| 1 | Construction of hybrid Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2) microsphere with visible-light-driven photocatalytic activity显示文摘A novel Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2)microsphere(g-C_(3)N_(4)/r-TiO_(2))has been successfully synthesized by a solvothermal method.The as-prepared samples with different contents of g-C_(3)N_(4)were characterized by X-ray diffraction,electron paramagnetic resonance,scanning electron microscope,UV evis.diffuse reflectance and photoluminescence spectra.The r-TiO_(2)microspheres are aggregated on the surface of g-C_(3)N_(4)sheets in the as-prepared g-C_(3)N_(4)/r-TiO_(2)composites.All g-C_(3)N_(4)/r-TiO_(2)catalysts show enhanced photocatalytic activity for the degradation of rhodamine B under visible light irradiation.It could be attributed to these influences of oxygen vacancy(changing the band gap of TiO_(2)),the large specific surface area(providing much more active sites for photocatalytic reaction),and the synergetic effect between g-C_(3)N_(4)and r-TiO_(2)(promoting the separation for photoinduced electron-hole pairs).Moreover,the Z-scheme carriers transfer mechanism in the photocatalytic process has been discussed through trapping experiments of active species.The work demonstrates the strategies of the construction of Z-scheme carriers transfer system,the introduction of oxygen vacancy and structure designing are beneficial to design materials toward solar energy conversion like contaminant degradation. | C.Zhou N.F.Ye X.H.Yan J.J.Wang J.M.Pan D.F.Wang Q.Wang J.X.Zu X.N.Cheng | 2018 | Journal of Materiomics2018，4，3： | 2 |
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