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您的检索式：作者名="Muhammad A.Shehzad"
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| 1 | Fast Bulky Anion Conduction Enabled by Free Shuttling Phosphonium Cations显示文摘Highly conductive anion-exchange membranes(AEMs)are desirable for applications in various energy storage and conversion technologies.However,conventional AEMs with bulky HCO3-or Br-as counterion generally exhibit low conductivity because the covalent bonding restrains the tethered cationic group’s mobility and rotation.Here,we report an alternative polyrotaxane AEM with nontethered and free-shuttling phosphonium cation.As proved by temperature-dependent NMR,solid-state NMR,and molecular dynamics simulation,the phosphonium cation possesses a thermally trigged shuttling behavior,broader extension range,and greater mobility,thus accelerating the diffusion conduction of bulky anions.Owing to this striking feature,high HCO_(3)-conductivity of 105 mS cm^(-1) at 90℃ was obtained at a relatively lower ion-exchange capacity of 1.17 mmol g^(-1).This study provides a new concept for developing highly conductive anion-exchange membranes and will catalyze the exploration of new applications for polyrotaxanes in ion conduction processes. | Xiaolin Ge Yubin He Kaiyu Zhang Xian Liang Chengpeng Wei Muhammad A.Shehzad Wanjie Song Zijuan Ge Geng Li Weisheng Yu Liang Wu Tongwen Xu | 2022 | Research2022，，1： | 0 |
| 2 | Fast Bulky Anion Conduction Enabled by Free Shuttling Phosphonium Cations显示文摘Highly conductive anion-exchange membranes(AEMs)are desirable for applications in various energy storage and conversion technologies.However,conventional AEMs with bulky HCO_(3)^(-)or Br-as counterion generally exhibit low conductivity because the covalent bonding restrains the tethered cationic group’s mobility and rotation.Here,we report an alternative polyrotaxane AEM with nontethered and free-shuttling phosphonium cation.As proved by temperature-dependent NMR,solid-state NMR,and molecular dynamics simulation,the phosphonium cation possesses a thermally trigged shuttling behavior,broader extension range,and greater mobility,thus accelerating the diffusion conduction of bulky anions.Owing to this striking feature,high HCO_(3)^(-)conductivity of 105 mS cm^(-1)at 90℃ was obtained at a relatively lower ion-exchange capacity of 1.17 mmol g^(-1).This study provides a new concept for developing highly conductive anion-exchange membranes and will catalyze the exploration of new applications for polyrotaxanes in ion conduction processes. | Xiaolin Ge Yubin He Kaiyu Zhang Xian Liang Chengpeng Wei Muhammad A.Shehzad Wanjie Song Zijuan Ge Geng Li Weisheng Yu Liang Wu Tongwen Xu | 2021 | Research2021，，1： | 0 |
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