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| 1 | Paleomagnetic data from Early Cretaceous volcanic rocks of West Liaoning:Evidence for intracontinental rotation显示文摘Detailed rock magnetic studies of 55 lavas from Yixian and Fuxin area, West Liaoning, show the primary carriers of remanence to be pseudo-single domain ti-tanomagnetite. K/Ar dating indicates that the volcanic sequence spans 93 to 133 Ma. Stepwise thermal demagnetization successfully isolated well-defined characteristic magnetization (ChRM) in all lavas thermal-treated above 250℃ The mean paleodirections are D/I=5.9°/58.8° (α95 = 2.9°) and D/I =179.2°/-59.9° (α95 = 5.2°) for 27 normally magnetized flows and 28 reversibly magnetized flows, respectively. It indicates that since the Early Cretaceous there is no significant horizontal movement and rotation between the Yixian-Fuxin area and Eurasia. However, Korea Peninsula may have undergone a clockwise rotation of 33.9° relative to the Yixian-Fuxin area during the Cretaceous. On the basis of characteristics of hotspot origins (core-mantle boundary or upper mantle), the clockwise rotation of Korea Peninsula relative to Eurasia is assumed to be | ZHU Rixiang SHAO Ji’an PAN Yongxin SHI Ruiping SHI Guanghai LI Darning | 2002 | Chinese Science Bulletin2002，47，21： | 31 |
| 2 | First observation of mesospheric and thermospheric winds by a Fabry-Perot interferometer in China显示文摘A Fabry-Perot interferometer,funded by the Meridian Project in China,was deployed at the Xinglong station(40.2°N,117.4°E) of the National Astronomical Observatories in Hebei Province,China.The instrument has been operating since April 2010,measuring mesospheric and thermospheric winds.The first observational data of winds at three heights in the mesosphere and thermosphere were analyzed,demonstrating the capacity of this instrument to aid basic scientific research.The wavelengths of three airglow emissions were OH892.0,OI 557.7,and OI 630.0 nm,which corresponded to heights of 87,98,and 250 km,respectively.Three 38-day data sets of horizontal winds,from April 5,2010 to May 12,2010,show clear day-to-day variations at the same height.The minimum and maximum meridional winds at heights of 87,98,and 250 km were-16.5 to 8.7 m/s,-24.4 to 15.9 m/s,and-43.6 to 1.5 m/s.Measurements of zonal winds were-5.4 to 7.6 m/s,2.3 to 23.0 m/s,and-22.6 to 49.3 m/s.The average data from the observations was consistent with the data from HWM93.The wind data at heights of 87 and 98 km suggest a semi-diurnal oscillation,clearly consistent with HWM93 results.Conversely there was a clear discrepancy between the observations and the model at 250 km.In general,this Fabry-Perot interferometer is a useful ground-based instrument for measuring mesospheric and thermospheric winds at middle latitudes. | YUAN Wei XU JiYao MA RuiPing WU Qian JIANG GuoYing GAO Hong LIU Xiao CHEN SunZheng | 2010 | Chinese Science Bulletin2010，55，35： | 18 |
| 3 | Characterization of the Songhua River sediments and evaluation of their adsorption behavior for nitrobenzene显示文摘The explosion at a plant of the Jilin Petrochemical Corporation on 13 November,2005,and the spill of an estimated 100 t of toxic substances (nitrobenzene as the main component) into the Songhua River received worldwide attention.This study has focused on the adsorption behavior of nitrobenzene that spilled onto sediments along the Songhua River,which was one of the efforts to evaluate the fate of nitrobenzene after the spillage event.The organic carbon contents of these sediments along the Songhua River ... | Liu Ruiping Liu Huijuan Wan Dongjin Yang Min | 2008 | Journal of Environmental Sciences2008，20，7： | 15 |
| 4 | Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium–sulfur batteries显示文摘Lithium-sulfur(Li-S) battery is a potential energy storage technology with high energy density and low cost. However, the gap between theoretical expectation and practical performance limits its wide implementation. Herein, we report a nitrogen-doped porous carbon derived from biomass pomelo peel as sulfur host material for Li-S batteries. The hierarchical porous architecture and the polar surface introduced by N-doping render a favorable combination of physical and chemical sulfur confinements as well as an expedite electron/ion transfer, thus contributing to a facilitated and stabilized sulfur electrochemistry. As a result, the corresponding sulfur composite electrodes exhibit an ultrahigh initial capacity of 1534.6 mAh g^-1, high coulombic efficiency over 98% upon 300 cycles, and decent rate capability up to 2 C. This work provides an economical and effective strategy for the fabrication of advanced carbonaceous sulfur host material as well as the significant improvement of Li-S battery performance. | Qinghuiqiang Xiao Gaoran Li Minjie Li Ruiping Liu Haibo Li Pengfei Ren Yue Dong Ming Feng Zhongwei Chen | 2020 | Journal of Energy Chemistry2020，29，5： | 15 |
| 5 | Visible light-induced N-doped TiO_2 nanoparticles for the degradation of microcystin-LR显示文摘N-doped nano-crystalline TiO2 powders have been synthesized by the sol-gel method.The shape and crystal structure of the resulting N-doped TiO2 were investigated by X-ray Photoelectron Spectroscopy (XPS),X-ray spectroscopy (XRD),Transmission Electron Microscopy (TEM) and UV-vis reflection spectrum.The results showed that doping TiO2 with nitrogen can lower its band gap and apparently shift its optical response to the visible region.Under the visible light (λ> 420 nm) irradiation,the MC-LR was degraded by the synthesized N-TiO2 nano-material.The variation of MC-LR amount and its intermediates were detected by high performance liquid chromatography (HPLC) and LC-MS,respectively.The mineralization of MC-LR was determined by total organic carbon (TOC) analysis.Simultaneously,transient oxidative species generated during photocatalysis were tracked by electron spin resonance (ESR) and Peroxidase method.All these results indicated that visible-light excited N-TiO2 can activate molecular oxygen and thereby achieve degradation of MC-LR completely within 14 h.The removal of 59% of TOC was achieved after 20 h irradiation.The major oxidative species in the system were hydroxyl radical (·OH) and H2O2.13 Kinds of intermediates were primarily identified in the process.Based on these results,a reasonable conclusion was drawn for the degradation of MC-LR wherein its four positions are easy to be attacked by the photo-generated OH radical followed by the hydrolyzation of peptides. | YANG Jing,CHEN DengXia,DENG AnPing,FANG YanFen,LUO GuangFu,LI DeJiang,LI RuiPing & HUANG YingPing Alan G.MacDiarmid Research Institute of Renewable Energy,China Three Gorges University,Yichang 443000,China | 2010 | Science China Chemistry2010，53，8： | 12 |
| 6 | Practical performance and its efficiency of arsenic removal from groundwater using Fe-Mn binary oxide显示文摘A treatment unit packed by granular adsorbent of Fe-Mn binary oxide incorporated into diatomite (FMBO(1:1)-diatomite) was studied to remove arsenic from anaerobic groundwater without any pre-treatment or post-treatment. The raw anaerobic groundwater containing 35-45 μg/L of arsenic was collected from suburb of Beijing. Arsenic(III) constituted roughly 60%-80% of the total arsenic content. Approximately 7,000 bed volumes (ratio of efluent volume to adsorbent volume) treated water with arsenic concentration below 10 μg/L were produced in the operation period of four months. The regeneration of FMBO(1:1)-diatomite had been operated for 15 times. In the first stage, the regeneration process significantly improved the adsorption capacity of FMBO(1:1)-diatomite. With increased loading amount of Fe-Mn binary oxide, the adsorption capacity for arsenic decreased 20%-40%. Iron and manganese in anaerobic groundwater were oxidized and adsorptive filtrated by FMBO(1:1)-diatomite efficiently. The final concentrations of iron and manganese in efluents were nearly zero. The continued safe performance of the treatment units proved that adsorbent FMBO(1:1)-diatomite had high oxidation ability and exhibited strong adsorptive filtration. | Fangfang Chang Jiuhui Qu Ruiping Liu Xu Zhao Pengju Lei | 2010 | Journal of Environmental Sciences2010，22，1： | 11 |
| 7 | Pantograph and catenary system with double pantographs for high-speed trains at 350 km/h or higher显示文摘The paper is aimed at developing an optimized design of the pantograph and catenary system with double pantographs at a speed of 350 km/h for the Wuhan-Guangzhou high-speed railway.First,the pantograph and catenary system for the Beijing-Tianjin high-speed railway was analyzed to verify whether its design objective could be fulfilled.It shows that the system is not able to satisfy the requirement of a sustainable running speed of 350 km/h.Then a new scheme for the pantograph and catenary system is proposed through optimization and renovation of the structure and parameters of the pantograph and catenary system,including the suspension type of the catenary,tension of the contact wire,and space between two pantographs.Finally,the dynamic performance of the new system was verified by simulation and line testing.The results show that the new scheme of the pantograph and catenary system for the WuhanGuangzhou high-speed railway is acceptable,in which the steady contact between the rear pantograph and the catenary at the space of 200 m can be maintained to ensure the current-collection quality.A current collection with double pantographs at a speed of 350 km/h or higher can be achieved. | Weihua ZHANG Ning ZHOU Ruiping LI Guiming MEI Dongli SONG | 2011 | Journal of Modern Transportation2011，19，1： | 8 |
| 8 | New discoveries on the effects of desertification on the ground temperature of permafrost and its significance to the Qinghai-Tibet Plateau显示文摘The desert and permafrost conditions of the Qinghai-Tibet Plateau are unique.However,the effects of desertification on the ground temperature of permafrost are currently unclear.Recently,understanding this problem has become more urgent because of increasing desertification on the plateau.For this reason,an observational field experiment was undertaken by the authors at Honglianghe on the Qinghai-Tibet Plateau.Thermistor ground temperature probes were used,and synchronized contrasting observations were made in an open area.Observations of the ground temperature of permafrost below sand layers with a range of thicknesses were made from May 2010 to April 2011.The sand layers were found to play a key role in the protection of the underlying permafrost.The ground temperature below a permafrost table overlain by a thick sand layer was lower than that of the average annual temperature for the natural ground surface,and the temperature drop was roughly constant at 0.2°C.During the warmer part of the year (May to September),the maximum temperature drops over the five months were 3.40,3.72,4.85,3.16,and 1.88°C,respectively.The ground temperature near a permafrost table overlain by a thin sand layer was also lower than that of the average annual temperature for the natural ground surface.However,in this case the average of the annual maximum temperature drop was significantly less,0.71°C.The scientific significance of our preliminary conclusions is not only to present an exploration of the interaction between desertification and permafrost,but also to provide new engineering ideas for protecting the permafrost in regions where construction is required on the Qinghai-Tibet Plateau. | XIE ShengBo QU JianJun ZU RuiPing ZHANG KeCun HAN QingJie | 2012 | Chinese Science Bulletin2012，57，8： | 8 |
| 9 | Heavy metal content in scalp hair of the inhabitants near Dexing Copper Mine,Jiangxi Province,China显示文摘Levels of seven metals(Mn,Cu,Zn,Pb,Cr,Cd,and Se) in the scalp hair of Daicun and Xiangtian inhabitants were determined by ICP-MS/AFS.Daicun,as an experimental site,is near Dexing Copper Mine,Jiangxi Province,China,and exposed to mining pollution;Xiangtian,as a control site,is free from any mining and other industrial pollution.The heavy metal distribution in the scalp hair of the two diverse population segments exposed to different environments was discussed against the background of the heavy metal content of local plants,waters,and soils.The results show:1) Levels of Cu,Zn,Pb,Cr,and Cd in the scalp hair of Daicun inhabitants were higher compared with Xiangtian counterparts which showed higher comparative levels of Se and Mn.But there were no significant differences of the levels of Cu and Zn in the hair samples between the two villages.In the hair of the inhabitants in the two villages,the levels for Se,Zn,and Cu were lower,while the level for Mn was higher,than the corresponding levels from other regions of the world.Compared with the standard issued by the Trace Element Research Council of China for Chinese inhabitants there were serious Se,Zn,Cu and Cr-deficiency phenomena in the hair samples from Daicun and Xiangtian.2) Against the geological background of high levels of Zn,Cu,Se and Cr,there were deficiencies of Zn,Cu,Se and Cr in the hair samples of the Daicun population.This may have been caused by the distribution forms of the heavy metals in the soils,and antagonism among the elements.3) Principal Component Analysis(PCA) and Cluster Analysis(CA) indicated that the origins of the heavy metals in the hair samples from the two villages had some differences as well as some similarities,this should be contributed mainly to the influence of the mining activities. | NI ShanQin LI RuiPing WANG AnJian | 2011 | Science China Earth Sciences2011，54，5： | 6 |
| 10 | Review of pantograph and catenary interaction显示文摘 | Weihua ZHANG Dong ZOU Mengying TAN Ning ZHOU Ruiping LI Guiming MEI | 2018 | Frontiers of Mechanical Engineering2018，13，2： | 6 |
| 11 | Development of systems for detection,early warning,and control of pipeline leakage in drinking water distribution:A case study显示文摘Water leakage in drinking water distribution systems is a serious problem for many cities and a huge challenge for water utilities.An integrated system for the detection,early warning,and control of pipeline leakage has been developed and successfully used to manage the pipeline networks in selected areas of Beijing.A method based on the geographic information system has been proposed to quickly and automatically optimize the layout of the instruments which detect leaks.Methods are also proposed to estimate the probability of each pipe segment leaking (on the basis of historic leakage data),and to assist in locating the leakage points (based on leakage signals).The district metering area (DMA) strategy is used.Guidelines and a flowchart for establishing a DMA to manage the large-scale looped networks in Beijing are proposed.These different functions have been implemented into a central software system to simplify the day-to-day use of the system.In 2007 the system detected 102 non-obvious leakages (i.e.,14.2% of the total detected in Beijing) in the selected areas,which was estimated to save a total volume of 2,385,000 m 3 of water.These results indicate the feasibility,efficiency and wider applicability of this system. | Weifeng Li Wencui Ling Suoxiang Liu Jing Zhao Ruiping Liu Qiuwen Chen Zhimin Qiang Jiuhui Qu | 2011 | Journal of Environmental Sciences2011，23，11： | 6 |
| 12 | Progression of motor symptoms in Parkinson’s disease显示文摘Parkinson's disease(PD)is a chronic progressive neurodegenerative disease that is clinically manifested by a triad of cardinal motor symptoms-rigidity,bradykinesia and tremor-due to loss of dopaminergic neurons.The motor symptoms of PD become progressively worse as the disease advances.PD is also a heterogeneous disease since rigidity and bradykinesia are the major complaints in some patients whereas tremor is predominant in others.In recent years,many studies have investigated the progression of the hallmark symptoms over time,and the cardinal motor symptoms have different rates of progression,with the disease usually progressing faster in patients with rigidity and bradykinesia than in those with predominant tremor.The current treatment regime of dopamine-replacement therapy improves motor symptoms and alleviates disability.Increasing the dosage of dopaminergic medication is commonly used to combat the worsening symptoms.However,the drug-induced involuntary body movements and motor complications can significantly contribute to overall disability.Further,none of the currently-available therapies can slow or halt the disease progression.Significant research efforts have been directed towards developing neuroprotective or disease-modifying agents that are intended to slow the progression.In this article,the most recent clinical studies investigating disease progression and current progress on the development of disease-modifying drug trials are reviewed. | Ruiping Xia Zhi-Hong Mao | 2012 | Neuroscience Bulletin2012，28，1： | 6 |
| 13 | Effect of Different Calcium Levels on Growth,Yield and Fruit Quality of Tomatoes in Substrate Culture显示文摘Tomato seedlings were grown in substrate culture with pots. The formulation of Holland Greenhouse Horticulture Research Institute was used(as CK) and the effects of different Ca concentrations(LCa, CK and HCa)on growth, yield, and fruit quality(protein, Vitamin C, nitrates, organic acid and soluble sugar) of tomato were studied keeping concentrations of other nutrients unchanged in the nutrient solution. The results showed that parameters related to the growth of tomato(plant height and Stem diameter), changes of tomato yield per plant and quality of tomato fruits were the highest when the plants were grown at 20% Ca treatments. In the second study, increased EC concentrations of nutrient solution resulted in stronger plants with improved yields and quality. Four different concentration gradients of nutrient solution treatment were designed based on the results of the first research stage(EC=1.5, 2.5, 3.5, 4.5 m S/cm, respectively). The single tomato plant had the highest production which is 2 268.994 g/plant, when the nutrient solution strength was at EC=1.5 m S cm, whereas they have the best fruit quality when the solution strength at EC 4.5 m S/cm. This suggests the need for wide popularization of the nutrient solution formula in large areas to improve the tomato production. | Jing FENG Ruiping LIU Hongyi LUO | 2015 | Agricultural Science & Technology2015，16，8： | 6 |
| 14 | Effect of microstructure on the mechanical and corrosion behaviors of a hot-extruded nickel aluminum bronze显示文摘In this paper,the influence of microstructure on the corrosion behavior of a hotextruded nickel aluminum bronze was studied.Three kinds of samples subjected to the hot-extrusion,annealing and quenching conditions were prepared and immersion tests in 3.5% NaCl solution were carried out.Microstructures and corrosion surface morphologies of the samples were observed by SEM.It was found that the retained β martensite and(α+κⅢ) lamella eutectoid in the as hot-extruded material were eliminated after annealing,and corrosion resistance of the alloy was improved.As to the as-quenched material,its corrosion rate was higher than that of the as hotextruded material since the volume fraction of β phase which was anodic to α phase increased after quenching.As regards the mechanical properties,the as-quenched sample possesses the highest hardness and tensile strength among the three kinds of samples,while the as-annealed sample possesses the highest elongation.That is to say,heat treatment plays different roles in the mechanical properties and corrosion resistance of the experimental alloy. | Datong ZHANG Ruiping CHEN Weiwen ZHANG Zongqiang LUO Yuanyuan LI | 2010 | Acta Metallurgica Sinica(English Letters)2010，23，2： | 5 |
| 15 | Preferential binding between intracellular organic matters and Al_(13) polymer to enhance coagulation performance显示文摘Coagulation is the best available method for removing intracellular organic matter(IOM),which is released from algae cells and is an important precursor to disinfection by-products in drinking water treatment. To gain insight into the best strategy to optimize IOM removal, the coagulation performance of two Al salts, i.e., aluminum chloride(AlCl_3) and polyaluminum chloride(PACl, containing 81.2% Al_(13)), was investigated to illuminate the effect of Al species distribution on IOM removal. PACl showed better removal efficiency than AlCl_3 with regard to the removal of turbidity and dissolved organic carbon(DOC), owing to the higher charge neutralization effect and greater stability of pre-formed Al_(13) species. High pressure size exclusion chromatography analysis indicated that the superiority of PACl in DOC removal could be ascribed to the higher binding affinity between Al_(13) polymer and the low and medium molecular weight(MW) fractions of IOM. The results of differential log-transformed absorbance at 254 and 350 nm indicated more significant formation of complexes between AlCl_3 and IOM, which benefits the removal of tryptophan-like proteins thereafter. Additionally,PACl showed more significant superiority compared to AlCl_3 in the removal of <5 kD a and hydrophilic fractions, which are widely viewed as the most difficult to remove by coagulation.This study provides insight into the interactions between Al species and IOM, and advances the optimization of coagulation for the removal of IOM in eutrophic water. | Ruiping Liu Tingting Guo Min Ma Mingquan Yan Jing Qi Chengzhi Hu Gang Liu Huijuan Liu Jiuhui Qu Walter van der Meer | 2019 | Journal of Environmental Sciences2019，31，2： | 5 |
| 16 | A novel design of 3D carbon host for stable lithium metal anode显示文摘Rational design of porous conductive hosts with high electrical conductivity,large surface area,and adequate interior space is desirable to suppressing dendritic lithium growth and accommodating large volume change of lithium metal anode during the Li plating/stripping process.However,due to the conductive nature of the conductive hosts,Li is easily deposited directly on the top of the hosts,which hinders it from fully functioning.To circumvent the issue,in this study,we designed a novel porous carbon host with a gradient-pore-size structure based on one-dimensional(1D)carbon with different diameters.With this kind of host,stable cycling with high and stable Coulombic efficiency of~98%is achieved at 0.5 mA cm^(−2) with an areal capacity of 1 mAh cm^(−2) over 320 cycles.In contrast,the normal three-dimensional(3D)carbon nanotube host presents a moss-like Li morphology with wildly fluctuating Coulombic efficiency after 100 cycles.The results reveal that the unique gradient-pore-size structure of the 3D conductive host greatly improves the performance of lithium metal batteries. | Hang Liu Jie Di Ping Wang Rui Gao Han Tian Pengfei Ren Qingxi Yuan Wanxia Huang Ruiping Liu Qiang Liu Ming Feng | 2022 | Carbon Energy2022，4，4： | 5 |
| 17 | Rapid and sensitive liquid chromatography–tandem mass spectrometric method for the quantitative determination of potentially harmful substance 5,5′-oxydimethylenebis (2-furfural) in traditional Chinese medicine injections显示文摘With the rapid development and wide application of traditional Chinese medicine injection(TCMI), a number of adverse events of some TCMIs have incessantly been reported and have drawn broad attention in recent years. Establishing effective and practical analytical methods for safety evaluation and quality control of TCMI can help to improve the safety of TCMIs in clinical applications. In this study, a sensitive and rapid high-performance liquid chromatography–tandem mass spectrometry(HPLC–MS/MS)method has been developed and validated for the quantitative determination of potentially harmful substance5,5′-oxydimethylenebis(2-furfural, OMBF) in TCMI samples. Chromatographic separation was performed on a C18 reversed-phase column(150 mm × 2.1 mm, 5 μm) by gradient elution, using methanol–water containing 0.1% formic acid as mobile phase at the flow rate of 0.3 m L/min. MS/MS detection was performed on a triple quadrupole mass spectrometer with positive electrospray ionization in the multiple reaction-monitoring mode. The method was sensitive with a limit of quantification of 0.3 ng/m L and linear over the range of 0.3–30 ng/m L(r = 0.9998). Intra-and inter-day precision for analyte was o9.52% RSD withrecoveries in the range 88.0–109.67% at three concentration levels. The validated method was successfully applied to quantitatively determine the compound OMBF in TCMIs and glucose injections. Our study indicates that this method is simple, sensitive, practicable and reliable, and could be applied for safety evaluation and quality control of TCMIs and glucose injections. | Qingce Zang Yang Gao Luojiao Huang Jiuming He Sheng Lin Hongtao Jin Ruiping Zhang Zeper Abliz | 2018 | Acta Pharmaceutica Sinica B2018，8，2： | 4 |
| 18 | 3D-Printed Superhydrophobic and Magnetic Device That Can Self-Powered Sense A Tiny Droplet Impact显示文摘Three-dimensional(3D)-printed magnetic soft architectures have attracted extensive attention and research from the engineering and material fields.The force-driven shape deformation of such architectures causes a change in the magnetic field distribution,indicating the capability to convert mechanical energy to electricity.Herein,we fabricate a flexible superhydrophobic and magnetic device by integrating two kinds of 3D printing approaches.The 3D-printed magnetic device(3DMD)exhibits a long-term stable mechanoelectrical conversion capacity under consecutive water droplet dripping.The output current of the 3DMD is higher than that of records in the existing literature.Combined with Maxwell numerical simulation,the mechanoelectrical conversion mechanism of the 3DMD is investigated,further guiding regulation of the diverse parameters.Moreover,three 3DMDs are integrated to light up a commercial light-emitting diode(LED)by a stream of collected rainwater.Such a combined design incorporating energy conversion is believed to promisingly motive advances in the 3D printing field. | Xuan Zhang Qi Wang Ruiping Zou Bo Song Chunze Yan Yusheng Shi Bin Su | 2022 | Engineering2022，8，8： | 4 |
| 19 | Reinforced polysulfide barrier by g-C_(3)N_(4)/CNT composite towards superior lithium-sulfur batteries显示文摘The notorious shuttle effect has long been obstructing lithium-sulfur(Li-S) batteries from yielding the expected high energy density and long lifespan.Herein,we develop a multifunctional polysulfide barrier reinforced by the graphitic carbon nitride/carbon nanotube(g-C_3 N_4/CNT) composite toward inhibited shuttling behavior and improved battery performance.The obtained g-C_3 N_4 delivers a unique spongelike architecture with massive ion transfer pathways and fully exposed active interfaces,while the abundant C-N heteroatomic structures impose strong chemical immobilization toward lithium polysulfides.Combined with the highly conductive agent,the g-C_3 N_4/CNT reinforced separator is endowed with great capability of confining and reutilizing the active sulfur within the cathode,thus contributing to an efficient and stable sulfur electrochemistry.Benefiting from these synergistic attributes,Li-S cells based on g-C_3 N_4/CNT separator exhibit an excellent cyclability with a minimum decay rate of 0.03% per cycle over 500 cycles and decent rate capability up to 2 C.Moreover,a high areal capacity of 7.69 mAh cm^(-2)can be achieved under a raised sulfur loading up to 10.1 mg cm^(-2).demonstrating a facile and efficient pathway toward superior Li-S batteries. | Xiangliang Wang Gaoran Li Minjie Li Ruiping Liu Haibo Li Tengyu Li Mingzhu Sun Yirui Deng Ming Feng Zhongwei Chen | 2021 | Journal of Energy Chemistry2021，30，2： | 4 |
| 20 | Green and efficient degradation of cefoperazone sodium by Bi_(4)O_(5)Br_(2) leading to the production of non-toxic products:Performance and degradation pathway显示文摘Photocatalytic process represents a promising approach to overcome the pollution challenge associated with the antibiotics-containing wastewater.This study provides a green,efficient and novel approach to remove cephalosporins,particularly cefoperazone sodium(CFP).Bi_(4)O_(5)Br_(2) was chosen for the first time to systematically study its degradation for CFP,including the analysis of material structure,degradation performance,the structure and toxicity of the transformation products,etc.The degradation rate results indicated that Bi_(4)O_(5)Br_(2) had an excellent catalytic activity leading to 78%CFP removal compared with the pure BiOBr(38%)within 120 min of visible light irradiation.In addition,the Bi_(4)O_(5)Br_(2) presents high stability and good organic carbon removal efficiency.The effects of the solution p H(3.12-8.75)on catalytic activity revealed that CFP was mainly photocatalyzed under acidic conditions and hydrolyzed under alkaline conditions.Combined with active species and degradation product identification,the photocatalytic degradation pathways of CFP by Bi_(4)O_(5)Br_(2) was proposed,including hydrolysis,oxidation,reduction and decarboxylation.Most importantly,the identified products were all hydrolysis rather than oxidation byproducts transformed from the intermediate ofβ-lactam bond cleavage in CFP molecule,quite different from the mostly previous studies.Furthermore,the final products were demonstrated to be less toxic through the toxicity analysis.Overall,this study illustrates the detailed mechanism of CFP degradation by Bi_(4)O_(5)Br_(2) and confirms Bi_(4)O_(5)Br_(2) to be a promising material for the photodegradation of CFP. | Yingying Chen Ruiping Li Yan Gu Hailin Tian Yingping Huang Junsong Chen Yanfen Fang Changying Yang | 2021 | Journal of Environmental Sciences2021，33，2： | 4 |
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