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| 1 | Biomass-derived bifunctional electrocatalysts for oxygen reduction and evolution reaction: A review显示文摘Oxygen electrode catalysts are important as inter-conversion of O_(2) and H_(2)O is crucial for energy technologies.However,the sluggish kinetics of oxygen reduction and evolution reactions(ORR and OER)are a hindrance to their scalable production,whereas scarce and costly Pt and Ir/Ru-based catalysts with the highest electrocatalytic activity are commercially unviable.Since good ORR catalysts are not always efficient for OER and vice versa,so bifunctional catalysts on which OER and ORR occurs on the same electrode are very desirable.Alternative catalysts based on heteroatom-doped carbon nanomaterials,though showed good electrocatalytic activity yet their high cost and complex synthesis is not viable for scalable production.To overcome these drawbacks,biomass-derived heteroatom-doped porous carbons have recently emerged as low-cost,earth-abundant,renewable and sustainable environment-friendly materials for bifunctional oxygen catalysts.The tunable morphology,mesoporous structure and high concentration of catalytic active sites of these materials due to heteroatom(N)-doping could further enhance their ORR and OER activity,along with tolerance to methanol crossover and good durability.Thus,biomassderived heteroatom-doped porous carbons with large surface area,rich edge defects,numerous micropores and thin 2 D nanoarchitecture could be suitable as efficient bifunctional oxygen catalysts.In the present article,synthesis,N-doping,ORR/OER mechanism and electrocatalytic performance of biomassderived bifunctional catalysts has been discussed.The selected biomass(chitin,eggs,euonymus japonicas,tobacco,lysine and plant residue)except wood,act as both C and N precursor,resulting in N selfdoping of porous carbons that avoids the use of toxic chemicals,thus making the synthesis a facile and environment-friendly green process.The synthetic strategy could be further optimized to develop future biomass-based N self-doped porous carbons as metal-free high performance bifunctional oxygen catalysts for commercial energy applications.Recent advances and the importance of biomass-based bifunctional oxygen catalysts in metal-air batteries and fuel cells has been highlighted.The material design,perspectives and future directions in this field are also provided. | Satpal Singh Sekhon Jaeyoung Lee Jin-Soo Park | 2022 | Journal of Energy Chemistry2022,31,2: | 3 |
| 2 | The Role and Timing of Decompression in Acute Spinal Cord Injury: What Do We Know? What Should We Do?显示文摘 | Michael G. Fehlings Lali H.S. Sekhon Charles Tator | 2001 | 2001 (24S)2001,,24: | 2 |
| 3 | Effect of projectile nose shape,impact velocity and target thickness on the de-formation behavior of layered plates显示文摘 | Gupta N K Iqbal M A Sekhon G S | 2008 | Int J Impact Eng2008,35,1: | 1 |
| 4 | Identification of cytomegalovirus in a liquid-based gynecologic sample using morphology, immunohistochemistry,and DNA real-time PCR detection显示文摘 | Sekhon HS Press RD Schmidt WA | 2004 | Diagn Cytopathol2004,30,6: | 1 |
| 5 | Complications with cervical arthroplasty显示文摘 | Pickett GE Sekhon LH Sears WR | 2006 | Journal of Neurosurgery Spine2006,4,2: | 1 |
| 6 | The role and timing of decompression in acute spinal cord injury 显示文摘 | Fehling MG Sekhon LH Tator C | 2001 | Spine2001,26,24: | 1 |
| 7 | Prebiotics, probiotics and synbiotics: an overview显示文摘 | Sekhon B S Jairath S | 2010 | J Pharm Educ Res2010,1,2: | 1 |
| 8 | Expression of a putative flavonoid 3'-hydroxylase in sorghum mesocotyls synthesizing 3-deoxyanthocyanidin phytoalexins 显示文摘 | Boddu J Svabek C Sekhon R | 2004 | Physiol Mol Plant Pathol2004,65,2: | 1 |
| 9 | Genome-wide atlas of transcription through maize development显示文摘 | Sekhon R S Lin H Childs K L Hirsch C N Buell C R de Leon N Kaeppler S M | 2011 | The Plant Journal2011,66,4: | 1 |
| 10 | False-positive troponin I measured with the Abbott AxSYM attributed to fibrin interference显示文摘 | Kazmierczak S C Sekhon H Richards C | 2005 | International Journal of Cardiology2005,101,: | 1 |
| 11 | Administration of N-acetylcysteine after focal cerebral ischemia protects brain and reduces inflammation in a rat model of experimental stroke显示文摘 | Khan M Sekhon B Jatana M | 2004 | J Neurosci Res2004,76,4: | 1 |
| 12 | N-Acetyl cysteine protects against injury in a rat model of focal cerebral ischemial 显示文摘 | Sekhon B Sekhon C Khan M | 2003 | Brain Research2003,971,1: | 1 |
| 13 | Nanodispersed polymer gel electrolytes: Conductivity modification with the addition of PMMA and fumed silica 显示文摘 | Sharma J P Sekhon S S | 2007 | Solid State Ionics2007,178,: | 1 |
| 14 | Study of lateral compression of round metallic tubes显示文摘 | Gupta N K Sekhon G S | 2005 | Thin-Walled Structures2005,,6: | 1 |
| 15 | S-Nitrosoglutathione reduces inflammation and protects brain against focal cerebral ischemia in a rat model of experimental stroke显示文摘 | Khan M Sekhon B Giri S | 2005 | J Cereb Blood Flow Metab2005,25,2: | 1 |
| 16 | Cervical arthroplasty after previous surgery: results of treating 24 discs in 15 patients显示文摘 | Sekhon LH Sears W Duggal N | 2005 | J Neuro- surg Spine2005,3,5: | 1 |
| 17 | Objective determination of the noise level in Doppler spectra显示文摘 | Hildebrand P H Sekhon R S | 1974 | Journal of Applied Mete- orology1974,13,7: | 1 |
| 18 | Timing of decompression and fixation after spinal cord injury-when is surgery optimal 显示文摘 | Ball JR Sekhon LH | 2006 | Crit Care Resusc2006,8,1: | 1 |
| 19 | Administration of Nacetylcysteine after focal cerebral Ischemia protects brain and reduces inflammation in a rat model of experimental stroke 显示文摘 | KHAN M SEKHON B JATANA M | 2004 | J Neurosci Res2004,6,4: | 1 |
| 20 | Myopia affects retinal nerve fiber layer measurements as determined by optical coherence tomography 显示文摘 | Rauscher FM Sekhon N Feuer WJ | 2009 | J Glaucoma2009,18,7: | 1 |