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| 1 | Facile one-pot emulsion/sol-gel method for preparing wrinkled silica microspheres显示文摘The present manuscript describes a facile and versatile method for preparing uniform wrinkled silica microspheres with diameters of tens of microns.The method comprises a one-pot emulsion/sol-gel method using silica precursors of organosilane and tetraethoxysilane.By controlling the sol-to-gel transition of the silica precursors,a series of silica microspheres based on uniform emulsion droplets was synthesized by membrane emulsification.The silica microspheres had a variety of surface morphologies ranging from smooth,maze-like wrinkles to polygon-like ravines.It was possible to alter the surface morphologies of the microspheres by controlling the amount of organosilane in the dispersed phase and the amount of ammonia catalyst in the continuous phase of the emulsion.The grooves on the wrinkled microspheres were able to trap polymer nanoparticles of matching size,thereby demonstrating the potential usefulness of the microspheres in separation science and drug delivery. | Yuning Hu Dongxia Hao Fangling Gong Yuanyuan Gao Xingran Yan Guanghui Ma | 2021 | Particuology2021，19，3： | 2 |
| 2 | Hydrogen-assisted scalable preparation of ultrathin Pt shells onto surfactant-free and uniform Pd nanoparticles for highly efficient oxygen reduction reaction in practical fuel cells显示文摘Concentrating active Pt atoms in the outer layers of electrocatalysts is a very effective approach to greatly reduce the Pt loading without compromising the electrocatalytic performance and the total electrochemically active surface area(ECSA)for the oxygen reduction reaction(ORR)in hydrogen-based proton-exchange membrane fuel cells.Accordingly,a facile,low-cost,and hydrogen-assisted two-step method is developed in this work,to massively prepare carbon-supported uniform,small-sized,and surfactant-free Pd nanoparticles(NPs)with ultrathin~3-atomic-layer Pt shells(Pd@Pt_(3L) NPs/C).Comprehensive physicochemical characterizations,electrochemical analyses,fuel cell tests,and density functional theory calculations reveal that,benefiting from the ultrathin Pt-shell nanostructure as well as the resulting ligand and geometric effects,Pd@Pt_(3L) NPs/C exhibits not only significantly enhanced ECSA,electrocatalytic activity,and noble-metal(NM)utilization compared to commercial Pt/C,showing 81.24 m^(2)/gPt,0.710 mA/cm^(2),and 352/577 mA/mgNM/Pt in ECSA,area-,and NM-/Pt-mass-specific activity,respectively;but also a much better electrochemical stability during the 10,000-cycle accelerated degradation test.More importantly,the corresponding 25-cm^(2) H2-air/O_(2) fuel cell with the low cathodic Pt loading of~0.152 mgPt/cm^(2)geo achieves the high power density of 0.962/1.261 W/cm^(2)geo at the current density of only 1,600 mA/cm^(2)geo,which is much higher than that for the commercial Pt/C.This work not only develops a high-performance and practical Pt-based ORR electrocatalyst,but also provides a scalable preparation method for fabricating the ultrathin Pt-shell nanostructure,which can be further expanded to other metal shells for other energy-conversion applications. | Liuxuan Luo Cehuang Fu Aiming Wu Zechao Zhuang Fengjuan Zhu Fangling Jiang Shuiyun Shen Xiyang Cai Qi Kang Zhifeng Zheng Chenyi Hu Jiewei Yin Guofeng Xia Junliang Zhang | 2022 | Nano Research2022，15，3： | 2 |
| 3 | Controlling factors on droplets uniformity in membrane emulsification: Experiment and modeling analysis 显示文摘 | Hao Dongxia Gong Fangling Hu Guohua | 2008 | Industrial and Engineering Chemistry Research2008，47，17： | 1 |
| 4 | Enantioselective synthesis of spirocyclic cyclopentenes: asymmetric [3+2] annulation of 2-arylideneindane-1,3-diones with MBH carbonates derivatives catalyzed by multifunctional thiourea–phosphines显示文摘 | Fangle Hu Yin Wei Min Shi | 2012 | Tetrahedron2012，，38： | 1 |
| 5 | MULTI-SCALE STRUCTURES IN EMULSION AND MICROSPHERE COMPLEX SYSTEMS显示文摘Multi-scale structures involved in emulsion and microsphere complex systems are presented and discussed. The stability and spatio-temporal structures of emulsions, as well as nano-structures formed on the surface of microspheres after polymerization, are affected by the molecular emulsifier/stabilizer structures and the adsorbed emulsifier/stabilizer nano-structures on the oil/water interface. The broad size distribution and variation of surface features of droplets are responsible for variations of the adsorbed emulsifier/stabilizer structures and the stability of the emulsions.On the other hand, preparation of a uniformly sized emulsion and employment of a combined emulsifier/stabilizer system can preserve the stability of the emulsions and microspheres. The above phenomena should be modeled by a multiscale method, in order to maintain the stability of individual emulsion systems and realize the desired nano-structures of microspheres by choosing adequate emulsifier/stabilizer and experimental parameters. | Guanghui Ma Fangling Gong Guohua Hu Dongxia Ha Rong Liu Renwei Wang | 2005 | China Particuology2005，3，6： | 1 |
| 6 | Efficient synthesis of forsterite via high-temperature thermochemical reactions from boron mud waste without briquetting显示文摘Forsterite is a highly demanded material in high-temperature industries due to its superior performance in elevated temperatures.This study proposes synthesizing high-quality forsterite via high-temperature thermochemical reactions using abundant boron mud waste.The new synthesis method capitalizes on the high reactivity of fine raw powder materials,enabling the reaction to reach completion at low temperatures rapidly.The chemical characteristics,microscopic morphology,and structure of synthe-sized samples are systematically studied using XRD and SEM.The results confirm that boron mud can be efficiently transformed into forsterite after 10 min of reactions at 1500℃.The synthesized products attain over 98.7%densification and contain more than 85.0%forsterite with well-developed grains.The activation energy of forsterite grain growth in the 1100-1500℃temperature range is 165.5 kJ/mol.This study provides a low-cost method for producing forsterite and an efficient and environmentally friendly solution for treating solid waste. | Fangling Hu Liangliang Fu Qingjin Zhang Guangwen Xu Dingrong Bai | 2024 | Particuology2024，87，4： | 0 |
| 7 | Protective effects of Achyranthes bidentata polypeptides on retinal ganglion cells post-optic nerve crush in rats显示文摘Achyranthes bidentata polypeptides(ABPP) have been reported to inhibit apoptosis of retinal ganglion cells(RGCs).The present study investigated the protective effects of ABPP on RGCs in a rat model of optic nerve injury.With prolonged injury time,RGC densities were gradually decreased.ABPP(5 μg) significantly increased RGC densities and upregulated growth associated protein 43 expression in rats with optic nerve injury.Results demonstrate that ABPP can protect RGCs and promote axonal growth after optic nerve crush. | Nan Hu Qi Zhao Fangling Zhang Junfang Zhang Xiaosong Gu | 2011 | Neural Regeneration Research2011，6，15： | 0 |
| 8 | Molecular Cloning and Bioinformatics Analysis of araC Gene of Vibrio alginolyticus显示文摘[Objective]To clone araC gene of Vibrio alginolyticus HY9901 strain,and analyze bioinformatics.[Methods]the whole genome sequence of Vibrio alginolyticus on GenBank was used to design specific primers.According to the principle of PCR amplification sequence,the target gene araC was amplified,and then the sequence was further analyzed by bioinformatics method to establish the phylogenetic tree of araC gene and its corresponding subunit three-dimensional structure model.[Results]Sequence analysis revealed araC gene is 711 bp and encodes a putative protein of 236 amino acids.The predicted molecular mass of AraC was 26.92 ku.Using Signal P 4.0 and TMHMM Server 2.0 software for analysis,it was predicted that the AraC protein did not contain a signal peptide or a transmembranous region.The AraC protein had two cAMP and cGMP dependent protein kinase phosphorylation site,five protein kinase C phosphorylation sites,three casein kinase II phosphorylation sites,one prenyl group binding site(CAAX box)and five microbodies C-terminal targeting signal.The predicted results of protein subcellular localization showed that AraC was located in the mitochondria,nucleus and cytoplasm.Its protein is unstable and hydrophilic.The AraC protein is a transcriptional regulatory protein which belongs to HTH_18 superfamily.According to the prediction,secondary structure:a-helix(Alpha helix)accounted for 52.12%,random coil(31.78%),extended strand(11.02%),b-fold(Beta turn)accounted for 5.08%.V.alginolyticus,Vibrio parahaemolyticus and Vibrio palustris were clustered together,which implies that the genetic relationship between these three species was the closest. | Fangling MO Gyamfua AFRIYIE Jialing HU Junling WANG Shihui ZHOU Zhongduo WANG F.K.A.KUEBUTORNYE Chuanhao PAN Huanying PANG | 2021 | Asian Agricultural Research2021，13，2： | 0 |
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