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| 1 | Fabrication of a nano-sized ZSM-5 zeolite with intercrystalline mesopores for conversion of methanol to gasoline显示文摘Carbon deposition during methanol to hydrocarbons leads to the quick deactivation of ZSM-5 catalyst and it is one of the major problems for this technology. Decreasing the crystal size or introducing mesopores into ZSM-5 zeolites can improve its diffusion property and decrease the coke formation. In this paper, nano-sized ZSM-5 zeolite with intercrystalline mesopores combining the mesoporous and nanosized structure was fabricated. For comparison, the mesoporous ZSM-5 and nano-sized ZSM-5 were also prepared. These catalyst samples were characterized by XRD, BET, NH3-TPD, TEM, Py-IR and TG techniques and used on the conversion of methanol to gasoline in a fixed-bed reactor at T = 405 °C, WHSV = 4.74 h-1and P = 1.0 MPa. It was found that the external surface area of the nano-sized ZSM-5 zeolite with intercrystalline mesopores reached 104 m2/g, larger than that of mesoporous ZSM-5(66 m2/g) and nanosized ZSM-5(76 m2/g). Catalytic lifetime of the nano-sized ZSM-5 zeolite with intercrystalline mesopores was 93 h, which was only longer than that of mesoporous ZSM-5(86 h), but shorter than that of nanosized ZSM-5(104 h). Strong acidity promoted the coke formation and thus decreased the catalytic lifetime of the nano-sized ZSM-5 zeolite with intercrystalline mesopores though it presented large external surface that could improve the diffusion property. The special zeolite catalyst was further dealuminated to decrease the strong acidity. After this, its coke formation rate was slowed and catalytic lifetime was prolonged to 106 h because of the large external surface area and decreased weak acidity. This special structural zeolite is a potential catalyst for methanol to gasoline reaction. | Tingjun Fu Jiangwei Chang Juan Shao Zhong Li | 2017 | Journal of Energy Chemistry2017，26，1： | 5 |
| 2 | Research into comprehensive gas extraction technology of single coal seams with low permeability in the Jiaozuo coal mining area显示文摘For a low permeability single coal seam prone to gas outbursts,pre-drainage of gas is difficult and inefficient,seriously restricting the safety and efficiency of production.Radical measures of increasing gas extraction efficiency are pressure relief and infrared antirefiection.We have analyzed the effect of mining conditions and the regularity of mine pressure distribution in front of the working face of a major coal mine of the Jiaozuo Industrial(Group) Co.as our test area,studied the width of the depressurization zone in slice mining and analyzed gas efficiency and fast drainage in the advanced stress relaxation zone.On that basis,we further investigated and practiced the exploitation technology of shallow drilling,fan drilling and grid shape drilling at the working face.Practice and our results show that the stress relaxation zone is the ideal region for quick and efflcient extraction of gas.By means of an integrated extraction technology,the amount of gas emitted into the zone was greatly reduced,while the risk of dangerous outbursts of coal and gas was lowered markedly.This exploration provides a new way to control for gas in working faces of coal mines with low permeability and risk of gas outbursts of single coal seams in the Jiaozuo mining area. | Fu Jiangwei Fu Xuehai Hu Xiao Chen Li Ou Jianchun | 2011 | Mining Science and Technology2011，21，4： | 5 |
| 3 | The spatial variation of soil bacterial community assembly processes affects the accuracy of source tracking in ten major Chinese cities显示文摘Urban soils harbor billions of bacterial cells and millions of species.However,the distribution patterns and assembly processes of bacterial communities remain largely uncharacterized in urban soils.It is also unknown if we can use the bacteria to track soil sources to certain cities and districts.Here,Illumina MiSeq sequencing was used to survey soil bacterial communities from 529 random plots spanning 61 districts and 10 major cities in China.Over a 3,000 km range,community similarity declined with increasing geographic distance(Mantel r=0.62),and community composition was clustered by city(R^(2)=0.50).Within cities(<100 km),the aforementioned biogeographic patterns were weakened.Process analysis showed that homogenizing dispersal and dispersal limitation dominated soil bacterial assembly at small and large spatial scales,respectively.Accordingly,the probabilities of accurately tracking random soil sources to certain cities and districts were 90.0% and 66.7%,respectively.When the tested samples originated from cities that were more than 1,265 km apart,the soil sources could be identified with nearly 100% accuracy.Overall,this study demonstrates the strong distance-decay relationship and the clear geographic zoning of urban soil bacterial communities among cities.The varied importance of different community assembly processes at multiple spatial scales strongly affects the accuracy of microbial source tracking. | Teng Yang Yu Shi Jun Zhu Chang Zhao Jianmei Wang Zhiyong Liu Xiao Fu Xu Liu Jiangwei Yan Meiqing Yuan Haiyan Chu | 2021 | Science China(Life Sciences)2021，64，9： | 4 |
| 4 | Technology Development Analysis on Low Carbon for Power of Heavy-Duty Commercial Vehicle显示文摘Commercial vehicle industry worldwide is facing challenges from environmental pressures,stringent limits of CO_(2) emission,governmental regulations as well as ever-increased customer demands.This paper analyzes the above-mentioned challenges,especially in China,including the potential improvement to increase the brake thermal efficiency(BTE),with five levels of BTE proposed,ranging from current 45 to 60%in future,corresponding to China fuel consumption regulation(CFCR)in different phases.The authors also proposed the technology roadmaps to meet the upcoming CFCR3 and CFCR4;finally,the authors draw the conclusions to conform with ever-stringent regulation in China. | Jiangwei Liu Jun Li Yongjun Wang Dalu Dong Yansheng Yin Huayu Jin Shijie Sun Huili Dou Yanbo Shi Lei Fu Fei Ge | 2019 | Automotive Innovation2019，2，1： | 1 |
| 5 | Construction of isolated Ni sites on nitrogen-doped hollow carbon spheres with Ni-N_(3) configuration for enhanced reduction of nitroarenes显示文摘Designing and synthesizing high-efficiency non-precious metal-based catalysts having uniform active sites increases the reactivity and selectivity of materials and provides a platform for an in-depth understanding of their catalytic reaction mechanism.In this study,we provided an approach for fabricating isolated nickel single-atom sites(Ni SAs)with high loading(4.9 wt.%)stabilized on nitrogen-doped hollow carbon spheres(NHCS)using a core–shell structured Zn/Ni bimetallic zeolitic imidazolate framework(ZIF)composite as the sacrificial template.The as-fabricated Ni SAs/NHCS catalyst shows superior activity,selectivity,and recycling durability for the catalytic transfer hydrogenation of nitrobenzene to aniline,thus achieving 100%yield of aniline with a turn-over frequency(TOF)value as high as 29.9 h^(−1) under mild conditions.This TOF value is considerably superior to the supported Ni nanoparticle catalysts.The experiments designed show that the hollow structure feature of NHCS facilitates accessible active sites and mass transfer,which thus contributes to the enhancement of the catalytic performance of Ni SAs/NHCS.Density functional theory calculations show the high chemo-selectivity and activity of the Ni SAs catalyst,arising from the unique role of the single Ni-N3 site on simultaneously activating the H donor(N_(2)H_(4))and substrate,as well as the hydrogenation of the–NOH group as the rate-determining step. | Binbin Feng Rou Guo Qiulan Cai Yaping Song Nan Li Yanghe Fu De-Li Chen Jiangwei Zhang Weidong Zhu Fumin Zhang | 2022 | Nano Research2022，15，7： | 0 |
| 6 | Knowledge Mapping of Opuntia Milpa Alta Since 1998: A Scientometric Analysis显示文摘Opuntia Milpa Alta is a cactus cultivated,domesticated,hybridized and selected from the plant Opuntia ficusindica by Mexican agricultural experts,which can be used as fruit and vegetable.Opuntia Milpa Alta leaves and fruit are superior to wild varieties and suitable for storage and transportation.In 1998,Opuntia Milpa Alta was introduced to China from Mexico by the Quality Product Development Center of the Ministry of Agriculture of China.Up to now,the Opuntia Milpa Alta has been cultivated on a certain scale in China.This study aims to identify the research progress and development trends of Opuntia Milpa Alta in China.Papers published between 1998 to 2019 from two major Chinese academic databases(CNKI and Wangfang)with a topic search related to Opuntia Milpa Alta were collected.The research progress and development trends were analyzed based on CiteSpace software of text mining and visualization.The analysis found that Opuntia Milpa Alta has gone through three obvious research phases after being introduced to China.In the first phase,the researchers paid attention to its cultivation method.Subsequently,researchers began to use extraction methods to extract some of its components,such as polysaccharides and flavonoids.Finally,these extracted ingredients began to be used in some biomedical research. | Meixiang Chen Hong Yang Zhengda Song Yonghua Gu Yuhong Zheng Jiangwei Zhu Aiwu Wang Li Fu | 2021 | Phyton-International Journal of Experimental Botany2021，90，5： | 0 |
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