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| 1 | Heterogeneous molecular catalysts for electrocatalytic CO2 reduction显示文摘This review provides an overview of the literature regarding heterogeneous molecular catalysts for electrochemical CO2 reduction (ECR).Fundamental aspects of the science,including aggregation,electrochemical rate laws,and electrode-catalyst electronic coupling,are discussed to provide a solid foundation on which to design experiments and interpret results.Mechanistic aspects of ECR are presented based on electrokinetic and spectroscopic measurements as well as density functional theory (DFT) calculations.Consensus is improving for electrokinetic measurements,but the redox state of the metal center under reaction conditions and DFT reaction pathways lack agreement in the literature.Concerning the tunable aspects of the molecular catalyst,the impacts of the metal center,ligand substituents,and electrode support on the activity and selectivity toward ECR are presented with an emphasis on those studies that controlled for aggregation and minimized mass-transport limitations.Extended three-dimensional (3D) structures such as polymers,metal-organic frameworks (MOFs),and covalent-organic frameworks (COFs) are discussed as highly tunable architectures that begin to mimic the catalytic pockets of enzyme active sites.To achieve the full potential of these catalysts,design principles must emerge based on a combination of deconvoluting measurements to extract intrinsic catalyst properties and more reliable theoretical calculations to predict reaction pathways. | Nathan Corbin Joy Zeng Kindle Williams Karthish Manthiram | 2019 | Nano Research2019，12，9： | 10 |
| 2 | Nitrate additives for lithium batteries:Mechanisms,applications,and prospects显示文摘Lithium-metal batteries(LMBs)are considered as one of the most promising energy storage devices due to the high energy density and low reduction potential of the Li-metal anode.However,the growth of lithium dendrites results in accumulated dead Li and safety issues,limiting the practical application of LMBs.LiNO_(3)is a well-known additive in lithium-sulfur batteries to regulate the solid-electrolyte interphase(SEI),effectively suppressing the redox shuttle of polysulfides.Recently,other nitrates have been investigated in various electrolyte and battery systems,yielding improved SEI stability and cycling performance.In this review,we provide an overview of various nitrates,including LiNO_(3)for lithium batteries,focusing on their mechanisms and performance.We first discuss the effect of nitrate anions on SEI formation,as well as the cathode-electrolyte interphase(CEI).The solvation behavior regulated by nitrates is also extensively explored.Some strategies to improve the solubility of LiNO_(3)in ester-based electrolytes are then summarized,followed by a discussion of recent progress in the application of nitrates in different systems.Finally,further research directions are presented,along with challenges.This review provides a comprehensive understanding of nitrates and affords new and interesting ideas for the design of better electrolytes and battery systems. | Xiang Li Ruxin Zhao Yongzhu Fu Arumugam Manthiram | 2021 | eScience2021，1，2： | 5 |
| 3 | Scalable Membraneless Direct Liquid Fuel Cells Based on a Catalyst-Selective Strategy显示文摘This perspective presents a membraneless direct liquid fuel cell(DLFC)concept based on a catalyst-selective strategy.The membraneless DLFCs are operated at low temperatures by employing a non-precious cathode catalyst with a high catalytic selectivity.The uniqueness is that the inexpensive cathode catalyst only catalyzes the oxygen reduction reaction but does not catalyze the oxidation reaction of a specific fuel.Therefore,during the operation of DLFCs,the liquid fuel can enter the cathode freely without any concern of fuel crossover.This catalyst-selective approach tactfully avoids the use of high-cost or technically unviable ion-exchange polymer membranes in DLFCs.The catalyst-selective operating principle also overcomes the scalability issue of the traditional laminar-flow membraneless DLFCs.Through a proper management of the anode and cathode catalysts in the cell,a variety of inexpensive,renewable alcohols,and small-molecule organics can be employed as anode fuels.This innovative approach of membraneless alkaline DLFCs offers a great opportunity for the development of inexpensive energy-generation systems for both mobile and stationary applications.In addition to summarizing the principle and the research progress of the unique membraneless DLFC platform,the challenges and future research directions are presented. | Xingwen Yu Arumugam Manthiram | 2018 | Energy & Environmental Materials2018，1，1： | 3 |
| 4 | Factors influencing the chemical lithium extraction rate from layered LiNi 1? y ? z Co y Mn z O 2 cathodes显示文摘 | S Venkatraman J Choi A Manthiram | 2004 | Electrochemistry Communications2004，，8： | 2 |
| 5 | Comparison of Pd- Co-Au electrocatalysts prepared by conventional borohydride and microemulsion methods for oxygen reduction in fuel cells显示文摘 | Raghuveer V Ferreira P J Manthiram A | 2006 | Eleetrochem Commun2006，8，5： | 1 |
| 6 | Tuning the electrocatalytic ac-tivity and durability of low cost Pd70Co30 nanoalloy for ox-ygen reduction reaction in fuel cells显示文摘 | LIU H MANTHIRAM A | 2008 | Electrochemistry Communications2008，10，： | 1 |
| 7 | Microwavesolvothermal synthesis of nanostructured Li2MSiO4/C (M =Mn and Fe) cathodes for lithium-ion batteries显示文摘 | Muraliganth T Stroukoff K R Manthiram A | | 0，，20： | 1 |
| 8 | Enhanced cyclability of lithium-sulfur batteries by a polymer acid doped polypyrrole mixed ionic-electronic conductor显示文摘 | Fu Y Z Manthiram A | 2012 | Chemistry of Materials2012，24，： | 1 |
| 9 | Nanostructured electrode materials for electrochemical energy storage and conversion显示文摘 | MANTHIRAM A VADIVEL MURUGAN A SARKAR A | 2008 | Energ Environ Sci2008，1，： | 1 |
| 10 | Challenges and prospects of lithium- sulfur batteries 显示文摘 | Manthiram A Fu Y Su Y S | 2012 | Acc Chem Res2012，46，5： | 1 |
| 11 | A new approach to improve cycle performance of rechargeable lithium-sulfur batteries by in- serting a free-standing MWCNT interlayer 显示文摘 | Su Y S Manthiram A | 2012 | Chem Com- mun (Camb)2012，48，70： | 1 |
| 12 | Aqueous chemical route to ferromagnetic 3-D arrays of iron nanorods显示文摘 | VAYSSIERES L RABENBERG L MANTHIRAM A | 2002 | Nano Letters2002，2，12： | 1 |
| 13 | Crystal Chemistry and Superconductivity of the Copper Oxides显示文摘 | Goodenough J B Manthiram A | 1990 | J Solid State Chem1990，88，： | 1 |
| 14 | Lithium-sulphur batteries with a micro- porous carbon paper as a bifunctional interlayer显示文摘 | Su Y S Manthiram A | 2012 | Nat Com- mun2012，3，： | 1 |
| 15 | Pd-Co-Mo electrocatalyst for the oxygen reduction reaction in proton exchange membrane fuel cells 显示文摘 | Raghuveer V Manthiram A Bard A J | 2005 | J Phys Chem B2005，109，22： | 1 |
| 16 | Rapid, facile microwave-solvothermal synthesis of graphene nanosheets and their polyaniline nanocomposites for energy strorage 显示文摘 | VADIVEL M A MURALIGANTH T MANTHIRAM A | 2009 | Chemistry of Materials2009，21，21： | 1 |
| 17 | Nanocomposite manganese oxides for rechargeable lithium batteries 显示文摘 | Manthiram A | 1998 | Electrochem Solid-State Lett1998，1，： | 1 |
| 18 | LnBaCo2O5 +δ oxides as cathodes for intermediate-temperature solid oxide fuel cells 显示文摘 | Kim J H Manthiram A | 2008 | Journal of The Electrochemical Society2008，155，4： | 1 |
| 19 | Nancrystalling manganese oxide for electrochemical capacitors with neutral electrolytes 显示文摘 | Manthiram A | 2002 | ibid2002，149，11： | 1 |
| 20 | Synthesis and lithium intercalation properties of nanocrystalline lithium iron oxides 显示文摘 | Kim J Manthiram A | 1999 | J Electrochem Soc1999，146，： | 1 |
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