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| 1 | Conceptual design of an extractive distillation process for the separation of azeotropic mixture of n-butanol-isobutanol-water显示文摘In many chemical processes, large amounts of wastewater containing butanol and isobutanol are produced.Given that n-butanol-isobutanol-water can form triple azeotrope, high-purity butanol cannot be recovered from the wastewater by ordinary distillation. To economically and effectively recover butanol from this kind of wastewater, 1,4-butanediol is selected as an extractant to break the formation of the azeotropes, and a doubleeffect extractive distillation process is proposed. The conceptual design of the proposed process is accomplished based on process simulation. With the proposed process, the purity of recovered butanol and water is greater than 99.99 wt%. In comparison with the conventional azeotropic distillation process, economic analysis shows that the operating cost of the proposed process is lower: when the capacity of wastewater treatment is 100 t·h^(-1), the total operating cost decreases by 5.385 ×10~6 USD per year, and the total annual cost of the new process decreases by 5.249 ×10~6 USD per year. In addition, in the extractive distillation system, variable effects on separation purities and cost are more complex than those in the ordinary distillation system. The method and steps to optimize the key variables of the extractive distillation system are also discussed in this paper and can provide reference for similar studies. | Hengjun Gai Kaiqiang Lin Yirong Feng Meng Xiao Kai Guo Hongbing Song | 2018 | Chinese Journal of Chemical Engineering2018，26，10： | 5 |
| 2 | Conceptual design of energy-saving stripping process for industrial sour water显示文摘Sour water contains ammonia,carbon dioxide,and hydrogen sulfides,producing from oil refining,coking,and coal gasification.To reduce the energy consumption in sour water stripping,a novel process is proposed which integrates with the bottom flashing mechanical vapor recompression heat pump(MVRHP)for treating such wastewater.Here,Aspen PlusTM as a powerful set of chemical process simulation software is utilized to investigate the economy and feasibility of the novel process.Comparison of the results of two process simulations,it can be seen that it is possible to reduce the total annual cost by nearly 45%to adopt the novel process,despite the capital investment increase 45%more than the conventional process.Thus,the provided conceptual design will play a guiding role in the industrialization of the process. | Hengjun Gai Shuo Chen Kaiqiang Lin Xiaowei Zhang Chun Wang Meng Xiao Tingting Huang Hongbing Song | 2020 | Chinese Journal of Chemical Engineering2020，28，5： | 2 |
| 3 | Modified g-C_(3)N_(4) derived from ionic liquid and urea for promoting visible-light photodegradation of organic pollutants显示文摘In this work,modified g-C_(3)N_(4) was fabricated successfully by calcination of ionic liquid(IL) and urea.The addition of IL changed the polymerization mode of urea,induced the self-assembly of urea molecules,modified the morphological structure of the tightly packed g-C_(3)N_(4),and extended the electron conjugation system.When using 1-butyl-3-methylimidazolium chloride([Bmim]Cl) as a modifier,the heteroatom Cl could be inserted into the g-C_(3)N_(4) to optimize the electronic structure.The results of characterizations indicate that the unique structure of modified g-C_(3)N_(4) has an expanded electron delocalization range,introduces an interlayer charge transmission channel,promotes the charge transmission,reduces the band gap,enhances the absorption of visible light,and inhibits electron-hole recombination.Modified g-C_(3)N_(4) showed excellent photocatalytic performance for the degradation of rhodamine B and tetracycline.Furthermore,the effect of different anions in 1-butyl-3-methylimidazolium salts([Bmim]Cl,[Bmim]Br,[Bmim][BF_(4)],and [Bmim][PF_6]) on the structure and function of g-C_(3) N_(4) are discussed. | Hongbing Song Lei Liu Bingxiao Feng Haozhong Wang Meng Xiao Hengjun Gai Yubao Tang Xiaofei Qu Tingting Huang | 2021 | Chinese Journal of Chemical Engineering2021，34，12： | 2 |
| 4 | Template-free synthesis of hollow TiO2 nanospheres supported Pt for selective photocatalytic oxidation of benzyl alcohol to benzaldehyde显示文摘Heterogeneous photocatalytic system are widely applied to degrade organic pollutants or converse into high value-added chemicals. Both environmental and energy aspects should be considered to improve these chemical processes, favoring reaction conditions that involve room temperature and ambient O2 pressure. In the present work, hollow titanium dioxide nanospheres were fabricated via template-free method. The prepared samples were characterized by X-ray diffraction, N2 adsorption–desorption isotherms, transmission electron microscopy, and X-ray photoelectron spectroscopy. The photocatalytic activity was evaluated by photocatalytic oxidation of benzyl alcohol to benzaldehyde with visible light under atmospheric pressure at room temperature. The designed hollow structure(2%Pt–TiO2–5) not only exhibited a very high surface area,but also promoted photonic behavior and multiple light scattering, which as an efficient photocatalyst performed moderate conversion(about 20%) and high selectivity(> 99%) for oxidation of benzyl alcohol to benzaldehyde at room temperature with visible light in solvent of toluene.This work suggests that both hollow structure and Pt nanoparticles have great potential for execution of oxidative transformations under visible light. | Hongbing Song Zong Liu Yongjie Wang Na Zhang Xiaofei Qu Kai Guo Meng Xiao Hengjun Gai | 2019 | Green Energy & Environment2019，4，3： | 2 |
| 5 | Public-transcriptome-database-assisted selection and validation of reliable reference genes for qRT-PCR in rice显示文摘Accurate quantitative reverse transcription PCR(q RT-PCR)requires reliable reference genes whose expression does not vary in different tissues and developmental stages.However,few reliable reference genes are available for q RT-PCR in rice(Oryza sativa).Here,we established an effective strategy for identifying novel reference genes(NRGs)for reliable normalization of q RT-PCR data in various rice organs and developmental stages.We selected candidate NRGs using the Information Commons for Rice Database and confirmed their expression in Rice Expression Profile Database(Rice XPro)data.Genes with low variation(<2.5 cycle quantification)across tissues and developmental stages,and little fluctuation in expression in heatmaps from Rice XPro data were considered stable NRGs.To validate this strategy,we selected 11 candidate NRGs and calculated their expression stability in different spatio-temporal conditions using five programs,and compared these genes with five established reference genes(ERGs).Only one of the ERGs(UBQ5)was reliable and 10 of the candidate NRGs were more stable than the four remaining ERGs.Therefore,public transcriptomic databases are useful for identifying NRGs.We selected two NRGs,UFC1(Homolog of UFM1-Conjugating Enzyme 1)and Fha B(Homolog of Adhesin Fha B)for q RT-PCR analysis in rice;their homologs might be suitable for other monocot plants. | Zhe Zhao Zixu Zhang Zhi Ding Hengjun Meng Rongxin Shen Huiwu Tang Yao-Guang Liu Letian Chen | 2020 | Science China(Life Sciences)2020，63，1： | 2 |
| 6 | A highly hydrothermal stable copper-based catalyst for catalytic wet air oxidation of m-cresol in coal chemical wastewater显示文摘Catalytic wet air oxidation(CWAO) can degrade some refractory pollutants at a low cost to improve the biodegradability of wastewater. However, in the presence of high temperature and high pressure and strong oxidizing free radicals, the stability of catalysts is often insufficient, which has become a bottleneck in the application of CWAO. In this paper, a copper-based catalyst with excellent hydrothermal stability was designed and prepared. TiO_(2) with excellent stability was used as the carrier to ensure the longterm anchoring of copper and reduce the leaching of the catalyst. The one pot sol–gel method was used to ensure the super dispersion and uniform distribution of copper nanoparticles on the carrier, so as to ensure that more active centers could be retained in a longer period. Experiments show that the catalyst prepared by this method has good stability and catalytic activity, and the catalytic effect is not significantly reduced after 10 cycles of use. The oxidation degradation experiment of m-cresol with the strongest biological toxicity and the most difficult to degrade in coal chemical wastewater was carried out with this catalyst. The results showed that under the conditions of 140℃, 2 MPa and 2 h, m-cresol with a concentration of up to 1000 mg·L^(-1) could be completely degraded, and the COD removal rate could reach 79.15%. The biological toxicity of wastewater was significantly reduced. The development of the catalyst system has greatly improved the feasibility of CWAO in the treatment of refractory wastewater such as coal chemical wastewater. | Bingxiao Feng Lining Hao Chaoting Deng Jiaqiang Wang Hongbing Song Meng Xiao Tingting Huang Quanhong Zhu Hengjun Gai | 2023 | Chinese Journal of Chemical Engineering2023，57，5： | 0 |
| 7 | Identification of flow regimes and determination of the boundaries for magnetized fluidized bed with Geldart-B particles显示文摘The magnetized fluidized bed(MFB)with Geldart-B particles exhibits many distinct flow regimes depend-ing on the magnetic field intensity(H)and gas velocity(U_(g)).The identification of these regimes was reviewed for the MFB with magnetizable particles and that with binary admixture of magnetizable and nonmagnetizable particles.Meanwhile,methods for determining the boundaries between two adjacent flow regimes were clarified.The MFB state was found to depend not only on H and Ug but also on their application sequence(i.e.,operation mode)within certain operating zones.The dependence feature arose from that the MFB therein could have different equilibrium states for the same combination of H and Ug.Furthermore,such a polymorphic characteristic of the MFB was revealed to result from the internal friction among the particles that were in unfluidized/packed state.Many of the MFB states were demon-strated to be in metastable equilibrium.Nevertheless,they differed significantly from the metastates well-known in the discipline of physical chemistry,such as supercooling and superheated.In fact,they belonged to the amorphous/glass state.This review will deepen our hydrodynamic understanding of the MFB and further promote its commercial application in the chemical and biochemical industries. | Quanhong Zhu Hengjun Gai Hongbing Song Meng Xiao Tingting Huang Weikang Hao | 2022 | Particuology2022，，12： | 0 |
| 8 | Enhanced activation of peroxymonosulfate by Fe/N co-doped ordered mesoporous carbon with dual active sites for efficient removal of m-cresol显示文摘The novel Fe-N co-doped ordered mesoporous carbon with high catalytic activity in m-cresol removal was prepared by urea-assisted impregnation and simple pyrolysis method.During the preparation of the Fe-NC catalyst,the complexation of N elements in urea could anchor Fe,and the formation of C3N4during urea pyrolysis could also prevent migration and aggregation of Fe species,which jointly improve the dispersion and stability of Fe.The FeN4sites and highly dispersed Fe nanoparticles synergistically trigger the dual-site peroxymonosulfate (PMS) activation for highly efficient m-cresol degradation,while the ordered mesoporous structure of the catalyst could improve the mass transfer rate of the catalytic process,which together promote catalytic degradation of m-cresol by PMS activation.Reactive oxygen species (ROS) analytic experiments demonstrate that the system degrades m-cresol by free radical pathway mainly based on SO_(4)^(-)·and·OH,and partially based on·OH as the active components,and a possible PMS activation mechanism by 5Fe-50 for m-cresol degradation was proposed.This study can provide theoretical guidance for the preparation of efficient and stable catalysts for the degradation of organic pollutants by activated PMS. | Donghui Li Wenzhe Wu Xue Ren Xixi Zhao Hongbing Song Meng Xiao Quanhong Zhu Hengjun Gai Tingting Huang | 2024 | Chinese Journal of Chemical Engineering2024，65，1： | 0 |
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