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| 1 | Regulating the morphology of fluorinated non-fullerene acceptor and polymer donor via binary solvent mixture for high efficiency polymer solar cells显示文摘Fluorinated non-fullerene acceptors(NFAs) usually have planar backbone and a higher tendency to crystallize compared to their non-fluorinated counterparts, which leads to enhanced charge mobility in organic solar cells(OSCs). However, this selforganization behavior may result in excessive phase separation with electron donors and thereby deteriorate device efficiency.Herein, we demonstrate an effective approach to tune the molecular organization of a fluorinated NFA(INPIC-4 F), and its phase separation with the donor PBDB-T, by varying the casting solvent. A prolonged film drying time encourages the crystallization of INPIC-4 F into spherulites and consequently results in excessive phase separation, leading to a low device power conversion efficiency(PCE) of 8.1%. Contrarily, a drying time leads to fine mixed domains with inefficient charge transport properties,resulting in a moderate device PCE of 11.4%. An intermediate film drying time results in the formation of face-on π-π stacked PBDB-T and INPIC-4 F domains with continuous phase-separated networks, which facilitates light absorption, exciton dissociation as well as balanced charge transport towards the electrode, and achieves a remarkable PCE of 13.1%. This work provides a rational guide for optimizing the molecular ordering of NFAs and electron donors for high device efficiency. | Mengxue Chen Zhuohan Zhang Wei Li Jinlong Cai Jiangsheng Yu Emma L. K. Spooner Rachel C. Kilbride Donghui Li Baocai Du Robert S. Gurney Dan Liu Weihua Tang David G. Lidzey Tao Wang | 2019 | Science China Chemistry2019，62，9： | 2 |
| 2 | A comparison of Cu, Pb, As, Cd, Zn, Fe, Ni and Mn determined by acid extraction/ICP–OES and ex situ field portable X-ray fluorescence analyses显示文摘 | C. Kilbride J. Poole T.R. Hutchings | 2005 | Environmental Pollution2005，，1： | 2 |
| 3 | Axillary staging prior to neoadjuvant chemotherapy for breast cancer:predictors of recurrence显示文摘 | Kilbride KE Lee MC Nees AV | 2008 | Ann Surg Oncol2008，15，11： | 1 |
| 4 | A comparison of Cu,Pb, As, Cd, Zn, Fe, Ni and Mn determined by acid extraction/ICP- OES and ex situ field portable X-ray fluorescence analyses 显示文摘 | Kilbride C Poole J Hutehings T R | 2006 | Environmental Pollution2006，143，1： | 1 |
| 5 | Effect of Sintering Endosures and Sintering Parameters on the Magnetic Properties of a High Permeability Manganese-Zinc Ferrite显示文摘 | Kilbride I P Freer R | | 0，，01： | 1 |
| 6 | Effect of epidural analgesia on colorectal anastomotic healing and colonic motility 显示文摘 | Schnitzler M Kilbride M J Senagore M | 1992 | Reg Anesth1992，17，3： | 1 |
| 7 | Perinatal outcome and later implications of intrauterine growth restriction 显示文摘 | Pallotto E K Kilbride H W | 2006 | Clin Obstet Gynecol2006，49，2： | 1 |
| 8 | Findings and Patterns on MRI and MR Spectroscopy in Neonates after Therapeutic Hypothermia for Hypoxic Ischemic Encephalopathy Treatment显示文摘 | Thakur N H Spencer A J Kilbride H W | 2013 | Southern medical journal2013，106，6： | 1 |
| 9 | A Cohort Study of Preweaning Piglet Mortality and Farrowing Accommodation on 112 Commercial Pig Farms in England 显示文摘 | Kilbride A L Mendl M Statham P | 2012 | Preventive Veterinary Medicine2012，104，3： | 1 |
| 10 | Cryptogenic New Onset Refractory Status Epilepticus (NORSE) in adults--Infectious or not?显示文摘 | Costello DJ Kilbride RD Cole AJ | 2009 | J Neurol Sci2009，277，： | 1 |
| 11 | Experimental observation of scaling laws for ahernating current and direct current conductivity in polymer carbon nanotube composite thin films 显示文摘 | KILBRIDE B E COLEMAN J N FRAYSSE J | 2002 | J Appl Phys2002，92，： | 1 |
| 12 | Perinatal outcome and later implications of intrauteirne growth restriction显示文摘 | Pallotto EK Kilbride HW | 2006 | Clin Obstet Gyneco12006，49，2： | 1 |
| 13 | Effect of epidural analgesia on colorectal anastomotic healing and colonic motility显示文摘 | Schnitzler M Kilbride M J Senagore M | 1992 | Reg Anesth1992，17，3： | 1 |
| 14 | Preschool outcome of less than 801-gram preterm infants compared with full-term siblings 显示文摘 | Kilbride HW Thorstad K Daily DK | 2004 | Pediatries2004，113，： | 1 |
| 15 | Preparation and properties of small diameter tubular solid oxide fuel cells for rapid start-up 显示文摘 | Kilbride I P | 1996 | J Power Sources1996，61，12： | 1 |
| 16 | Complex I is rate-limiting for oxygen consumption in the nerve terminal显示文摘 | Telford JE Kilbride SM Davey GP | | 0，，14： | 1 |
| 17 | Induction of tissue factor expression in human endothelial cells by CD40 ligand Is mediated via activator protein 1 Nuclear Factor KB, and Egr-1 显示文摘 | Bavendiek U Libby P Kilbride M | 2002 | J Biol Chem2002，277，25： | 1 |
| 18 | Comparison of a membrane surface adhesion recovery method with an IMS method for use in a polymerase chain reaction method to detect Escherichia coli O157:H7 in minced beef显示文摘 | FITZMAURICE J DUFFYB G KILBRIDE B | 2004 | Journal of Microbiological Methods2004，59，： | 1 |
| 19 | Utilizing vector space models for user modeling within e-learning environments 显示文摘 | Mangina E Kilbride J | 2008 | Computers & Education2008，51，2： | 1 |
| 20 | 显示文摘 | Kilbride I P Freer R | 2000 | IEEE Trans Magn2000，36，1： | 1 |
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