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| 1 | Cocrystallization of N-donor type compounds with 5-sulfosalicylic acid:The effect of hydrogen-bonding supramolecular architectures显示文摘Benzotriazole,N,N'-dimethylpiperazine and N-methylpiperazine were applied to crystallize with 5-sulfosalicylic acid(5-H2SSA),affording three new binary molecular cocrystals [(C6H6N3+).(C7H5O6S-)].H2O(1),[(C6H16N22+)1/2.(C7H5O6S-)].H2O(2) and [(C5H14N22+).(C7H5O6S-)2].3H2O(3) under general conditions.Proton-transferring occurs from acid to nitrogen of N-donor compounds in all compounds 1,2 and 3.Analysis of the hydrogen-bonding synthons and their effects on crystal packing were also presented in the context of crystal engineering and host-guest chemistry.In compound 1,1-D infinite chains are extended to a 2-D layered architecture via strong O-H...O hydrogen bonds and then to a 3-D network by N-H...O interactions.Compound 2 and 3 both have the 1-D chain which is formed by O-H...O bonds and weak C-H...O hydrogen bonds.A common intramolecular S(6) [synthon I] ring is formed by the hydroxyl with the carboxyl group in all three compounds. | WANG Lei XU LingYan XUE RuiFeng LU XiFeng CHEN RuiXin TAO XuTang | 2012 | Science China Chemistry2012,55,1: | 8 |
| 2 | TOOTH CONTACT ANALYSIS OF CONICAL INVOLUTE GEARS显示文摘圆锥形的复杂齿轮的数学模型基于传动和产生机制的理论被开发。牙齿接触分析(TCA ) 被执行用交叉并且交叉的轴检验圆锥形的复杂齿轮对的协调并且适用的接触。另外,齿轮表面的主要方向和弯曲被调查,交配牙齿表面的接触椭圆也被学习。最后,数字解说性的例子被提供表明计算结果,测试齿轮被成为忍受 fortooth 测试,并且结论被验证理论有适用性。 | HE Jingliang WU Xutang CUI Yahui NIE Gang | 2006 | Chinese Journal of Mechanical Engineering2006,19,1: | 6 |
| 3 | Single Crystal Fibers:Diversified Functional Crystal Material显示文摘Single crystal fibers(SCF)are considered to be a combination of bulk crystals and conventional fibers,thereby possessing the stable physical and chemical properties accompanied with excellent waveguide properties.This paper gives a detailed introduction to the development history of single crystal fibers,including the evolution of the growth technique and the optimization of the growth process.Laser-heated pedestal growth(LHPG)and Micro-pulling-down(μ-PD)methods are considered to be the most widely used growth techniques for growing single crystal fibers,and the advantages of the two methods are also introduced in detail.The second part of this paper describes the characterization of single crystal fibers,including diameter fluctuation,crystal quality and optical losses.A series of cladding approaches for SCF,such as magnetron sputtering,sol-gel,liquid phase epitaxy,co-drawing LHPG,ion implantation and micro-structure cladding will be reviewed.In addition,the research status of single crystal fiber laser and single crystal fiber sensor are also summarized in view of the current research foundation. | Tao Wang Jian Zhang Na Zhang Siyuan Wang Baiyi Wu Na Lin Peter Kusalik Zhitai Jia Xutang Tao | 2019 | Advanced Fiber Materials2019,1,3: | 5 |
| 4 | Toward emerging gallium oxide semiconductors:A roadmap显示文摘Owing to the advantages of ultra-wide bandgap and rich material systems,gallium oxide(Ga_(2)O_(3))has emerged as a highly viable semiconductor material for new researches.This article mainly focuses on the growth processes,material characteristics,and applications of Ga_(2)O_(3).Compared with single crystals and the epitaxial growth of other wide-bandgap semiconductors,large-size and high-quality��-Ga_(2)O_(3) single crystals can be efficiently grown with a low cost,making them highly competitive.Thanks to the availability of high-quality single crystals,epi-taxial films,and rich material systems,high-performance semiconductor devices based on Ga_(2)O_(3) go through a booming development in recent years.The defects and interfaces of Ga_(2)O_(3) are comprehensively analyzed owing to their significant influence on practical applications.In this study,the two most common applications of Ga_(2)O_(3) materials are introduced.The high breakdown electric field,high working temperature,and excellent Baliga’s figure-of-merit of Ga_(2)O_(3) represent an inspiring prospect for power electronic devices.In addition,the excellent absorption in deep-ultraviolet band provides new ideas for optoelectronic detectors and ensures the dramatic progress.Finally,the summary,challenges,and prospects of the Ga_(2)O_(3) materials and devices are presented and discussed. | Yuan Yuan Weibing Hao Wenxiang Mu Zhengpeng Wang Xuanhu Chen Qi Liu Guangwei Xu Chenlu Wang Hong Zhou Yanni Zou Xiaolong Zhao Zhitai Jia Jiandong Ye Jincheng Zhang Shibing Long Xutang Tao Rong Zhang Yue Hao | 2021 | Fundamental Research2021,1,6: | 5 |
| 5 | DESIGN OF NONCIRCULAR GEARS WITH DISCONTINUOUS PITCH CURVE显示文摘当非圆形的齿轮对与齿轮被用于连续地可变的传播(CVT ) 时,传播比率功能是不连续的,根据这“唯一的特征,设计的一条新途径和有不连续的沥青的非圆形的齿轮弄弯的分析被建议。有不连续的沥青曲线的各种各样的非圆形的齿轮对的设计功课基于花键适合和“ fairing 边界状况”的数字算法被统一。根据不连续的沥青曲线的个性,牙齿分发的规则和过程被推荐。undercut 为什么被形成并且怎么基于协调原则管理 undercut,详细被解释。另外,为每个牙齿侧面片断的计算公式也被导出。如果牙齿侧面数据是计算的,测量和切口处理因为非圆形的齿轮能被进行, CADsimulation 能容易被完成。保证传播的连续性,在沥青曲线关节点被定位的牙齿的传播干扰被 utilizingBezier 曲线与 CAD 管理软件。并且齿轮对的接触比率被获得。案例研究证明这条途径是成功的并且为非圆形的齿轮的设计开创一个新方法。 | ZHANG Rui WU Xutang | 2006 | Chinese Journal of Mechanical Engineering2006,19,4: | 5 |
| 6 | A review of β-Ga_2O_3 single crystal defects, their effects on device performance and their formation mechanism显示文摘As a wide-bandgap semiconductor(WBG), β-Ga_2O_3 is expected to be applied to power electronics and solar blind UV photodetectors. In this review, defects in β-Ga_2O_3 single crystals were summarized, including dislocations, voids, twin, and small defects. Their effects on device performance were discussed. Dislocations and their surrounding regions can act as paths for the leakage current of SBD in single crystals. However, not all voids lead to leakage current. There's no strong evidence yet to show small defects affect the electrical properties. Doping impurity was definitely irrelated to the leakage current. Finally, the formation mechanism of the defects was analyzed. Most small defects were induced by mechanical damages. The screw dislocation originated from a subgrain boundary. The edge dislocation lying on a plane slightly tilted towards the(102) plane, the(101) being the possible slip plane. The voids defects like hollow nanopipes, PNPs, NSGs and line-shaped grooves may be caused by the condensation of excess oxygen vacancies, penetration of tiny bubbles or local meltback. The nucleation of twin lamellae occurred at the initial stage of 'shoulder part' during the crystal growth. These results are helpful in controlling the occurrence of crystal defects and improving the device performance. | Bo Fu Zhitai Jia Wenxiang Mu Yanru Yin Jian Zhang Xutang Tao | 2019 | Journal of Semiconductors2019,40,1: | 5 |
| 7 | Recent progress in terahertz modulation using photonic structures based on two-dimensional materials显示文摘Terahertz(THz)technology has attracted great attention in the past few decades for its unique applications in various fields,including spectroscopy,noninvasive detection,wireless communications,and imaging.In parallel to this,the practical,fast,and broadband modulation of THz waves is becoming indispensable.Two-dimensional(2D)materials exhibit unusual optical and electrical properties,which has prompted tremendous interest and significant advances in THz modulation.This review provides the recent progress in 2D materials-based THz modulators,outlining the operating principles,including all-optical,electro-optic,magneto-optic,and other exotic mechanisms.We focus on the recent advances in THz modulation by the designed photonic structures,such as heterostructure,metamaterial,capacitor,optical cavity,and waveguide integration.Lastly,we discussed the challenges and opportunities for 2D materials-based THz modulators and presented our prospects for the future development. | Ziming Wang Jie Qiao Shuqi Zhao Shilei Wang Chuan He Xutang Tao Shanpeng Wang | 2021 | InfoMat2021,3,10: | 4 |
| 8 | Bulk gallium oxide single crystal growth显示文摘Gallium oxide, as a new type of ultra-wide bandgap semiconductor, is expected to be used in power electronics and solar blind UV photodetectors. The main cause of research and development onβ-Ga2O3 is inspired by its larger bandgap, higher breakdown field, bigger Baliga figure-of-merit (FOM), shorter absorption edge and lower cost compared to the third-generation semiconductors, such as SiC and GaN. | Xutang Tao | 2019 | Journal of Semiconductors2019,40,1: | 2 |
| 9 | Λ-Shaped optoelectronic materials based on Trger's base显示文摘Trger's base (TB) is a well-known chiral molecule with rigid concave shape that makes it applicable in different areas such as superamolecular chemistry,molecular recognition,biological labeling,and so on.In this article,we briefly summarize some recent research progress in the optoelectronic properties of novel TB analogues and their applications in optoelectronic field with emphasis on the developments achieved in our group. | YUAN ChunXue,XIN Qian,LIU HuiJun,WANG Lei,JIANG MinHua & TAO XuTang State Key Laboratory of Crystal Materials Shandong University,Jinan 250100,China | 2011 | Science China Chemistry2011,54,4: | 2 |
| 10 | Complex‐Formation‐Enhanced Fluorescence Quenching Effect for Efficient Detection of Picric Acid显示文摘 | Aixiang Ding Longmei Yang Yuyang Zhang Gaobin Zhang Lin Kong Xuanjun Zhang Yupeng Tian Xutang Tao Jiaxiang Yang | 2014 | Chem. Eur. J2014,,38: | 1 |
| 11 | Rapid epitaxy of 2-inch and high-quality α-Ga_(2)O_(3) films by mist-CVD method显示文摘High thickness uniformity and large-scale films of α-Ga_(2)O_(3) are crucial factors for the development of power devices.In this work, a high-quality 2-inch α-Ga_(2)O_(3) epitaxial film on c-plane sapphire substrates was prepared by the mist-CVD method.The growth rate and phase control mechanisms were systematically investigated. The growth rate of the α-Ga_(2)O_(3) films was limited by the evaporation of the microdroplets containing gallium acetylacetonate. By adjusting the substrate position(z) from 80 to 50 mm, the growth rate was increased from 307 nm/h to 1.45 μm/h when the growth temperature was fixed at 520 °C.When the growth temperature exceeded 560 °C, ε-Ga_(2)O_(3) was observed to form at the edges of 2-inch sapphire substrate.Phase control was achieved by adjusting the growth temperature. When the growth temperature was 540 °C and the substrate position was 50 mm, the full-width at half maximum(FWHM) of the rocking curves for the(0006) and(10-14) planes were 0.023° and 1.17°. The screw and edge dislocations were 2.3 × 10~6 and 3.9 × 10~(10)cm~(-2), respectively. Furthermore, the bandgaps and optical transmittance of α-Ga_(2)O_(3) films grown under different conditions were characterized utilizing UV-visible and near-IR scanning spectra. | Xiaojie Wang Wenxiang Mu Jiahui Xie Jinteng Zhang Yang Li Zhitai Jia Xutang Tao | 2023 | Journal of Semiconductors2023,44,6: | 1 |
| 12 | Top-seeded solution growth, morphology, and properties of a polar crystal Cs2TeMo3O12 显示文摘 | ZHANG Junjie TAO Xutang SUN Youxuan | 2011 | Cryst Growth Des2011,11,5: | 1 |
| 13 | Novel BaTeMo2O9 fine particles synthesized via a supercritical water route显示文摘 | ZHENG Qingxin LI Bo TAO Xutang | 2011 | Cryst Eng Comm2011,13,: | 1 |
| 14 | Bulk growth and characterization of a novel nonlinear optical crystal BaTeMo2O9 显示文摘 | ZHANG Weiguo TAO Xutang ZHANG Chengqian et al | 2008 | Cryst Growth Des2008,8,1: | 1 |
| 15 | Growth of CdSiP 2 single crystals by self-seeding vertical Bridgman method显示文摘 | Guodong Zhang Xutang Tao Huapeng Ruan Shanpeng Wang Qiong Shi | 2011 | Journal of Crystal Growth2011,,: | 1 |
| 16 | Structure and thermal properties of the nonlinear opti- cal crystal BaTeMo2O9 显示文摘 | ZHANG Weiguo TAO Xutang ZHANG Chengqian | 2009 | Cryst Growth Des2009,9,6: | 1 |
| 17 | Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal 显示文摘 | GAO Zeliang TAO Xutang YIN Xin | 2008 | Appl Phys Lett2008,93,25: | 1 |
| 18 | Hydrogen-bonding directed cocrystallization of flexible piperazine with hydroxybenzoic acid derivatives:Structural diversity and synthon prediction显示文摘Four hydroxybenzoic acid building blocks,m-hydroxybenzoic acid,2,4-dihydroxybenzoic acid,2,5-dihydroxyterephthalic acid,and 5-hydroxyisophthalic acid,have been synthesized as robust cocrystallizing agents and employed in reactions with piperazine,including [(C4H12N22+).(C7H5O3)2 ](1),[(C4H12N22+).(C 7H5O4)2 ](2),[(C4H12N22+).(C8H5O62)](3),and [(C4H12N22+)1/2.(C8H5O5)].2H2O(4).Hydrogen-bonded directed assemblies of four salts were validated by single-crystal X-ray diffraction analysis.In compounds 1-4,hydroxybenzoic acids are all deprotonated and piperazine molecules are all protonated to form piperazine dications and keep the chair conformation.Thermal stability of these compounds has been investigated. | WANG Lei XUE RuiFeng XU LingYan LU XiFeng CHEN RuiXin TAO XuTang | 2012 | Science China Chemistry2012,55,7: | 1 |
| 19 | Investigation on the key factors in the hydrothermal synthesis of BN: The way of introducing sodium azide显示文摘The way of introducing sodium azide (NaN_3) into the reaction solution played an important role in the preparation of cBN by hydrothermal synthesis method. The results showed that both cBN content and crystalline perfection of the samples improved with increasing R_N value, and pure cBN could be obtained at 300℃ and 10 MPa when R_N increased to 3:1. Here R_N is defined as R_N =NaN_3(I)/NaN_3(II), wherNaN_3(I) denotes the amount of NaN_3 (in molar) that is added into the autoclave at the beginning of threaction process, and NaN_3(II) is the amount of NaN_3 (also in molar) introduced into the autoclave ahigh temperature and high pressure (i.e. 300℃ and 10 MPa). In order to explain the experimental results, a preliminary model was proposed in this paper. | LI Kai JIANG HaiHui LIAN Gang WANG QiLong ZHAO Xian CUI DeLiang TAO XuTang | 2007 | Chinese Science Bulletin2007,52,13: | 1 |
| 20 | Output characteris- tics analysis of planetary elliptic gear train 显示文摘 | Xiong Zhenqin Wu Xutang Gao Benhe | | Chinese Jour- nal of Mechanical En-neering0,15,9: | 1 |