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1SnO2-based electron transporting layer materials for perovskite solar cells: A review of recent progress显示文摘In recent years, due to their high photo-to-electric power conversion efficiency(PCE)(up to 23%(certified)) and low cost, perovskite solar cells(PSCs) have attracted a great deal of attention in photovoltaics field. The high PCE can be attributed to the excellent physical properties of organic–inorganic hybrid perovskite materials, such as a long charge diffusion length and a high absorption coefficient in the visible range. There are different diffusion lengths of holes in electrons in a PSC device, and thus the electron transporting layer(ETL) plays a critical role in the performance of PSCs. An alternative for TiO2, to the most common ETL material is SnO2, which has similar physical properties to TiO2 but with much higher electron mobility, which is beneficial for electron extraction. In addition, there are many facile methods to fabricate SnO2 nanomaterials with low cost and low energy consumption. In this review paper, we focus on recent developments in SnO2 as the ETL of PSCs. The fabrication methods of SnO2 materials are briefly introduced. The influence of multiple Sn O2 types in the ETL on the performance of PSCs is then reviewed. Different methods for improving the PCE and long-term stability of PSCs based on SnO2 ETL are also summarized. The review provides a systematic and comprehensive understanding of the influence of different Sn O2 ETL types on PSC performance and potentially motivates further development of PSCs with an extension to SnO2-based PSCs.Yichuan Chen Qi Meng Linrui Zhang Changbao Han Hongli Gao Yongzhe Zhang Hui Yan 2019Journal of Energy Chemistry2019,28,8:6
2Identification for temperature model of accelerometer based on proximal SVR and particle swarm optimization algorithms显示文摘加速表上的温度的影响将直接影响惯性的航行系统(INS ) 的精确。消除加速表的测量错误,这份报纸为产生要求答案挑选线性方程的系统的线性或非线性的回归建议一个近似支持向量回归(PSVR ) 算法。PSVR 被用来识别加速表的静态的温度模型。为了改进识别表演,核参数和惩罚, PSVR 的因素被正规粒子群优化(CPSO ) 优化。在不同温度条件下面的实验被进行。试验性的结果证明建议 PSVR 能正确地识别石英弯曲加速表的静态的温度模型并且是比标准 SVR 和最不方形的算法的那些更有效的。Xiangtao YU Lan ZHANG Linrui GUO Feng ZHOU 2012控制理论与应用(英文版)2012,10,3:3
3Laser irradiation construction of nanomaterials toward electrochemical energy storage and conversion:Ongoing progresses and challenges显示文摘The emerging use of laser irradiation in synthesis smartly bridges“nanotech-nology”and“light”,and has attracted enormous attention as an efficient syn-thetic methodology for versatile nanomaterials toward electrochemical energy storage and conversion devices(ESCDs).In this review,recent contributions and progress regarding the laser-induced nanomaterials for ESCDs are com-prehensively summarized,with a special focus on their practical utilization in rechargeable batteries,supercapacitors and electrocatalysis.The laser-induced synthesis strategies and corresponding mechanisms involved in nano-architecture generation/regulation,including pulsed laser deposition and laser irradiation in liquid,are also discussed in detail.With the in-depth insights into the mechanisms and revolutionary advancements of laser irradiation tech-nology,the comprehensive performances of ESCDs have been strikingly opti-mized.Finally,the existing challenges and future directions in this booming research field are outlined.This review will exert the significant guidance for future design and purposeful fabrication of advanced laser-induced nano-materials with appealing properties for advanced ESCDs and beyond.Li Li Jinyang Zhang Yuyan Wang Fakhr Uz Zaman Yaming Zhang Linrui Hou Changzhou Yuan 2021InfoMat2021,3,12:2
4Oscillation of a class of partial functional population model显示文摘Changyou Wang Shu Wang Xiangping Yan Linrui Li 2010Journal of Mathematical Analysis and Applications2010,,1:2
5On a delay ratio-dependent predator-prey system with feedback controls and shelter for the prey显示文摘In this paper,a class of three-species multi-delay Lotka-Volterra ratio-dependent predator-prey model with feedback controls and shelter for the prey is considered.A set of easily verifiable sufficient conditions which guarantees the permanence of the system and the global attractivity of positive solution for the predator-prey system are established by developing some new analysis methods and using the theory of differentim inequalities as well as constructing a suitable Lyapunov function.Furthermore,some conditions for the existence,uniqueness and stability of positive periodic solution for the corresponding periodic system are obtained by using the fixed point theory and some new analysis techniques.In addition,some numerical solutions of the equations describing the system are given to show that the obtained criteria are new,general,and easily verifiable.Finally,we still solve numerically the corresponding stochastic predator-prey models with multiplicative noise sources,and obtain some new interesting dynamical behaviors of the system.At the same time,the influence of the delays and shelters on the dynamics behavior of the system is also considered by solving numerically the predator-prey models.Changyou Wang Linrui Lit Yuqian Zhou Rui Li 2018International Journal of Biomathematics2018,11,7:2
6显示文摘HaoZhixian(郝志显) WuPengfei(武鹏飞) LiZheng(李铮) LuoHao(罗浩) ZhuZhirong(朱志荣) LinRui(林瑞) 化学学报0,,:1
7In-situ growth of hybrid NaTi8O13/NaTiO2 nanoribbons on layered MXene Ti3C2 as a competitive anode for high-performance sodium-ion batteries显示文摘In the work,we successfully explore a two-step hydrothermal method for scalable synthesis of the hybrid sodium titanate(NaTi8O13/NaTiO2) nanoribbons well in-situ formed on the multi-layered MXene Ti3C2(designed as NTO/Ti3C2).Benefiting from the inherent structural and componential superiorities,the resulted NTO/Ti3C2 composite exhibits long-duration cycling stability and superior rate behaviors when evaluated as a hybrid anode for advanced SIBs,which delivers a reversible and stable capacity of^82 mAh/g even after 1900 cycles at 2000 mA/g for SIBs.Xuan Sun Ke Tan Yang Liu Jinyang Zhang Linrui Hou Changzhou Yuan 2020Chinese Chemical Letters2020,31,9:1
8显示文摘HaoZhixian(郝志显) LiZheng(李铮) LinRui(林瑞) GanLihua(甘礼华) XuZijie(徐子颉) ChenLongwu(陈龙武) 化学学报0,,:1
9Efficient Sunlight-Induced Methylene Blue Removal over One-Dimensional Mesoporous Monoclinic BiVO<sub>4</sub> Nanorods显示文摘Linrui Hou Long Yang Jiaoyang Li Jie Tan Changzhou Yuan Kea-Tiong Tang 2012Journal of Analytical Methods in Chemistry2012,,:1
10OVERVIEW OFHUMANCLONORCHIASISSINENSISINCHINA显示文摘LiXue-ming ChenYing-dan OuyangYI ZhangHong-man LinRui MaoWei 2011huManclonorchiaSiSSinenSiSinchina2011,42,2:1
11Facile Fabrication of Hierarchical Porous N/O Functionalized Carbon Derived from Blighted Grains Towards Electrochemical Capacitors显示文摘The hierarchical porous N/O co-functionalized carbon(HPNOC)was scalably prepared by using the lowcost and renewable blighted grains as the raw material coupled with mild KHCO_3 activation for electrochemical capacitors(ECs).The elemental N was in situ doped in the obtained HPNOC without any N-containing additives.Remarkably,the obtained HPNOC was endowed with a large specific surface area(about 2 624m^2·g^(-1)),high pore volume(about 1.35cm^3·g^(-1)),as well as high-content N/O functionalization(about 1.9%(in atom)N and about 10.2%(in atom)O.Furthermore,the as-resulted HPNOC electrode with a high mass loading of 5mg·cm^(-2 )exhibited competitive gravimetric capacitances of about 373.6F·g^(-1 )at 0.5A·g^(-1),and even about 260.4F·g^(-1 )at a high rate of 10A·g^(-1);superior capacitance retention of about 98.8%at 1A·g^(-1 )over 10 000consecutive cycles;and high specific energy of about 9.6W·h·kg^(-1 )at a power of 500W·kg^(-1),when evaluated as a promising electrode in 6mol KOH for advanced electrochemical supercapacitors.More encouragingly,the green synthetic strategy we developed holds a huge promise in generalizing for other biomass-derived carbon materials for versatile energy-related applications.Chen Zhiyi Wang Zhengluo Zhao Zhiwei Sun Xuan Hou Linrui Yuan Changzhou 2018Transactions of Nanjing University of Aeronautics and Astronautics2018,35,4:1
12Preparation and photocatalytie property of sunlight-driven photoeatalyst Bi38ZnO58显示文摘HOU Linrui YUAN Changzhou Peng Yang 2006J Mol Catal A: Chem2006,252,12:1
13Conductive metal-organic frameworks: Recent advances in electrochemical energy-related applications and perspectives显示文摘Metal-organic frameworks(MOFs),typically constructed with metallic nodes and organic linkers,have influenced the development of modular solid materials.Their adjustable molecular structure provides a remarkable variety of MOF-based solid-state structures towards diverse applications.However,the low conductivity of traditional MOFs extremely hinders their applications in electronic and electrochemical devices.The emerging conductive MOFs,generally possessing twodimensional layered structures,are endowed with both the structural merits of common MOFs and exceptional electronic/ionic conductivities.Besides,the selection and optimization of ligands and metal centers,as well as synthetic methods enormously affects the intrinsic conductivity of conductive MOFs.The distinctive crystal structures and superb conductivity promise their appealing applications in electrochemical energy-related fields.In the review,we mainly summarize representative crystal features,conducting mechanisms and recent advances in rational design and synthesis of conductive MOFs,along with their versatile applications as electrodes for electrochemical capacitors and rechargeable batteries,and as catalysts towards electrocatalysis.Finally,the involved challenges and future trends/prospects of the conductive MOFs for electrochemical energyrelated applications are further proposed.Lingzhi Guo Jinfeng Sun Jingxuan Wei Yang Liu Linrui Hou Changzhou Yuan 2020Carbon Energy2020,2,2:1
14Genomic scanning enabling discovery of a new antibacterial bicyclic carbamate-containing alkaloid显示文摘Non-ribosomal peptides are a group of structurally diverse natural products with various important therapeutic and agrochemical applications.Bacterial pyrrolizidine alkaloids(PAs),containing a scaffold of two fused five-membered ring system with a nitrogen atom at the bridgehead,have been found to originate from a multidomain non-ribosomal peptide synthetase to generate indolizidine intermediates,followed by multistep oxidation,catalysed by single Bayer-Villiger(BV)enzymes,to yield PA scaffolds.Although bacterial PAs are rare in natural product inventory,bioinformatics analysis suggested that the biosynthetic gene clusters(BGCs)that are likely to be responsible for the production of PA-like metabolites are widely distributed in bacterial genomes.However,most of the strains containing PA-like BGCs are not deposited in the public domain,therefore preventing further assessment of the chemical spaces of this group of bioactive metabolites.Here,we report a genomic scanning strategy to assess the potential of PA metabolites production in our culture collection without prior knowledge of genome information.Among the strains tested,we found fifteen contain the key BV enzymes that are likely to be involved in the last step of PA ring formation.Subsequently one-strain-many-compound(OSMAC)method,supported by a combination of HR-MS,NMR,SMART 2.0 technology,and GNPS analysis,allowed identification and characterization of a new[5+7]heterobicyclic carbamate,legoncarbamate,together with five known PAs,bohemamine derivatives,from Streptomyces sp.CT37,a Ghanaian soil isolate.The absolute stereochemistry of legoncarbamate was determined by comparison of measured and calculated ECD spectra.Legoncarbamate displays antibacterial activity against E.coli ATCC 25922 with an MIC value of 3.1μg/mL.Finally,a biosynthetic model of legoncarbamate and other bohemamines was proposed based on the knowledge we have gained so far.Qing Fang Linrui Wu Caroline Urwald Morgane Mugat Shan Wang Kwaku Kyeremeh Carol Philips Samantha Law d Yongjun Zhou Hai Deng 2021Synthetic and Systems Biotechnology2021,6,1:1
15Geobacter sulfurreducens promoted the biosynthesis of reduced graphene oxide and coupled it for nitrobenzene reduction显示文摘In order to explore an efficient and green method to deal with nitrobenzene(NB)pollutant,reduced graphene oxide(r GO)as an electron shuttle was applied to enhance the extracellular electron transfer(EET)process of Geobacter sulfurreducens,which was a typical electrochemically active bacteria(EAB).In this study,r GO biosynthesis was achieved via the reduction of graphene oxide(GO)by G.sulfurreducens PCA within 3 days.Also,the r GOPCA combining system completely reduced 50-200μmol/L of NB to aniline as end product within one day.SEM characterization revealed that PCA cells were partly wrapped by rGO,and therefore the distance of electron transfer between strain PCA and r GO material was reduced.Beside,the ID/IGof GO,r GO,and r GO-PCA combining system were 0.990,1.293 and 1.31,respectively.Moreover,highest currents were observed in r GO-PCA-NB as 12.950μA/-12.560μA at -408 m V/156 m V,attributing to the faster electron transfer efficiency in EET process.Therefore,the NB reduction was mainly due to:(I)direct EET process from G.sulfurreducens PCA to NB;(II)r GO served as electron shuttle and accelerated electron transfer to NB,which was the main degradation pathway.Overall,the biosynthesis of r GO via GO reduction by Geobacter promoted the NB removal process,which provided a facile strategy to alleviate the problematic nitroaromatic pollution in the environment.Shoujuan Zhang Qi Liu Linrui Zhong Jianhong Jiang Xiaozhe Luo Xingxin Hu Qian Liu Yue Lu 2024Journal of Environmental Sciences2024,,4:0
16Healing the defects in CsPbI_(3)solar cells by CsPbBr_(3)quantum dots显示文摘Cesium lead iodide(CsPbI_(3))is a promising photo-absorber for perovskite photovoltaics due to its high thermal stability and relatively small bandgap.However,there are many defects in solution processed polycrystalline CsPbI_(3)films especially at the grain boundaries(GBs),which limit the power conversion efficiency(PCE)of CsPbI_(3)solar cells.In this work,we introduced CsPbBr_(3)quantum dots(QDs)on top of the CsPbI_(3)film to passivate the defects.As CsPbBr_(3)QDs have a small size and a similar crystal structure as the CsPbI_(3),they are excellent modifiers to fill in the GBs and heal the defects.Moreover,we find there is an anion exchange reaction between the CsPbBr_(3)QDs and CsPbI_(3)films,which is evidenced by photoluminescence spectra and grazing incidence X-ray diffraction patterns.The QDs treated films show enhanced carrier lifetime and reduced defect density.Additionally,the ligands on CsPbBr_(3)QDs increase the hydrophobicity of the films.As a result,the QDs treated CsPbI_(3)solar cells prepared at high temperature obtain PCEs exceeding 16%with high stability.Yanyan Li Linrui Duan Zhuang Zhang Huanhuan Wang Tianyang Chen Jingshan Luo 2023Nano Research2023,16,4:0
17Boosting sodium-storage properties of hierarchical Na_(3)V_(2)(PO_(4))_(3)@C micro-flower cathodes by tiny Cr doping:The effect of“four ounces moving a thousand pounds”显示文摘Na_(3)V_(2)(PO_(4))_(3)(NVP),as a great potential cathode candidate for Na-ion batteries(NIBs),has attracted enormous interest due to its three-dimensional(3D)large open framework for convenient Na+transport,yet its practical application is still limited by its inferior electron conductivity and sluggish Na+diffusion kinetics.Herein,the tiny Cr doped hierarchical NVP micro-flower cathodes(i.e.,Na_(3)V_(2-x)Crx(PO_(4))_(3)@C,x≤0.1),which are self-assembled with single-crystal nanoflake subunits in-situ coated with carbon nano-shell,are designed and fabricated via a scalable avenue.The optimized cathode,i.e.,Na_(3)V_(1.94)Cr_(0.06)(PO_(4))_(3)@C(NVCP-6),was endowed with more electro-active Na(2)sites and higher electronic/ionic conductivity for efficient sodium storage.Benefiting from these competitive merits,the NVCP-6,when evaluated as a cathode towards NIBs,exhibits an ultrahigh-rate capability of 99.8 mAh·g^(-1)at 200 C and superior stability of 82.2%over 7300 cycles at 50 C.Furthermore,the NVCP-6 based full NIBs display remarkable electrochemical properties in terms of both high-rate capacities and long-duration cycling properties at different temperatures(-20–50°C).The contribution,i.e.,the design of“four ounces can move a thousand pounds”,here will promote the practical industrial application of NVP towards advanced NIBs.Yongjia Wang Guoshuai Su Xiaoying Li Linrui Hou Longwei Liang Changzhou Yuan 2024Nano Research2024,17,1:0
18Solid-state template-free fabrication of uniform Mo2C microflowers with lithium storage towards Li-ion batteries显示文摘Herein,we first report one-step synthesis of uniform Mo2 C microflowers(MCMFs)from low-cost precursors via industrialized solid-state strategy.With fine optimization in precursor ratio and pyrolysis temperatures,the as-fabricated MCMFs are assembled well with interconnected single-crystalline nanosheet subunits.More encouragingly,the resultant MCMFs are further highlighted as a competitive anode with robust and long-duration lithium-storage behaviors towards high-performance Li-ion batteries.Jinfeng Sun Lingzhi Guo Miaomiao Gao Xuan Sun Jinyang Zhang Longwei Liang Yang Liu Linrui Hou Changzhou Yuan 2020Chinese Chemical Letters2020,31,6:0
19Binary molten salt in situ synthesis of sandwich-structure hybrids of hollowβ-Mo2C nanotubes and N-doped carbon nanosheets for hydrogen evolution reaction显示文摘Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution.Tianyu Gong Yang Liu Kai Cui Jiali Xu Linrui Hou Haowen Xu Ruochen Liu Jianlin Deng Changzhou Yuan 2023Carbon Energy2023,5,12:0
20Thermal and hydraulic characteristics of a large-scaled parabolic trough solar field (PTSF) under cloud passages显示文摘To better understand the characteristics of a large-scaled parabolic trough solar field(PTSF)under cloud passages,a novel method which combines a closed-loop thermal hydraulic model(CLTHM)and cloud vector(CV)is developed.Besides,the CLTHM is established and validated based on a pilot plant.Moreover,some key parameters which are used to characterize a typical PTSF and CV are presented for further simulation.Furthermore,two sets of results simulated by the CLTHM are compared and discussed.One set deals with cloud passages by the CV,while the other by the traditionally distributed weather stations(DWSs).Because of considering the solar irradiance distribution in a more detailed and realistically way,compared with the distributed weather station(DWS)simulation,all essential parameters,such as the total flowrate,flow distribution,outlet temperature,thermal and exergetic efficiency,and exergetic destruction tend to be more precise and smoother in the CV simulation.For example,for the runner outlet temperature,which is the most crucial parameter for a running PTSF,the maximum relative error reaches−15%in the comparison.In addition,the mechanism of thermal and hydraulic unbalance caused by cloud passages are explained based on the simulation.Linrui MA Zhifeng WANG Ershu XU Li XU 2020Frontiers in Energy2020,14,2:0
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