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| 1 | 天然气中氮的地球化学研究进展显示文摘综合分析了国内外大量文献,指出了天然气中氮的地球化学研究进展。天然气中氮的主要来源有地球深部氮的运移和沉积物中有机与无机成因氮的释放。不同热解实验结果研究表明,氮气的生成既可以在低温也可在高温,但形成机理各不相同:低温主要是以大量蛋白质发生水解作用而产生氨基酸,氨基酸很不稳定,在粘土矿物的作用下生成NH3,而NH3被进一步氧化生成氮;而高温阶段主要以煤岩芳构化重新组合形成吡咯与吡啶释放出氮。不同环境下形成的氮,其1δ5N值是不同的,陆相N2的1δ5N低于+3‰,海相N2的1δ5N则高于+4‰。不同成因形成的氮,其同位素组份也各不一样,一般有机质经微生物作用生成N2的1δ5N通常小于-10‰,有机质热解形成N2的1δ5N>-10‰,N2/A r值远大于84;沉积岩中含氮矿物高温变质作用生成N2的1δ5N为+1.0‰^+3.5‰,N2/A r>84;地壳深部或上地幔来源N2的1δ5N值主要集中在-20‰^+1‰之间,40A r/36A r>2000,3H e/4H e为>1.39×1-0 6。 | 刘全有 刘文汇 Krooss B M 王万春 戴金星 | 2006 | 天然气地球科学2006，17，1： | 12 |
| 2 | 塔里木盆地煤及其显微组分超高温开放体系热模拟实验气态产物对比研究显示文摘通过对塔里木盆地煤及其显微组分进行以1K/min升温速率的开放体系热模拟实验(最高实验温度为1200℃),获得了煤岩与各显微组分气态产物产率与累计产量变化。对比分析了煤及其显微组分生成气态产物CH4、N2和CO变化特征,其中N2生成温度高于CH4和CO;H2生成时间与CH4相一致(说明了氢为烃类气体形成的关键因素)。煤及其显微组分生烃潜力具有壳质组>镜质组>煤>半丝质组≥丝质组的特征,说明煤岩生烃潜力主要由其显微组分控制;虽然壳质组在煤岩中含量很低,但生烃潜力高于其他显微组分。煤岩生成的N2具有双峰型特征,说明了前后峰N2具有不同来源,前者来源于无机矿物(如含铵粘土)的分解,后者来源于有机质热降解;显微组分生成N2主要为高温阶段,说明了显微组分在分离过程中可能造成部分无机矿物的损失。 | 刘全有 Bernhard M Krooss 金之钧 王毅 Jan Hollenstein Ralf Littke 刘文汇 | 2008 | 天然气地球科学2008，19，6： | 5 |
| 3 | High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals显示文摘 | B.M Krooss F van Bergen Y Gensterblum N Siemons H.J.M Pagnier P David | 2002 | International Journal of Coal Geology2002，，2： | 3 |
| 4 | Geological controls on the methane storage capacity in organic-rich shales显示文摘 | Matus Gasparik Pieter Bertier Yves Gensterblum Amin Ghanizadeh Bernhard M. Krooss Ralf Littke | 2014 | International Journal of Coal Geology2014，，： | 3 |
| 5 | Experimental study of gas and water transport processes in the inter-cleat (matrix) system of coal: Anthracite from Qinshui Basin, China显示文摘 | Fengshuang Han Andreas Busch Niels van Wageningen Jianli Yang Zhenyu Liu Bernhard M. Krooss | 2009 | International Journal of Coal Geology2009，，2： | 2 |
| 6 | Modelling isotope fractionation during primary cracking of natural gas:a reaction kinetic approach显示文摘 | Cramer B Krooss B M Littke R | 1998 | Chemical Geology1998，149，： | 1 |
| 7 | High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals显示文摘 | Krooss B M van Bergen F Gensterblum Y Siemons N Pagnier H J M David P | 2002 | Int J Coal Geol2002，51，2： | 1 |
| 8 | Nitrogen-rich natural ga- ses:qualitative and quantitative aspects of naturaX gas aeeurnula tion in reservoirs显示文摘 | Krooss B M Leythaeuser D Lillack H | 1993 | ErdOl and Kohle Erdgas Petrochernie vere- inigt rnit Brennstoff-Chemie1993，46，78： | 1 |
| 9 | Experimental investigation of the compositional variation of petroleum during primary migration 显示文摘 | ESEME E LITTKE R KROOSS B M | 2007 | Organic Geochemistry2007，38，： | 1 |
| 10 | High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals显示文摘 | KROOSS B M BERGEN F V GENSTERBLUM Y | 2002 | International Journal of Coal Geology2002，51，2： | 1 |
| 11 | Modelling isotope fractionation during pri mary cracking of natural gas: a reaction kinetic approach显示文摘 | Cramer B Krooss B M Littke R | 1998 | Chemical Geology1998，149，34： | 1 |
| 12 | Reaction kinetics of stable carbon isotopes in natural gas - Insights from dry, open system pyrolysis experiments 显示文摘 | Cramer B Faber E Gerling P Krooss B M | 2001 | Energ Fuel2001，15，3： | 1 |
| 13 | High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals 显示文摘 | Krooss B M Van Bergen F Gensterblum Y | 2002 | International Journal of Coal Geology2002，51，： | 1 |
| 14 | Methane and carbon dioxide adsorption-diffusion experiments on coal: upscaling and modeling显示文摘 | Busch A Gensterblum Y Krooss B M | 2004 | Coal Geology2004，，60： | 1 |
| 15 | The effect of different farming systems on epigeic arthropods:a five-year study on the rove beetle fauna (Coleoptera:Staphylinidae) of winter wheat显示文摘 | Krooss S Schaefer M | 1998 | Agriculture Ecosystem and Environment1998，69，： | 1 |
| 16 | Investigation of high - pressure selective adsorption/desorption behavior of CO2 and CH4 on coals: An experimental study 显示文摘 | Busch A Gensterblum Y Krooss B M | 2006 | International Journal of Coal Geology2006，，1： | 1 |
| 17 | Evolution of methane sorption capacity of coal seams as a function of burial history - a case study from the Campine Basin, NE Belgium显示文摘 | Hildenbrand A Krooss B M Busch A Gaschnitz R | 2005 | International Journal of Coal Geology2005，19，： | 1 |
| 18 | Quantification ot7 loss of calcite, pyrite, and organic matter due to weathering of Toarcian black shales and effects on kerogen and bitumen characteristics显示文摘 | Littke R Klussmann U Krooss B | 1991 | Geochimica et Cosmochimica Acta1991，55，11： | 1 |
| 19 | Experimental investigation on the carbon isotope fractionation of methane during gas migration by diffusion through sedimentary rocks at elevated temperature and pressure显示文摘 | Zhang T W Krooss B M | 2001 | Geochimiea et Cosmoehimica Aeta2001，65，16： | 1 |
| 20 | High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals显示文摘 | KROOSS B M VAN BERGEN F GENSTERBLUM Y | 2002 | Int J Coal Geology2002，51，1： | 1 |
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