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| 1 | Kinetics and corrosion products of aqueous nitrate reduction by iron powder without reaction conditions control显示文摘Although considerable research has been conducted on nitrate reduction by zero-valent iron powder (Fe0), these studies were mostly operated under anaerobic conditions with invariable pH that was unsuitable for practical application. Without reaction conditions (dissolved oxygen or reaction pH) control, this work aimed at subjecting the kinetics of denitrification by microscale Fe0 (160–200 mesh) to analysis the factors affecting the denitrification of nitrate and the composition of iron reductive products coating upon the iron surface. Results of the kinetics study have indicated that a higher initial concentration of nitrate would yield a greater reaction rate constant. The reduction rate of nitrate increased with increasing Fe0 dosage. The reaction can be described as a pseudo-first order reaction with respect to nitrate concentration or Fe0 dosage. Experimental results also suggested that nitrate reduction by microscale Fe0 without reaction condition control primarily was an acid-driven surface-mediated process, and the reaction order was 0.65 with respect to hydrogen ion concentration. The analyses of X-ray diffractometry and X-ray photoelectron spectroscopy indicated that a black coating, consisted of Fe2O3, Fe3O4 and FeO(OH), was formed on the surface of iron grains as an iron corrosion product when the system initial pH was lower than 5. The proportion of FeO(OH) increased as reaction time went on, whereas the proportion of Fe3O4 decreased. | FAN Xiaomeng GUAN Xiaohong MA Jun AI Hengyu | 2009 | Journal of Environmental Sciences2009，21，8： | 17 |
| 2 | Roles of MAP kinase signaling pathway in oocyte meiosis显示文摘Mitogen-activated protein kinase (MAPK) is a family of Ser/Thr protein kinases expressed widely in eu-karyotic cells. MAPK is activated by a cascade of protein kinase phosphorylation and plays pivotal roles in regulating meiosis process in oocytes. As an important physical substrate of MAPK, p90rsk mediates numerous MAPK functions. MAPK was activated at G2/M transition during meiosis. Its activity reached the peak at M I stage and maintained at this level until the time before the pronuclear formation after fertilization. There is complex interplay between MAPK and MPF in the meiosis regulation. Furthermore, other intracel-lular signal transducers, such as cAMP, protein kinase C and protein phosphotase, ect., also regulated the activity of MAPK at different stages during meiosis in oocytes. In the present article, the roles of MAPK signaling pathway in oo-cyte meiosis are reviewed and discussed. | Hengyu Fan Chao Tong Dayuan Chen Qingyuan Sun | 2002 | Chinese Science Bulletin2002，47，14： | 5 |
| 3 | Molecular transport under extreme confinement显示文摘Mass transport through the nanoporous medium is ubiquitous in nature and industry.Unlike the macroscale transport phenomena which have been well understood by the theory of continuum mechanics,the relevant physics and mechanics on the nanoscale transport still remain mysterious.Recent developments in fabrication of slit-like nanocapillaries with precise dimensions and atomically smooth surfaces have promoted the fundamental research on the molecular transport under extreme confinement.In this review,we summarized the contemporary progress in the study of confined molecular transport of water,ions and gases,based on both experiments and molecular dynamics simulations.The liquid exhibits a pronounced layered structure that extends over several intermolecular distances from the solid surface,which has a substantial influence on static properties and transport behaviors under confinement.Latest studies have also shown that those molecular details could provide some new understanding on the century-old classical theory in this field. | FengChao Wang JianHao Qian JingCun Fan JinChuan Li HengYu Xu HengAn Wu | 2022 | Science China(Physics,Mechanics & Astronomy)2022，65，6： | 3 |
| 4 | Structured hierarchical Mn–Co mixed oxides supported on silicalite-1 foam catalyst for catalytic combustion显示文摘Silicalite-1(S1)foam was functionalized by supporting manganese-cobalt(Mn-Co)mixed oxides to develop the structured hierarchical catalyst(Mn-Co@SlF)for catalytic combustion for the first time.The self-supporting S1 foam with hierarchical porosity was prepared via hydrothermal synthesis with polyurethane(PU)foam as the template.Subsequently,Mn-Co oxide nano sheets were uniformly grown on the surface of S1 foams under hydrothermal conditions to prepare the structured hierarchical catalyst with specific surface area of 354 m^2·g^-1,micropore volume of 0.141 cm^3·g^-1 and total pore volume of 0.217 cm3·g^-1,as well as a good capacity to adsorb toluene(1.7 mmol·g^-1 at p/p0=0.99).Comparative catalytic combustion of toluene of over developed structured catalyst Mn-Co@SlF was performed against the control catalysts of bulk Mn-Co@S1(i.e.,the crushed Mn-Co@SlF)and unsupported Mn-Co oxides(i.e.,Mn-Co).Mn-Co@SlF exhibited comparatively the best catalytic performance,that is,complete and stable toluene conversion at 2480 C over 65 h due to the synergy between Mn-Co oxides and S1 foam,which provided a large number of oxygen vacancies,high redox capacity.In addition,the hierarchical porous structure also improved the accessibility of active sites and facilitated the global mass transfer across the catalyst bed,being beneficial to the catalysis and catalyst longevity. | Yanan Guan Hengyu Shen Xing Guo Boyang Mao Zhenyuan Yang Yangtao Zhou He Liang Xiaolei Fan Yilai Jiao jinsong Zhang | 2020 | Chinese Journal of Chemical Engineering2020，28，9： | 3 |
| 5 | MAPK regulates cell cycle progression in pig oocytes and fertilized eggs显示文摘Oocytes collected from prepubertal gilt ovaries were matured in vitro (IVM), and fertilized in vitro (IVF) or electrically activated. Phosphorylation of mitogen-activated protein kinase (MAPK) was detected with SDS-PAGE and Western blotting, and translocation of ERK2 was observed with immunofluorescent cytochemistry. We found that the quantity of MAPK kept unchanged during oocyte maturation. There was no phosphorylated MAPK in porcine oocytes at the germinal vesicle (GV) stage; a little MAPK was phosphorylated at 20 h of IVM; a high level phosphory-lation was detected at 30 h, while MAPK phosphorylation decreased at 36 h; and then MAPK phosphorylation increased again to the peak level from 40 to 60 h. ERK2 translocated from the peripheral cytoplasm to inner cytoplasm and nuclear area during oocyte maturation. There was nearly no phosphorylated MAPK at 18 and 20 h of electrically activated oocytes, but phosphorylation increased at 22 h. There was no phosphorylated MAPK at 12 h of IVF, while | LI Manyu FAN Hengyu TONG Chao CHEN Dayuan XIA Guoliang SUN Qingyuan | 2002 | Chinese Science Bulletin2002，47，10： | 1 |
| 6 | Additive manufacturing of sodalite monolith for continuous heavy metal removal from water sources显示文摘Herein,we present a simple strategy for preparing monolithic sodalite adsorbents via sequential additive manufacturing and post-treatments.In detail,the method includes(i)3D printing of cylindrical monoliths using clay as the base material;(ii)thermal activation of the 3D-printed clay monoliths by calcination(to produce reactive alumina and silica species and enable mechanical stabilization);(iii)conversion of the activated clay monoliths to hierarchical porous sodalite monoliths via hydrothermal alkaline treatment.Parametric studies on the effect of calcination temperature,alkaline concentration and hydrothermal treatment time on the property of the resulting materials(such as phase composition and morphology)at different stages of preparation was conducted.Under the optimal conditions(i.e.,calcination temperature of 850℃,NaOH concentration of 3.3 mol·L^(-1),reaction temperature of 150℃,and reaction time of 6 h),a high-quality pure sodalite monolith was obtained,which possesses a relatively high BET surface area(58 m^(2)·g^(-1))and hierarchically micro-meso-macroporous structure.In the proposed application of continuous removal of heavy metals(chromium ion as the model)from wastewater,the developed 3D-printed sodalite monolith showed excellent Cr^(3+)removal performance and fast kinetics(~98%removal efficiency within 25 cycles),which outperformed the packed bed using sodalite pellets(made by extrusion). | Hengyu Shen Run Zou Yangtao Zhou Xing Guo Yanan Guan Duo Na Jinsong Zhang Xiaolei Fan Yilai Jiao | 2022 | Chinese Journal of Chemical Engineering2022，35，2： | 1 |
| 7 | Single-cell DNA methylome analysis of circulating tumor cells显示文摘Objective: Previous investigations of circulating tumor cells(CTCs) have mainly focused on their genomic or transcriptomic features, leaving their epigenetic landscape relatively uncharacterized. Here, we investigated the genome-wide DNA methylome of CTCs with a view to understanding the epigenetic regulatory mechanisms underlying cancer metastasis.Methods: We evaluated single-cell DNA methylome and copy number alteration(CNA) in 196 single cells,including 107 CTCs collected from 17 cancer patients covering six different cancer types. Our single-cell bisulfite sequencing(sc BS-seq) covered on average 11.78% of all Cp G dinucleotides and accurately deduced the CNA patterns at 500 kb resolution.Results: We report distinct subclonal structures and different evolutionary histories of CTCs inferred from CNA and DNA methylation profiles. Furthermore, we demonstrate potential tumor origin classification based on the tissue-specific DNA methylation profiles of CTCs.Conclusions: Our work provides a comprehensive survey of genome-wide DNA methylome in single CTCs and reveals 5-methylcytosine(5-m C) heterogeneity in CTCs, addressing the potential epigenetic regulatory mechanisms underlying cancer metastasis and facilitating the future clinical application of CTCs. | Hengyu Chen Zhe Su Ruoyan Li Ning Zhang Hua Guo Fan Bai | 2021 | Chinese Journal of Cancer Research2021，33，3： | 0 |
| 8 | The DDB1-DCAF2 complex is essential for B cell development because it regulates cell cycle progression显示文摘B cell development in the bone marrow is critical for producing numerous B cells that play an essential role in the adaptive immune response.B cells develop from common lymphoid progenitors(CLPs),which then differentiate through a series of stages,which include prepro-B cells,pro-B cells,pre-B cells,immature B cells,and mature B cells. | Zhonghui Xue Jing Guo Ruoyu Ma Lina Zhou Yixin Guo Yong Cang Hengyu Fan Jian Chen Wenbin Qian Lie Wang | 2021 | Cellular & Molecular Immunology2021，18，3： | 0 |
| 9 | A sampling method based on forecasting and combinatorial optimization for high performance A/B testing显示文摘1 Introduction A/B testing[1]is a popular statistical method for many applications,especially,widely used by Internet companies for user experience research.The sampling algorithm is an important part of A/B testing and has a critical impact on the performance of A/B testing.There are two challenges to achieving high performance in A/B testing.(1)The features of individuals being sampled change over time and the sampling results used for evaluation are valid only for a period of time.(2)The sampling methods in A/B testing require determining whether the two groups of samples have an identical distribution while Simple Random Sampling(SRS)has a different purpose,which only concerns whether the sample distribution is identical to the population. | Fan LI Tiancheng ZHANG Shengjia CUI Hengyu LIU Zhibin REN Donglin DI Xiao WANG Po ZHANG Ge YU | 2023 | Frontiers of Computer Science2023，17，6： | 0 |
| 10 | Roles of protein kinase C in oocyte meiotic maturation and fertilization显示文摘Protein kinase C(PKC)is a superfamily of Ser/Thr protein kinases that is distributed widely in eukaryotes.It plays key regulatory roles at multiple steps of oocyte meiotic maturation and fertilization.During the process of meiotic maturation,the activation of PKC in cumulus cells stimulates meiotic maturation,whereas the activation of PKC in oocytes results in the inhibition of gerrninal vesicle breakdown.PKC activity increases following the meiotic maturation,and decreases at the transition of metaphase/anaphase in meiosis I,so as to facilitate the release of the first polar body and the entry of meiosis II,In fertilization of mammalian oocytes.PKC may act as one of the downstream targets of Ca^2+ to stimulate the cortical granule exocytosis,release the oocytes from MII arrest and to induce pronucleus formation.PKC is also involved in the regulation of maturation promoting factor(MPF) and mitogen-activated protein kinase (MAPK).Several PKC isoforins have been identified in mammalian oocytes.and there is evidence showing that classical PKCs may be the principal mediator oocyte cortical reaction. | FAN Hengyu, TONG Chao, CHEN Dayuan and SUN Qingyuan(State Key Laboratory of Reproductive Biology, Institute of Zoology, Chinese Academy of Sciences, Beijing 100080, China) | 2003 | Progress in Natural Science:Materials International2003，13，6： | 0 |
| 11 | Improved multiparty quantum key agreement in travelling mode显示文摘The need to simultaneously balance security and fairness in quantum key agreement(QKA) makes it challenging to design a flawless QKA protocol, especially a multiparty quantum key agreement(MQKA) protocol. When designing an MQKA protocol,two modes can be used to transmit the quantum information carriers: travelling mode and distributed mode. MQKA protocols usually have a higher qubit efficiency in travelling mode than in distributed mode. Thus, several travelling mode MQKA protocols have been proposed. However, almost all of these are vulnerable to collusion attacks from internal betrayers. This paper proposes an improved MQKA protocol that operates in travelling mode with Einstein-Podolsky-Rosen pairs. More importantly, we present a new travelling mode MQKA protocol that uses single photons, which is more feasible than previous methods under current technologies. | Wei Huang Qi Su BingJie Xu Bin Liu Fan Fan HengYue Jia YingHui Yang | 2016 | Science China(Physics,Mechanics & Astronomy)2016，59，12： | 0 |
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