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您的检索式：作者名="Hanping Pan"
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| 1 | Experimental investigation on constitutive behaviour of superconducting powder BSCCO显示文摘 | Yinghong Zhao Pan Zeng Liping Lei Hanping Yi | 2007 | Journal of Materials Science2007，，12： | 1 |
| 2 | Insoluble carbonaceous materials as electron shuttles enhance the anaerobic/anoxic bioremediation of redox pollutants:Recent advances显示文摘Carbonaceous materials can accelerate extracellular electron transfer for the biotransformation of many recalcitrant,redox-sensitive contaminants and have received considerable attention in fields related to anaerobic bioremediation.As important electron shuttles(ESs),carbonaceous materials effectively participate in redox biotransformation processes,especially microbially-driven Fe reduction or oxidation coupled with pollutions transformation and anaerobic fermentation for energy and by-product recovery.The related bioprocesses are reviewed here to show that carbonaceous ESs can facilitate electron transfer between microbes and extracellular substrates.The classification and characteristics of carbon-containing ESs are summarized,with an emphasis on activated carbon,graphene,carbon nanotubes and carbonbased immobilized mediators.The influencing factors,including carbon material properties(redox potential,electron transfer capability and solubility)and environmental factors(temperature,p H,substrate concentration and microbial species),on pollution catalytic efficiency are discussed.Furthermore,we briefly describe the prospects of carbonaceous ESs in the field of microbial-driven environmental remediation. | Ning Li Jin Jiang Yanbin Xu Hanping Pan Xiaonan Luo Yingbin Hu Jie Cao | 2022 | Chinese Chemical Letters2022，33，1： | 0 |
| 3 | Oxidation of diclofenac by permanganate: Kinetics, products and effect of inorganic reductants显示文摘The large consumption and discharge of diclofenac(DCF) lead to its frequent detection in surface water and groundwater, posing great threats to humans and ecosystems. This study explored the oxidation kinetics of DCF by permanganate(Mn(Ⅶ)), and expounded the underlying reason for the unusual p Hdependency that was unclear in previous studies. The kinetics of DCF analogues(i.e., aromatic secondary amines) by Mn(Ⅶ) oxidation were comparatively investigated. Then, a tentative kinetic model involving the formation of an intermediate between Mn(Ⅶ) and DCF or its analogues was proposed to fit the p H-rate profile. Since DCF contained two chloro groups, and a carboxyl group which could be ionized by negative electrospray ionization, a precursor ionization scanning approach was used for the first time for detection of N-containing chlorinated oxidation products. New degradation pathways of DCF containing ring opening, carboxylation, carbonylation, electrophilic addition, hydroxylation and dehydrogenation were proposed based on the identified oxidation products. Moreover, it was demonstrated that the introduction of various reducing agents such as Mn(Ⅱ), Fe(Ⅱ) and bisulfite significantly improved the oxidation kinetics of DCF by Mn(Ⅶ). The positive effects of Mn(Ⅱ) and Fe(Ⅱ) were mainly attributed to the accelerated formation of MnO_(2)that acted as a catalyst or co-oxidizer contributing to DCF degradation. The presence of bisulfite caused two-stage kinetics, where a sharp drop of DCF concentration followed by a slowdown of DCF removal. In the first stage, potent reactive manganese species(e.g., Mn(Ⅲ), Mn(V), and Mn(VI)) and sulfate radical were generated during reaction of bisulfite with Mn(Ⅶ), whereas bisulfite was depleted fast due to excess Mn(Ⅶ) concentrations and the system became the Mn(Ⅶ)/MnO_(2)system in the second stage. These results provide new insight into reaction mechanism of DCF with Mn(Ⅶ)as well as propose a feasible strategy for enhancing the treatment of DCF contaminated water by Mn(Ⅶ). | Run Huang Chaoting Guan Qin Guo Zhen Wang Hanping Pan Jin Jiang | 2023 | Chinese Chemical Letters2023，34，4： | 0 |
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