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2篇 您的检索式:作者名="Ivan Jerman"
    题名 作者 年代 出处 被引量
1Inherent defects in sol-precipitation/hydrothermally derived SrTiO 3 nanopowders显示文摘Tina ?etinc Matja? Spreitzer Damjan Vengust Ivan Jerman Danilo Suvorov 2013Ceramics International2013,,6:1
2Electrochemical Mechanism of Al Metal–Organic Battery Based on Phenanthrenequinone显示文摘Al metal-organic batteries are a perspective high-energy battery technology based on abundant materials.However,the practical energy density of Al metal-organic batteries is strongly dependent on its electrochemical mechanism.Energy density is mostly governed by the nature of the aluminium complex ion and utilization of redox activity of the organic group.Although organic cathodes have been used before,detailed study of the electrochemical mechanism is typically not the primary focus.In the present work,electrochemical mechanism of Al metal-phenanthrenequinone battery is investigated with a range of different analytical techniques.Firstly,its capacity retention is optimized through the preparation of insoluble cross-coupled polymer,which exemplifies extremely low capacity fade and long-term cycling stability.Ex situ and operando ATR-IR confirm that reduction of phenanthrenequinone group proceeds through the two-electron reduction of carbonyl groups,which was previously believed to exchange only one-electron,severely limiting cathode capacity.Nature of aluminium complex ion interacting with organic cathode is determined through multiprong approach using SEM-EDS,XPS,and solid-state NMR,which all point to the dominant contribution of AlCl2+cation.Upon full capacity utilization,Al metal-polyphenanthrenequinone battery utilizing AlCl2+offers an energy density of more than 200Wh/kg making it a viable solution for stationary electrical energy storage.Jan Bitenc Urban Košir Alen Vizintin Niklas Lindahl AndražKrajnc Klemen Pirnat Ivan Jerman Robert Dominko 2021Energy Material Advances2021,,1:0
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