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| 1 | Ternary MOF‑Based Redox Active Sites Enabled 3D‑on‑2D Nanoarchitectured Battery‑Type Electrodes for High‑Energy‑Density Supercapatteries显示文摘Designing rationally combined metal-organic frameworks(MOFs)with multifunctional nanogeometries is of significant research interest to enable the electrochemical properties in advanced energy storage devices.Herein,we explored a new class of binderfree dual-layered Ni-Co-Mn-based MOFs(NCM-based MOFs)with three-dimensional(3D)-on-2D nanoarchitectures through a polarityinduced solution-phase method for high-performance supercapatteries.The hierarchical NCM-based MOFs having grown on nickel foam exhibit a battery-type charge storage mechanism with superior areal capacity(1311.4μAh cm^−2 at 5 mA cm^−2),good rate capability(61.8%;811.67μAh cm^−2 at 50 mA cm^−2),and an excellent cycling durability.The superior charge storage properties are ascribed to the synergistic features,higher accessible active sites of dual-layered nanogeometries,and exalted redox chemistry of multi metallic guest species,respectively.The bilayered NCM-based MOFs are further employed as a battery-type electrode for the fabrication of supercapattery paradigm with biomass-derived nitrogen/oxygen doped porous carbon as a negative electrode,which demonstrates excellent capacity of 1.6 mAh cm^−2 along with high energy and power densities of 1.21 mWh cm^−2 and 32.49 mW cm^−2,respectively.Following,the MOF-based supercapattery was further assembled with a renewable solar power harvester to use as a self-charging station for various portable electronic applications. | Goli Nagaraju SChandra Sekhar Bhimanaboina Ramulu SkKhaja Hussain DNarsimulu Jae Su Yu | 2021 | Nano-Micro Letters2021，13，1： | 3 |
| 2 | Multifunctional core-shell-like nanoarchitectures for hybrid supercapacitors with high capacity and long-term cycling durability显示文摘Transition metal oxide/hydroxide with multif unctional hierarchical nano structures has attracted widespread attention in supercapacitors(SCs)because of their large accessible surface area,high electrochemical activity and superior redox chemistry.Herein,core-shell-like copper(Cu)hydroxide nano tube arrays grafted nickel aluminum layered double hydroxide n anosheets were facilely synthesized on porous Cu foam(CH NTAs@NiAI LDH NSs)for use as an efficient battery-type electrode in hybrid SCs.With the synergistic effects of NiAl LDH NSs on well-adhered CH NTAs/CF,the core-shell-like composite(prepared for 24 h)delivered a maximum areal capacity of 334.3 pAh/cm2 at a current density of 3 mA/cm2 in 2 M KOH electrolyte,which is comparatively higher than other samples synthesized at different growth times.Moreover,the core-shell-like CH NTAs@NiAI LDH NSs-24 demonstrated an outstanding cycling stability of 134.3%after 10,000 cycles.Utilizing high capacity and stability of CH NTAs@NiAI LDH NSs-24,a pouch-type hybrid SC was further assembled with core-shell-like composite as a positive electrode and reduced graphene oxide as a negative electrode with a filter paper as a separator in aqueous alkaline electrolyte.The hybrid SC showed a high areal capacity of 250 pAh/cm2 at 2 mA/cm2 with maximum areal energy and power densities of 181.9 pWh/cm2 and 24,991.5 pW/cm2,respectively.Successfully harvest!ng the solar energy via solar cell panel and subsequently delivering the stored en ergy to switching and proximity applicati ons also dem on strated the real-time applicability of our hybrid SCs. | S.Chandra Sekhar Goli Nagaraju Bhimanaboina Ramulu Sk.Khaja Hussain D.Narsimulu Jae Su Yu | 2019 | Nano Research2019，12，10： | 2 |
| 3 | Orthogonal cutting mechanisms of graphite/epoxy composite. Part I: unidirectional laminate显示文摘 | D.H. Wang M. Ramulu D. Arola | 1995 | International Journal of Machine Tools and Manufacture1995，，12： | 2 |
| 4 | Flow cytometric analysis of polysomaty and in vitro genetic instability in potato显示文摘 | Ramulu S Dijkhwis K P | 1986 | Plant Cell Reports1986，5，： | 1 |
| 5 | Mixed model assembly alternatives for low-volume manufacturing:the case of the aerospace industry显示文摘 | HEIKE G RAMULU M SORENSON E | 2001 | International Journal of Production Economics2001，72，2： | 1 |
| 6 | Adsorption of Cr(Ⅵ) using thermally activated weed Salvinia cucullata 显示文摘 | Baral S S Das N Ramulu T S | 2008 | Chem Eng J2008，139，2： | 1 |
| 7 | Micro- protoplast-mediated transfer of single specific chromosomes between sexually incompatible plants 显示文摘 | Ramulu K S Dijkhuis P Rutgers E | 1996 | Genome1996，39，： | 1 |
| 8 | Damage assessment of basaltic rock mass due to repeated blasting in a railway tunnelling project - A case study显示文摘 | Ramulu M Chakraborty A K Sitharam T G | 2009 | Tunnelling and Underground Space Technology2009，24，2： | 1 |
| 9 | Accelerated-ageing Test for RTV-coated Insulators: Analysis of Electricaland Material Properties显示文摘 | Devendranath D Aravind K A Ramulu A | 2005 | IEE Proceedings-Gneration Transmission and Distribution2005，152，5： | 1 |
| 10 | Flyrock prediction and control in opencast mines:a critical appraisal显示文摘 | Bhowmik S Raina AK Chakraborty AK Ramulu M Sahu PB Haldar A Choudury PB Srinivas P Bandopadhyay C | | 0，，： | 1 |
| 11 | Waterjet machining and peening of metals显示文摘 | RAMULU M KUNAPORN S AROLA D | 2000 | Journal of Pressure Vessel Technology of the ASME2000，122，1： | 1 |
| 12 | A compari- son of the effects of various spindle toxins onmetaphase arrest and formation of micronuclei in cell-suspension cultures of Nicotia plumbno- lia显示文摘 | Ramulu K S Verhoeven H A Dijkhuis P | 1990 | Planta1990，182，： | 1 |
| 13 | An examination of the effects from surface texture on the strength of fiber rein- forced plastics显示文摘 | Arola D Ramulu M | 1999 | Journal of Composite Materials1999，33，2： | 1 |
| 14 | Variation in phenotype and chromosome number of plants regenerated from protoplast of dihaploid and tetraploid potato显示文摘 | RAMULU K S DYKHUSS P ROEST S | 1986 | Plant Breeding1986，，97： | 1 |
| 15 | A study on the drilling of composite and titanium stacks显示文摘 | Ramulu M Branson T Kim D | 2001 | Composite Structures2001，54，1： | 1 |
| 16 | Orthogonal cutting mechanisms of graphite/epoxy composite, part Ⅰ: unidirectional laminate 显示文摘 | Wang D H Ramulu M Arola D | 1995 | International Journal of Machine Tools & Manufacture1995，35，12： | 1 |
| 17 | Drilling process optimization for graphite/bismaleimide-titanium alloy stacks显示文摘 | Kim D Ramulu M | 2004 | Composite Structures2004，63，1： | 1 |
| 18 | Orthogonal cutting mechanisms of graphite/epoxy composite, part Ⅱ: multi-directional laminate 显示文摘 | Wang D H Ramulu M Arola D | 1995 | International Journal of Machine Tools & Manufacture1995，35，12： | 1 |
| 19 | EDM surface effects on the fatigue strength of a 15vol% SiCp/Al metal matrix composite material 显示文摘 | Ramulu M Paul G | 2001 | Composite structures2001，，54： | 1 |
| 20 | Dynamic photoelastic inve8figation on the mechanics of waterjet and abrasive waterjet machining显示文摘 | | 1993 | Optics and Lasers in Engineering1993，19，13： | 1 |
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