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2篇 您的检索式:作者名="Nathan Corbin"
    题名 作者 年代 出处 被引量
1Heterogeneous molecular catalysts for electrocatalytic CO2 reduction显示文摘This review provides an overview of the literature regarding heterogeneous molecular catalysts for electrochemical CO2 reduction (ECR).Fundamental aspects of the science,including aggregation,electrochemical rate laws,and electrode-catalyst electronic coupling,are discussed to provide a solid foundation on which to design experiments and interpret results.Mechanistic aspects of ECR are presented based on electrokinetic and spectroscopic measurements as well as density functional theory (DFT) calculations.Consensus is improving for electrokinetic measurements,but the redox state of the metal center under reaction conditions and DFT reaction pathways lack agreement in the literature.Concerning the tunable aspects of the molecular catalyst,the impacts of the metal center,ligand substituents,and electrode support on the activity and selectivity toward ECR are presented with an emphasis on those studies that controlled for aggregation and minimized mass-transport limitations.Extended three-dimensional (3D) structures such as polymers,metal-organic frameworks (MOFs),and covalent-organic frameworks (COFs) are discussed as highly tunable architectures that begin to mimic the catalytic pockets of enzyme active sites.To achieve the full potential of these catalysts,design principles must emerge based on a combination of deconvoluting measurements to extract intrinsic catalyst properties and more reliable theoretical calculations to predict reaction pathways.Nathan Corbin Joy Zeng Kindle Williams Karthish Manthiram 2019Nano Research2019,12,9:10
2非晶硅TFT AMOLEDs显示文摘如果说非晶硅不是制作有机发光二极管显示器有源矩阵背板的理想材料,为什么会有这么多人正试图使用它呢?Corbin Church Arokia Nathan 代永平 2005现代显示2005,,6:2
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