| 1 | Synergistic O^(2-)/Li^(+) Dual Ion Transportation at Atomic Scale显示文摘Te ion migration during electrochemical process is a fundamental scientifc issue for phase transition behavior and of technical importance for various functional devices,where cations or anions are active under electrical bias.Usually only one type of functional ion,O^(2-)or Li^(+),is activated due to their diferent migration energy barriers,cooperated by the valence change of other immobile ions in the host lattice matrix,e.g.,Co^(2+)/Co^(3+)and Mn^(3+)/Mn4+redox couples,owing to the charge neutralization.Here we select spinel Li4Ti5O12 as anode and construct an all-solid-state battery under a transmission electron microscope;a synergistic transportation of O^(2-)and Li^(+)driven by an electrical bias was directly observed at the atomic scale.A small amount of oxygen anions was extracted frstly as a result of its lowest vacancy formation energy under 2.2 V,leading to the vertical displacement of oxygen.Up to 2.7 V,an ordered phase with both Li-and O-defciency formed.Te Li^(+)and O^(2-)ions are simultaneously extracted out from the[LiO_(4)]tetrahedra due to the electroneutrality principle.Te migration paths of O and Li have been proposed and verifed by frst-principles calculations.Tese results reveal a brand new synergistic ion migration manner and may provide up-to-date insights on the transportation process of lithium ion conductors. | F.Q.Meng Q.H.Zhang A.Gao X.Z.Liu J.N.Zhang S.Y.Peng X.Lu L.Gu H.Li | 2019 | Research2019，，1： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员