4篇
您的检索式：作者名="Xifeng Shi"
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| 1 | Mn3O4 nanoparticles@reduced graphene oxide composite:An efficient electrocatalyst for artificial N2 fixation to NH3 at ambient conditions显示文摘Currently,industrial-scale NH3 production almost relies on energy-intensive Haber-Bosch process from atmospheric N2 with large amount of CO2 emission,while low-cost and high-efficient catalysts are demanded for the N2 reduction reaction (NRR).In this study,Mn3O4 nanoparticles@reduced graphene oxide (Mn3O4@rGO) composite is reported as an efficient NRR electrocatalyst with excellent selectivity for NH3 formation.In 0.1 M Na2SO4 solution,such catalyst obtains a NH3 yield of 17.4 μg·h^-1·mg^-1cat.and a Faradaic efficiency of 3.52% at-0.85 V vs.reversible hydrogen electrode.Notably,it also shows high electrochemical stability during electrolysis process.Density functional theory (DFT) calculations also demonstrate that the (112) planes of Mn3O4 possess superior NRR activity. | Hong Huang Feng Gong Yuan Wang Huanbo Wang Xiufeng Wu Wenbo Lu Runbo Zhao Hongyu Chen Xifeng Shi Abdullah M.Asiri Tingshuai Li Qian Liu Xuping Sun | 2019 | Nano Research2019，12，5： | 8 |
| 2 | Enhancing electrocatalytic N_(2)-to-NH_(3) fixation by suppressing hydrogen evolution with alkylthiols modified Fe_(3)P nanoarrays显示文摘Electrocatalytic N_(2) reduction provides an attractive alternative to Haber-Bosch process for artificial NH_(3) synthesis.The difficulty of suppressing competing proton reduction,however,largely impedes its practical use.Herein,we design a hydrophobic octadecanethiol-modified Fe_(3)P nanoarrays supported on carbon paper(C18@Fe_(3)P/CP)to effectively repel water,concentrate N_(2),and enhance N_(2)-to-NH_(3) conversion.Such catalyst achieves an NH_(3) yield of 1.80×10^(-10) mol s^(-1)·cm^(-2) and a high Faradaic efficiency of 11.22%in 0.1 M Na_(2)SO_(4),outperforming the non-modified Fe_(3)P/CP(2.16×10^(-11) mol s^(-1)·cm^(-2),0.9%)counterpart.Significantly,C18@Fe_(3)P/CP renders steady Nrfixing activlty/selectivity in cycling test and exhibits durability for at least 25 h.First-principles calculations suggest that the surface electronic structure and chemical activity of Fe_(3)P can be well tuned by the thiol modification,which facilitates N_(2) electroreduction activity and catalytic formation of NH_(3). | Tong Xu Jie Liang Yuanyuan Wang Shaoxiong Li Zhaobai Du Tingshuai Li Qian Liu Yonglan Luo Fang Zhang Xifeng Shi Bo Tang Qingquan Kong Abdullah M.Asiri Chun Yang Dongwei Ma Xuping Sun | 2022 | Nano Research2022，15，2： | 4 |
| 3 | High Performance Supercapacitors from Hierarchical Porous Carbon Aerogels Based on Sliced Bread显示文摘 | Pin Hao Guanwei Cui Xifeng Shi Junfeng Xie Xinyuan Xia Yuanhua Sang C. P. Wong Hong Liu Bo Tang | 2017 | Chinese Journal of Chemistry2017，35，5： | 2 |
| 4 | Associations between cytochrome P4502E1 genotype,mutagen sensitivity,cigarette smoking and susceptibility to lung cancer显示文摘 | Xifeng Wu Huihui Shi Hong Jiang | 1997 | Carcinogenesis1997，18，5： | 1 |
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