperglycemia and adverse pregnancy outcomes study (HAPO) demonstrated that the risk of adverse maternal,fetal,and neonatal outcomes continuously increase as a function of maternal glycemia at 24-28 weeks,even within ranges previously considered normal for pregnancy.[2] After reviewing the results of the HAPO study,many international diabetes study groups,including the International Association of Diabetes and Pregnancy Study Groups and ADA have adopted the 75 g oral glucose tolerance test (OGTT) at 24-28 weeks as a screening and diagnostic test and defined new cut-off values for GDM diagnosis.The Ministry of Health of China published the criteria for GDM,that is the same as the ADA criteria on July 1,2011.World Health Organization (WHO) has recommended the 75 g OGTT with different cut-offvalues as a diagnostic test since 1999,changed its recommendation on 2013.In Hongkong and Yunnan province in China,most hospital adopted the WHO 1999 criteria,nevertheless,there is no evidence of multicenter and large sample to show that the GDM population within the same ethnic group diagnosed by the new WHO criteria matches those diagnosed by the old one and consistency between the two criteria has not been reported.Thus,we conducted this study to analyze the two criteria in Chinese pregnant women.Weiwei Zhu Huixia Yang Yumei Wei Zilian Wang Xuelan Li Hairong Wu Nan Li Meihua Zhang Xinghui Liu Hua Zhang Yunhui Wang Jianmin Niu Yujie Gan Liruo Zhong Yunfeng Wang Anil Kapur 2015Chinese Medical Journal2015,,1:42
2Phase 1 clinical trial demonstrated that MUC1 positive metastatic seminal vesicle cancer can be effectively eradicated by modified Anti-MUC1 chimeric antigen receptor transduced T cells显示文摘Recent progress in chimeric antigen receptor-modified T-cell(CAR-T cell) technology in cancer therapy is extremely promising, especially in the treatment of patients with B-cell acute lymphoblastic leukemia. In contrast, due to the hostile immunosuppressive microenvironment of a solid tumor, CAR T-cell accessibility and survival continue to pose a considerable challenge, which leads to their limited therapeutic efficacy. In this study, we constructed two anti-MUC1 CAR-T cell lines. One set of CAR-T cells contained SM3 single chain variable fragment(sc Fv) sequence specifically targeting the MUC1 antigen and co-expressing interleukin(IL) 12(named SM3-CAR). The other CAR-T cell line carried the SM3 sc Fv sequence modified to improve its binding to MUC1 antigen(named p SM3-CAR) but did not co-express IL-12. When those two types of CAR-T cells were injected intratumorally into two independent metastatic lesions of the same MUC1+ seminal vesicle cancer patient as part of an interventional treatment strategy, the initial results indicated no side-effects of the MUC1 targeting CAR-T cell approach, and patient serum cytokines responses were positive. Further evaluation showed that p SM3-CAR effectively caused tumor necrosis, providing new options for improved CAR-T therapy in solid tumors.Fengtao You Licui Jiang Bozhen Zhang Qiang Lu Qiao Zhou Xiaoyang Liao Hong Wu Kaiqi Du Youcai Zhu Huimin Meng Zhishu Gong Yunhui Zong Lei Huang Man Lu Jirong Tang Yafen Li Xiaochen Zhai Xiangling Wang Sisi Ye Dan Chen Lei Yuan Lin Qi Lin Yang 2016Science China(Life Sciences)2016,59,4:16
3Theoretical prediction,synthesis,and crystal structure determination of new MAX phase compound V2SnC显示文摘Guided by the theoretical prediction,a new MAX phase V2SnC was synthesized experimentally for the first time by reaction of V,Sn,and C mixtures at 1000°C.The chemical composition and crystal structure of this new compound were identified by the cross-check combination of first-principles calculations,X-ray diffraction(XRD),energy dispersive X-ray spectroscopy(EDS),and high resolution scanning transmission electron microscopy(HR-STEM).The stacking sequence of V2C and Sn layers results in a crystal structure of space group P63/mmc.The a-and c-lattice parameters,which were determined by the Rietveld analysis of powder XRD pattern,are 0.2981(0)nm and 1.3470(6)nm,respectively.The atomic positions are V at 4f(1/3,2/3,0.0776(5)),Sn at 2d(2/3,1/3,1/4),and C at 2a(0,0,0).A new set of XRD data of V2SnC was also obtained.Theoretical calculations suggest that this new compound is stable with negative formation energy and formation enthalpy,satisfied Born-Huang criteria of mechanical stability,and positive phonon branches over the Brillouin zone.It also has low shear deformation resistance c44(second-order elastic constant,cij)and shear modulus(G),positive Cauchy pressure,and low Pugh’s ratio(G/B=0.500<0.571),which is regarded as a quasi-ductile MAX phase.The mechanism underpinning the quasi-ductility is associated with the presence of a metallic bond.Qiang Xu Yanchun Zhou Haiming Zhang Anna Jiang Quanzheng Tao Jun Lu Johanna Rosén Yunhui Niu Salvatore Grasso Chunfeng Hu 2020Journal of Advanced Ceramics2020,9,4:8
4Study on Steel-Mushy Al-20Sn Alloy Bonding显示文摘Steel-mushy Al-20Sn alloy bonding was studied for the first time. The relationship model about preheat temperature of steel plate, solid fraction of Al-20Sn alloy mushy, rolling speed and interfacial shear strength of bonding plate could be established by artificial neural networks perfectly. This model could be optimized with a genetic algorithm. The optimum bonding parameters were: 505’C for preheat temperature of steel plate, 34.3% for solid fraction of Al20Sn alloy musry and 10 mm/s for rolling speed, and the largest interfacial shear strength of bonding plate was 71.2 MPa.Peng ZHANG, Yunhui DU and Daben ZENG Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China Jianzhong CUI Metal Forming Department, NEU, Shenyang 110006, China Limin BA Anshan Automobile Fittings Factory, Anshan 114014, China 2001Journal of Materials Science & Technology2001,17,2:7
5Electrospinning of ultrafine core/shell fibers for biomedical applications显示文摘Because of the inherent appearance similar to the natural extracellular matrix,ultrafine fibrous membranes prepared via electrospinning exhibit widespread applications,especially in the biomedical area.Extensional modifications of coaxial and emulsion electrospinning have drawn much attention in preparation of core/shell fibers for applications as tissue engineering scaffolds and controlled delivery systems for bioactive substances.Due to incorporation of multi-components in the electrospun core/ shell fibers,the process of coaxial and emulsion electrospinning became more susceptible.The theories have not been fully understood.A series of investigations were carried out evaluating the systematic and processing parameters.This paper reviews advantages and potentials of electrospun core/shell fibers as well as factors influencing their formation on the basis of our research and new progress.ZHANG Hong,ZHAO ChenGuang,ZHAO YunHui,TANG GongWen & YUAN XiaoYan School of Materials Science and Engineering,and Tianjin Key Laboratory of Composite and Functional Materials,Tianjin University,Tianjin 300072,China 2010Science China Chemistry2010,53,6:7
6The application of nanostructured transition metal sulfides as anodes for lithium ion batteries显示文摘With wide application of electric vehicles and large-scale in energy storage systems, the requirement of secondary batteries with higher power density and better safety gets urgent. Owing to the merits of high theoretical capacity, relatively low cost and suitable discharge voltage, much attention has been paid to the transition metal sulfides. Recently, a large amount of research papers have reported about the application of transition metal sulfides in lithium ion batteries. However, the practical application of transition metal sulfides is still impeded by their fast capacity fading and poor rate performance. More well-focused researches should be operated towards the commercialization of transition metal sulfides in lithium ion batteries. In this review, recent development of using transition metal sulfides such as copper sulfides,molybdenum sulfides, cobalt sulfides, and iron sulfides as electrode materials for lithium ion batteries is presented. In addition, the electrochemical reaction mechanisms and synthetic strategy of transition metal sulfides are briefly summarized. The critical issues, challenges, and perspectives providing a further understanding of the associated electrochemical processes are also discussed.Jinbao Zhao Yiyong Zhang Yunhui Wang He Li Yueying Peng 2018Journal of Energy Chemistry2018,27,6:7
7Radial Distribution of SiC Particles in Mechanical Stirring of A356-SiC_p Liquid显示文摘The mechanical stirring of A356-2.5 vol.% SiC p liquid was conducted in a cylindrical crucible by a straightblade stirrer.The radial distribution of SiC particles in A356 liquid was studied under the conditions of 25 deg.for gradient angle α of blade and 10 mm/s for speed of moving up and down of stirrer.The results show that there exists a nonlinear relationship between rotating speed of stirrer and radial relative deviation of SiC p content in A356 liquid between the center and the periphery of crucible.The greater the rotating speed of stirrer is,the bigger the radial relative deviation of SiC p content in A356 liquid becomes and the more nonhomogeneous the radial distribution of SiC particles in A356 liquid turns.In addition,when the rotating speed of stirrer is about 200 r/min,the vertical distribution of SiC particles in A356 liquid is relative uniform.It can be seen that the nonhomogeneous distribution of SiC particles in A356 liquid results from the nonhomogeneous radial distribution of SiC particles in A356 liquid in straight-blade mechanical stirring ultimately.Yunhui Du Peng Zhang Jun Zhang Shasha Yao 2012Journal of Materials Science & Technology2012,28,10:5
8Spatial Correlation and Ecological Characteristics Analysis of Man-agement Area for Biodiversity Conservation and Relevant Regionalization显示文摘Formulation of different ecological zone plans according to the corresponding protection targets and the necessity of proper conservation policy is one of the measures to achieve the goal of ecological conservation in China.In order to clarify the interrelation among key ecological zone plans,this paper carried out the research on spatial relation of priority areas of biodiversity conservation and three key ecological areas(key ecological function areas,key regions of ecological service function,national nature reserves)and the research on ecological conditions,based on multi-scale ecological spatial theme information,which incorporates elements like ecological quality and type,and by the aid of spatial information analysis and GIS modeling.The results showed a contrastively fine spatial consistency with 68.8%of priority areas of biodiversity conservation overlapping with three key ecological areas.Although the environment in priority areas of biodiversity conservation were in good conditions,protection pressure is also increasing,powerful supervision and protection should not be ignored.The environmental conditions in the overlapping areas,as a whole,were superior to those in the non-overlapping areas.Since two areas have different characteristics,targeted protection measures should be formulated based on this difference,which will be very important for biodiversity conservation in priority areas of biodiversity conservation.WANG Wenjie ZHENG Hua XU Chao JIANG Weiguo DU Yunhui WANG Wei ZHANG Zhe LIU Xiaofu 2014Chinese Geographical Science2014,24,1:5
9Highly Enhanced Visible-Light-Driven Photoelectrochemical Performance of ZnO-Modified In_2S_3 Nanosheet Arrays by Atomic Layer Deposition显示文摘Photoanodes based on In_2S_3/ZnO heterojunction nanosheet arrays(NSAs) have been fabricated by atomic layer deposition of ZnO over In_2S_3 NSAs, which were in situ grown on fluorine-doped tin oxide glasses via a facile solvothermal process. The as-prepared photoanodes show dramatically enhanced performance for photoelectrochemical(PEC) water splitting, compared to single semiconductor counterparts. The optical and PEC properties of In_2S_3/ZnO NSAs have been optimized by modulating the thickness of the Zn O overlayer. After pairing with ZnO, the NSAs exhibit a broadened absorption range and an increased light absorptance over a wide wavelength region of 250–850 nm. The optimized sample of In_2S_3/ZnO-50 NSAs shows a photocurrent density of 1.642 m A cm^(-2)(1.5 V vs. RHE) and an incident photonto-current efficiency of 27.64% at 380 nm(1.23 V vs.RHE), which are 70 and 116 times higher than those of the pristine In_2S_3 NSAs, respectively. A detailed energy band edge analysis reveals the type-II band alignment of the In_2S_3/ZnO heterojunction, which enables efficient separation and collection of photogenerated carriers,especially with the assistance of positive bias potential, and then results in the significantly increased PEC activity.Ming Li Xinglong Tu Yunhui Wang Yanjie Su Jing Hu Baofang Cai Jing Lu Zhi Yang Yafei Zhang 2018Nano-Micro Letters2018,10,3:5
10Synthesis and modification of well-ordered layered cathode oxide LiNi_(2/3)Mn_(1/3)O_2显示文摘Oxalic-acid-based co-precipitation method was employed to prepare LiNi2/3Mn1/3O2 sample with a high-ordered structure. Li+,Ni2+ and Mn2+ acetates were used as starting materials. The influence of the amount of lithium source in the starting materials on Li+ content,disorder of Li+-Ni2+ ions,and electrochemical performance has been investigated. Rietveld refinement shows that the sample prepared with 20% excess Li-source in the starting materials exhibits a perfect ordered structure. A specific discharge capacity is as high as 172 mAh/g at C/20 in the voltage range of 4.35?2.7 V. However,the cyclability is not satisfactory:about 25.3% fade in capacity was observed over 50 cycles. Chemically stable SiO2 was coated on the surface of LiNi2/3Mn1/3O2 particles. A significant improvement in cyclability was attained with 3 wt% SiO2 coating,which is ascribable to the protection of LiNi2/3Mn1/3O2 particles from being dissolved into the electrolyte.XIONG XiaoQin JIANG Yan XIA ShengAn ZHANG WuXing Yuan LiXia LIU ShanTang HUANG YunHui 2010Chinese Science Bulletin2010,55,30:5
11Morphology-controllable solvothermal synthesis of nanoscale LiFePO_4 in a binary solvent显示文摘LiFePO4(LFP) nanobars,microplates and nanorods have been selectively synthesized via a solvothermal method in a water-ethylene glycol(EG) binary solvent with H3PO4,LiOH·H2O,and FeSO4·7H2O as starting materials.The morphology and size of the as-obtained LFP products can be deliberately controlled by varying the volume ratio of EG to water.The formation mechanism and electrochemical properties of different LFP morphologies have been investigated.With carbon coating,the Li-ion diffusion coefficients of LFP nanorods,nanobars and micro-plates are 2.58×10-9,2.91×10-10,and 7.22×10-10 cm2 s-1,respectively.For the carbon-coated nanorods,excellent rate capability and cyclability were attained.At 5 C,the capacity was 141 mAh g-1 for the first cycle and maintained 120 mAh g-1 after 100 cycles;at 10 C,the capacity was still as high as 132 mAh g-1.WU Miao WANG ZhaoHui YUAN LiXia ZHANG WuXing HU XianLuo HUANG YunHui 2012Chinese Science Bulletin2012,57,32:4
12MicroRNA Expression Signature and Antisense-Mediated Depletion Reveal an Essential Role of MicroRNA in Vascular Neointimal Lesion Formation显示文摘Ruirui Ji Yunhui Cheng Junming Yue Jian Yang Xiaojun Liu He Chen David B. Dean Chunxiang Zhang 2007Circulation Research2007,,11:4
13Synthesis,microstructure,and properties of high purity Mo_(2)TiAlC_(2) ceramics fabricated by spark plasma sintering显示文摘The synthesis,microstructure,and properties of high purity dense bulk Mo_(2)TiAlC_(2) ceramics were studied.High purity Mo_(2)TiAlC_(2) powder was synthesized at 1873 K starting from Mo,Ti,Al,and graphite powders with a molar ratio of 2:1:1.25:2.The synthesis mechanism of Mo_(2)TiAlC_(2) was explored by analyzing the compositions of samples sintered at different temperatures.It was found that the Mo_(2)TiAlC_(2) phase was formed from the reaction among Mo3Al2C,Mo2C,TiC,and C.Dense Mo_(2)TiAlC_(2) bulk sample was prepared by spark plasma sintering(SPS)at 1673 K under a pressure of 40 MPa.The relative density of the dense sample was 98.3%.The mean grain size was 3.5μm in length and 1.5μm in width.The typical layered structure could be clearly observed.The electrical conductivity of Mo_(2)TiAlC_(2) ceramic measured at the temperature range of 2-300 K decreased from 0.95×10^(6) to 0.77×10^(6)Ω^(-1)·m^(-1).Thermal conductivity measured at the temperature range of 300-1273 K decreased from 8.0 to 6.4 W·(m·K)^(-1).The thermal expansion coefficient(TEC)of Mo_(2)TiAlC_(2) measured at the temperature of 350-1100 K was calculated as 9.0×10^(-6) K^(-1).Additionally,the layered structure and fine grain size benefited for excellent mechanical properties of low intrinsic Vickers hardness of 5.2 GPa,high flexural strength of 407.9 MPa,high fracture toughness of 6.5 MPa·m^(1/2),and high compressive strength of 1079 MPa.Even at the indentation load of 300 N,the residual flexural strength could hold 84% of the value of undamaged one,indicating remarkable damage tolerance.Furthermore,it was confirmed that Mo_(2)TiAlC_(2) ceramic had a good oxidation resistance below 1200 K in the air.Yunhui NIU Shuai FU Kuibao ZHANG Bo DAI Haibin ZHANG Salvatore GRASSO Chunfeng HU 2020Journal of Advanced Ceramics2020,9,6:4
14Nature and evolution of the lithospheric mantle revealed by water contents and He-Ar isotopes of peridotite xenoliths from Changbaishan and Longgang basalts in Northeast China显示文摘The nature and evolution of the lithospheric mantle underlying Northeast(NE)China were investigated by assessing the mineral chemistry,water contents,and noble gas(He-Ar)isotopes of peridotite xenoliths captured by Cenozoic basalts from the Changbaishan and Longgang regions.The xenoliths,which have863–1141℃ equilibration temperatures,primarily comprise spinel lherzolites and rare spinel harzburgites.The Mg#(Fo)values of olivine in the peridotite xenoliths vary from 86.9 to 91.3.The clinopyroxenes have high Ti/Eu and low(La/Yb)N,and their chondrite-normalized rare earth elements(REEs)exhibit light REE-depletion to-enrichment patterns,indicating that the mantle underneath the investigated region was predominantly subjected to partial melting(1%–10%)and was metasomatized by silicate melts.The measured3He/4He ratios of the Changbaishan xenoliths have a narrow range from 5.8 Ra to 8.4 Ra with an average of 7.4 Ra.The3He/4He isotopic ratios of the Longgang xenoliths varied from 4.7 Ra to8.1 Ra with an average of 5.9 Ra;slightly lower than the Changbaishan xenoliths.The whole-rock H2Ocontents of the studied peridotite ranged from 9 to 132 ppm.The high H2O contents in excess of50 ppm(up to 132 ppm)might represent newly accreted and cooled asthenospheric materials,while those with H2O contents lower than 50 ppm(as little as 9 ppm)may represent thinned,relic,ancient lithospheric mantle.These geochemical evidences,in combination with published data,indicated that the lithospheric mantle beneath the Changbaishan and Longgang in NE China is dominated by the younger and more fertile lithospheric mantle with a minor ancient and refractory keel.In addition,the lithospheric mantle of this area was metasomatized by melts related to the recent subduction event(e.g.,Pacific oceanic plate).Therefore,the westward-dipping Pacific oceanic plate subduction had an important contribution to the transformation of the lithospheric mantle beneath NE China.Qinghu Xu Jiaqi Liu Huaiyu He Yunhui Zhang 2019Science Bulletin2019,64,18:4
15Semi-solid Processing of Al-7Graghite Composite显示文摘Al-7graphite composite was processed using Al-7graphite mushy prepared by electromagnetic-mechanical stirring method, and the influence of solid fraction on the distributing of graphite particles in ingot was studied. The results shows that the relationship between solid fraction and stirring temperature of mushy is:fs=591.5-0.897 t(wherefs is the solid fraction, t is the stirring temperature). For Al-7graphite composite, with the increasing of solid fraction, the aggregation extent of graphite particles reduced gradually, and when solid fraction was larger than 30%, graphite particles could distribute evenly in ingot.Peng Zhang, Yunhui Du, Daben Zeng Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China 2001Journal of University of Science and Technology Beijing2001,8,3:4
16Analysis of the mass of behind-armor debris generated by RHA subjected to normal penetration of variable cross-section EFP显示文摘Analyzing the mass of behind-armor debris (BAD) generated by Rolled Homogeneous Armor (RHA) subjected to normal penetration of variable cross-section Explosively Formed Projectile (EFP) is the purpose of this paper. So theoretical analysis, numerical simulation and experimental data are combined to analyze the influence of variable cross-section characteristic on the time history of crater radius. Moreover the relationships between time history of crater radius (as well as mass of BAD) and the thickness of RHA (from 30mm to 70 mm) and the impact velocity of EFP (1650 m/s to 1860 m/s) are also investigated. The results indicate that: 1) being compared to the variable cross-section characteristic is ignored, the theoretical time history of crater radius is in better agreement with the simulation results when the variable cross-section characteristic is considered;2) being compared to the other three conditions of plug, the theoretical mass of BAD is in the best agreement with the simulation results when the shape of plug is frustum of a cone and the angle between generatrix and bottom is 45- and the axial length of mushroom is considered.Boyang Xing Dongjiang Zhang Zhenyan Guo Yunhui Hou Rui Guo Rongzhong Liu Liang Chen Hao Zhou Yongliang Yang Jianhua Luo 2019Defence Technology(防务技术)2019,15,3:4
17Natural Feature-based Visual Servoing for Grasping Target with an Aerial Manipulator显示文摘Aerial transportation and manipulation have attracted increasing attention in the unmanned aerial vehicle field,and visual servoing methodology is widely used to achieve the autonomous aerial grasping of a target object.However,the existing marker-based solutions pose a challenge to the practical application of target grasping owing to the difficulty in attaching markers on targets.To address this problem,this study proposes a novel image-based visual servoing controller based on natural features instead of artificial markers.The natural features are extracted from the target images and further processed to provide servoing feature points.A six degree-of-freedom(6-DoF)aerial manipulator system is proposed with differential kinematics deduced to achieve aerial grasping.Furthermore,a controller is designed when the target object is outside a manipulator's workspace by utilizing both the degrees-of-freedom of nnmanned aerial vehicle and manipulator joints.Thereafter,a weight matrix is used as basis to develop a multi-tasking visual servoing framework to integrate the controllers inside and outside the manipulator's workspace.Lastly,experimental results are provided to verify the effectiveness of the proposed approach.Bin Luo Haoyao Chen Fengyu Quan Shiwu Zhang Yunhui Liu 2020Journal of Bionic Engineering2020,17,2:4
18Combination of hydrophobically modified γ-poly(glutamic acid)and trehalose achieving high cryosurvival of RBCs显示文摘Trehalose is expected to be an alternative for toxic glycerol as a biocompatible cryoprotectant of red blood cells(RBCs).In this work,γ-poly(glutamic acid)(PGA)is modified by grafting hydrophobic phenethylamine,3,4-dimethoxyphenylethylamine and dodecylamine,respectively.The graft-modified PGA can significantly enhance cryosurvival of RBCs in combination with trehalose.Analyses of dynamic light scattering,hemolysis assay,atomic force microscope and confocal laser scanning microscope suggest that the modified PGA polymers can self-assemble into nanoparticles in phosphate buffer saline solutions at the pH range of 6.0–7.4,and exhibit membrane-disruptive activity due to hydrogen bond,conjugation and hydrophobic interactions with cell membranes.It is assumed that the modified PGA polymers can improve the cryosurvival of RBCs by promoting membrane permeability of trehalose.Among the three graft-modified polymers,phenethylamine-grafted PGA(PGA-g-PEA)can significantly increase the intracellular trehalose-loading content to 11.3±2.4 m M at pH 7.4,much higher than the value0.17±0.66 m M when trehalose is used without any polymers.In view of the aforementioned merit,the cryosurvival rate of sheep RBCs is increased to about 90%by incubation with 1.0 mg mL-1 PGA-g-PEA and 0.36 M trehalose.In vitro cell culture of L929 fibroblasts demonstrates low cytotoxicity of PGA-g-PEA.Therefore,hydrophobic PEA-modified PGA with enhanced intracellular trehalose-loading ability can be potentially applied in glycerol-free RBC cryopreservation or other related biomacromolecule delivery systems.ZHANG QiFa LIU Bo CHONG JingHui REN LiXia ZHAO YunHui YUAN XiaoYan 2021Science China(Technological Sciences)2021,64,4:4
19Improved breakdown strength and energy density of polyimide composites by interface engineering between BN and BaTiO3 fibers显示文摘Conventionally,interface effects between polymers and fillers are essential for determining the breakdown strength and energy storage density of polymer-based dielectric composites.In this study,we found that interface effects between different fillers have similar behavior.BN and Ba TiO3 fiber composite fillers with three different interface bonding strengths were successfully achieved by controlling composite processes(BT-fiber/BNBaoquan Wan Haiyu Li Yunhui Xiao Zhongbin Pan Qiwei Zhang 2021Journal of Materials Science & Technology2021,,15:4
20Post-Synthetic and In Situ Vacancy Repairing of Iron Hexacyanoferrate Toward Highly Stable Cathodes for Sodium-Ion Batteries显示文摘Iron hexacyanoferrate(FeHCF)is a promising cathode material for sodium-ion batteries.However,FeHCF always suffers from a poor cycling stability,which is closely related to the abundant vacancy defects in its framework.Herein,post-synthetic and in-situ vacancy repairing strategies are proposed for the synthesis of highquality FeHCF in a highly concentrated Na_(4)Fe(CN)_(6) solution.Both the post-synthetic and in-situ vacancy repaired FeHCF products(FeHCF-P and FeHCF-I)show the significant decrease in the number of vacancy defects and the reinforced structure,which can suppress the side reactions and activate the capacity from low-spin Fe in FeHCF.In particular,FeHCF-P delivers a reversible discharge capacity of 131 mAh g^(−1) at 1 C and remains 109 mAh g^(−1) after 500 cycles,with a capacity retention of 83%.FeHCF-I can deliver a high discharge capacity of 158.5 mAh g^(−1) at 1 C.Even at 10 C,the FeHCF-I electrode still maintains a discharge specific capacity of 103 mAh g^(−1) and retains 75% after 800 cycles.This work provides a new vacancy repairing strategy for the solution synthesis of high-quality FeHCF.Min Wan Rui Zeng Jingtao Meng Zexiao Cheng Weilun Chen Jiayu Peng Wuxing Zhang Yunhui Huang 2022Nano-Micro Letters2022,14,1:3
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